---
_id: '8067'
abstract:
- lang: eng
text: "With the lithium-ion technology approaching its intrinsic limit with graphite-based
anodes, lithium metal is recently receiving renewed interest from the battery
community as potential high capacity anode for next-generation rechargeable batteries.
In this focus paper, we review the main advances in this field since the first
attempts in the\r\nmid-1970s. Strategies for enabling reversible cycling and avoiding
dendrite growth are thoroughly discussed, including specific applications in all-solid-state
(polymeric and inorganic), Lithium-sulphur and Li-O2 (air) batteries. A particular
attention is paid to review recent developments in regard of prototype manufacturing
and current state-ofthe-art of these battery technologies with respect to the
2030 targets of the EU Integrated Strategic Energy Technology Plan (SET-Plan)
Action 7."
alternative_title:
- IST Austria Technical Report
article_processing_charge: No
author:
- first_name: Alberto
full_name: Varzi, Alberto
last_name: Varzi
- first_name: Katharina
full_name: Thanner, Katharina
last_name: Thanner
- first_name: Roberto
full_name: Scipioni, Roberto
last_name: Scipioni
- first_name: Daniele
full_name: Di Lecce, Daniele
last_name: Di Lecce
- first_name: Jusef
full_name: Hassoun, Jusef
last_name: Hassoun
- first_name: Susanne
full_name: Dörfler, Susanne
last_name: Dörfler
- first_name: Holger
full_name: Altheus, Holger
last_name: Altheus
- first_name: Stefan
full_name: Kaskel, Stefan
last_name: Kaskel
- first_name: Christian
full_name: Prehal, Christian
last_name: Prehal
- first_name: Stefan Alexander
full_name: Freunberger, Stefan Alexander
id: A8CA28E6-CE23-11E9-AD2D-EC27E6697425
last_name: Freunberger
orcid: 0000-0003-2902-5319
citation:
ama: Varzi A, Thanner K, Scipioni R, et al. Current Status and Future Perspectives
of Lithium Metal Batteries. IST Austria doi:10.15479/AT:ISTA:8067
apa: Varzi, A., Thanner, K., Scipioni, R., Di Lecce, D., Hassoun, J., Dörfler, S.,
… Freunberger, S. A. (n.d.). Current status and future perspectives of Lithium
metal batteries. IST Austria. https://doi.org/10.15479/AT:ISTA:8067
chicago: Varzi, Alberto, Katharina Thanner, Roberto Scipioni, Daniele Di Lecce,
Jusef Hassoun, Susanne Dörfler, Holger Altheus, Stefan Kaskel, Christian Prehal,
and Stefan Alexander Freunberger. Current Status and Future Perspectives of
Lithium Metal Batteries. IST Austria, n.d. https://doi.org/10.15479/AT:ISTA:8067.
ieee: A. Varzi et al., Current status and future perspectives of Lithium
metal batteries. IST Austria.
ista: Varzi A, Thanner K, Scipioni R, Di Lecce D, Hassoun J, Dörfler S, Altheus
H, Kaskel S, Prehal C, Freunberger SA. Current status and future perspectives
of Lithium metal batteries, IST Austria, 63p.
mla: Varzi, Alberto, et al. Current Status and Future Perspectives of Lithium
Metal Batteries. IST Austria, doi:10.15479/AT:ISTA:8067.
short: A. Varzi, K. Thanner, R. Scipioni, D. Di Lecce, J. Hassoun, S. Dörfler, H.
Altheus, S. Kaskel, C. Prehal, S.A. Freunberger, Current Status and Future Perspectives
of Lithium Metal Batteries, IST Austria, n.d.
date_created: 2020-06-30T07:37:39Z
date_published: 2020-07-01T00:00:00Z
date_updated: 2023-08-22T09:20:36Z
day: '01'
ddc:
- '540'
department:
- _id: StFr
doi: 10.15479/AT:ISTA:8067
file:
- access_level: open_access
checksum: d183ca1465a1cbb4f8db27875cd156f7
content_type: application/pdf
creator: dernst
date_created: 2020-07-02T07:36:04Z
date_updated: 2020-07-14T12:48:08Z
file_id: '8076'
file_name: 20200612_JPS_review_Li_metal_submitted.pdf
file_size: 2612498
relation: main_file
file_date_updated: 2020-07-14T12:48:08Z
has_accepted_license: '1'
keyword:
- Battery
- Lithium metal
- Lithium-sulphur
- Lithium-air
- All-solid-state
language:
- iso: eng
month: '07'
oa: 1
oa_version: Published Version
page: '63'
publication_identifier:
issn:
- 2664-1690
publication_status: submitted
publisher: IST Austria
related_material:
record:
- id: '8361'
relation: later_version
status: public
status: public
title: Current status and future perspectives of Lithium metal batteries
type: technical_report
user_id: 8b945eb4-e2f2-11eb-945a-df72226e66a9
year: '2020'
...
