[{"article_processing_charge":"Yes (via OA deal)","user_id":"4359f0d1-fa6c-11eb-b949-802e58b17ae8","type":"journal_article","date_updated":"2023-08-21T06:14:21Z","oa_version":"Published Version","day":"01","language":[{"iso":"eng"}],"license":"https://creativecommons.org/licenses/by-nc-nd/4.0/","doi":"10.1016/j.electacta.2020.137175","department":[{"_id":"StFr"}],"has_accepted_license":"1","acknowledgement":"S.A.F. thanks the International Society of Electrochemistry for awarding the Tajima Prize 2019 “in recognition of outstanding re- searches on Li-Air batteries by the use of a range of in-situ elec- trochemical methods to achieve comprehensive understanding of the reactions taking place at the oxygen electrode”. This article is dedicated to the special issue of Electrochmica Acta associated with the awarding conference. S.A.F. is indebted to and the Austrian Federal Ministry of Science, Research and Economy and the Austrian Research Promotion Agency (grant No. 845364 ) and the European Research Council (ERC) under the European Union’s Horizon 2020 research and innovation programme (grant agreement No 636069). The authors thank J. Schlegl for manufacturing instrumentation, M. Winkler of Acib GmbH and G. Strohmeier for help with HPLC measurements, S. Eder for cyclic voltammetry measurements, and C. Slugovc for discussions and continuous support. We thank S. Borisov for access and advice with fluorescence measurements. We thank EL-Cell GmbH, Hamburg, Germany for providing the PAT-Cell-Press electrochemical cell.","date_published":"2020-12-01T00:00:00Z","file":[{"access_level":"open_access","file_name":"2020_ElectrochimicaActa_Samojlov.pdf","checksum":"1ab1aa2024d431e2a089ea336bc08298","file_id":"8593","date_updated":"2020-10-01T13:20:45Z","success":1,"file_size":1404030,"creator":"dernst","content_type":"application/pdf","date_created":"2020-10-01T13:20:45Z","relation":"main_file"}],"external_id":{"isi":["000582869700060"]},"scopus_import":"1","citation":{"apa":"Samojlov, A., Schuster, D., Kahr, J., &#38; Freunberger, S. A. (2020). Surface and catalyst driven singlet oxygen formation in Li-O2 cells. <i>Electrochimica Acta</i>. Elsevier. <a href=\"https://doi.org/10.1016/j.electacta.2020.137175\">https://doi.org/10.1016/j.electacta.2020.137175</a>","mla":"Samojlov, Aleksej, et al. “Surface and Catalyst Driven Singlet Oxygen Formation in Li-O2 Cells.” <i>Electrochimica Acta</i>, vol. 362, no. 12, 137175, Elsevier, 2020, doi:<a href=\"https://doi.org/10.1016/j.electacta.2020.137175\">10.1016/j.electacta.2020.137175</a>.","ieee":"A. Samojlov, D. Schuster, J. Kahr, and S. A. Freunberger, “Surface and catalyst driven singlet oxygen formation in Li-O2 cells,” <i>Electrochimica Acta</i>, vol. 362, no. 12. Elsevier, 2020.","ama":"Samojlov A, Schuster D, Kahr J, Freunberger SA. Surface and catalyst driven singlet oxygen formation in Li-O2 cells. <i>Electrochimica Acta</i>. 2020;362(12). doi:<a href=\"https://doi.org/10.1016/j.electacta.2020.137175\">10.1016/j.electacta.2020.137175</a>","ista":"Samojlov A, Schuster D, Kahr J, Freunberger SA. 2020. Surface and catalyst driven singlet oxygen formation in Li-O2 cells. Electrochimica Acta. 362(12), 137175.","chicago":"Samojlov, Aleksej, David Schuster, Jürgen Kahr, and Stefan Alexander Freunberger. “Surface and Catalyst Driven Singlet Oxygen Formation in Li-O2 Cells.” <i>Electrochimica Acta</i>. Elsevier, 2020. <a href=\"https://doi.org/10.1016/j.electacta.2020.137175\">https://doi.org/10.1016/j.electacta.2020.137175</a>.","short":"A. Samojlov, D. Schuster, J. Kahr, S.A. Freunberger, Electrochimica Acta 362 (2020)."},"author":[{"full_name":"Samojlov, Aleksej","first_name":"Aleksej","last_name":"Samojlov"},{"full_name":"Schuster, David","last_name":"Schuster","first_name":"David"},{"first_name":"Jürgen","last_name":"Kahr","full_name":"Kahr, Jürgen"},{"last_name":"Freunberger","first_name":"Stefan Alexander","orcid":"0000-0003-2902-5319","full_name":"Freunberger, Stefan Alexander","id":"A8CA28E6-CE23-11E9-AD2D-EC27E6697425"}],"quality_controlled":"1","tmp":{"legal_code_url":"https://creativecommons.org/licenses/by-nc-nd/4.0/legalcode","short":"CC BY-NC-ND (4.0)","name":"Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0)","image":"/images/cc_by_nc_nd.png"},"year":"2020","title":"Surface and catalyst driven singlet oxygen formation in Li-O2 cells","publication":"Electrochimica Acta","oa":1,"ddc":["540"],"_id":"7672","publication_status":"published","abstract":[{"text":"Large overpotentials upon discharge and charge of Li-O2 cells have motivated extensive research into heterogeneous