[{"language":[{"iso":"eng"}],"month":"04","acknowledged_ssus":[{"_id":"EM-Fac"},{"_id":"NanoFab"}],"oa_version":"Published Version","project":[{"name":"International IST Doctoral Program","grant_number":"665385","call_identifier":"H2020","_id":"2564DBCA-B435-11E9-9278-68D0E5697425"}],"has_accepted_license":"1","status":"public","user_id":"8b945eb4-e2f2-11eb-945a-df72226e66a9","related_material":{"record":[{"status":"public","id":"10806","relation":"part_of_dissertation"},{"id":"10042","relation":"part_of_dissertation","status":"public"},{"id":"12237","relation":"part_of_dissertation","status":"public"},{"status":"public","relation":"part_of_dissertation","id":"9118"},{"status":"public","id":"10123","relation":"part_of_dissertation"}]},"file":[{"file_name":"Thesis_Calcabrini.docx","content_type":"application/vnd.openxmlformats-officedocument.wordprocessingml.document","date_updated":"2023-05-02T07:43:18Z","checksum":"9347b0e09425f56fdcede5d3528404dc","file_size":99627036,"date_created":"2023-05-02T07:43:18Z","creator":"mcalcabr","file_id":"12887","access_level":"closed","relation":"source_file"},{"date_created":"2023-05-02T07:42:45Z","file_size":8742220,"checksum":"2d188b76621086cd384f0b9264b0a576","date_updated":"2023-05-02T07:42:45Z","content_type":"application/pdf","file_name":"Thesis_Calcabrini_pdfa.pdf","success":1,"access_level":"open_access","relation":"main_file","file_id":"12888","creator":"mcalcabr"}],"supervisor":[{"orcid":"0000-0001-5013-2843","full_name":"Ibáñez, Maria","first_name":"Maria","last_name":"Ibáñez","id":"43C61214-F248-11E8-B48F-1D18A9856A87"}],"oa":1,"publication_identifier":{"isbn":["978-3-99078-028-2"],"issn":["2663-337X"]},"date_published":"2023-04-28T00:00:00Z","type":"dissertation","publisher":"Institute of Science and Technology Austria","file_date_updated":"2023-05-02T07:43:18Z","page":"82","ec_funded":1,"alternative_title":["ISTA Thesis"],"title":"Nanoparticle-based semiconductor solids: From synthesis to consolidation","publication_status":"published","department":[{"_id":"GradSch"},{"_id":"MaIb"}],"date_created":"2023-05-02T07:58:57Z","article_processing_charge":"No","author":[{"id":"45D7531A-F248-11E8-B48F-1D18A9856A87","orcid":"0000-0003-4566-5877","full_name":"Calcabrini, Mariano","first_name":"Mariano","last_name":"Calcabrini"}],"_id":"12885","ddc":["546","541"],"abstract":[{"lang":"eng","text":"High-performance semiconductors rely upon precise control of heat and charge transport. This can be achieved by precisely engineering defects in polycrystalline solids. There are multiple approaches to preparing such polycrystalline semiconductors, and the transformation of solution-processed colloidal nanoparticles is appealing because colloidal nanoparticles combine low cost with structural and compositional tunability along with rich surface chemistry. However, the multiple processes from nanoparticle synthesis to the final bulk nanocomposites are very complex. They involve nanoparticle purification, post-synthetic modifications, and finally consolidation (thermal treatments and densification). All these properties dictate the final material’s composition and microstructure, ultimately affecting its functional properties. This thesis explores the synthesis, surface chemistry and consolidation of colloidal semiconductor nanoparticles into dense solids. In particular, the transformations that take place during these processes, and their effect on the material’s transport properties are evaluated. "}],"degree_awarded":"PhD","doi":"10.15479/at:ista:12885","day":"28","date_updated":"2023-08-14T07:25:26Z","citation":{"ieee":"M. Calcabrini, “Nanoparticle-based semiconductor solids: From synthesis to consolidation,” Institute of Science and Technology Austria, 2023.","chicago":"Calcabrini, Mariano. “Nanoparticle-Based Semiconductor Solids: From Synthesis to Consolidation.” Institute of Science and Technology Austria, 2023. <a href=\"https://doi.org/10.15479/at:ista:12885\">https://doi.org/10.15479/at:ista:12885</a>.","apa":"Calcabrini, M. (2023). <i>Nanoparticle-based semiconductor solids: From synthesis to consolidation</i>. Institute of Science and Technology Austria. <a href=\"https://doi.org/10.15479/at:ista:12885\">https://doi.org/10.15479/at:ista:12885</a>","ama":"Calcabrini M. Nanoparticle-based semiconductor solids: From synthesis to consolidation. 2023. doi:<a href=\"https://doi.org/10.15479/at:ista:12885\">10.15479/at:ista:12885</a>","ista":"Calcabrini M. 2023. Nanoparticle-based semiconductor solids: From synthesis to consolidation. Institute of Science and Technology Austria.","short":"M. Calcabrini, Nanoparticle-Based Semiconductor Solids: From Synthesis to Consolidation, Institute of Science and Technology Austria, 2023.","mla":"Calcabrini, Mariano. <i>Nanoparticle-Based Semiconductor Solids: From Synthesis to Consolidation</i>. Institute of Science and Technology Austria, 2023, doi:<a href=\"https://doi.org/10.15479/at:ista:12885\">10.15479/at:ista:12885</a>."},"year":"2023"},{"oa_version":"None","month":"05","publication":"ACS Nano","language":[{"iso":"eng"}],"publication_identifier":{"eissn":["1936-086X"],"issn":["1936-0851"]},"type":"journal_article","date_published":"2023-05-09T00:00:00Z","status":"public","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","date_created":"2023-05-07T22:01:04Z","article_processing_charge":"No","department":[{"_id":"MaIb"}],"publication_status":"published","intvolume":"        17","title":"Thermoelectric performance of surface-engineered Cu1.5–xTe–Cu2Se nanocomposites","scopus_import":"1","_id":"12915","pmid":1,"issue":"9","author":[{"last_name":"Xing","first_name":"Congcong","full_name":"Xing, Congcong"},{"full_name":"Zhang, Yu","first_name":"Yu","last_name":"Zhang"},{"full_name":"Xiao, Ke","last_name":"Xiao","first_name":"Ke"},{"full_name":"Han, Xu","first_name":"Xu","last_name":"Han"},{"orcid":"0000-0001-7313-6740","full_name":"Liu, Yu","first_name":"Yu","last_name":"Liu","id":"2A70014E-F248-11E8-B48F-1D18A9856A87"},{"full_name":"Nan, Bingfei","first_name":"Bingfei","last_name":"Nan"},{"id":"1ffff7cd-ed76-11ed-8d5f-be5e7c364eb9","last_name":"Ramon","first_name":"Maria Garcia","full_name":"Ramon, Maria Garcia"},{"last_name":"Lim","first_name":"Khak Ho","full_name":"Lim, Khak Ho"},{"last_name":"Li","first_name":"Junshan","full_name":"Li, Junshan"},{"last_name":"Arbiol","first_name":"Jordi","full_name":"Arbiol, Jordi"},{"full_name":"Poudel, Bed","last_name":"Poudel","first_name":"Bed"},{"full_name":"Nozariasbmarz, Amin","first_name":"Amin","last_name":"Nozariasbmarz"},{"full_name":"Li, Wenjie","first_name":"Wenjie","last_name":"Li"},{"last_name":"Ibáñez","first_name":"Maria","full_name":"Ibáñez, Maria","orcid":"0000-0001-5013-2843","id":"43C61214-F248-11E8-B48F-1D18A9856A87"},{"full_name":"Cabot, Andreu","last_name":"Cabot","first_name":"Andreu"}],"publisher":"American Chemical Society","article_type":"original","quality_controlled":"1","page":"8442-8452","day":"09","doi":"10.1021/acsnano.3c00495","abstract":[{"text":"Cu2–xS and Cu2–xSe have recently been reported as promising thermoelectric (TE) materials for medium-temperature applications. In contrast, Cu2–xTe, another member of the copper chalcogenide family, typically exhibits low Seebeck coefficients that limit its potential to achieve a superior thermoelectric figure of merit, zT, particularly in the low-temperature range where this material could be effective. To address this, we investigated the TE performance of Cu1.5–xTe–Cu2Se nanocomposites by consolidating surface-engineered Cu1.5Te nanocrystals. This surface engineering strategy allows for precise adjustment of Cu/Te ratios and results in a reversible phase transition at around 600 K in Cu1.5–xTe–Cu2Se