---
_id: '8081'
abstract:
- lang: eng
text: "Here, we employ micro- and nanosized cellulose particles, namely paper fines
and cellulose\r\nnanocrystals, to induce hierarchical organization over a wide
length scale. After processing\r\nthem into carbonaceous materials, we demonstrate
that these hierarchically organized materials\r\noutperform the best materials
for supercapacitors operating with organic electrolytes reported\r\nin literature
in terms of specific energy/power (Ragone plot) while showing hardly any capacity\r\nfade
over 4,000 cycles. The highly porous materials feature a specific surface area
as high as\r\n2500 m2ˑg-1 and exhibit pore sizes in the range of 0.5 to 200 nm
as proven by scanning electron\r\nmicroscopy and N2 physisorption. The carbonaceous
materials have been further investigated\r\nby X-ray photoelectron spectroscopy
and RAMAN spectroscopy. Since paper fines are an\r\nunderutilized side stream
in any paper production process, they are a cheap and highly available\r\nfeedstock
to prepare carbonaceous materials with outstanding performance in electrochemical\r\napplications. "
acknowledgement: 'The authors M.A.H., S.S., R.E., and W.B. acknowledge the industrial
partners Sappi Gratkorn, Zellstoff Pöls and Mondi Frantschach, the Austrian Research
Promotion Agency (FFG), COMET, BMVIT, BMWFJ, the Province of Styria and Carinthia
for their financial support of the K-project Flippr²-Process Integration. E.M. and
S.A.F. are indebted to the European Research Council (ERC) under the European Union’s
Horizon 2020 research and innovation program (grant agreement No 636069). W. T.
and S. E. thank FWO (G.0C60.13N) and the European Union’s European Fund for Regional
Development and Flanders Innovation & Entrepreneurship (Accelerate3 project, Interreg
Vlaanderen-Nederland program) for financial support. W. T. also thanks the Provincie
West-Vlaanderen (Belgium) for his Provincial Chair in Advanced Materials. S. B.
thanks the European Regional Development Fund (EFRE) and the province of Upper Austria
for financial support through the program IWB 2014-2020 (project BioCarb-K). AMR
gratefully acknowledges funding support through the SC EPSCoR/IDeAProgram under
Award #18-SR03, and the NASA EPSCoR Program under Award #NNH17ZHA002C. Icons in
Scheme 1 were provided by Good Ware, monkik, photo3idea_studio, and OCHA from www.flaticon.com.'
article_processing_charge: No
author:
- first_name: 'Mathias A. '
full_name: 'Hobisch, Mathias A. '
last_name: Hobisch
- first_name: 'Eléonore '
full_name: 'Mourad, Eléonore '
last_name: Mourad
- first_name: 'Wolfgang J. '
full_name: 'Fischer, Wolfgang J. '
last_name: Fischer
- first_name: 'Christian '
full_name: 'Prehal, Christian '
last_name: Prehal
- first_name: 'Samuel '
full_name: 'Eyley, Samuel '
last_name: Eyley
- first_name: 'Anthony '
full_name: 'Childress, Anthony '
last_name: Childress
- first_name: 'Armin '
full_name: 'Zankel, Armin '
last_name: Zankel
- first_name: 'Andreas '
full_name: 'Mautner, Andreas '
last_name: Mautner
- first_name: 'Stefan '
full_name: 'Breitenbach, Stefan '
last_name: Breitenbach
- first_name: 'Apparao M. '
full_name: 'Rao, Apparao M. '
last_name: Rao
- first_name: 'Wim '
full_name: 'Thielemans, Wim '
last_name: Thielemans
- first_name: Stefan Alexander
full_name: Freunberger, Stefan Alexander
id: A8CA28E6-CE23-11E9-AD2D-EC27E6697425
last_name: Freunberger
orcid: 0000-0003-2902-5319
- first_name: 'Rene '
full_name: 'Eckhart, Rene '
last_name: Eckhart
- first_name: 'Wolfgang '
full_name: 'Bauer, Wolfgang '
last_name: Bauer
- first_name: 'Stefan '
full_name: 'Spirk, Stefan '
last_name: Spirk
citation:
ama: Hobisch MA, Mourad E, Fischer WJ, et al. High specific capacitance supercapacitors
from hierarchically organized all-cellulose composites.
apa: Hobisch, M. A., Mourad, E., Fischer, W. J., Prehal, C., Eyley, S., Childress,
A., … Spirk, S. (n.d.). High specific capacitance supercapacitors from hierarchically
organized all-cellulose composites.
chicago: Hobisch, Mathias A. , Eléonore Mourad, Wolfgang J. Fischer, Christian Prehal,
Samuel Eyley, Anthony Childress, Armin Zankel, et al. “High Specific Capacitance
Supercapacitors from Hierarchically Organized All-Cellulose Composites,” n.d.