solid electrocatalysts or non-carbon electrodes with the aim to improve rate capability, round-trip efficiency and cycle life. These features are equally governed by parasitic reactions, which are now recognized to be caused by the highly reactive singlet oxygen (1O2). However, the link between the presence of electrocatalysts and 1O2 formation in metal-O2 cells is unknown. Here, we show that, compared to pristine carbon black electrodes, a representative selection of electrocatalysts or non-carbon electrodes (noble metal, transition metal compounds) may both slightly reduce or severely increase the 1O2 formation. The individual reaction steps, where the surfaces impact the 1O2 yield are deciphered, showing that 1O2 yield from superoxide disproportionation as well as the decomposition of trace H2O2 are sensitive to catalysts. Transition metal compounds in general are prone to increase 1O2.","lang":"eng"}],"issue":"12","volume":362,"file_date_updated":"2020-10-01T13:20:45Z","publisher":"Elsevier","article_type":"original","intvolume":"       362","isi":1,"date_created":"2020-04-20T19:29:31Z","month":"12","status":"public","article_number":"137175"},{"scopus_import":"1","publication_identifier":{"eissn":["1521-3773"],"issn":["1433-7851"]},"external_id":{"pmid":["32390281"],"isi":["000541488700001"]},"file":[{"content_type":"application/pdf","creator":"dernst","file_size":1966184,"relation":"main_file","date_created":"2020-09-17T08:57:16Z","checksum":"7b6c2fc20e9b0ff4353352f7a7004e2d","file_name":"2020_AngChemieINT_Buchal.pdf","access_level":"open_access","success":1,"file_id":"8400","date_updated":"2020-09-17T08:57:16Z"}],"date_published":"2020-09-07T00:00:00Z","page":"15913-1591","department":[{"_id":"StFr"}],"has_accepted_license":"1","doi":"10.1002/anie.202005378","language":[{"iso":"eng"}],"oa_version":"Published Version","date_updated":"2023-09-05T16:02:53Z","type":"journal_article","day":"07","article_processing_charge":"No","user_id":"c635000d-4b10-11ee-a964-aac5a93f6ac1","month":"09","date_created":"2020-05-14T21:00:30Z","status":"public","intvolume":"        59","isi":1,"file_date_updated":"2020-09-17T08:57:16Z","article_type":"original","publisher":"Wiley","issue":"37","volume":59,"abstract":[{"lang":"eng","text":"Water-in-salt electrolytes based on highly concentrated bis(trifluoromethyl)sulfonimide (TFSI) promise aqueous electrolytes with stabilities nearing 3 V. However, especially with an electrode approaching the cathodic (reductive) stability, cycling stability is insufficient. While stability critically relies on a solid electrolyte interphase (SEI), the mechanism behind the cathodic stability limit remains unclear. Here, we reveal two distinct reduction potentials for the chemical environments of 'free' and 'bound' water and that both contribute to SEI formation. Free-water is reduced ~1V above bound water in a hydrogen evolution reaction (HER) and responsible for SEI formation via reactive intermediates of the HER; concurrent LiTFSI precipitation/dissolution establishes a dynamic interface. The free-water population emerges, therefore, as the handle to extend the cathodic limit of aqueous electrolytes and the battery cycling stability. "}],"publication_status":"published","pmid":1,"title":"Competitive salt precipitation/dissolution during free‐water reduction in water‐in‐salt electrolyte","publication":"Angewandte Chemie International Edition","_id":"7847","oa":1,"ddc":["540","546"],"tmp":{"image":"/images/cc_by.png","name":"Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)","short":"CC BY (4.0)","legal_code_url":"https://creativecommons.org/licenses/by/4.0/legalcode"},"year":"2020","citation":{"apa":"Bouchal, R., Li, Z., Bongu, C., Le Vot, S., Berthelot, R., Rotenberg, B., … Fontaine, O. (2020). Competitive salt precipitation/dissolution during free‐water reduction in water‐in‐salt electrolyte. <i>Angewandte Chemie International Edition</i>. Wiley. <a href=\"https://doi.org/10.1002/anie.202005378\">https://doi.org/10.1002/anie.202005378</a>","mla":"Bouchal, Roza, et al. “Competitive Salt Precipitation/Dissolution during Free‐water Reduction in Water‐in‐salt Electrolyte.” <i>Angewandte Chemie International Edition</i>, vol. 59, no. 37, Wiley, 2020, pp. 15913–1591, doi:<a href=\"https://doi.org/10.1002/anie.202005378\">10.1002/anie.202005378</a>.","ama":"Bouchal R, Li Z, Bongu C, et al. Competitive salt precipitation/dissolution during free‐water reduction in water‐in‐salt electrolyte. <i>Angewandte Chemie International Edition</i>. 2020;59(37):15913-1591. doi:<a href=\"https://doi.org/10.1002/anie.202005378\">10.1002/anie.202005378</a>","ieee":"R. Bouchal <i>et al.