{"article_processing_charge":"No","day":"22","acknowledgement":"We acknowledge funding from the European Union’s Horizon 2020 Research and Innovation Program [European Research Council grants 820008 (Ra.K.) and 101045223 (A.P.) and Marie Skłodowska-Curie grants 812868 (J.G.) and 101022777 (T.-P.R.)], the Academy of Finland [Center of Excellence Programme LIBER grant 346107 (A.P.), Flagship Programme PREIN grant 320165 (A.P.), and Postdoctoral Researcher grant 340103 (T.-P.R.)], Zuckerman STEM Leadership Program Fellowship (J.R.C.), President’s PhD Scholarship (M.O.), and the EPSRC [Established Career Fellowship grant EP/R00188X/1 (M.J.F.)].","abstract":[{"lang":"eng","text":"Photoisomerization of azobenzenes from their stable E isomer to the metastable Z state is the basis of numerous applications of these molecules. However, this reaction typically requires ultraviolet light, which limits applicability. In this study, we introduce disequilibration by sensitization under confinement (DESC), a supramolecular approach to induce the E-to-Z isomerization by using light of a desired color, including red. DESC relies on a combination of a macrocyclic host and a photosensitizer, which act together to selectively bind and sensitize E-azobenzenes for isomerization. The Z isomer lacks strong affinity for and is expelled from the host, which can then convert additional E-azobenzenes to the Z state. In this way, the host–photosensitizer complex converts photon energy into chemical energy in the form of out-of-equilibrium photostationary states, including ones that cannot be accessed through direct photoexcitation."}],"date_created":"2023-08-01T08:26:15Z","language":[{"iso":"eng"}],"publisher":"American Association for the Advancement of Science","oa":1,"doi":"10.1126/science.adh9059","main_file_link":[{"url":"https://doi.org/10.26434/chemrxiv-2023-gq2h0","open_access":"1"}],"author":[{"full_name":"Gemen, Julius","last_name":"Gemen","first_name":"Julius"},{"last_name":"Church","first_name":"Jonathan R.","full_name":"Church, Jonathan R."},{"first_name":"Tero-Petri","last_name":"Ruoko","full_name":"Ruoko, Tero-Petri"},{"last_name":"Durandin","first_name":"Nikita","full_name":"Durandin, Nikita"},{"first_name":"Michał J.","last_name":"Białek","full_name":"Białek, Michał J."},{"first_name":"Maren","last_name":"Weissenfels","full_name":"Weissenfels, Maren"},{"full_name":"Feller, Moran","last_name":"Feller","first_name":"Moran"},{"full_name":"Kazes, Miri","first_name":"Miri","last_name":"Kazes"},{"last_name":"Borin","first_name":"Veniamin A.","full_name":"Borin, Veniamin A."},{"first_name":"Magdalena","last_name":"Odaybat","full_name":"Odaybat, Magdalena"},{"full_name":"Kalepu, Rishir","last_name":"Kalepu","first_name":"Rishir"},{"last_name":"Diskin-Posner","first_name":"Yael","full_name":"Diskin-Posner, Yael"},{"full_name":"Oron, Dan","first_name":"Dan","last_name":"Oron"},{"full_name":"Fuchter, Matthew J.","last_name":"Fuchter","first_name":"Matthew J."},{"full_name":"Priimagi, Arri","first_name":"Arri","last_name":"Priimagi"},{"full_name":"Schapiro, Igor","first_name":"Igor","last_name":"Schapiro"},{"full_name":"Klajn, Rafal","id":"8e84690e-1e48-11ed-a02b-a1e6fb8bb53b","last_name":"Klajn","first_name":"Rafal"}],"type":"journal_article","intvolume":"       381","publication_identifier":{"eissn":["1095-9203"]},"date_updated":"2023-10-03T08:11:26Z","date_published":"2023-09-22T00:00:00Z","publication_status":"published","quality_controlled":"1","article_type":"original","year":"2023","scopus_import":"1","volume":381,"publication":"Science","oa_version":"Preprint","status":"public","title":"Disequilibrating azoarenes by visible-light sensitization under confinement","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","issue":"6664","department":[{"_id":"RaKl"}],"page":"1357-1363","citation":{"mla":"Gemen, Julius, et al. “Disequilibrating Azoarenes by Visible-Light Sensitization under Confinement.” <i>Science</i>, vol. 381, no. 6664, American Association for the Advancement of Science, 2023, pp. 1357–63, doi:<a href=\"https://doi.org/10.1126/science.adh9059\">10.1126/science.adh9059</a>.","apa":"Gemen, J., Church, J. R., Ruoko, T.-P., Durandin, N., Białek, M. J., Weissenfels, M., … Klajn, R. (2023). Disequilibrating azoarenes by visible-light sensitization under confinement. <i>Science</i>. American Association for the Advancement of Science. <a href=\"https://doi.org/10.1126/science.adh9059\">https://doi.org/10.1126/science.adh9059</a>","chicago":"Gemen, Julius, Jonathan R. Church, Tero-Petri Ruoko, Nikita Durandin, Michał J. Białek, Maren Weissenfels, Moran Feller, et al. “Disequilibrating Azoarenes by Visible-Light Sensitization under Confinement.” <i>Science</i>. American Association for the Advancement of Science, 2023. <a href=\"https://doi.org/10.1126/science.adh9059\">https://doi.org/10.1126/science.adh9059</a>.","short":"J. Gemen, J.R. Church, T.-P. Ruoko, N. Durandin, M.J. Białek, M. Weissenfels, M. Feller, M. Kazes, V.A. Borin, M. Odaybat, R. Kalepu, Y. Diskin-Posner, D. Oron, M.J. Fuchter, A. Priimagi, I. Schapiro, R. Klajn, Science 381 (2023) 1357–1363.","ista":"Gemen J, Church JR, Ruoko T-P, Durandin N, Białek MJ, Weissenfels M, Feller M, Kazes M, Borin VA, Odaybat M, Kalepu R, Diskin-Posner Y, Oron D, Fuchter MJ, Priimagi A, Schapiro I, Klajn R. 2023. Disequilibrating azoarenes by visible-light sensitization under confinement. Science. 381(6664), 1357–1363.","ieee":"J. Gemen <i>et al.</i>, “Disequilibrating azoarenes by visible-light sensitization under confinement,” <i>Science</i>, vol. 381, no. 6664. American Association for the Advancement of Science, pp. 1357–1363, 2023.","ama":"Gemen J, Church JR, Ruoko T-P, et al. Disequilibrating azoarenes by visible-light sensitization under confinement. <i>Science</i>. 2023;381(6664):1357-1363. doi:<a href=\"https://doi.org/10.1126/science.adh9059\">10.1126/science.adh9059</a>"},"_id":"13340","month":"09"}