ieee: M. A. Hobisch et al., “High specific capacitance supercapacitors from
hierarchically organized all-cellulose composites.” .
ista: Hobisch MA, Mourad E, Fischer WJ, Prehal C, Eyley S, Childress A, Zankel A,
Mautner A, Breitenbach S, Rao AM, Thielemans W, Freunberger SA, Eckhart R, Bauer
W, Spirk S. High specific capacitance supercapacitors from hierarchically organized
all-cellulose composites.
mla: Hobisch, Mathias A., et al. High Specific Capacitance Supercapacitors from
Hierarchically Organized All-Cellulose Composites.
short: M.A. Hobisch, E. Mourad, W.J. Fischer, C. Prehal, S. Eyley, A. Childress,
A. Zankel, A. Mautner, S. Breitenbach, A.M. Rao, W. Thielemans, S.A. Freunberger,
R. Eckhart, W. Bauer, S. Spirk, (n.d.).
date_created: 2020-07-02T20:24:42Z
date_published: 2020-07-13T00:00:00Z
date_updated: 2022-06-17T08:39:49Z
day: '13'
ddc:
- '540'
department:
- _id: StFr
file:
- access_level: open_access
checksum: 6970d621984c03ebc2eee71adfe706dd
content_type: application/pdf
creator: sfreunbe
date_created: 2020-07-02T20:21:59Z
date_updated: 2020-07-14T12:48:09Z
file_id: '8082'
file_name: AM.pdf
file_size: 1129852
relation: main_file
- access_level: open_access
checksum: cd74c7bd47d6e7163d54d67f074dcc36
content_type: application/pdf
creator: cziletti
date_created: 2020-07-08T12:14:04Z
date_updated: 2020-07-14T12:48:09Z
file_id: '8102'
file_name: Supporting_Information.pdf
file_size: 945565
relation: supplementary_material
file_date_updated: 2020-07-14T12:48:09Z
has_accepted_license: '1'
language:
- iso: eng
month: '07'
oa: 1
oa_version: Submitted Version
publication_status: submitted
status: public
title: High specific capacitance supercapacitors from hierarchically organized all-cellulose
composites
type: preprint
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
year: '2020'
...
---
_id: '8329'
abstract:
- lang: eng
text: We show the synthesis of a redox‐active quinone, 2‐methoxy‐1,4‐hydroquinone
(MHQ), from a bio‐based feedstock and its suitability as electrolyte in aqueous
redox flow batteries. We identified semiquinone intermediates at insufficiently
low pH and quinoid radicals as responsible for decomposition of MHQ under electrochemical
conditions. Both can be avoided and/or stabilized, respectively, using H 3 PO
4 electrolyte, allowing for reversible cycling in a redox flow battery for hundreds
of cycles.
acknowledgement: The Austrian Research Promotion Agency (FFG) is gratefully acknowledged
for financial support of the project LignoBatt (860429).
article_processing_charge: No
article_type: original
author:
- first_name: Werner
full_name: Schlemmer, Werner
last_name: Schlemmer
- first_name: Philipp
full_name: Nothdurft, Philipp
last_name: Nothdurft
- first_name: Alina
full_name: Petzold, Alina
last_name: Petzold
- first_name: Philipp
full_name: Frühwirt, Philipp
last_name: Frühwirt
- first_name: Max
full_name: Schmallegger, Max
last_name: Schmallegger
- first_name: Georg
full_name: Gescheidt-Demner, Georg
last_name: Gescheidt-Demner
- first_name: Roland
full_name: Fischer, Roland
last_name: Fischer
- first_name: Stefan Alexander
full_name: Freunberger, Stefan Alexander
id: A8CA28E6-CE23-11E9-AD2D-EC27E6697425
last_name: Freunberger
orcid: 0000-0003-2902-5319
- first_name: Wolfgang
full_name: Kern, Wolfgang
last_name: Kern
- first_name: Stefan
full_name: Spirk, Stefan
last_name: Spirk
citation:
ama: Schlemmer W, Nothdurft P, Petzold A, et al. 2‐methoxyhydroquinone from vanillin
for aqueous redox‐flow batteries. Angewandte Chemie International Edition.
2020;59(51):22943-22946. doi:10.1002/anie.202008253
apa: Schlemmer, W., Nothdurft, P., Petzold, A., Frühwirt, P., Schmallegger, M.,
Gescheidt-Demner, G., … Spirk, S. (2020). 2‐methoxyhydroquinone from vanillin
for aqueous redox‐flow batteries. Angewandte Chemie International Edition.