nanocomposites, as systematically confirmed by in situ high-temperature X-ray diffraction combined with differential scanning calorimetry analysis. The phase transition leads to a conversion from metallic-like to semiconducting-like TE properties. Additionally, a layer of Cu2Se generated around Cu1.5–xTe nanoparticles effectively inhibits Cu1.5–xTe grain growth, minimizing thermal conductivity and decreasing hole concentration. These properties indicate that copper telluride based compounds have a promising thermoelectric potential, translated into a high dimensionless zT of 1.3 at 560 K.","lang":"eng"}],"year":"2023","citation":{"ista":"Xing C, Zhang Y, Xiao K, Han X, Liu Y, Nan B, Ramon MG, Lim KH, Li J, Arbiol J, Poudel B, Nozariasbmarz A, Li W, Ibáñez M, Cabot A. 2023. Thermoelectric performance of surface-engineered Cu1.5–xTe–Cu2Se nanocomposites. ACS Nano. 17(9), 8442–8452.","short":"C. Xing, Y. Zhang, K. Xiao, X. Han, Y. Liu, B. Nan, M.G. Ramon, K.H. Lim, J. Li, J. Arbiol, B. Poudel, A. Nozariasbmarz, W. Li, M. Ibáñez, A. Cabot, ACS Nano 17 (2023) 8442–8452.","mla":"Xing, Congcong, et al. “Thermoelectric Performance of Surface-Engineered Cu1.5–XTe–Cu2Se Nanocomposites.” <i>ACS Nano</i>, vol. 17, no. 9, American Chemical Society, 2023, pp. 8442–52, doi:<a href=\"https://doi.org/10.1021/acsnano.3c00495\">10.1021/acsnano.3c00495</a>.","chicago":"Xing, Congcong, Yu Zhang, Ke Xiao, Xu Han, Yu Liu, Bingfei Nan, Maria Garcia Ramon, et al. “Thermoelectric Performance of Surface-Engineered Cu1.5–XTe–Cu2Se Nanocomposites.” <i>ACS Nano</i>. American Chemical Society, 2023. <a href=\"https://doi.org/10.1021/acsnano.3c00495\">https://doi.org/10.1021/acsnano.3c00495</a>.","ieee":"C. Xing <i>et al.</i>, “Thermoelectric performance of surface-engineered Cu1.5–xTe–Cu2Se nanocomposites,” <i>ACS Nano</i>, vol. 17, no. 9. American Chemical Society, pp. 8442–8452, 2023.","apa":"Xing, C., Zhang, Y., Xiao, K., Han, X., Liu, Y., Nan, B., … Cabot, A. (2023). Thermoelectric performance of surface-engineered Cu1.5–xTe–Cu2Se nanocomposites. <i>ACS Nano</i>. American Chemical Society. <a href=\"https://doi.org/10.1021/acsnano.3c00495\">https://doi.org/10.1021/acsnano.3c00495</a>","ama":"Xing C, Zhang Y, Xiao K, et al. Thermoelectric performance of surface-engineered Cu1.5–xTe–Cu2Se nanocomposites. <i>ACS Nano</i>. 2023;17(9):8442-8452. doi:<a href=\"https://doi.org/10.1021/acsnano.3c00495\">10.1021/acsnano.3c00495</a>"},"date_updated":"2023-10-04T11:29:22Z","external_id":{"pmid":["37071412"],"isi":["000976063200001"]},"isi":1,"acknowledgement":"The authors acknowledge support from the projects ENE2016-77798-C4-3-R and NANOGEN (PID2020-116093RB-C43) funded by MCIN/AEI/10.13039/501100011033/and by “ERDF A way of making Europe”, and by the “European Union”. K.X. and B.N. thank the China Scholarship Council (CSC) for scholarship support. The authors acknowledge funding from Generalitat de Catalunya 2017 SGR 327 and 2017 SGR 1246. ICN2 is supported by the Severo Ochoa program from the Spanish MCIN/AEI (Grant No.: CEX2021-001214-S). IREC and ICN2 are funded by the CERCA Programme/Generalitat de Catalunya. J.L. acknowledges support from the Natural Science Foundation of Sichuan province (2022NSFSC1229). Part of the present work was performed in the frameworks of Universitat de Barcelona Nanoscience Ph.D. program and Universitat Autònoma de Barcelona Materials Science Ph.D. program. Y.L. acknowledges funding from the National Natural Science Foundation of China (Grant No. 22209034) and the Innovation and Entrepreneurship Project of Overseas Returnees in Anhui Province (Grants No. 2022LCX002). K.H.L. acknowledges the financial support of the National Natural Science Foundation of China (Grant No. 22208293).","volume":17},{"date_created":"2022-03-06T23:01:54Z","department":[{"_id":"MaIb"}],"article_processing_charge":"No","publication_status":"published","intvolume":"         7","title":"Field-effect transistor with a plasmonic fiber optic gate electrode as a multivariable biosensor device","license":"https://creativecommons.org/licenses/by-nc-nd/4.0/","scopus_import":"1","_id":"10829","issue":"2","author":[{"first_name":"Roger","last_name":"Hasler","full_name":"Hasler, Roger"},{"first_name":"Ciril","last_name":"Reiner-Rozman","full_name":"Reiner-Rozman, Ciril"},{"full_name":"Fossati, Stefan","first_name":"Stefan","last_name":"Fossati"},{"last_name":"Aspermair","first_name":"Patrik","full_name":"Aspermair, Patrik"},{"full_name":"Dostalek, Jakub","last_name":"Dostalek","first_name":"Jakub"},{"id":"BB243B88-D767-11E9-B658-BC13E6697425","first_name":"Seungho","last_name":"Lee","orcid":"0000-0002-6962-8598","full_name":"Lee, Seungho"},{"id":"43C61214-F248-11E8-B48F-1D18A9856A87","full_name":"Ibáñez, Maria","orcid":"0000-0001-5013-2843","last_name":"Ibáñez","first_name":"Maria"},{"full_name":"Bintinger, Johannes","first_name":"Johannes","last_name":"Bintinger"},{"full_name":"Knoll, Wolfgang","first_name":"Wolfgang","last_name":"Knoll"}],"publisher":"American Chemical Society","article_type":"original","quality_controlled":"1","page":"504-512","file_date_updated":"2022-03-07T08:15:01Z","day":"08","doi":"10.1021/acssensors.1c02313","abstract":[{"text":"A novel multivariable system, combining a transistor with fiber optic-based surface plasmon resonance spectroscopy with the gate electrode simultaneously acting as the fiber optic sensor surface, is reported. The dual-mode sensor allows for discrimination of mass and charge contributions for binding assays on the same sensor surface. Furthermore, we optimize the sensor geometry by investigating the influence of the fiber area to transistor channel area ratio and distance. We show that larger fiber optic tip diameters are favorable for electronic and optical signals and demonstrate the reversibility of plasmon resonance wavelength shifts after electric field application. As a proof of principle, a layer-by-layer assembly of polyelectrolytes is performed to benchmark the system against multivariable sensing platforms with planar surface plasmon resonance configurations. Furthermore, the biosensing performance is assessed using a thrombin binding assay with surface-immobilized aptamers as receptors, allowing for the detection of medically relevant thrombin concentrations.","lang":"eng"}],"year":"2022","citation":{"ieee":"R. Hasler <i>et al.</i>, “Field-effect transistor with a plasmonic fiber optic gate electrode as a multivariable biosensor device,” <i>ACS Sensors</i>, vol. 7, no. 2. American Chemical Society, pp. 504–512, 2022.","chicago":"Hasler, Roger, Ciril Reiner-Rozman, Stefan Fossati, Patrik Aspermair, Jakub Dostalek, Seungho Lee, Maria Ibáñez, Johannes Bintinger, and Wolfgang Knoll. “Field-Effect Transistor with a Plasmonic Fiber Optic Gate Electrode as a Multivariable Biosensor Device.” <i>ACS Sensors</i>. American Chemical Society, 2022. <a href=\"https://doi.org/10.1021/acssensors.1c02313\">https://doi.org/10.1021/acssensors.1c02313</a>.","apa":"Hasler, R., Reiner-Rozman, C., Fossati, S., Aspermair, P., Dostalek, J., Lee, S., … Knoll, W. (2022). Field-effect transistor with a plasmonic fiber optic gate electrode as a multivariable biosensor device. <i>ACS Sensors</i>. American Chemical Society. <a href=\"https://doi.org/10.1021/acssensors.1c02313\">https://doi.org/10.1021/acssensors.1c02313</a>","ama":"Hasler R, Reiner-Rozman C, Fossati S, et al. Field-effect transistor with a plasmonic fiber optic gate electrode as a multivariable biosensor device. <i>ACS Sensors</i>. 2022;7(2):504-512. doi:<a href=\"https://doi.org/10.1021/acssensors.1c02313\">10.1021/acssensors.1c02313</a>","ista":"Hasler R, Reiner-Rozman C, Fossati S, Aspermair P, Dostalek J, Lee S, Ibáñez M, Bintinger J, Knoll W. 2022. Field-effect transistor with a plasmonic fiber optic gate electrode as a multivariable biosensor device. ACS Sensors. 