</i>, “Competitive salt precipitation/dissolution during free‐water reduction in water‐in‐salt electrolyte,” <i>Angewandte Chemie International Edition</i>, vol. 59, no. 37. Wiley, pp. 15913–1591, 2020.","ista":"Bouchal R, Li Z, Bongu C, Le Vot S, Berthelot R, Rotenberg B, Favier F, Freunberger SA, Salanne M, Fontaine O. 2020. Competitive salt precipitation/dissolution during free‐water reduction in water‐in‐salt electrolyte. Angewandte Chemie International Edition. 59(37), 15913–1591.","short":"R. Bouchal, Z. Li, C. Bongu, S. Le Vot, R. Berthelot, B. Rotenberg, F. Favier, S.A. Freunberger, M. Salanne, O. Fontaine, Angewandte Chemie International Edition 59 (2020) 15913–1591.","chicago":"Bouchal, Roza, Zhujie Li, Chandra Bongu, Steven Le Vot, Romain Berthelot, Benjamin Rotenberg, Fréderic Favier, Stefan Alexander Freunberger, Mathieu Salanne, and Olivier Fontaine. “Competitive Salt Precipitation/Dissolution during Free‐water Reduction in Water‐in‐salt Electrolyte.” <i>Angewandte Chemie International Edition</i>. Wiley, 2020. <a href=\"https://doi.org/10.1002/anie.202005378\">https://doi.org/10.1002/anie.202005378</a>."},"quality_controlled":"1","author":[{"first_name":"Roza","last_name":"Bouchal","full_name":"Bouchal, Roza"},{"full_name":"Li, Zhujie","first_name":"Zhujie","last_name":"Li"},{"full_name":"Bongu, Chandra","last_name":"Bongu","first_name":"Chandra"},{"full_name":"Le Vot, Steven","last_name":"Le Vot","first_name":"Steven"},{"last_name":"Berthelot","first_name":"Romain","full_name":"Berthelot, Romain"},{"last_name":"Rotenberg","first_name":"Benjamin","full_name":"Rotenberg, Benjamin"},{"full_name":"Favier, Fréderic","first_name":"Fréderic","last_name":"Favier"},{"id":"A8CA28E6-CE23-11E9-AD2D-EC27E6697425","orcid":"0000-0003-2902-5319","full_name":"Freunberger, Stefan Alexander","last_name":"Freunberger","first_name":"Stefan Alexander"},{"full_name":"Salanne, Mathieu","last_name":"Salanne","first_name":"Mathieu"},{"full_name":"Fontaine, Olivier","first_name":"Olivier","last_name":"Fontaine"}]},{"title":"Lithium-oxygen batteries and related systems: Potential, status, and future","publication":"Chemical Reviews","pmid":1,"oa":1,"ddc":["540"],"_id":"7985","publication_status":"published","abstract":[{"lang":"eng","text":"The goal of limiting global warming to 1.5 °C requires a drastic reduction in CO2 emissions across many sectors of the world economy. Batteries are vital to this endeavor, whether used in electric vehicles, to store renewable electricity, or in aviation. Present lithium-ion technologies are preparing the public for this inevitable change, but their maximum theoretical specific capacity presents a limitation. Their high cost is another concern for commercial viability. Metal–air batteries have the highest theoretical energy density of all possible secondary battery technologies and could yield step changes in energy storage, if their practical difficulties could be overcome. The scope of this review is to provide an objective, comprehensive, and authoritative assessment of the intensive work invested in nonaqueous rechargeable metal–air batteries over the past few years, which identified the key problems and guides directions to solve them. We focus primarily on the challenges and outlook for Li–O2 cells but include Na–O2, K–O2, and Mg–O2 cells for comparison. Our review highlights the interdisciplinary nature of this field that involves a combination of materials chemistry, electrochemistry, computation, microscopy, spectroscopy, and surface science. The mechanisms of O2 reduction and evolution are considered in the light of recent findings, along with developments in positive and negative electrodes, electrolytes, electrocatalysis on surfaces and in solution, and the degradative effect of singlet oxygen, which is typically formed in Li–O2 cells."}],"citation":{"mla":"Kwak, WJ, et al. “Lithium-Oxygen Batteries and Related Systems: Potential, Status, and Future.” <i>Chemical Reviews</i>, vol. 120, no. 14, American Chemical Society, 2020, pp. 6626–83, doi:<a href=\"https://doi.org/10.1021/acs.chemrev.9b00609\">10.1021/acs.chemrev.9b00609</a>.","apa":"Kwak, W., Sharon, D., Xia, C., Kim, H., Johnson, L., Bruce, P., … Aurbach, D. (2020). Lithium-oxygen batteries and related systems: Potential, status, and future. <i>Chemical Reviews</i>. American Chemical Society. <a href=\"https://doi.org/10.1021/acs.chemrev.9b00609\">https://doi.org/10.1021/acs.chemrev.9b00609</a>","short":"W. Kwak, D. Sharon, C. Xia, H. Kim, L. Johnson, P. Bruce, L. Nazar, Y. Sun, A. Frimer, M. Noked, S.A. Freunberger, D. Aurbach, Chemical Reviews 120 (2020) 6626–6683.","chicago":"Kwak, WJ, D Sharon, C Xia, H Kim, LR Johnson, PG Bruce, LF Nazar, et al. “Lithium-Oxygen Batteries and Related Systems: Potential, Status, and Future.” <i>Chemical Reviews</i>. American Chemical Society, 2020. <a href=\"https://doi.org/10.1021/acs.chemrev.9b00609\">https://doi.org/10.1021/acs.chemrev.9b00609</a>.","ista":"Kwak W, Sharon D, Xia C, Kim H, Johnson L, Bruce P, Nazar L, Sun Y, Frimer A, Noked M, Freunberger SA, Aurbach D. 2020. Lithium-oxygen batteries and related systems: Potential, status, and future. Chemical Reviews. 