Wiley. https://doi.org/10.1002/anie.202008253
chicago: Schlemmer, Werner, Philipp Nothdurft, Alina Petzold, Philipp Frühwirt,
Max Schmallegger, Georg Gescheidt-Demner, Roland Fischer, Stefan Alexander Freunberger,
Wolfgang Kern, and Stefan Spirk. “2‐methoxyhydroquinone from Vanillin for Aqueous
Redox‐flow Batteries.” Angewandte Chemie International Edition. Wiley,
2020. https://doi.org/10.1002/anie.202008253.
ieee: W. Schlemmer et al., “2‐methoxyhydroquinone from vanillin for aqueous
redox‐flow batteries,” Angewandte Chemie International Edition, vol. 59,
no. 51. Wiley, pp. 22943–22946, 2020.
ista: Schlemmer W, Nothdurft P, Petzold A, Frühwirt P, Schmallegger M, Gescheidt-Demner
G, Fischer R, Freunberger SA, Kern W, Spirk S. 2020. 2‐methoxyhydroquinone from
vanillin for aqueous redox‐flow batteries. Angewandte Chemie International Edition.
59(51), 22943–22946.
mla: Schlemmer, Werner, et al. “2‐methoxyhydroquinone from Vanillin for Aqueous
Redox‐flow Batteries.” Angewandte Chemie International Edition, vol. 59,
no. 51, Wiley, 2020, pp. 22943–46, doi:10.1002/anie.202008253.
short: W. Schlemmer, P. Nothdurft, A. Petzold, P. Frühwirt, M. Schmallegger, G.
Gescheidt-Demner, R. Fischer, S.A. Freunberger, W. Kern, S. Spirk, Angewandte
Chemie International Edition 59 (2020) 22943–22946.
date_created: 2020-09-03T16:10:56Z
date_published: 2020-12-14T00:00:00Z
date_updated: 2023-09-05T16:03:47Z
day: '14'
department:
- _id: StFr
doi: 10.1002/anie.202008253
external_id:
isi:
- '000576148700001'
intvolume: ' 59'
isi: 1
issue: '51'
language:
- iso: eng
main_file_link:
- open_access: '1'
url: https://doi.org/10.1002/anie.202008253
month: '12'
oa: 1
oa_version: Published Version
page: 22943-22946
publication: Angewandte Chemie International Edition
publication_identifier:
eissn:
- 1521-3773
issn:
- 1433-7851
publication_status: published
publisher: Wiley
quality_controlled: '1'
related_material:
record:
- id: '9780'
relation: research_data
status: public
scopus_import: '1'
status: public
title: 2‐methoxyhydroquinone from vanillin for aqueous redox‐flow batteries
type: journal_article
user_id: c635000d-4b10-11ee-a964-aac5a93f6ac1
volume: 59
year: '2020'
...
---
_id: '8361'
abstract:
- lang: eng
text: With the lithium-ion technology approaching its intrinsic limit with graphite-based
anodes, Li metal is recently receiving renewed interest from the battery community
as potential high capacity anode for next-generation rechargeable batteries. In
this focus paper, we review the main advances in this field since the first attempts
in the mid-1970s. Strategies for enabling reversible cycling and avoiding dendrite
growth are thoroughly discussed, including specific applications in all-solid-state
(inorganic and polymeric), Lithium–Sulfur (Li–S) and Lithium-O2 (air) batteries.
A particular attention is paid to recent developments of these battery technologies
and their current state with respect to the 2030 targets of the EU Integrated
Strategic Energy Technology Plan (SET-Plan) Action 7.
acknowledgement: A.V. and K.T. acknowledge, respectively, the financial support of
the Helmholtz Association and BMW AG. J.H. acknowledges the collabo-ration project
“Accordo di Collaborazione Quadro 2015” between Uni-versity of Ferrara (Department
of Chemical and Pharmaceutical Sciences) and Sapienza University of Rome (Department
of Chemistry). S.D., H.A. and S.K. thank the Fraunhofer Gesellschaft, Technische
Uni-versit ̈at Dresden and would like to acknowledge European Union’s Horizon
2020 research and innovation programme under grant agree-ment No 814471. S.A.F.
and C.P. are indebted to the European Research Council (ERC) under the European
Union’s Horizon 2020 research and innovation program (grant agreement no. 636069)
and IST Austria.