7(2), 504–512.","short":"R. Hasler, C. Reiner-Rozman, S. Fossati, P. Aspermair, J. Dostalek, S. Lee, M. Ibáñez, J. Bintinger, W. Knoll, ACS Sensors 7 (2022) 504–512.","mla":"Hasler, Roger, et al. “Field-Effect Transistor with a Plasmonic Fiber Optic Gate Electrode as a Multivariable Biosensor Device.” <i>ACS Sensors</i>, vol. 7, no. 2, American Chemical Society, 2022, pp. 504–12, doi:<a href=\"https://doi.org/10.1021/acssensors.1c02313\">10.1021/acssensors.1c02313</a>."},"date_updated":"2023-08-02T14:46:17Z","external_id":{"isi":["000765113000016"]},"isi":1,"acknowledgement":"This project has received funding from the European Union’s Horizon 2020 Research and Innovation Programme under the Marie Skłodowska-Curie grant agreement No. 813863-\r\nBORGES. Additionally, we gratefully acknowledge the financial support from the Austrian Research Promotion Agency (FFG; 870025 and 873541) for this research. The data that support the findings of this study are openly available in Zenodo (DOI: 10.5281/zenodo.5500360)","volume":7,"ddc":["540"],"oa_version":"Published Version","month":"02","has_accepted_license":"1","publication":"ACS Sensors","language":[{"iso":"eng"}],"publication_identifier":{"eissn":["23793694"]},"oa":1,"tmp":{"legal_code_url":"https://creativecommons.org/licenses/by-nc-nd/4.0/legalcode","short":"CC BY-NC-ND (4.0)","name":"Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0)","image":"/images/cc_by_nc_nd.png"},"type":"journal_article","date_published":"2022-02-08T00:00:00Z","file":[{"date_created":"2022-03-07T08:15:01Z","file_size":2969415,"checksum":"d704af7262cd484da9bb84b7d84e2b09","date_updated":"2022-03-07T08:15:01Z","content_type":"application/pdf","file_name":"2022_ACSSensors_Hasler.pdf","success":1,"access_level":"open_access","relation":"main_file","file_id":"10832","creator":"dernst"}],"status":"public","user_id":"4359f0d1-fa6c-11eb-b949-802e58b17ae8","related_material":{"record":[{"relation":"research_data","id":"10833","status":"public"}]}},{"year":"2022","citation":{"ista":"Hasler R, Reiner-Rozman C, Fossati S, Aspermair P, Dostalek J, Lee S, Ibáñez M, Bintinger J, Knoll W. 2022. Field-effect transistor with a plasmonic fiber optic gate electrode as a multivariable biosensor device, Zenodo, <a href=\"https://doi.org/10.5281/ZENODO.5500360\">10.5281/ZENODO.5500360</a>.","short":"R. Hasler, C. Reiner-Rozman, S. Fossati, P. Aspermair, J. Dostalek, S. Lee, M. Ibáñez, J. Bintinger, W. Knoll, (2022).","mla":"Hasler, Roger, et al. <i>Field-Effect Transistor with a Plasmonic Fiber Optic Gate Electrode as a Multivariable Biosensor Device</i>. Zenodo, 2022, doi:<a href=\"https://doi.org/10.5281/ZENODO.5500360\">10.5281/ZENODO.5500360</a>.","chicago":"Hasler, Roger, Ciril Reiner-Rozman, Stefan Fossati, Patrik Aspermair, Jakub Dostalek, Seungho Lee, Maria Ibáñez, Johannes Bintinger, and Wolfgang Knoll. “Field-Effect Transistor with a Plasmonic Fiber Optic Gate Electrode as a Multivariable Biosensor Device.” Zenodo, 2022. <a href=\"https://doi.org/10.5281/ZENODO.5500360\">https://doi.org/10.5281/ZENODO.5500360</a>.","ieee":"R. Hasler <i>et al.</i>, “Field-effect transistor with a plasmonic fiber optic gate electrode as a multivariable biosensor device.” Zenodo, 2022.","ama":"Hasler R, Reiner-Rozman C, Fossati S, et al. Field-effect transistor with a plasmonic fiber optic gate electrode as a multivariable biosensor device. 2022. doi:<a href=\"https://doi.org/10.5281/ZENODO.5500360\">10.5281/ZENODO.5500360</a>","apa":"Hasler, R., Reiner-Rozman, C., Fossati, S., Aspermair, P., Dostalek, J., Lee, S., … Knoll, W. (2022). Field-effect transistor with a plasmonic fiber optic gate electrode as a multivariable biosensor device. Zenodo. <a href=\"https://doi.org/10.5281/ZENODO.5500360\">https://doi.org/10.5281/ZENODO.5500360</a>"},"date_updated":"2023-08-02T14:46:16Z","type":"research_data_reference","date_published":"2022-02-08T00:00:00Z","day":"08","doi":"10.5281/ZENODO.5500360","oa":1,"abstract":[{"lang":"eng","text":"Detailed information about the data set see \"dataset description.txt\" file."}],"main_file_link":[{"url":"https://doi.org/10.5281/zenodo.5500360","open_access":"1"}],"status":"public","related_material":{"record":[{"status":"public","id":"10829","relation":"used_in_publication"}]},"user_id":"6785fbc1-c503-11eb-8a32-93094b40e1cf","ddc":["540"],"_id":"10833","author":[{"full_name":"Hasler, Roger","last_name":"Hasler","first_name":"Roger"},{"last_name":"Reiner-Rozman","first_name":"Ciril","full_name":"Reiner-Rozman, Ciril"},{"full_name":"Fossati, Stefan","first_name":"Stefan","last_name":"Fossati"},{"first_name":"Patrik","last_name":"Aspermair","full_name":"Aspermair, Patrik"},{"full_name":"Dostalek, Jakub","first_name":"Jakub","last_name":"Dostalek"},{"id":"BB243B88-D767-11E9-B658-BC13E6697425","full_name":"Lee, Seungho","orcid":"0000-0002-6962-8598","last_name":"Lee","first_name":"Seungho"},{"orcid":"0000-0001-5013-2843","full_name":"Ibáñez, Maria","first_name":"Maria","last_name":"Ibáñez","id":"43C61214-F248-11E8-B48F-1D18A9856A87"},{"last_name":"Bintinger","first_name":"Johannes","full_name":"Bintinger, Johannes"},{"last_name":"Knoll","first_name":"Wolfgang","full_name":"Knoll, Wolfgang"}],"department":[{"_id":"MaIb"}],"date_created":"2022-03-07T08:19:11Z","article_processing_charge":"No","oa_version":"Published Version","title":"Field-effect transistor with a plasmonic fiber optic gate electrode as a multivariable biosensor device","month":"02","publisher":"Zenodo"},{"scopus_import":"1","_id":"11142","author":[{"last_name":"Hong","first_name":"Tao","full_name":"Hong, Tao"},{"full_name":"Guo, Changrong","last_name":"Guo","first_name":"Changrong"},{"full_name":"Wang, Dongyang","last_name":"Wang","first_name":"Dongyang"},{"full_name":"Qin, Bingchao","first_name":"Bingchao","last_name":"Qin"},{"id":"9E331C2E-9F27-11E9-AE48-5033E6697425","orcid":"0000-0002-9515-4277","full_name":"Chang, Cheng","first_name":"Cheng","last_name":"Chang"},{"full_name":"Gao, Xiang","last_name":"Gao","first_name":"Xiang"},{"last_name":"Zhao","first_name":"Li Dong","full_name":"Zhao, Li Dong"}],"date_created":"2022-04-10T22:01:39Z","article_processing_charge":"No","department":[{"_id":"MaIb"}],"publication_status":"published","intvolume":"        25","title":"Enhanced thermoelectric performance in SnTe due to the energy filtering effect introduced by Bi2O3","quality_controlled":"1","publisher":"Elsevier","article_type":"original","year":"2022","citation":{"ista":"Hong T, Guo C, Wang D, Qin B, Chang C, Gao X, Zhao LD. 2022. Enhanced thermoelectric performance in SnTe due to the energy filtering effect introduced by Bi2O3. Materials Today Energy. 25, 100985.","short":"T. Hong, C. Guo, D. Wang, B. Qin, C. Chang, X. Gao, L.D. Zhao, Materials Today Energy 25 (2022).","mla":"Hong, Tao, et al. “Enhanced Thermoelectric Performance in SnTe Due to the Energy Filtering Effect Introduced by Bi2O3.” <i>Materials Today Energy</i>, vol. 25, 100985, Elsevier, 2022, doi:<a href=\"https://doi.org/10.1016/j.mtener.2022.100985\">10.1016/j.mtener.2022.100985</a>.","chicago":"Hong, Tao, Changrong Guo, Dongyang Wang, Bingchao Qin, Cheng Chang, Xiang Gao, and Li Dong Zhao. “Enhanced Thermoelectric Performance in SnTe Due to the Energy Filtering Effect Introduced by Bi2O3.” <i>Materials Today Energy</i>. Elsevier, 2022. <a href=\"https://doi.org/10.1016/j.mtener.2022.100985\">https://doi.org/10.1016/j.mtener.2022.100985</a>.","ieee":"T. Hong <i>et al.