120(14), 6626–6683.","ieee":"W. Kwak <i>et al.</i>, “Lithium-oxygen batteries and related systems: Potential, status, and future,” <i>Chemical Reviews</i>, vol. 120, no. 14. American Chemical Society, pp. 6626–6683, 2020.","ama":"Kwak W, Sharon D, Xia C, et al. Lithium-oxygen batteries and related systems: Potential, status, and future. <i>Chemical Reviews</i>. 2020;120(14):6626-6683. doi:<a href=\"https://doi.org/10.1021/acs.chemrev.9b00609\">10.1021/acs.chemrev.9b00609</a>"},"quality_controlled":"1","author":[{"first_name":"WJ","last_name":"Kwak","full_name":"Kwak, WJ"},{"first_name":"D","last_name":"Sharon","full_name":"Sharon, D"},{"full_name":"Xia, C","first_name":"C","last_name":"Xia"},{"first_name":"H","last_name":"Kim","full_name":"Kim, H"},{"full_name":"Johnson, LR","last_name":"Johnson","first_name":"LR"},{"first_name":"PG","last_name":"Bruce","full_name":"Bruce, PG"},{"full_name":"Nazar, LF","first_name":"LF","last_name":"Nazar"},{"full_name":"Sun, YK","last_name":"Sun","first_name":"YK"},{"full_name":"Frimer, AA","first_name":"AA","last_name":"Frimer"},{"full_name":"Noked, M","last_name":"Noked","first_name":"M"},{"id":"A8CA28E6-CE23-11E9-AD2D-EC27E6697425","orcid":"0000-0003-2902-5319","full_name":"Freunberger, Stefan Alexander","first_name":"Stefan Alexander","last_name":"Freunberger"},{"last_name":"Aurbach","first_name":"D","full_name":"Aurbach, D"}],"year":"2020","intvolume":"       120","isi":1,"date_created":"2020-06-19T08:42:47Z","month":"03","status":"public","volume":120,"issue":"14","file_date_updated":"2020-07-14T12:48:06Z","publisher":"American Chemical Society","article_type":"review","language":[{"iso":"eng"}],"doi":"10.1021/acs.chemrev.9b00609","has_accepted_license":"1","department":[{"_id":"StFr"}],"acknowledgement":"S.A.F. is indebted to the European Research Council (ERC) under the European Union’s\r\nHorizon 2020 research and innovation programme (grant agreement No 636069).","user_id":"c635000d-4b10-11ee-a964-aac5a93f6ac1","article_processing_charge":"No","date_updated":"2023-09-05T12:04:28Z","type":"journal_article","oa_version":"Submitted Version","day":"05","publication_identifier":{"issn":["0009-2665"],"eissn":["1520-6890"]},"scopus_import":"1","date_published":"2020-03-05T00:00:00Z","external_id":{"isi":["000555413600008"],"pmid":["32134255"]},"file":[{"date_updated":"2020-07-14T12:48:06Z","file_id":"8060","checksum":"1a683353d46c5841c8bb2ee0a56ac7be","file_name":"ChemRev_final.pdf","access_level":"open_access","relation":"main_file","date_created":"2020-06-29T16:36:01Z","content_type":"application/pdf","creator":"sfreunbe","file_size":8525678}],"page":"6626-6683"},{"publication_identifier":{"issn":["0044-8249"],"eissn":["1521-3757"]},"scopus_import":"1","page":"16047-16051","date_published":"2020-09-07T00:00:00Z","file":[{"relation":"main_file","date_created":"2020-09-17T08:59:43Z","file_size":1904552,"content_type":"application/pdf","creator":"dernst","success":1,"file_id":"8401","date_updated":"2020-09-17T08:59:43Z","file_name":"2020_AngChemieDE_Bouchal.pdf","checksum":"7dd0a56f6bd5de08ea75b1ec388c91bc","access_level":"open_access"}],"language":[{"iso":"eng"}],"doi":"10.1002/ange.202005378","department":[{"_id":"StFr"}],"has_accepted_license":"1","user_id":"c635000d-4b10-11ee-a964-aac5a93f6ac1","article_processing_charge":"No","day":"07","type":"journal_article","date_updated":"2023-09-05T15:47:50Z","oa_version":"Published Version","intvolume":"       132","status":"public","date_created":"2020-06-29T16:15:49Z","month":"09","issue":"37","volume":132,"publisher":"Wiley","article_type":"original","file_date_updated":"2020-09-17T08:59:43Z","oa":1,"ddc":["540","541"],"_id":"8057","publication":"Angewandte Chemie","title":"Competitive salt precipitation/dissolution during free‐water reduction in water‐in‐salt electrolyte","publication_status":"published","abstract":[{"lang":"eng","text":"Water-in-salt electrolytes based on highly concentrated