article_number: '228803'
article_processing_charge: No
article_type: original
author:
- first_name: Alberto
full_name: Varzi, Alberto
last_name: Varzi
orcid: 0000-0001-5069-0589
- first_name: Katharina
full_name: Thanner, Katharina
last_name: Thanner
orcid: 0000-0001-5394-2323
- first_name: Roberto
full_name: Scipioni, Roberto
last_name: Scipioni
orcid: 0000-0003-1926-421X
- first_name: Daniele
full_name: Di Lecce, Daniele
last_name: Di Lecce
- first_name: Jusef
full_name: Hassoun, Jusef
last_name: Hassoun
- first_name: Susanne
full_name: Dörfler, Susanne
last_name: Dörfler
- first_name: Holger
full_name: Altheus, Holger
last_name: Altheus
- first_name: Stefan
full_name: Kaskel, Stefan
last_name: Kaskel
- first_name: Christian
full_name: Prehal, Christian
last_name: Prehal
orcid: 0000-0003-0654-0940
- first_name: Stefan Alexander
full_name: Freunberger, Stefan Alexander
id: A8CA28E6-CE23-11E9-AD2D-EC27E6697425
last_name: Freunberger
orcid: 0000-0003-2902-5319
citation:
ama: Varzi A, Thanner K, Scipioni R, et al. Current status and future perspectives
of lithium metal batteries. Journal of Power Sources. 2020;480(12). doi:10.1016/j.jpowsour.2020.228803
apa: Varzi, A., Thanner, K., Scipioni, R., Di Lecce, D., Hassoun, J., Dörfler, S.,
… Freunberger, S. A. (2020). Current status and future perspectives of lithium
metal batteries. Journal of Power Sources. Elsevier. https://doi.org/10.1016/j.jpowsour.2020.228803
chicago: Varzi, Alberto, Katharina Thanner, Roberto Scipioni, Daniele Di Lecce,
Jusef Hassoun, Susanne Dörfler, Holger Altheus, Stefan Kaskel, Christian Prehal,
and Stefan Alexander Freunberger. “Current Status and Future Perspectives of Lithium
Metal Batteries.” Journal of Power Sources. Elsevier, 2020. https://doi.org/10.1016/j.jpowsour.2020.228803.
ieee: A. Varzi et al., “Current status and future perspectives of lithium
metal batteries,” Journal of Power Sources, vol. 480, no. 12. Elsevier,
2020.
ista: Varzi A, Thanner K, Scipioni R, Di Lecce D, Hassoun J, Dörfler S, Altheus
H, Kaskel S, Prehal C, Freunberger SA. 2020. Current status and future perspectives
of lithium metal batteries. Journal of Power Sources. 480(12), 228803.
mla: Varzi, Alberto, et al. “Current Status and Future Perspectives of Lithium Metal
Batteries.” Journal of Power Sources, vol. 480, no. 12, 228803, Elsevier,
2020, doi:10.1016/j.jpowsour.2020.228803.
short: A. Varzi, K. Thanner, R. Scipioni, D. Di Lecce, J. Hassoun, S. Dörfler, H.
Altheus, S. Kaskel, C. Prehal, S.A. Freunberger, Journal of Power Sources 480
(2020).
date_created: 2020-09-10T10:48:40Z
date_published: 2020-12-31T00:00:00Z
date_updated: 2023-08-22T09:20:37Z
day: '31'
department:
- _id: StFr
doi: 10.1016/j.jpowsour.2020.228803
external_id:
isi:
- '000593857300001'
intvolume: ' 480'
isi: 1
issue: '12'
language:
- iso: eng
main_file_link:
- open_access: '1'
url: https://doi.org/10.1016/j.jpowsour.2020.228803
month: '12'
oa: 1
oa_version: Published Version
publication: Journal of Power Sources
publication_identifier:
issn:
- 0378-7753
publication_status: published
publisher: Elsevier
quality_controlled: '1'
related_material:
record:
- id: '8067'
relation: earlier_version
status: public
status: public
title: Current status and future perspectives of lithium metal batteries
type: journal_article
user_id: 4359f0d1-fa6c-11eb-b949-802e58b17ae8
volume: 480
year: '2020'
...
---
_id: '8568'
abstract:
- lang: eng
text: Aqueous iodine based electrochemical energy storage is considered a potential
candidate to improve sustainability and performance of current battery and supercapacitor
technology. It harnesses the redox activity of iodide, iodine, and polyiodide
species in the confined geometry of nanoporous carbon electrodes. However, current
descriptions of the electrochemical reaction mechanism to interconvert these species
are elusive. Here we show that electrochemical oxidation of iodide in nanoporous
carbons forms persistent solid iodine deposits. Confinement slows down dissolution
into triiodide and pentaiodide, responsible for otherwise significant self-discharge
via shuttling. The main tools for these insights are in situ Raman spectroscopy
and in situ small and wide-angle X-ray scattering (in situ SAXS/WAXS). In situ
Raman confirms the reversible formation of triiodide and pentaiodide. In situ
SAXS/WAXS indicates remarkable amounts of solid iodine deposited in the carbon
nanopores. Combined with stochastic modeling, in situ SAXS allows quantifying
the solid iodine volume fraction and visualizing the iodine structure on 3D lattice
models at the sub-nanometer scale. Based on the derived mechanism, we demonstrate
strategies for improved iodine pore filling capacity and prevention of self-discharge,
applicable to hybrid supercapacitors and batteries.
