{"title":"Recyclable, bifunctional metallaphotocatalysts for C−S cross‐coupling reactions","scopus_import":"1","quality_controlled":"1","main_file_link":[{"url":"https://doi.org/10.1002/cptc.202100062","open_access":"1"}],"oa_version":"Published Version","issue":"8","language":[{"iso":"eng"}],"intvolume":" 5","day":"01","publisher":"Wiley","article_type":"letter_note","year":"2021","date_published":"2021-08-01T00:00:00Z","doi":"10.1002/cptc.202100062","author":[{"first_name":"Susanne","full_name":"Reischauer, Susanne","last_name":"Reischauer"},{"orcid":"0000-0001-8689-388X","full_name":"Pieber, Bartholomäus","first_name":"Bartholomäus","id":"93e5e5b2-0da6-11ed-8a41-af589a024726","last_name":"Pieber"}],"_id":"11965","abstract":[{"text":"Metallaphotocatalytic cross-coupling reactions are typically carried out by combining homogeneous or heterogeneous photocatalysts with a soluble nickel complex. Previous attempts to realize recyclable catalytic systems use immobilized iridium complexes to harvest light. We present bifunctional materials based on semiconductors for metallaphotocatalytic C−S cross-coupling reactions that can be reused without losing their catalytic activity. Key to the success is the permanent immobilization of a nickel complex on the surface of a heterogeneous semiconductor through phosphonic acid anchors. The optimized catalyst harvests a broad range of the visible light spectrum and requires a nickel loading of only ∼0.1 mol %.","lang":"eng"}],"publication_status":"published","publication":"ChemPhotoChem","type":"journal_article","extern":"1","volume":5,"date_updated":"2023-02-21T10:09:37Z","publication_identifier":{"eissn":["2367-0932"]},"page":"716-720","status":"public","oa":1,"user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","article_processing_charge":"No","date_created":"2022-08-25T08:31:11Z","month":"08","citation":{"apa":"Reischauer, S., & Pieber, B. (2021). Recyclable, bifunctional metallaphotocatalysts for C−S cross‐coupling reactions. ChemPhotoChem. Wiley. https://doi.org/10.1002/cptc.202100062","chicago":"Reischauer, Susanne, and Bartholomäus Pieber. “Recyclable, Bifunctional Metallaphotocatalysts for C−S Cross‐coupling Reactions.” ChemPhotoChem. Wiley, 2021. https://doi.org/10.1002/cptc.202100062.","ista":"Reischauer S, Pieber B. 2021. Recyclable, bifunctional metallaphotocatalysts for C−S cross‐coupling reactions. ChemPhotoChem. 5(8), 716–720.","ieee":"S. Reischauer and B. Pieber, “Recyclable, bifunctional metallaphotocatalysts for C−S cross‐coupling reactions,” ChemPhotoChem, vol. 5, no. 8. Wiley, pp. 716–720, 2021.","mla":"Reischauer, Susanne, and Bartholomäus Pieber. “Recyclable, Bifunctional Metallaphotocatalysts for C−S Cross‐coupling Reactions.” ChemPhotoChem, vol. 5, no. 8, Wiley, 2021, pp. 716–20, doi:10.1002/cptc.202100062.","ama":"Reischauer S, Pieber B. Recyclable, bifunctional metallaphotocatalysts for C−S cross‐coupling reactions. ChemPhotoChem. 2021;5(8):716-720. doi:10.1002/cptc.202100062","short":"S. Reischauer, B. Pieber, ChemPhotoChem 5 (2021) 716–720."}}