bis(trifluoromethyl)sulfonimide (TFSI) promise aqueous electrolytes with stabilities approaching 3 V. However, especially with an electrode approaching the cathodic (reductive) stability, cycling stability is insufficient. While stability critically relies on a solid electrolyte interphase (SEI), the mechanism behind the cathodic stability limit remains unclear. Here, we reveal two distinct reduction potentials for the chemical environments of ‘free’ and ‘bound’ water and that both contribute to SEI formation. Free-water is reduced ~1V above bound water in a hydrogen evolution reaction (HER) and responsible for SEI formation via reactive intermediates of the HER; concurrent LiTFSI precipitation/dissolution establishes a dynamic interface. The free-water population emerges, therefore, as the handle to extend the cathodic limit of aqueous electrolytes and the battery cycling stability."}],"author":[{"full_name":"Bouchal, Roza","first_name":"Roza","last_name":"Bouchal"},{"first_name":"Zhujie","last_name":"Li","full_name":"Li, Zhujie"},{"first_name":"Chandra","last_name":"Bongu","full_name":"Bongu, Chandra"},{"last_name":"Le Vot","first_name":"Steven","full_name":"Le Vot, Steven"},{"full_name":"Berthelot, Romain","first_name":"Romain","last_name":"Berthelot"},{"last_name":"Rotenberg","first_name":"Benjamin","full_name":"Rotenberg, Benjamin"},{"full_name":"Favier, Frederic","last_name":"Favier","first_name":"Frederic"},{"last_name":"Freunberger","first_name":"Stefan Alexander","id":"A8CA28E6-CE23-11E9-AD2D-EC27E6697425","full_name":"Freunberger, Stefan Alexander","orcid":"0000-0003-2902-5319"},{"first_name":"Mathieu","last_name":"Salanne","full_name":"Salanne, Mathieu"},{"first_name":"Olivier","last_name":"Fontaine","full_name":"Fontaine, Olivier"}],"quality_controlled":"1","citation":{"ama":"Bouchal R, Li Z, Bongu C, et al. Competitive salt precipitation/dissolution during free‐water reduction in water‐in‐salt electrolyte. <i>Angewandte Chemie</i>. 2020;132(37):16047-16051. doi:<a href=\"https://doi.org/10.1002/ange.202005378\">10.1002/ange.202005378</a>","ieee":"R. Bouchal <i>et al.</i>, “Competitive salt precipitation/dissolution during free‐water reduction in water‐in‐salt electrolyte,” <i>Angewandte Chemie</i>, vol. 132, no. 37. Wiley, pp. 16047–16051, 2020.","ista":"Bouchal R, Li Z, Bongu C, Le Vot S, Berthelot R, Rotenberg B, Favier F, Freunberger SA, Salanne M, Fontaine O. 2020. Competitive salt precipitation/dissolution during free‐water reduction in water‐in‐salt electrolyte. Angewandte Chemie. 132(37), 16047–16051.","short":"R. Bouchal, Z. Li, C. Bongu, S. Le Vot, R. Berthelot, B. Rotenberg, F. Favier, S.A. Freunberger, M. Salanne, O. Fontaine, Angewandte Chemie 132 (2020) 16047–16051.","chicago":"Bouchal, Roza, Zhujie Li, Chandra Bongu, Steven Le Vot, Romain Berthelot, Benjamin Rotenberg, Frederic Favier, Stefan Alexander Freunberger, Mathieu Salanne, and Olivier Fontaine. “Competitive Salt Precipitation/Dissolution during Free‐water Reduction in Water‐in‐salt Electrolyte.” <i>Angewandte Chemie</i>. Wiley, 2020. <a href=\"https://doi.org/10.1002/ange.202005378\">https://doi.org/10.1002/ange.202005378</a>.","mla":"Bouchal, Roza, et al. “Competitive Salt Precipitation/Dissolution during Free‐water Reduction in Water‐in‐salt Electrolyte.” <i>Angewandte Chemie</i>, vol. 132, no. 37, Wiley, 2020, pp. 16047–51, doi:<a href=\"https://doi.org/10.1002/ange.202005378\">10.1002/ange.202005378</a>.","apa":"Bouchal, R., Li, Z., Bongu, C., Le Vot, S., Berthelot, R., Rotenberg, B., … Fontaine, O. (2020). Competitive salt precipitation/dissolution during free‐water reduction in water‐in‐salt electrolyte. <i>Angewandte Chemie</i>. Wiley. <a href=\"https://doi.org/10.1002/ange.202005378\">https://doi.org/10.1002/ange.202005378</a>"},"year":"2020","tmp":{"image":"/images/cc_by.png","name":"Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)","short":"CC BY (4.0)","legal_code_url":"https://creativecommons.org/licenses/by/4.0/legalcode"}},{"doi":"10.15479/AT:ISTA:8067","language":[{"iso":"eng"}],"department":[{"_id":"StFr"}],"has_accepted_license":"1","day":"01","type":"technical_report","date_updated":"2023-08-22T09:20:36Z","oa_version":"Published Version","user_id":"8b945eb4-e2f2-11eb-945a-df72226e66a9","article_processing_charge":"No","publication_identifier":{"issn":["2664-1690"]},"alternative_title":["IST Austria Technical Report"],"page":"63","date_published":"2020-07-01T00:00:00Z","keyword":["Battery","Lithium