{"publication":"Journal of Applied Physics","author":[{"full_name":"Higginbotham, Andrew P","id":"4AD6785A-F248-11E8-B48F-1D18A9856A87","last_name":"Higginbotham","first_name":"Andrew P","orcid":"0000-0003-2607-2363"},{"first_name":"Jacqueline","last_name":"Cole","full_name":"Cole, Jacqueline"},{"first_name":"Martin","last_name":"Blood Forsythe","full_name":"Blood Forsythe, Martin"},{"full_name":"Hickstein, Daniel","last_name":"Hickstein","first_name":"Daniel"}],"day":"07","doi":"10.1063/1.3678593","type":"journal_article","date_updated":"2021-01-12T08:21:50Z","month":"02","issue":"3","date_published":"2012-02-07T00:00:00Z","publication_status":"published","extern":"1","citation":{"ista":"Higginbotham AP, Cole J, Blood Forsythe M, Hickstein D. 2012. Identifying and evaluating organic nonlinear optical materials via molecular moments. Journal of Applied Physics. 111(3), 033512.","chicago":"Higginbotham, Andrew P, Jacqueline Cole, Martin Blood Forsythe, and Daniel Hickstein. “Identifying and Evaluating Organic Nonlinear Optical Materials via Molecular Moments.” <i>Journal of Applied Physics</i>. American Institute of Physics, 2012. <a href=\"https://doi.org/10.1063/1.3678593\">https://doi.org/10.1063/1.3678593</a>.","apa":"Higginbotham, A. P., Cole, J., Blood Forsythe, M., &#38; Hickstein, D. (2012). Identifying and evaluating organic nonlinear optical materials via molecular moments. <i>Journal of Applied Physics</i>. American Institute of Physics. <a href=\"https://doi.org/10.1063/1.3678593\">https://doi.org/10.1063/1.3678593</a>","ama":"Higginbotham AP, Cole J, Blood Forsythe M, Hickstein D. Identifying and evaluating organic nonlinear optical materials via molecular moments. <i>Journal of Applied Physics</i>. 2012;111(3). doi:<a href=\"https://doi.org/10.1063/1.3678593\">10.1063/1.3678593</a>","short":"A.P. Higginbotham, J. Cole, M. Blood Forsythe, D. Hickstein, Journal of Applied Physics 111 (2012).","mla":"Higginbotham, Andrew P., et al. “Identifying and Evaluating Organic Nonlinear Optical Materials via Molecular Moments.” <i>Journal of Applied Physics</i>, vol. 111, no. 3, 033512, American Institute of Physics, 2012, doi:<a href=\"https://doi.org/10.1063/1.3678593\">10.1063/1.3678593</a>.","ieee":"A. P. Higginbotham, J. Cole, M. Blood Forsythe, and D. Hickstein, “Identifying and evaluating organic nonlinear optical materials via molecular moments,” <i>Journal of Applied Physics</i>, vol. 111, no. 3. American Institute of Physics, 2012."},"abstract":[{"lang":"eng","text":"We demonstrate how to appropriately estimate the zero-frequency (static) hyperpolarizability of an organic molecule from its charge distribution, and we explore applications of these estimates for identifying and evaluating new organic nonlinear optical (NLO) materials. First, we calculate hyperpolarizabilities from Hartree-Fock-derived charge distributions and find order-of-magnitude agreement with experimental values. We show that these simple arithmetic calculations will enable systematic searches for new organic NLO molecules. Second, we derive hyperpolarizabilities from crystallographic data using a multipolar charge-density analysis and find good agreement with empirical calculations. This demonstrates an experimental determination of the full static hyperpolarizability tensor in a solid-state sample. "}],"_id":"91","article_number":"033512","language":[{"iso":"eng"}],"date_created":"2018-12-11T11:44:35Z","user_id":"3E5EF7F0-F248-11E8-B48F-1D18A9856A87","publist_id":"7963","volume":111,"oa_version":"None","intvolume":"       111","year":"2012","publisher":"American Institute of Physics","status":"public","acknowledgement":"This work was supported by The Winston Churchill Foundation of the United States (A.P.H., M.A.B.F., D.D.H.), The Royal Society via a University Research Fellowship (J.M.C.), and the University of New Brunswick via The Vice-Chancellor’s Research Chair (J.M.C.).","quality_controlled":"1","title":"Identifying and evaluating organic nonlinear optical materials via molecular moments"}