{"intvolume":"         1","language":[{"iso":"eng"}],"issue":"5","oa_version":"None","scopus_import":"1","quality_controlled":"1","title":"Irreversible bleaching of donor-acceptor stenhouse adducts on the surfaces of magnetite nanoparticles","keyword":["Organic Chemistry","Physical and Theoretical Chemistry","Analytical Chemistry"],"date_published":"2017-05-01T00:00:00Z","publisher":"Wiley","article_type":"original","year":"2017","day":"01","publication_identifier":{"eissn":["2367-0932"]},"date_updated":"2023-08-07T12:08:05Z","volume":1,"extern":"1","type":"journal_article","publication_status":"published","publication":"ChemPhotoChem","abstract":[{"lang":"eng","text":"Two novel donor–acceptor Stenhouse adducts (DASAs) featuring the catechol moiety were synthesized and characterized. Both compounds bind strongly to the surfaces of magnetite nanoparticles. An adrenaline-derived DASA renders the particles insoluble in all common solvents, likely because of poor solvation of the zwitterionic isomer generated on the nanoparticle surfaces. Well-soluble nanoparticles were successfully obtained using dopamine-derived DASA equipped with a long alkyl chain. Upon its attachment to nanoparticles, this DASA undergoes an irreversible decoloration reaction owing to the formation of the zwitterionic form. The reaction follows first-order kinetics and proceeds more rapidly on large nanoparticles. Interestingly, decoloration can be suppressed in the presence of free DASA molecules in solution or at high nanoparticle concentrations."}],"_id":"13383","author":[{"first_name":"Johannes","full_name":"Ahrens, Johannes","last_name":"Ahrens"},{"full_name":"Bian, Tong","first_name":"Tong","last_name":"Bian"},{"full_name":"Vexler, Tom","first_name":"Tom","last_name":"Vexler"},{"first_name":"Rafal","full_name":"Klajn, Rafal","id":"8e84690e-1e48-11ed-a02b-a1e6fb8bb53b","last_name":"Klajn"}],"doi":"10.1002/cptc.201700009","citation":{"ista":"Ahrens J, Bian T, Vexler T, Klajn R. 2017. Irreversible bleaching of donor-acceptor stenhouse adducts on the surfaces of magnetite nanoparticles. ChemPhotoChem. 1(5), 230–236.","chicago":"Ahrens, Johannes, Tong Bian, Tom Vexler, and Rafal Klajn. “Irreversible Bleaching of Donor-Acceptor Stenhouse Adducts on the Surfaces of Magnetite Nanoparticles.” <i>ChemPhotoChem</i>. Wiley, 2017. <a href=\"https://doi.org/10.1002/cptc.201700009\">https://doi.org/10.1002/cptc.201700009</a>.","apa":"Ahrens, J., Bian, T., Vexler, T., &#38; Klajn, R. (2017). Irreversible bleaching of donor-acceptor stenhouse adducts on the surfaces of magnetite nanoparticles. <i>ChemPhotoChem</i>. Wiley. <a href=\"https://doi.org/10.1002/cptc.201700009\">https://doi.org/10.1002/cptc.201700009</a>","mla":"Ahrens, Johannes, et al. “Irreversible Bleaching of Donor-Acceptor Stenhouse Adducts on the Surfaces of Magnetite Nanoparticles.” <i>ChemPhotoChem</i>, vol. 1, no. 5, Wiley, 2017, pp. 230–36, doi:<a href=\"https://doi.org/10.1002/cptc.201700009\">10.1002/cptc.201700009</a>.","ama":"Ahrens J, Bian T, Vexler T, Klajn R. Irreversible bleaching of donor-acceptor stenhouse adducts on the surfaces of magnetite nanoparticles. <i>ChemPhotoChem</i>. 2017;1(5):230-236. doi:<a href=\"https://doi.org/10.1002/cptc.201700009\">10.1002/cptc.201700009</a>","short":"J. Ahrens, T. Bian, T. Vexler, R. Klajn, ChemPhotoChem 1 (2017) 230–236.","ieee":"J. Ahrens, T. Bian, T. Vexler, and R. Klajn, “Irreversible bleaching of donor-acceptor stenhouse adducts on the surfaces of magnetite nanoparticles,” <i>ChemPhotoChem</i>, vol. 1, no. 5. Wiley, pp. 230–236, 2017."},"month":"05","date_created":"2023-08-01T09:41:43Z","article_processing_charge":"No","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","status":"public","page":"230-236"}