metal","Lithium-sulphur","Lithium-air","All-solid-state"],"file":[{"file_size":2612498,"content_type":"application/pdf","creator":"dernst","date_created":"2020-07-02T07:36:04Z","relation":"main_file","access_level":"open_access","file_name":"20200612_JPS_review_Li_metal_submitted.pdf","checksum":"d183ca1465a1cbb4f8db27875cd156f7","file_id":"8076","date_updated":"2020-07-14T12:48:08Z"}],"publication_status":"submitted","abstract":[{"text":"With the lithium-ion technology approaching its intrinsic limit with graphite-based anodes, lithium metal is recently receiving renewed interest from the battery community as potential high capacity anode for next-generation rechargeable batteries. In this focus paper, we review the main advances in this field since the first attempts in the\r\nmid-1970s. Strategies for enabling reversible cycling and avoiding dendrite growth are thoroughly discussed, including specific applications in all-solid-state (polymeric and inorganic), Lithium-sulphur and Li-O2 (air) batteries. A particular attention is paid to review recent developments in regard of prototype manufacturing and current state-ofthe-art of these battery technologies with respect to the 2030 targets of the EU Integrated Strategic Energy Technology Plan (SET-Plan) Action 7.","lang":"eng"}],"related_material":{"record":[{"id":"8361","relation":"later_version","status":"public"}]},"oa":1,"ddc":["540"],"_id":"8067","title":"Current status and future perspectives of Lithium metal batteries","year":"2020","author":[{"full_name":"Varzi, Alberto","last_name":"Varzi","first_name":"Alberto"},{"first_name":"Katharina","last_name":"Thanner","full_name":"Thanner, Katharina"},{"full_name":"Scipioni, Roberto","first_name":"Roberto","last_name":"Scipioni"},{"full_name":"Di Lecce, Daniele","last_name":"Di Lecce","first_name":"Daniele"},{"first_name":"Jusef","last_name":"Hassoun","full_name":"Hassoun, Jusef"},{"last_name":"Dörfler","first_name":"Susanne","full_name":"Dörfler, Susanne"},{"full_name":"Altheus, Holger","first_name":"Holger","last_name":"Altheus"},{"full_name":"Kaskel, Stefan","last_name":"Kaskel","first_name":"Stefan"},{"first_name":"Christian","last_name":"Prehal","full_name":"Prehal, Christian"},{"last_name":"Freunberger","first_name":"Stefan Alexander","id":"A8CA28E6-CE23-11E9-AD2D-EC27E6697425","orcid":"0000-0003-2902-5319","full_name":"Freunberger, Stefan Alexander"}],"citation":{"apa":"Varzi, A., Thanner, K., Scipioni, R., Di Lecce, D., Hassoun, J., Dörfler, S., … Freunberger, S. A. (n.d.). <i>Current status and future perspectives of Lithium metal batteries</i>. IST Austria. <a href=\"https://doi.org/10.15479/AT:ISTA:8067\">https://doi.org/10.15479/AT:ISTA:8067</a>","mla":"Varzi, Alberto, et al. <i>Current Status and Future Perspectives of Lithium Metal Batteries</i>. IST Austria, doi:<a href=\"https://doi.org/10.15479/AT:ISTA:8067\">10.15479/AT:ISTA:8067</a>.","chicago":"Varzi, Alberto, Katharina Thanner, Roberto Scipioni, Daniele Di Lecce, Jusef Hassoun, Susanne Dörfler, Holger Altheus, Stefan Kaskel, Christian Prehal, and Stefan Alexander Freunberger. <i>Current Status and Future Perspectives of Lithium Metal Batteries</i>. IST Austria, n.d. <a href=\"https://doi.org/10.15479/AT:ISTA:8067\">https://doi.org/10.15479/AT:ISTA:8067</a>.","short":"A. Varzi, K. Thanner, R. Scipioni, D. Di Lecce, J. Hassoun, S. Dörfler, H. Altheus, S. Kaskel, C. Prehal, S.A. Freunberger, Current Status and Future Perspectives of Lithium Metal Batteries, IST Austria, n.d.","ista":"Varzi A, Thanner K, Scipioni R, Di Lecce D, Hassoun J, Dörfler S, Altheus H, Kaskel S, Prehal C, Freunberger SA. Current status and future perspectives of Lithium metal batteries, IST Austria, 63p.","ieee":"A. Varzi <i>et al.</i>, <i>Current status and future perspectives of Lithium metal batteries</i>. IST Austria.","ama":"Varzi A, Thanner K, Scipioni R, et al. <i>Current Status and Future Perspectives of Lithium Metal Batteries</i>. IST Austria doi:<a href=\"https://doi.org/10.15479/AT:ISTA:8067\">10.15479/AT:ISTA:8067</a>"},"status":"public","date_created":"2020-06-30T07:37:39Z","month":"07","publisher":"IST Austria","file_date_updated":"2020-07-14T12:48:08Z"},{"month":"07","date_created":"2020-07-02T20:24:42Z","status":"public","file":[{"checksum":"6970d621984c03ebc2eee71adfe706dd","file_name":"AM.pdf","access_level":"open_access","file_id":"8082","date_updated":"2020-07-14T12:48:09Z","creator":"sfreunbe","content_type":"application/pdf","file_size":1129852,"relation":"main_file","date_created":"2020-07-02T20:21:59Z"},{"date_created":"2020-07-08T12:14:04Z","relation":"supplementary_material","content_type":"application/pdf","creator":"cziletti","file_size":945565,"file_id":"8102","date_updated":"2020-07-14T12:48:09Z","access_level":"open_access","file_name":"Supporting_Information.pdf","checksum":"cd74c7bd47d6e7163d54d67f074dcc36"}],"date_published":"2020-07-13T00:00:00Z","file_date_updated":"2020-07-14T12:48:09Z","title":"High