article_number: '4838'
article_processing_charge: No
article_type: original
author:
- first_name: Christian
full_name: Prehal, Christian
last_name: Prehal
- first_name: Harald
full_name: Fitzek, Harald
last_name: Fitzek
- first_name: Gerald
full_name: Kothleitner, Gerald
last_name: Kothleitner
- first_name: Volker
full_name: Presser, Volker
last_name: Presser
- first_name: Bernhard
full_name: Gollas, Bernhard
last_name: Gollas
- first_name: Stefan Alexander
full_name: Freunberger, Stefan Alexander
id: A8CA28E6-CE23-11E9-AD2D-EC27E6697425
last_name: Freunberger
orcid: 0000-0003-2902-5319
- first_name: Qamar
full_name: Abbas, Qamar
last_name: Abbas
citation:
ama: Prehal C, Fitzek H, Kothleitner G, et al. Persistent and reversible solid iodine
electrodeposition in nanoporous carbons. Nature Communications. 2020;11.
doi:10.1038/s41467-020-18610-6
apa: Prehal, C., Fitzek, H., Kothleitner, G., Presser, V., Gollas, B., Freunberger,
S. A., & Abbas, Q. (2020). Persistent and reversible solid iodine electrodeposition
in nanoporous carbons. Nature Communications. Springer Nature. https://doi.org/10.1038/s41467-020-18610-6
chicago: Prehal, Christian, Harald Fitzek, Gerald Kothleitner, Volker Presser, Bernhard
Gollas, Stefan Alexander Freunberger, and Qamar Abbas. “Persistent and Reversible
Solid Iodine Electrodeposition in Nanoporous Carbons.” Nature Communications.
Springer Nature, 2020. https://doi.org/10.1038/s41467-020-18610-6.
ieee: C. Prehal et al., “Persistent and reversible solid iodine electrodeposition
in nanoporous carbons,” Nature Communications, vol. 11. Springer Nature,
2020.
ista: Prehal C, Fitzek H, Kothleitner G, Presser V, Gollas B, Freunberger SA, Abbas
Q. 2020. Persistent and reversible solid iodine electrodeposition in nanoporous
carbons. Nature Communications. 11, 4838.
mla: Prehal, Christian, et al. “Persistent and Reversible Solid Iodine Electrodeposition
in Nanoporous Carbons.” Nature Communications, vol. 11, 4838, Springer
Nature, 2020, doi:10.1038/s41467-020-18610-6.
short: C. Prehal, H. Fitzek, G. Kothleitner, V. Presser, B. Gollas, S.A. Freunberger,
Q. Abbas, Nature Communications 11 (2020).
date_created: 2020-09-25T07:23:13Z
date_published: 2020-09-24T00:00:00Z
date_updated: 2023-08-22T09:37:24Z
day: '24'
ddc:
- '530'
department:
- _id: StFr
doi: 10.1038/s41467-020-18610-6
external_id:
isi:
- '000573756600004'
file:
- access_level: open_access
checksum: eada7bc8dd16a49390137cff882ef328
content_type: application/pdf
creator: dernst
date_created: 2020-09-28T13:16:15Z
date_updated: 2020-09-28T13:16:15Z
file_id: '8585'
file_name: 2020_NatureComm_Prehal.pdf
file_size: 1822469
relation: main_file
success: 1
file_date_updated: 2020-09-28T13:16:15Z
has_accepted_license: '1'
intvolume: ' 11'
isi: 1
keyword:
- General Biochemistry
- Genetics and Molecular Biology
- General Physics and Astronomy
- General Chemistry
language:
- iso: eng
license: https://creativecommons.org/licenses/by/4.0/
month: '09'
oa: 1
oa_version: Published Version
publication: Nature Communications
publication_identifier:
issn:
- 2041-1723
publication_status: published
publisher: Springer Nature
quality_controlled: '1'
related_material:
link:
- relation: erratum
url: https://doi.org/10.1038/s41467-020-19720-x
status: public
title: Persistent and reversible solid iodine electrodeposition in nanoporous carbons
tmp:
image: /images/cc_by.png
legal_code_url: https://creativecommons.org/licenses/by/4.0/legalcode
name: Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)
short: CC BY (4.0)
type: journal_article
user_id: 4359f0d1-fa6c-11eb-b949-802e58b17ae8
volume: 11
year: '2020'
...
---
_id: '7672'
abstract:
- lang: eng
text: Large overpotentials upon discharge and charge of Li-O2 cells have motivated
extensive research into heterogeneous solid electrocatalysts or non-carbon electrodes
with the aim to improve rate capability, round-trip efficiency and cycle life.
These features are equally governed by parasitic reactions, which are now recognized
to be caused by the highly reactive singlet oxygen (1O2). However, the link between
the presence of electrocatalysts and 1O2 formation in metal-O2 cells is unknown.