</i>, “Enhanced thermoelectric performance in SnTe due to the energy filtering effect introduced by Bi2O3,” <i>Materials Today Energy</i>, vol. 25. Elsevier, 2022.","ama":"Hong T, Guo C, Wang D, et al. Enhanced thermoelectric performance in SnTe due to the energy filtering effect introduced by Bi2O3. <i>Materials Today Energy</i>. 2022;25. doi:<a href=\"https://doi.org/10.1016/j.mtener.2022.100985\">10.1016/j.mtener.2022.100985</a>","apa":"Hong, T., Guo, C., Wang, D., Qin, B., Chang, C., Gao, X., &#38; Zhao, L. D. (2022). Enhanced thermoelectric performance in SnTe due to the energy filtering effect introduced by Bi2O3. <i>Materials Today Energy</i>. Elsevier. <a href=\"https://doi.org/10.1016/j.mtener.2022.100985\">https://doi.org/10.1016/j.mtener.2022.100985</a>"},"date_updated":"2023-08-03T06:28:16Z","external_id":{"isi":["000798679100010"]},"isi":1,"day":"01","doi":"10.1016/j.mtener.2022.100985","abstract":[{"text":"SnTe is a promising Pb-free thermoelectric (TE) material with high electrical conductivity. We discovered the synergistic effect of Bi2O3 on enhancing the average power factor (PF) and overall ZT value of the SnTe-based thermoelectric material. The introduction of Bi2O3 forms plenty of SnO2, Bi2O3, and Bi-rich nanoprecipitates. These interfaces between the SnTe matrix and the nanoprecipitates can enhance the average PF through the energy filtering effect. On the other hand, abundant and diverse nanoprecipitates can significantly diminish the lattice thermal conductivity (κlat) through enhanced phonon scattering. The synergistic effect of Bi2O3 resulted in a maximum ZT (ZTmax) value of 0.9 at SnTe-2% Bi2O3 and an average ZT (ZTave) value of 0.4 for SnTe-4% Bi2O3 from 300 K to 823 K. The work provides an excellent reference to develop non-toxic high-performance TE materials.","lang":"eng"}],"volume":25,"acknowledgement":"This work was supported by National Natural Science Foundation of China (52002042), National Key Research and Development Program of China (2018YFA0702100 and 2018YFB0703600), 111 Project (B17002) and Lise Meitner Project M 2889-N. This work was also supported by the National Postdoctoral Program for Innovative Talents (BX20200028). L.D.Z. appreciates the support of the high-performance computing (HPC) resources at Beihang University, the National Science Fund for Distinguished Young Scholars (51925101), and center for High Pressure Science and Technology Advanced Research (HPSTAR) for SEM and TEM measurements.","publication":"Materials Today Energy","project":[{"_id":"9B8804FC-BA93-11EA-9121-9846C619BF3A","grant_number":"M02889","name":"Bottom-up Engineering for Thermoelectric Applications"}],"oa_version":"None","article_number":"100985","month":"04","language":[{"iso":"eng"}],"type":"journal_article","date_published":"2022-04-01T00:00:00Z","publication_identifier":{"eissn":["2468-6069"]},"user_id":"4359f0d1-fa6c-11eb-b949-802e58b17ae8","status":"public"},{"publication":"Science","month":"03","oa_version":"None","project":[{"_id":"9B8804FC-BA93-11EA-9121-9846C619BF3A","name":"Bottom-up Engineering for Thermoelectric Applications","grant_number":"M02889"}],"language":[{"iso":"eng"}],"date_published":"2022-03-25T00:00:00Z","type":"journal_article","publication_identifier":{"eissn":["1095-9203"]},"status":"public","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","author":[{"first_name":"Lizhong","last_name":"Su","full_name":"Su, Lizhong"},{"first_name":"Dongyang","last_name":"Wang","full_name":"Wang, Dongyang"},{"full_name":"Wang, Sining","last_name":"Wang","first_name":"Sining"},{"first_name":"Bingchao","last_name":"Qin","full_name":"Qin, Bingchao"},{"full_name":"Wang, Yuping","first_name":"Yuping","last_name":"Wang"},{"full_name":"Qin, Yongxin","last_name":"Qin","first_name":"Yongxin"},{"full_name":"Jin, Yang","first_name":"Yang","last_name":"Jin"},{"orcid":"0000-0002-9515-4277","full_name":"Chang, Cheng","first_name":"Cheng","last_name":"Chang","id":"9E331C2E-9F27-11E9-AE48-5033E6697425"},{"full_name":"Zhao, Li Dong","last_name":"Zhao","first_name":"Li Dong"}],"issue":"6587","_id":"11144","pmid":1,"scopus_import":"1","title":"High thermoelectric performance realized through manipulating layered phonon-electron decoupling","intvolume":"       375","publication_status":"published","date_created":"2022-04-10T22:01:40Z","article_processing_charge":"No","department":[{"_id":"MaIb"}],"page":"1385-1389","quality_controlled":"1","article_type":"original","publisher":"American Association for the Advancement of Science","isi":1,"external_id":{"isi":["000778894800038"],"pmid":["35324303"]},"date_updated":"2023-10-16T09:10:36Z","year":"2022","citation":{"ieee":"L. Su <i>et al.</i>, “High thermoelectric performance realized through manipulating layered phonon-electron decoupling,” <i>Science</i>, vol. 375, no. 6587. American Association for the Advancement of Science, pp. 1385–1389, 2022.","chicago":"Su, Lizhong, Dongyang Wang, Sining Wang, Bingchao Qin, Yuping Wang, Yongxin Qin, Yang Jin, Cheng Chang, and Li Dong Zhao. “High Thermoelectric Performance Realized through Manipulating Layered Phonon-Electron Decoupling.” <i>Science</i>. American Association for the Advancement of Science, 2022. <a href=\"https://doi.org/10.1126/science.abn8997\">https://doi.org/10.1126/science.abn8997</a>.","apa":"Su, L., Wang, D., Wang, S., Qin, B., Wang, Y., Qin, Y., … Zhao, L. D. (2022). High thermoelectric performance realized through manipulating layered phonon-electron decoupling. <i>Science</i>. American Association for the Advancement of Science. <a href=\"https://doi.org/10.1126/science.abn8997\">https://doi.org/10.1126/science.abn8997</a>","ama":"Su L, Wang D, Wang S, et al. High thermoelectric performance realized through manipulating layered phonon-electron decoupling. <i>Science</i>. 2022;375(6587):1385-1389. doi:<a href=\"https://doi.org/10.1126/science.abn8997\">10.1126/science.abn8997</a>","ista":"Su L, Wang D, Wang S, Qin B, Wang Y, Qin Y, Jin Y, Chang C, Zhao LD. 2022. High thermoelectric performance realized through manipulating layered phonon-electron decoupling. Science. 375(6587), 1385–1389.","mla":"Su, Lizhong, et al. “High Thermoelectric Performance Realized through Manipulating Layered Phonon-Electron Decoupling.” <i>Science</i>, vol. 375, no. 6587, American Association for the Advancement of Science, 2022, pp. 1385–89, doi:<a href=\"https://doi.org/10.1126/science.abn8997\">10.1126/science.abn8997</a>.","short":"L. Su, D. Wang, S. Wang, B. Qin, Y. Wang, Y. Qin, Y. Jin, C. Chang, L.D. Zhao, Science 375 (2022) 1385–1389."},"abstract":[{"lang":"eng","text":"Thermoelectric materials allow for direct conversion between heat and electricity, offering the potential for power generation. The average dimensionless figure of merit ZTave determines device efficiency. N-type tin selenide crystals exhibit outstanding three-dimensional charge and two-dimensional phonon transport along the out-of-plane direction, contributing to a high maximum figure of merit Zmax of ~3.6 × 10−3 per kelvin but a moderate ZTave of ~1.1. We found an attractive high Zmax of ~4.1 × 10−3 per kelvin at 748 kelvin and a ZTave of ~1.7 at 300 to 773 kelvin in chlorine-doped and lead-alloyed tin selenide crystals by phonon-electron decoupling. The chlorine-induced low deformation potential improved the carrier mobility. The lead-induced mass and strain fluctuations reduced the lattice thermal conductivity. Phonon-electron decoupling plays a critical role to achieve high-performance thermoelectrics."}],"doi":"10.1126/science.abn8997","day":"25","acknowledgement":"This work was supported by the Basic Science Center Project of the National Natural Science Foundation of China (51788104), the National Key Research and Development Program of China (2018YFA0702100), the National Science Fund for Distinguished Young Scholars (51925101), the 111 Project (B17002), the Lise Meitner Project (M2889-N), and the National Key Research and Development Program of China (2018YFB0703600). This work is also supported by the National Postdoctoral Program for Innovative Talents (BX20200028). L.