specific capacitance supercapacitors from hierarchically organized all-cellulose composites","has_accepted_license":"1","_id":"8081","department":[{"_id":"StFr"}],"oa":1,"language":[{"iso":"eng"}],"ddc":["540"],"acknowledgement":"The authors M.A.H., S.S., R.E., and W.B. acknowledge the industrial partners Sappi Gratkorn, Zellstoff Pöls and Mondi Frantschach, the Austrian Research Promotion Agency (FFG), COMET, BMVIT, BMWFJ, the Province of Styria and Carinthia for their financial support of the K-project Flippr²-Process Integration. E.M. and S.A.F. are indebted to the European Research Council (ERC) under the European Union’s Horizon 2020 research and innovation program (grant agreement No 636069). W. T. and S. E. thank FWO (G.0C60.13N) and the European Union’s European Fund for Regional Development and Flanders Innovation & Entrepreneurship (Accelerate3 project, Interreg Vlaanderen-Nederland program) for financial support. W. T. also thanks the Provincie West-Vlaanderen (Belgium) for his Provincial Chair in Advanced Materials. S. B. thanks the European Regional Development Fund (EFRE) and the province of Upper Austria for financial support through the program IWB 2014-2020 (project BioCarb-K). AMR gratefully acknowledges funding support through the SC EPSCoR/IDeAProgram under Award #18-SR03, and the NASA EPSCoR Program under Award #NNH17ZHA002C. Icons in Scheme 1 were provided by Good Ware, monkik, photo3idea_studio, and OCHA from www.flaticon.com.","abstract":[{"text":"Here, we employ micro- and nanosized cellulose particles, namely paper fines and cellulose\r\nnanocrystals, to induce hierarchical organization over a wide length scale. After processing\r\nthem into carbonaceous materials, we demonstrate that these hierarchically organized materials\r\noutperform the best materials for supercapacitors operating with organic electrolytes reported\r\nin literature in terms of specific energy/power (Ragone plot) while showing hardly any capacity\r\nfade over 4,000 cycles. The highly porous materials feature a specific surface area as high as\r\n2500 m2ˑg-1 and exhibit pore sizes in the range of 0.5 to 200 nm as proven by scanning electron\r\nmicroscopy and N2 physisorption. The carbonaceous materials have been further investigated\r\nby X-ray photoelectron spectroscopy and RAMAN spectroscopy. Since paper fines are an\r\nunderutilized side stream in any paper production process, they are a cheap and highly available\r\nfeedstock to prepare carbonaceous materials with outstanding performance in electrochemical\r\napplications. ","lang":"eng"}],"publication_status":"submitted","citation":{"ista":"Hobisch MA, Mourad E, Fischer WJ, Prehal C, Eyley S, Childress A, Zankel A, Mautner A, Breitenbach S, Rao AM, Thielemans W, Freunberger SA, Eckhart R, Bauer W, Spirk S. High specific capacitance supercapacitors from hierarchically organized all-cellulose composites.","chicago":"Hobisch, Mathias A. , Eléonore  Mourad, Wolfgang J.  Fischer, Christian  Prehal, Samuel  Eyley, Anthony  Childress, Armin  Zankel, et al. “High Specific Capacitance Supercapacitors from Hierarchically Organized All-Cellulose Composites,” n.d.","short":"M.A. Hobisch, E. Mourad, W.J. Fischer, C. Prehal, S. Eyley, A. Childress, A. Zankel, A. Mautner, S. Breitenbach, A.M. Rao, W. Thielemans, S.A. Freunberger, R. Eckhart, W. Bauer, S. Spirk, (n.d.).","ama":"Hobisch MA, Mourad E, Fischer WJ, et al. High specific capacitance supercapacitors from hierarchically organized all-cellulose composites.","ieee":"M. A. Hobisch <i>et al.</i>, “High specific capacitance supercapacitors from hierarchically organized all-cellulose composites.” .","apa":"Hobisch, M. A., Mourad, E., Fischer, W. J., Prehal, C., Eyley, S., Childress, A., … Spirk, S. (n.d.). High specific capacitance supercapacitors from hierarchically organized all-cellulose composites.","mla":"Hobisch, Mathias A., et al. <i>High Specific Capacitance Supercapacitors from Hierarchically Organized All-Cellulose Composites</i>."