Here, we show that, compared to pristine carbon black electrodes, a representative
selection of electrocatalysts or non-carbon electrodes (noble metal, transition
metal compounds) may both slightly reduce or severely increase the 1O2 formation.
The individual reaction steps, where the surfaces impact the 1O2 yield are deciphered,
showing that 1O2 yield from superoxide disproportionation as well as the decomposition
of trace H2O2 are sensitive to catalysts. Transition metal compounds in general
are prone to increase 1O2.
acknowledgement: S.A.F. thanks the International Society of Electrochemistry for awarding
the Tajima Prize 2019 “in recognition of outstanding re- searches on Li-Air batteries
by the use of a range of in-situ elec- trochemical methods to achieve comprehensive
understanding of the reactions taking place at the oxygen electrode”. This article
is dedicated to the special issue of Electrochmica Acta associated with the awarding
conference. S.A.F. is indebted to and the Austrian Federal Ministry of Science,
Research and Economy and the Austrian Research Promotion Agency (grant No. 845364
) and the European Research Council (ERC) under the European Union’s Horizon 2020
research and innovation programme (grant agreement No 636069). The authors thank
J. Schlegl for manufacturing instrumentation, M. Winkler of Acib GmbH and G. Strohmeier
for help with HPLC measurements, S. Eder for cyclic voltammetry measurements, and
C. Slugovc for discussions and continuous support. We thank S. Borisov for access
and advice with fluorescence measurements. We thank EL-Cell GmbH, Hamburg, Germany
for providing the PAT-Cell-Press electrochemical cell.
article_number: '137175'
article_processing_charge: Yes (via OA deal)
article_type: original
author:
- first_name: Aleksej
full_name: Samojlov, Aleksej
last_name: Samojlov
- first_name: David
full_name: Schuster, David
last_name: Schuster
- first_name: Jürgen
full_name: Kahr, Jürgen
last_name: Kahr
- first_name: Stefan Alexander
full_name: Freunberger, Stefan Alexander
id: A8CA28E6-CE23-11E9-AD2D-EC27E6697425
last_name: Freunberger
orcid: 0000-0003-2902-5319
citation:
ama: Samojlov A, Schuster D, Kahr J, Freunberger SA. Surface and catalyst driven
singlet oxygen formation in Li-O2 cells. Electrochimica Acta. 2020;362(12).
doi:10.1016/j.electacta.2020.137175
apa: Samojlov, A., Schuster, D., Kahr, J., & Freunberger, S. A. (2020). Surface
and catalyst driven singlet oxygen formation in Li-O2 cells. Electrochimica
Acta. Elsevier. https://doi.org/10.1016/j.electacta.2020.137175
chicago: Samojlov, Aleksej, David Schuster, Jürgen Kahr, and Stefan Alexander Freunberger.
“Surface and Catalyst Driven Singlet Oxygen Formation in Li-O2 Cells.” Electrochimica
Acta. Elsevier, 2020. https://doi.org/10.1016/j.electacta.2020.137175.
ieee: A. Samojlov, D. Schuster, J. Kahr, and S. A. Freunberger, “Surface and catalyst
driven singlet oxygen formation in Li-O2 cells,” Electrochimica Acta, vol.
362, no. 12. Elsevier, 2020.
ista: Samojlov A, Schuster D, Kahr J, Freunberger SA. 2020. Surface and catalyst
driven singlet oxygen formation in Li-O2 cells. Electrochimica Acta. 362(12),
137175.
mla: Samojlov, Aleksej, et al. “Surface and Catalyst Driven Singlet Oxygen Formation
in Li-O2 Cells.” Electrochimica Acta, vol. 362, no. 12, 137175, Elsevier,
2020, doi:10.1016/j.electacta.2020.137175.
short: A. Samojlov, D. Schuster, J. Kahr, S.A. Freunberger, Electrochimica Acta
362 (2020).
date_created: 2020-04-20T19:29:31Z
date_published: 2020-12-01T00:00:00Z
date_updated: 2023-08-21T06:14:21Z
day: '01'
ddc:
- '540'
department:
- _id: StFr
doi: 10.1016/j.electacta.2020.137175
external_id:
isi:
- '000582869700060'
file:
- access_level: open_access
checksum: 1ab1aa2024d431e2a089ea336bc08298
content_type: application/pdf
creator: dernst
date_created: 2020-10-01T13:20:45Z
date_updated: 2020-10-01T13:20:45Z
file_id: '8593'
file_name: 2020_ElectrochimicaActa_Samojlov.pdf
file_size: 1404030
relation: main_file
success: 1
file_date_updated: 2020-10-01T13:20:45Z
has_accepted_license: '1'
intvolume: ' 362'
isi: 1
issue: '12'
language:
- iso: eng
license: https://creativecommons.org/licenses/by-nc-nd/4.0/
month: '12'
oa: 1
oa_version: Published Version
publication: Electrochimica Acta
publication_status: published
publisher: Elsevier
quality_controlled: '1'
scopus_import: '1'
status: public
title: Surface and catalyst driven singlet oxygen formation in Li-O2 cells
tmp:
image: /images/cc_by_nc_nd.png
legal_code_url: https://creativecommons.org/licenses/by-nc-nd/4.0/legalcode
name: Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International
(CC BY-NC-ND 4.0)
short: CC BY-NC-ND (4.0)
type: journal_article
user_id: 4359f0d1-fa6c-11eb-b949-802e58b17ae8
volume: 362
year: '2020'
...