-D.Z. is thankful for the high-performance computing resources at Beihang University.","volume":375},{"language":[{"iso":"eng"}],"publication":"Science Bulletin","month":"06","project":[{"name":"Bottom-up Engineering for Thermoelectric Applications","grant_number":"M02889","_id":"9B8804FC-BA93-11EA-9121-9846C619BF3A"}],"oa_version":"Published Version","status":"public","user_id":"4359f0d1-fa6c-11eb-b949-802e58b17ae8","main_file_link":[{"url":"https://doi.org/10.1016/j.scib.2022.04.007","open_access":"1"}],"type":"journal_article","date_published":"2022-06-15T00:00:00Z","oa":1,"publication_identifier":{"eissn":["2095-9281"],"issn":["2095-9273"]},"quality_controlled":"1","page":"1105-1107","article_type":"letter_note","publisher":"Elsevier","issue":"11","author":[{"orcid":"0000-0002-9515-4277","full_name":"Chang, Cheng","first_name":"Cheng","last_name":"Chang","id":"9E331C2E-9F27-11E9-AE48-5033E6697425"},{"full_name":"Qin, Bingchao","first_name":"Bingchao","last_name":"Qin"},{"full_name":"Su, Lizhong","last_name":"Su","first_name":"Lizhong"},{"full_name":"Zhao, Li Dong","first_name":"Li Dong","last_name":"Zhao"}],"scopus_import":"1","_id":"11356","intvolume":"        67","title":"Distinct electron and hole transports in SnSe crystals","department":[{"_id":"MaIb"}],"article_processing_charge":"No","date_created":"2022-05-08T22:01:44Z","publication_status":"published","volume":67,"acknowledgement":"This work was supported by the National Science Fund for Distinguished Young Scholars (51925101), National Key Research and Development Program of China (2018YFA0702100), 111 Project (B17002), and Lise Meitner Project (M2889-N).","external_id":{"isi":["000835291100006"]},"isi":1,"citation":{"ista":"Chang C, Qin B, Su L, Zhao LD. 2022. Distinct electron and hole transports in SnSe crystals. Science Bulletin. 67(11), 1105–1107.","mla":"Chang, Cheng, et al. “Distinct Electron and Hole Transports in SnSe Crystals.” <i>Science Bulletin</i>, vol. 67, no. 11, Elsevier, 2022, pp. 1105–07, doi:<a href=\"https://doi.org/10.1016/j.scib.2022.04.007\">10.1016/j.scib.2022.04.007</a>.","short":"C. Chang, B. Qin, L. Su, L.D. Zhao, Science Bulletin 67 (2022) 1105–1107.","chicago":"Chang, Cheng, Bingchao Qin, Lizhong Su, and Li Dong Zhao. “Distinct Electron and Hole Transports in SnSe Crystals.” <i>Science Bulletin</i>. Elsevier, 2022. <a href=\"https://doi.org/10.1016/j.scib.2022.04.007\">https://doi.org/10.1016/j.scib.2022.04.007</a>.","ieee":"C. Chang, B. Qin, L. Su, and L. D. Zhao, “Distinct electron and hole transports in SnSe crystals,” <i>Science Bulletin</i>, vol. 67, no. 11. Elsevier, pp. 1105–1107, 2022.","apa":"Chang, C., Qin, B., Su, L., &#38; Zhao, L. D. (2022). Distinct electron and hole transports in SnSe crystals. <i>Science Bulletin</i>. Elsevier. <a href=\"https://doi.org/10.1016/j.scib.2022.04.007\">https://doi.org/10.1016/j.scib.2022.04.007</a>","ama":"Chang C, Qin B, Su L, Zhao LD. Distinct electron and hole transports in SnSe crystals. <i>Science Bulletin</i>. 2022;67(11):1105-1107. doi:<a href=\"https://doi.org/10.1016/j.scib.2022.04.007\">10.1016/j.scib.2022.04.007</a>"},"year":"2022","date_updated":"2023-08-03T07:04:10Z","day":"15","doi":"10.1016/j.scib.2022.04.007"},{"oa_version":"Published Version","article_number":"42","month":"05","has_accepted_license":"1","publication":"NPG Asia Materials","language":[{"iso":"eng"}],"publication_identifier":{"issn":["1884-4049"],"eissn":["1884-4057"]},"oa":1,"tmp":{"legal_code_url":"https://creativecommons.org/licenses/by/4.0/legalcode","short":"CC BY (4.0)","image":"/images/cc_by.png","name":"Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)"},"type":"journal_article","date_published":"2022-05-13T00:00:00Z","file":[{"file_size":6202545,"checksum":"0579997cc1d28bf66e29357e08e3e39d","date_created":"2022-05-23T06:47:57Z","content_type":"application/pdf","file_name":"2022_NPGAsiaMaterials_Nguyen.pdf","date_updated":"2022-05-23T06:47:57Z","success":1,"relation":"main_file","access_level":"open_access","creator":"dernst","file_id":"11404"}],"status":"public","user_id":"4359f0d1-fa6c-11eb-b949-802e58b17ae8","department":[{"_id":"MaIb"}],"article_processing_charge":"No","date_created":"2022-05-22T22:01:40Z","publication_status":"published","intvolume":"        14","title":"Unidentified major p-type source in SnSe: Multivacancies","scopus_import":"1","_id":"11401","author":[{"full_name":"Nguyen, Van Quang","first_name":"Van Quang","last_name":"Nguyen"},{"last_name":"Trinh","first_name":"Thi Ly","full_name":"Trinh, Thi Ly"},{"orcid":"0000-0002-9515-4277","full_name":"Chang, Cheng","first_name":"Cheng","last_name":"Chang","id":"9E331C2E-9F27-11E9-AE48-5033E6697425"},{"last_name":"Zhao","first_name":"Li Dong","full_name":"Zhao, Li Dong"},{"full_name":"Nguyen, Thi Huong","last_name":"Nguyen","first_name":"Thi Huong"},{"last_name":"Duong","first_name":"Van Thiet","full_name":"Duong, Van Thiet"},{"first_name":"Anh Tuan","last_name":"Duong","full_name":"Duong, Anh Tuan"},{"full_name":"Park, Jong Ho","last_name":"Park","first_name":"Jong Ho"},{"first_name":"Sudong","last_name":"Park","full_name":"Park, Sudong"},{"full_name":"Kim, Jungdae","first_name":"Jungdae","last_name":"Kim"},{"last_name":"Cho","first_name":"Sunglae","full_name":"Cho, Sunglae"}],"publisher":"Springer Nature","article_type":"original","quality_controlled":"1","file_date_updated":"2022-05-23T06:47:57Z","day":"13","doi":"10.1038/s41427-022-00393-5","abstract":[{"text":"Tin selenide (SnSe) is considered a robust candidate for thermoelectric applications due to its very high thermoelectric figure of merit, ZT, with values of 2.6 in p-type and 2.8 in n-type single crystals. Sn has been replaced with various lower group dopants to achieve successful p-type doping in SnSe with high ZT values. A known, facile, and powerful alternative way to introduce a hole carrier is to use a natural single Sn vacancy, VSn. Through transport and scanning tunneling microscopy studies, we discovered that VSn are dominant in high-quality (slow cooling rate) SnSe single crystals, while multiple vacancies, Vmulti, are dominant in low-quality (high cooling rate) single crystals. Surprisingly, both VSn and Vmulti help to increase the power factors of SnSe, whereas samples with dominant VSn have superior thermoelectric properties in SnSe single crystals. Additionally, the observation that Vmulti are good p-type sources observed in relatively low-quality single crystals is useful in thermoelectric applications because polycrystalline SnSe can be used due to its mechanical strength; this substance is usually fabricated at very high cooling speeds.","lang":"eng"}],"year":"2022","citation":{"ieee":"V. Q. Nguyen <i>et al.</i>, “Unidentified major p-type source in SnSe: Multivacancies,” <i>NPG Asia Materials</i>, vol. 14. Springer Nature, 2022.","chicago":"Nguyen, Van Quang, Thi Ly Trinh, Cheng Chang, Li Dong Zhao, Thi Huong Nguyen, Van Thiet Duong, Anh Tuan Duong, et al. “Unidentified Major P-Type Source in SnSe: Multivacancies.” <i>NPG Asia Materials</i>. Springer Nature, 2022. <a href=\"https://doi.org/10.1038/s41427-022-00393-5\">https://doi.org/10.1038/s41427-022-00393-5</a>.","apa":"Nguyen, V. Q., Trinh, T. L., Chang, C., Zhao, L. D., Nguyen, T. H., Duong, V. T., … Cho, S. (2022). Unidentified major p-type source in SnSe: Multivacancies. <i>NPG Asia Materials</i>. Springer Nature. <a href=\"https://doi.org/10.1038/s41427-022-00393-5\">https://doi.org/10.1038/s41427-022-00393-5</a>","ama":"Nguyen VQ, Trinh TL, Chang C, et al. Unidentified major p-type source in SnSe: Multivacancies. <i>NPG Asia Materials</i>. 