{"type":"journal_article","day":"13","article_processing_charge":"No","month":"08","pmid":1,"date_updated":"2023-08-08T07:25:37Z","extern":"1","publication_status":"published","date_published":"2014-08-13T00:00:00Z","issue":"32","abstract":[{"text":"A compound combining the features of a molecular rotor and a photoswitch was synthesized and was shown to exist as three diastereomers, which interconvert via a reversible cyclic reaction scheme. Each of the three diastereomers was isolated, and by following the equilibration kinetics, activation barriers for all reactions were calculated. The results indicate that the properties of molecular switches depend heavily on their immediate chemical environment. The conclusions are important in the context of designing new switchable molecules and materials.","lang":"eng"}],"oa_version":"None","date_created":"2023-08-01T09:46:12Z","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","publisher":"American Chemical Society","scopus_import":"1","quality_controlled":"1","title":"Cyclic kinetics during thermal equilibration of an axially chiral bis-spiropyran","status":"public","doi":"10.1021/ja505948q","page":"11276-11279","publication":"Journal of the American Chemical Society","author":[{"full_name":"Kundu, Pintu K.","last_name":"Kundu","first_name":"Pintu K."},{"first_name":"Avishai","last_name":"Lerner","full_name":"Lerner, Avishai"},{"last_name":"Kučanda","first_name":"Kristina","full_name":"Kučanda, Kristina"},{"full_name":"Leitus, Gregory","first_name":"Gregory","last_name":"Leitus"},{"first_name":"Rafal","last_name":"Klajn","full_name":"Klajn, Rafal","id":"8e84690e-1e48-11ed-a02b-a1e6fb8bb53b"}],"external_id":{"pmid":["25072292"]},"publication_identifier":{"eissn":["1520-5126"],"issn":["0002-7863"]},"article_type":"original","citation":{"ieee":"P. K. Kundu, A. Lerner, K. Kučanda, G. Leitus, and R. Klajn, “Cyclic kinetics during thermal equilibration of an axially chiral bis-spiropyran,” <i>Journal of the American Chemical Society</i>, vol. 136, no. 32. American Chemical Society, pp. 11276–11279, 2014.","mla":"Kundu, Pintu K., et al. “Cyclic Kinetics during Thermal Equilibration of an Axially Chiral Bis-Spiropyran.” <i>Journal of the American Chemical Society</i>, vol. 136, no. 32, American Chemical Society, 2014, pp. 11276–79, doi:<a href=\"https://doi.org/10.1021/ja505948q\">10.1021/ja505948q</a>.","short":"P.K. Kundu, A. Lerner, K. Kučanda, G. Leitus, R. Klajn, Journal of the American Chemical Society 136 (2014) 11276–11279.","chicago":"Kundu, Pintu K., Avishai Lerner, Kristina Kučanda, Gregory Leitus, and Rafal Klajn. “Cyclic Kinetics during Thermal Equilibration of an Axially Chiral Bis-Spiropyran.” <i>Journal of the American Chemical Society</i>. American Chemical Society, 2014. <a href=\"https://doi.org/10.1021/ja505948q\">https://doi.org/10.1021/ja505948q</a>.","ista":"Kundu PK, Lerner A, Kučanda K, Leitus G, Klajn R. 2014. Cyclic kinetics during thermal equilibration of an axially chiral bis-spiropyran. Journal of the American Chemical Society. 136(32), 11276–11279.","apa":"Kundu, P. K., Lerner, A., Kučanda, K., Leitus, G., &#38; Klajn, R. (2014). Cyclic kinetics during thermal equilibration of an axially chiral bis-spiropyran. <i>Journal of the American Chemical Society</i>. American Chemical Society. <a href=\"https://doi.org/10.1021/ja505948q\">https://doi.org/10.1021/ja505948q</a>","ama":"Kundu PK, Lerner A, Kučanda K, Leitus G, Klajn R. Cyclic kinetics during thermal equilibration of an axially chiral bis-spiropyran. <i>Journal of the American Chemical Society</i>. 2014;136(32):11276-11279. doi:<a href=\"https://doi.org/10.1021/ja505948q\">10.1021/ja505948q</a>"},"language":[{"iso":"eng"}],"_id":"13401","intvolume":"       136","volume":136,"year":"2014","keyword":["Colloid and Surface Chemistry","Biochemistry","General Chemistry","Catalysis"]}