---
_id: '9780'
abstract:
- lang: eng
text: "PADREV : 4,4'-dimethoxy[1,1'-biphenyl]-2,2',5,5'-tetrol\r\nSpace Group: C
2 (5), Cell: a 24.488(16)Å b 5.981(4)Å c 3.911(3)Å, α 90° β 91.47(3)° γ 90°"
article_processing_charge: No
author:
- first_name: Werner
full_name: Schlemmer, Werner
last_name: Schlemmer
- first_name: Philipp
full_name: Nothdurft, Philipp
last_name: Nothdurft
- first_name: Alina
full_name: Petzold, Alina
last_name: Petzold
- first_name: Gisbert
full_name: Riess, Gisbert
last_name: Riess
- first_name: Philipp
full_name: Frühwirt, Philipp
last_name: Frühwirt
- first_name: Max
full_name: Schmallegger, Max
last_name: Schmallegger
- first_name: Georg
full_name: Gescheidt-Demner, Georg
last_name: Gescheidt-Demner
- first_name: Roland
full_name: Fischer, Roland
last_name: Fischer
- first_name: Stefan Alexander
full_name: Freunberger, Stefan Alexander
id: A8CA28E6-CE23-11E9-AD2D-EC27E6697425
last_name: Freunberger
orcid: 0000-0003-2902-5319
- first_name: Wolfgang
full_name: Kern, Wolfgang
last_name: Kern
- first_name: Stefan
full_name: Spirk, Stefan
last_name: Spirk
citation:
ama: 'Schlemmer W, Nothdurft P, Petzold A, et al. CCDC 1991959: Experimental Crystal
Structure Determination. 2020. doi:10.5517/ccdc.csd.cc24vsrk'
apa: 'Schlemmer, W., Nothdurft, P., Petzold, A., Riess, G., Frühwirt, P., Schmallegger,
M., … Spirk, S. (2020). CCDC 1991959: Experimental Crystal Structure Determination.
CCDC. https://doi.org/10.5517/ccdc.csd.cc24vsrk'
chicago: 'Schlemmer, Werner, Philipp Nothdurft, Alina Petzold, Gisbert Riess, Philipp
Frühwirt, Max Schmallegger, Georg Gescheidt-Demner, et al. “CCDC 1991959: Experimental
Crystal Structure Determination.” CCDC, 2020. https://doi.org/10.5517/ccdc.csd.cc24vsrk.'
ieee: 'W. Schlemmer et al., “CCDC 1991959: Experimental Crystal Structure
Determination.” CCDC, 2020.'
ista: 'Schlemmer W, Nothdurft P, Petzold A, Riess G, Frühwirt P, Schmallegger M,
Gescheidt-Demner G, Fischer R, Freunberger SA, Kern W, Spirk S. 2020. CCDC 1991959:
Experimental Crystal Structure Determination, CCDC, 10.5517/ccdc.csd.cc24vsrk.'
mla: 'Schlemmer, Werner, et al. CCDC 1991959: Experimental Crystal Structure
Determination. CCDC, 2020, doi:10.5517/ccdc.csd.cc24vsrk.'
short: W. Schlemmer, P. Nothdurft, A. Petzold, G. Riess, P. Frühwirt, M. Schmallegger,
G. Gescheidt-Demner, R. Fischer, S.A. Freunberger, W. Kern, S. Spirk, (2020).
date_created: 2021-08-06T07:41:07Z
date_published: 2020-03-22T00:00:00Z
date_updated: 2023-09-05T16:03:47Z
day: '22'
department:
- _id: StFr
doi: 10.5517/ccdc.csd.cc24vsrk
main_file_link:
- open_access: '1'
url: https://dx.doi.org/10.5517/ccdc.csd.cc24vsrk
month: '03'
oa: 1
oa_version: Published Version
publisher: CCDC
related_material:
record:
- id: '8329'
relation: used_in_publication
status: public
status: public
title: 'CCDC 1991959: Experimental Crystal Structure Determination'
type: research_data_reference
user_id: 6785fbc1-c503-11eb-8a32-93094b40e1cf
year: '2020'
...