2022;14. doi:<a href=\"https://doi.org/10.1038/s41427-022-00393-5\">10.1038/s41427-022-00393-5</a>","ista":"Nguyen VQ, Trinh TL, Chang C, Zhao LD, Nguyen TH, Duong VT, Duong AT, Park JH, Park S, Kim J, Cho S. 2022. Unidentified major p-type source in SnSe: Multivacancies. NPG Asia Materials. 14, 42.","short":"V.Q. Nguyen, T.L. Trinh, C. Chang, L.D. Zhao, T.H. Nguyen, V.T. Duong, A.T. Duong, J.H. Park, S. Park, J. Kim, S. Cho, NPG Asia Materials 14 (2022).","mla":"Nguyen, Van Quang, et al. “Unidentified Major P-Type Source in SnSe: Multivacancies.” <i>NPG Asia Materials</i>, vol. 14, 42, Springer Nature, 2022, doi:<a href=\"https://doi.org/10.1038/s41427-022-00393-5\">10.1038/s41427-022-00393-5</a>."},"date_updated":"2023-08-03T07:13:58Z","external_id":{"isi":["000794880200001"]},"isi":1,"volume":14,"acknowledgement":"This work was supported by the National Research Foundation of Korea [NRF-2019R1F1A1058473, NRF-2019R1A6A1A11053838, and NRF-2020K1A4A7A02095438].","ddc":["540"]},{"related_material":{"record":[{"status":"public","id":"11695","relation":"research_data"}]},"user_id":"4359f0d1-fa6c-11eb-b949-802e58b17ae8","status":"public","file":[{"success":1,"access_level":"open_access","relation":"main_file","creator":"dernst","file_id":"11696","file_size":1303202,"checksum":"2a3ee0bb59e044b808ebe85cd94ac899","date_created":"2022-07-29T09:29:20Z","file_name":"2022_AngewandteChemieInternat_Parvizian.pdf","content_type":"application/pdf","date_updated":"2022-07-29T09:29:20Z"}],"type":"journal_article","date_published":"2022-08-01T00:00:00Z","tmp":{"legal_code_url":"https://creativecommons.org/licenses/by/4.0/legalcode","short":"CC BY (4.0)","image":"/images/cc_by.png","name":"Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)"},"oa":1,"publication_identifier":{"eissn":["1521-3773"],"issn":["1433-7851"]},"language":[{"iso":"eng"}],"has_accepted_license":"1","publication":"Angewandte Chemie - International Edition","article_number":"e202207013","month":"08","oa_version":"Published Version","ddc":["540"],"volume":61,"acknowledgement":"J.D.R. and M.P. acknowledge the SNF Eccellenza funding scheme (project number: 194172). We acknowledge DESY (Hamburg, Germany), a member of the Helmholtz Association HGF, for the provision of experimental facilities. Parts of this research were carried out at beamline P21.1, PETRA III. We thank Dr. Soham Banerjee for acquiring the PDF data and helpful advice. A.R. acknowledges the support from the Analytical Chemistry Trust Fund for her CAMS-UK Fellowship. C.K. acknowledges the support from the Department of Chemistry, UCL. The authors acknowledge Dr Stephan Lany from NREL for providing the Cu3N DFT calculations. The authors thank Prof. Raymond Schaak and Dr. Robert William Lord for helpful advice and suggestions regarding the purification procedure. Open access funding provided by Universitat Basel.","external_id":{"isi":["000811084000001"],"pmid":["35612297"]},"isi":1,"citation":{"chicago":"Parvizian, Mahsa, Alejandra Duràn Balsa, Rohan Pokratath, Curran Kalha, Seungho Lee, Dietger Van Den Eynden, Maria Ibáñez, Anna Regoutz, and Jonathan De Roo. “The Chemistry of Cu₃N and Cu₃PdN Nanocrystals.” <i>Angewandte Chemie - International Edition</i>. Wiley, 2022. <a href=\"https://doi.org/10.1002/anie.202207013\">https://doi.org/10.1002/anie.202207013</a>.","ieee":"M. Parvizian <i>et al.</i>, “The chemistry of Cu₃N and Cu₃PdN nanocrystals,” <i>Angewandte Chemie - International Edition</i>, vol. 61, no. 31. Wiley, 2022.","ama":"Parvizian M, Duràn Balsa A, Pokratath R, et al. The chemistry of Cu₃N and Cu₃PdN nanocrystals. <i>Angewandte Chemie - International Edition</i>. 2022;61(31). doi:<a href=\"https://doi.org/10.1002/anie.202207013\">10.1002/anie.202207013</a>","apa":"Parvizian, M., Duràn Balsa, A., Pokratath, R., Kalha, C., Lee, S., Van Den Eynden, D., … De Roo, J. (2022). The chemistry of Cu₃N and Cu₃PdN nanocrystals. <i>Angewandte Chemie - International Edition</i>. Wiley. <a href=\"https://doi.org/10.1002/anie.202207013\">https://doi.org/10.1002/anie.202207013</a>","ista":"Parvizian M, Duràn Balsa A, Pokratath R, Kalha C, Lee S, Van Den Eynden D, Ibáñez M, Regoutz A, De Roo J. 2022. The chemistry of Cu₃N and Cu₃PdN nanocrystals. Angewandte Chemie - International Edition. 61(31), e202207013.","short":"M. Parvizian, A. Duràn Balsa, R. Pokratath, C. Kalha, S. Lee, D. Van Den Eynden, M. Ibáñez, A. Regoutz, J. De Roo, Angewandte Chemie - International Edition 61 (2022).","mla":"Parvizian, Mahsa, et al. “The Chemistry of Cu₃N and Cu₃PdN Nanocrystals.” <i>Angewandte Chemie - International Edition</i>, vol. 61, no. 31, e202207013, Wiley, 2022, doi:<a href=\"https://doi.org/10.1002/anie.202207013\">10.1002/anie.202207013</a>."},"year":"2022","date_updated":"2023-08-03T07:19:12Z","abstract":[{"text":"The precursor conversion chemistry and surface chemistry of Cu3N and Cu3PdN nanocrystals are unknown or contested. Here, we first obtain phase-pure, colloidally stable nanocubes. Second, we elucidate the pathway by which copper(II) nitrate and oleylamine form Cu3N. We find that oleylamine is both a reductant and a nitrogen source. Oleylamine is oxidized by nitrate to a primary aldimine, which reacts further with excess oleylamine to a secondary aldimine, eliminating ammonia. Ammonia reacts with CuI to form Cu3N. Third, we investigated the surface chemistry and find a mixed ligand shell of aliphatic amines and carboxylates (formed in situ). While the carboxylates appear tightly bound, the amines are easily desorbed from the surface. Finally, we show that doping with palladium decreases the band gap and the material becomes semi-metallic. These results bring insight into the chemistry of metal nitrides and might help the development of other metal nitride nanocrystals.","lang":"eng"}],"day":"01","doi":"10.1002/anie.202207013","file_date_updated":"2022-07-29T09:29:20Z","quality_controlled":"1","article_type":"original","publisher":"Wiley","issue":"31","author":[{"full_name":"Parvizian, Mahsa","first_name":"Mahsa","last_name":"Parvizian"},{"first_name":"Alejandra","last_name":"Duràn Balsa","full_name":"Duràn Balsa, Alejandra"},{"full_name":"Pokratath, Rohan","first_name":"Rohan","last_name":"Pokratath"},{"first_name":"Curran","last_name":"Kalha","full_name":"Kalha, Curran"},{"last_name":"Lee","first_name":"Seungho","full_name":"Lee, Seungho","orcid":"0000-0002-6962-8598","id":"BB243B88-D767-11E9-B658-BC13E6697425"},{"full_name":"Van Den Eynden, Dietger","last_name":"Van Den Eynden","first_name":"Dietger"},{"first_name":"Maria","last_name":"Ibáñez","orcid":"0000-0001-5013-2843","full_name":"Ibáñez, Maria","id":"43C61214-F248-11E8-B48F-1D18A9856A87"},{"first_name":"Anna","last_name":"Regoutz","full_name":"Regoutz, Anna"},{"last_name":"De Roo","first_name":"Jonathan","full_name":"De Roo, Jonathan"}],"scopus_import":"1","_id":"11451","pmid":1,"intvolume":"        61","title":"The chemistry of Cu₃N and Cu₃PdN nanocrystals","article_processing_charge":"No","date_created":"2022-06-19T22:01:58Z","department":[{"_id":"MaIb"}],"publication_status":"published"},{"status":"public","related_material":{"record":[{"status":"public","relation":"used_in_publication","id":"11451"}]},"user_id":"6785fbc1-c503-11eb-8a32-93094b40e1cf","ddc":["540"],"main_file_link":[{"url":"https://doi.org/10.5281/ZENODO.6542908","open_access":"1"}],"type":"research_data_reference","date_published":"2022-05-12T00:00:00Z","citation":{"ama":"Parvizian M, Duran Balsa A, Pokratath R, et al. Data for “The chemistry of Cu3N and Cu3PdN nanocrystals.” 