{"date_published":"2003-06-16T00:00:00Z","day":"16","article_type":"original","publisher":"Elsevier","year":"2003","keyword":["Organic Chemistry","Drug Discovery","Biochemistry"],"oa_version":"None","issue":"25","title":"Cross-metathesis reaction of vinyl sulfones and sulfoxides","scopus_import":"1","quality_controlled":"1","language":[{"iso":"eng"}],"intvolume":" 59","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","page":"4525-4531","status":"public","date_created":"2023-08-01T10:39:34Z","month":"06","citation":{"chicago":"Michrowska, Anna, Michał Bieniek, Mikhail Kim, Rafal Klajn, and Karol Grela. “Cross-Metathesis Reaction of Vinyl Sulfones and Sulfoxides.” Tetrahedron. Elsevier, 2003. https://doi.org/10.1016/s0040-4020(03)00682-3.","ista":"Michrowska A, Bieniek M, Kim M, Klajn R, Grela K. 2003. Cross-metathesis reaction of vinyl sulfones and sulfoxides. Tetrahedron. 59(25), 4525–4531.","apa":"Michrowska, A., Bieniek, M., Kim, M., Klajn, R., & Grela, K. (2003). Cross-metathesis reaction of vinyl sulfones and sulfoxides. Tetrahedron. Elsevier. https://doi.org/10.1016/s0040-4020(03)00682-3","ama":"Michrowska A, Bieniek M, Kim M, Klajn R, Grela K. Cross-metathesis reaction of vinyl sulfones and sulfoxides. Tetrahedron. 2003;59(25):4525-4531. doi:10.1016/s0040-4020(03)00682-3","mla":"Michrowska, Anna, et al. “Cross-Metathesis Reaction of Vinyl Sulfones and Sulfoxides.” Tetrahedron, vol. 59, no. 25, Elsevier, 2003, pp. 4525–31, doi:10.1016/s0040-4020(03)00682-3.","short":"A. Michrowska, M. Bieniek, M. Kim, R. Klajn, K. Grela, Tetrahedron 59 (2003) 4525–4531.","ieee":"A. Michrowska, M. Bieniek, M. Kim, R. Klajn, and K. Grela, “Cross-metathesis reaction of vinyl sulfones and sulfoxides,” Tetrahedron, vol. 59, no. 25. Elsevier, pp. 4525–4531, 2003."},"article_processing_charge":"No","abstract":[{"text":"Cross-metathesis reactions of α,β-unsaturated sulfones and sulfoxides in the presence of molybdenum and ruthenium pre-catalysts were tested. A selective metahesis reaction was achieved between functionalized terminal olefins and vinyl sulfones by using the ‘second generation’ ruthenium catalysts 1c–h while the highly active Schrock catalyst 1b was found to be functional group incompatible with vinyl sulfones. The cross-metathesis products were isolated in good yields with an excellent (E)-selectivity. Both the molybdenum and ruthenium-based complexes were, however, incompatible with α,β- and β,γ-unsaturated sulfoxides.","lang":"eng"}],"publication_status":"published","publication":"Tetrahedron","doi":"10.1016/s0040-4020(03)00682-3","author":[{"last_name":"Michrowska","first_name":"Anna","full_name":"Michrowska, Anna"},{"full_name":"Bieniek, Michał","first_name":"Michał","last_name":"Bieniek"},{"last_name":"Kim","first_name":"Mikhail","full_name":"Kim, Mikhail"},{"last_name":"Klajn","id":"8e84690e-1e48-11ed-a02b-a1e6fb8bb53b","full_name":"Klajn, Rafal","first_name":"Rafal"},{"full_name":"Grela, Karol","first_name":"Karol","last_name":"Grela"}],"_id":"13436","publication_identifier":{"eissn":["1464-5416"],"issn":["0040-4020"]},"type":"journal_article","extern":"1","volume":59,"date_updated":"2023-08-08T12:44:17Z"}