},"author":[{"full_name":"Hobisch, Mathias A. ","first_name":"Mathias A. ","last_name":"Hobisch"},{"full_name":"Mourad, Eléonore ","first_name":"Eléonore ","last_name":"Mourad"},{"full_name":"Fischer, Wolfgang J. ","first_name":"Wolfgang J. ","last_name":"Fischer"},{"full_name":"Prehal, Christian ","last_name":"Prehal","first_name":"Christian "},{"full_name":"Eyley, Samuel ","first_name":"Samuel ","last_name":"Eyley"},{"full_name":"Childress, Anthony ","last_name":"Childress","first_name":"Anthony "},{"last_name":"Zankel","first_name":"Armin ","full_name":"Zankel, Armin "},{"last_name":"Mautner","first_name":"Andreas ","full_name":"Mautner, Andreas "},{"full_name":"Breitenbach, Stefan ","last_name":"Breitenbach","first_name":"Stefan "},{"first_name":"Apparao M. ","last_name":"Rao","full_name":"Rao, Apparao M. "},{"full_name":"Thielemans, Wim ","first_name":"Wim ","last_name":"Thielemans"},{"last_name":"Freunberger","first_name":"Stefan Alexander","id":"A8CA28E6-CE23-11E9-AD2D-EC27E6697425","orcid":"0000-0003-2902-5319","full_name":"Freunberger, Stefan Alexander"},{"full_name":"Eckhart, Rene ","last_name":"Eckhart","first_name":"Rene "},{"last_name":"Bauer","first_name":"Wolfgang ","full_name":"Bauer, Wolfgang "},{"full_name":"Spirk, Stefan ","last_name":"Spirk","first_name":"Stefan "}],"user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","article_processing_charge":"No","oa_version":"Submitted Version","date_updated":"2022-06-17T08:39:49Z","type":"preprint","year":"2020","day":"13"},{"abstract":[{"text":"PADREV : 4,4'-dimethoxy[1,1'-biphenyl]-2,2',5,5'-tetrol\r\nSpace Group: C 2 (5), Cell: a 24.488(16)Å b 5.981(4)Å c 3.911(3)Å, α 90° β 91.47(3)° γ 90°","lang":"eng"}],"_id":"9780","department":[{"_id":"StFr"}],"oa":1,"doi":"10.5517/ccdc.csd.cc24vsrk","related_material":{"record":[{"status":"public","relation":"used_in_publication","id":"8329"}]},"title":"CCDC 1991959: Experimental Crystal Structure Determination","year":"2020","day":"22","oa_version":"Published Version","type":"research_data_reference","date_updated":"2023-09-05T16:03:47Z","article_processing_charge":"No","author":[{"first_name":"Werner","last_name":"Schlemmer","full_name":"Schlemmer, Werner"},{"full_name":"Nothdurft, Philipp","first_name":"Philipp","last_name":"Nothdurft"},{"full_name":"Petzold, Alina","first_name":"Alina","last_name":"Petzold"},{"full_name":"Riess, Gisbert","last_name":"Riess","first_name":"Gisbert"},{"last_name":"Frühwirt","first_name":"Philipp","full_name":"Frühwirt, Philipp"},{"full_name":"Schmallegger, Max","last_name":"Schmallegger","first_name":"Max"},{"full_name":"Gescheidt-Demner, Georg","first_name":"Georg","last_name":"Gescheidt-Demner"},{"last_name":"Fischer","first_name":"Roland","full_name":"Fischer, Roland"},{"orcid":"0000-0003-2902-5319","full_name":"Freunberger, Stefan Alexander","id":"A8CA28E6-CE23-11E9-AD2D-EC27E6697425","first_name":"Stefan Alexander","last_name":"Freunberger"},{"first_name":"Wolfgang","last_name":"Kern","full_name":"Kern, Wolfgang"},{"last_name":"Spirk","first_name":"Stefan","full_name":"Spirk, Stefan"}],"user_id":"6785fbc1-c503-11eb-8a32-93094b40e1cf","main_file_link":[{"url":"https://dx.doi.org/10.5517/ccdc.csd.cc24vsrk","open_access":"1"}],"citation":{"mla":"Schlemmer, Werner, et al. <i>CCDC 1991959: Experimental Crystal Structure Determination</i>. CCDC, 2020, doi:<a href=\"https://doi.org/10.5517/ccdc.csd.cc24vsrk\">10.5517/ccdc.csd.cc24vsrk</a>.","apa":"Schlemmer, W., Nothdurft, P., Petzold, A., Riess, G., Frühwirt, P., Schmallegger, M., … Spirk, S. (2020). CCDC 1991959: Experimental Crystal Structure Determination. CCDC. <a href=\"https://doi.org/10.5517/ccdc.csd.cc24vsrk\">https://doi.org/10.5517/ccdc.csd.cc24vsrk</a>","ama":"Schlemmer W, Nothdurft P, Petzold A, et al. CCDC 1991959: Experimental Crystal Structure Determination. 2020. doi:<a href=\"https://doi.org/10.5517/ccdc.csd.cc24vsrk\">10.5517/ccdc.csd.cc24vsrk</a>","ieee":"W. Schlemmer <i>et al.</i>, “CCDC 1991959: Experimental Crystal Structure Determination.” CCDC, 2020.","chicago":"Schlemmer, Werner, Philipp Nothdurft, Alina Petzold, Gisbert Riess, Philipp Frühwirt, Max Schmallegger, Georg Gescheidt-Demner, et al. “CCDC 1991959: Experimental Crystal Structure Determination.” CCDC, 2020. <a href=\"https://doi.org/10.5517/ccdc.csd.cc24vsrk\">https://doi.org/10.5517/ccdc.csd.cc24vsrk</a>.","short":"W. Schlemmer, P. Nothdurft, A. Petzold, G. Riess, P. Frühwirt, M. Schmallegger, G. Gescheidt-Demner, R. Fischer, S.A. Freunberger, W. Kern, S. Spirk, (2020).","ista":"Schlemmer W, Nothdurft P, Petzold A, Riess G, Frühwirt P, Schmallegger M, Gescheidt-Demner G, Fischer R, Freunberger SA, Kern W, Spirk S. 2020. CCDC 1991959: Experimental Crystal Structure Determination, CCDC, <a href=\"https://doi.org/10.5517/ccdc.csd.cc24vsrk\">10.5517/ccdc.csd.cc24vsrk</a>."},"status":"public","month":"03","date_created":"2021-08-06T07:41:07Z","publisher":"CCDC","date_published":"2020-03-22T00:00:00Z"}]