2022. doi:<a href=\"https://doi.org/10.5281/ZENODO.6542908\">10.5281/ZENODO.6542908</a>","apa":"Parvizian, M., Duran Balsa, A., Pokratath, R., Kalha, C., Lee, S., Van den Eynden, D., … De Roo, J. (2022). Data for “The chemistry of Cu3N and Cu3PdN nanocrystals.” Zenodo. <a href=\"https://doi.org/10.5281/ZENODO.6542908\">https://doi.org/10.5281/ZENODO.6542908</a>","chicago":"Parvizian, Mahsa, Alejandra Duran Balsa, Rohan Pokratath, Curran Kalha, Seungho Lee, Dietger Van den Eynden, Maria Ibáñez, Anna Regoutz, and Jonathan De Roo. “Data for ‘The Chemistry of Cu3N and Cu3PdN Nanocrystals.’” Zenodo, 2022. <a href=\"https://doi.org/10.5281/ZENODO.6542908\">https://doi.org/10.5281/ZENODO.6542908</a>.","ieee":"M. Parvizian <i>et al.</i>, “Data for ‘The chemistry of Cu3N and Cu3PdN nanocrystals.’” Zenodo, 2022.","short":"M. Parvizian, A. Duran Balsa, R. Pokratath, C. Kalha, S. Lee, D. Van den Eynden, M. Ibáñez, A. Regoutz, J. De Roo, (2022).","mla":"Parvizian, Mahsa, et al. <i>Data for “The Chemistry of Cu3N and Cu3PdN Nanocrystals.”</i> Zenodo, 2022, doi:<a href=\"https://doi.org/10.5281/ZENODO.6542908\">10.5281/ZENODO.6542908</a>.","ista":"Parvizian M, Duran Balsa A, Pokratath R, Kalha C, Lee S, Van den Eynden D, Ibáñez M, Regoutz A, De Roo J. 2022. Data for ‘The chemistry of Cu3N and Cu3PdN nanocrystals’, Zenodo, <a href=\"https://doi.org/10.5281/ZENODO.6542908\">10.5281/ZENODO.6542908</a>."},"year":"2022","date_updated":"2023-08-03T07:19:12Z","tmp":{"legal_code_url":"https://creativecommons.org/licenses/by/4.0/legalcode","short":"CC BY (4.0)","image":"/images/cc_by.png","name":"Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)"},"oa":1,"abstract":[{"text":"Data underlying the figures in the publication \"The chemistry of Cu3N and Cu3PdN nanocrystals\" ","lang":"eng"}],"day":"12","doi":"10.5281/ZENODO.6542908","publisher":"Zenodo","author":[{"full_name":"Parvizian, Mahsa","first_name":"Mahsa","last_name":"Parvizian"},{"last_name":"Duran Balsa","first_name":"Alejandra","full_name":"Duran Balsa, Alejandra"},{"full_name":"Pokratath, Rohan","last_name":"Pokratath","first_name":"Rohan"},{"first_name":"Curran","last_name":"Kalha","full_name":"Kalha, Curran"},{"first_name":"Seungho","last_name":"Lee","full_name":"Lee, Seungho"},{"last_name":"Van den Eynden","first_name":"Dietger","full_name":"Van den Eynden, Dietger"},{"full_name":"Ibáñez, Maria","orcid":"0000-0001-5013-2843","last_name":"Ibáñez","first_name":"Maria","id":"43C61214-F248-11E8-B48F-1D18A9856A87"},{"first_name":"Anna","last_name":"Regoutz","full_name":"Regoutz, Anna"},{"full_name":"De Roo, Jonathan","last_name":"De Roo","first_name":"Jonathan"}],"_id":"11695","month":"05","title":"Data for \"The chemistry of Cu3N and Cu3PdN nanocrystals\"","department":[{"_id":"MaIb"}],"article_processing_charge":"No","date_created":"2022-07-29T09:31:13Z","oa_version":"Published Version"},{"tmp":{"legal_code_url":"https://creativecommons.org/licenses/by/4.0/legalcode","short":"CC BY (4.0)","image":"/images/cc_by.png","name":"Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)"},"type":"journal_article","date_published":"2022-08-26T00:00:00Z","publication_identifier":{"eissn":["1521-3773"],"issn":["1433-7851"]},"oa":1,"file":[{"file_id":"12476","creator":"dernst","success":1,"access_level":"open_access","relation":"main_file","date_updated":"2023-02-02T08:01:00Z","file_name":"2022_AngewandteChemieInternat_Chang.pdf","content_type":"application/pdf","date_created":"2023-02-02T08:01:00Z","checksum":"ad601f2b9e26e46ab4785162be58b5ed","file_size":4072650}],"status":"public","user_id":"4359f0d1-fa6c-11eb-b949-802e58b17ae8","has_accepted_license":"1","publication":"Angewandte Chemie - International Edition","project":[{"grant_number":"M02889","name":"Bottom-up Engineering for Thermoelectric Applications","_id":"9B8804FC-BA93-11EA-9121-9846C619BF3A"},{"call_identifier":"H2020","_id":"260C2330-B435-11E9-9278-68D0E5697425","name":"ISTplus - Postdoctoral Fellowships","grant_number":"754411"}],"acknowledged_ssus":[{"_id":"EM-Fac"},{"_id":"NanoFab"}],"oa_version":"Published Version","article_number":"e202207002","month":"08","language":[{"iso":"eng"}],"year":"2022","citation":{"mla":"Chang, Cheng, et al. “Surface Functionalization of Surfactant-Free Particles: A Strategy to Tailor the Properties of Nanocomposites for Enhanced Thermoelectric Performance.” <i>Angewandte Chemie - International Edition</i>, vol. 61, no. 35, e202207002, Wiley, 2022, doi:<a href=\"https://doi.org/10.1002/anie.202207002\">10.1002/anie.202207002</a>.","short":"C. Chang, Y. Liu, S. Lee, M. Spadaro, K.M. Koskela, T. Kleinhanns, T. Costanzo, J. Arbiol, R.L. Brutchey, M. Ibáñez, Angewandte Chemie - International Edition 61 (2022).","ista":"Chang C, Liu Y, Lee S, Spadaro M, Koskela KM, Kleinhanns T, Costanzo T, Arbiol J, Brutchey RL, Ibáñez M. 2022. Surface functionalization of surfactant-free particles: A strategy to tailor the properties of nanocomposites for enhanced thermoelectric performance. Angewandte Chemie - International Edition. 61(35), e202207002.","apa":"Chang, C., Liu, Y., Lee, S., Spadaro, M., Koskela, K. M., Kleinhanns, T., … Ibáñez, M. (2022). Surface functionalization of surfactant-free particles: A strategy to tailor the properties of nanocomposites for enhanced thermoelectric performance. <i>Angewandte Chemie - International Edition</i>. Wiley. <a href=\"https://doi.org/10.1002/anie.202207002\">https://doi.org/10.1002/anie.202207002</a>","ama":"Chang C, Liu Y, Lee S, et al. Surface functionalization of surfactant-free particles: A strategy to tailor the properties of nanocomposites for enhanced thermoelectric performance. <i>Angewandte Chemie - International Edition</i>. 2022;61(35). doi:<a href=\"https://doi.org/10.1002/anie.202207002\">10.1002/anie.202207002</a>","ieee":"C. Chang <i>et al.</i>, “Surface functionalization of surfactant-free particles: A strategy to tailor the properties of nanocomposites for enhanced thermoelectric performance,” <i>Angewandte Chemie - International Edition</i>, vol. 61, no. 35. Wiley, 2022.","chicago":"Chang, Cheng, Yu Liu, Seungho Lee, Maria Spadaro, Kristopher M. Koskela, Tobias Kleinhanns, Tommaso Costanzo, Jordi Arbiol, Richard L. Brutchey, and Maria Ibáñez. “Surface Functionalization of Surfactant-Free Particles: A Strategy to Tailor the Properties of Nanocomposites for Enhanced Thermoelectric Performance.” <i>Angewandte Chemie - International Edition</i>. Wiley, 2022. <a href=\"https://doi.org/10.1002/anie.202207002\">https://doi.org/10.1002/anie.202207002</a>."},"date_updated":"2023-08-03T12:23:52Z","external_id":{"isi":["000828274200001"]},"isi":1,"day":"26","doi":"10.1002/anie.202207002","abstract":[{"text":"The broad implementation of thermoelectricity requires high-performance and low-cost materials. One possibility is employing surfactant-free solution synthesis to produce nanopowders. We propose the strategy of functionalizing “naked” particles’ surface by inorganic molecules to control the nanostructure and, consequently, thermoelectric performance. In particular, we use bismuth thiolates to functionalize surfactant-free SnTe particles’ surfaces. Upon thermal processing, bismuth thiolates decomposition renders SnTe-Bi2S3 nanocomposites with synergistic functions: 1) carrier concentration optimization by Bi doping; 2) Seebeck coefficient enhancement and bipolar effect suppression by energy filtering; and 3) lattice thermal conductivity reduction by small grain domains, grain boundaries and nanostructuration. Overall, the SnTe-Bi2S3 nanocomposites exhibit peak z T up to 1.3 at 873 K and an average z T of ≈0.6 at 300–873 K, which is among the highest reported for solution-processed SnTe.","lang":"eng"}],"acknowledgement":"This research was supported by the Scientific Service Units (SSU) of IST Austria through resources provided by Electron Microscopy Facility (EMF) and the Nanofabrication Facility (NNF). This work was financially supported by IST Austria and the Werner Siemens Foundation. C.C. acknowledges funding from the FWF “Lise Meitner Fellowship” grant agreement M 2889-N. Lise Meitner Project (M2889-N). Y.L. acknowledges funding from the European Union's Horizon 2020 research and innovation program under the Marie Sklodowska-Curie grant agreement No. 754411. R.L.B. thanks the National Science Foundation for support under DMR-1904719. MCS acknowledge MINECO Juan de la Cierva Incorporation fellowship (JdlCI 2019) and Severo Ochoa. M.C.S. and J.A. acknowledge funding from Generalitat de Catalunya 2017 SGR 327. ICN2 is supported by the Severo Ochoa program from Spanish MINECO (Grant no. SEV-2017-0706) and is funded by the CERCA Programme/Generalitat de Catalunya. This study was supported by MCIN with funding from European Union NextGenerationEU (PRTR-C17.I1) and Generalitat de Catalunya.","volume":61,"ddc":["540"],"scopus_import":"1","_id":"11705","issue":"35","author":[{"id":"9E331C2E-9F27-11E9-AE48-5033E6697425","first_name":"Cheng","last_name":"Chang","orcid":"0000-0002-9515-4277","full_name":"Chang, Cheng"},{"id":"2A70014E-F248-11E8-B48F-1D18A9856A87","first_name":"Yu","last_name":"Liu","orcid":"0000-0001-7313-6740","full_name":"Liu, Yu"},{"last_name":"Lee","first_name":"Seungho","full_name":"Lee, Seungho","orcid":"0000-0002-6962-8598","id":"BB243B88-D767-11E9-B658-BC13E6697425"},{"full_name":"Spadaro, Maria","last_name":"Spadaro","first_name":"Maria"},{"full_name":"Koskela, Kristopher M.","first_name":"Kristopher M.","last_name":"Koskela"},{"id":"8BD9DE16-AB3C-11E9-9C8C-2A03E6697425","last_name":"Kleinhanns","first_name":"Tobias","full_name":"Kleinhanns, Tobias"},{"id":"D93824F4-D9BA-11E9-BB12-F207E6697425","first_name":"Tommaso","last_name":"Costanzo","orcid":"0000-0001-9732-3815","full_name":"Costanzo, Tommaso"},{"last_name":"Arbiol","first_name":"Jordi","full_name":"Arbiol, Jordi"},{"full_name":"Brutchey, Richard L.","last_name":"Brutchey","first_name":"Richard L."},{"id":"43C61214-F248-11E8-B48F-1D18A9856A87","last_name":"Ibáñez","first_name":"Maria","full_name":"Ibáñez, Maria","orcid":"0000-0001-5013-2843"}],"date_created":"2022-07-31T22:01:48Z","article_processing_charge":"Yes (via OA deal)","department":[{"_id":"MaIb"},{"_id":"EM-Fac"}],"publication_status":"published","intvolume":"        61","title":"Surface functionalization of surfactant-free particles: A strategy to tailor the properties of nanocomposites for enhanced thermoelectric performance","ec_funded":1,"quality_controlled":"1","file_date_updated":"2023-02-02T08:01:00Z","publisher":"Wiley","article_type":"original"},{"quality_controlled":"1","page":"638-639","publisher":"Springer Nature","article_type":"letter_note","_id":"14437","pmid":1,"issue":"7941","author":[{"full_name":"Utzat, Hendrik","first_name":"Hendrik","last_name":"Utzat"},{"last_name":"Ibáñez","first_name":"Maria","full_name":"Ibáñez, Maria","orcid":"0000-0001-5013-2843","id":"43C61214-F248-11E8-B48F-1D18A9856A87"}],"article_processing_charge":"No","department":[{"_id":"MaIb"}],"date_created":"2023-10-17T11:14:43Z","publication_status":"published","intvolume":"       612","title":"Molecular engineering enables bright blue LEDs","volume":612,"citation":{"short":"H. Utzat, M. Ibáñez, Nature 612 (2022) 638–639.","mla":"Utzat, Hendrik, and Maria Ibáñez. “Molecular Engineering Enables Bright Blue LEDs.” <i>Nature</i>, vol. 612, no. 7941, Springer Nature, 2022, pp. 638–39, doi:<a href=\"https://doi.org/10.1038/d41586-022-04447-0\">10.1038/d41586-022-04447-0</a>.","ista":"Utzat H, Ibáñez M. 2022. Molecular engineering enables bright blue LEDs. Nature. 612(7941), 638–639.","ama":"Utzat H, Ibáñez M. Molecular engineering enables bright blue LEDs. <i>Nature</i>. 2022;612(7941):638-639. doi:<a href=\"https://doi.org/10.1038/d41586-022-04447-0\">10.1038/d41586-022-04447-0</a>","apa":"Utzat, H., &#38; Ibáñez, M. (2022). Molecular engineering enables bright blue LEDs. <i>Nature</i>. Springer Nature. <a href=\"https://doi.org/10.1038/d41586-022-04447-0\">https://doi.org/10.1038/d41586-022-04447-0</a>","ieee":"H. Utzat and M. Ibáñez, “Molecular engineering enables bright blue LEDs,” <i>Nature</i>, vol. 612, no. 7941. Springer Nature, pp. 638–639, 2022.","chicago":"Utzat, Hendrik, and Maria Ibáñez. “Molecular Engineering Enables Bright Blue LEDs.” <i>Nature</i>. Springer Nature, 2022. <a href=\"https://doi.org/10.1038/d41586-022-04447-0\">https://doi.org/10.1038/d41586-022-04447-0</a>."},"year":"2022","date_updated":"2023-10-18T06:26:30Z","external_id":{"pmid":["36543947"]},"day":"21","doi":"10.1038/d41586-022-04447-0","abstract":[{"text":"Future LEDs could be based on lead halide perovskites. A breakthrough in preparing device-compatible solids composed of nanoscale perovskite crystals overcomes a long-standing hurdle in making blue perovskite LEDs.","lang":"eng"}],"keyword":["Multidisciplinary"],"language":[{"iso":"eng"}],"publication":"Nature","oa_version":"None","month":"12","status":"public","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","type":"journal_article","date_published":"2022-12-21T00:00:00Z","publication_identifier":{"issn":["0028-0836"],"eissn":["1476-4687"]}},{"language":[{"iso":"eng"}],"keyword":["tin selenide","nanocomposite","grain growth","Zener pinning","thermoelectricity","annealing","solution processing"],"oa_version":"Published Version","project":[{"call_identifier":"H2020","_id":"260C2330-B435-11E9-9278-68D0E5697425","grant_number":"754411","name":"ISTplus - Postdoctoral Fellowships"},{"grant_number":"665385","name":"International IST Doctoral Program","_id":"2564DBCA-B435-11E9-9278-68D0E5697425","call_identifier":"H2020"},{"_id":"9B8F7476-BA93-11EA-9121-9846C619BF3A","name":"HighTE: The Werner Siemens Laboratory for the High Throughput Discovery of Semiconductors for Waste Heat Recovery"},{"name":"Bottom-up Engineering for Thermoelectric Applications","grant_number":"M02889","_id":"9B8804FC-BA93-11EA-9121-9846C619BF3A"}],"month":"01","publication":"ACS Nano","has_accepted_license":"1","file":[{"date_created":"2022-03-02T16:17:29Z","checksum":"74f9c1aa5f95c0b992a4328e8e0247b4","file_size":9050764,"date_updated":"2022-03-02T16:17:29Z","file_name":"2022_ACSNano_Liu.pdf","content_type":"application/pdf","access_level":"open_access","success":1,"relation":"main_file","file_id":"10808","creator":"cchlebak"}],"status":"public","user_id":"4359f0d1-fa6c-11eb-b949-802e58b17ae8","related_material":{"record":[{"status":"public","id":"12885","relation":"dissertation_contains"}]},"publication_identifier":{"eissn":["1936-086X"],"issn":["1936-0851"]},"oa":1,"tmp":{"legal_code_url":"https://creativecommons.org/licenses/by/4.0/legalcode","short":"CC BY (4.0)","image":"/images/cc_by.png","name":"Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)"},"date_published":"2022-01-25T00:00:00Z","type":"journal_article","publisher":"American Chemical Society ","article_type":"original","page":"78-88","ec_funded":1,"quality_controlled":"1","file_date_updated":"2022-03-02T16:17:29Z","publication_status":"published","date_created":"2021-09-24T07:55:12Z","department":[{"_id":"MaIb"}],"article_processing_charge":"Yes (via OA deal)","title":"Defect engineering in solution-processed polycrystalline SnSe leads to high thermoelectric performance","intvolume":"        16","_id":"10042","pmid":1,"scopus_import":"1","author":[{"id":"2A70014E-F248-11E8-B48F-1D18A9856A87","orcid":"0000-0001-7313-6740","full_name":"Liu, Yu","first_name":"Yu","last_name":"Liu"},{"id":"45D7531A-F248-11E8-B48F-1D18A9856A87","full_name":"Calcabrini, Mariano","last_name":"Calcabrini","first_name":"Mariano"},{"last_name":"Yu","first_name":"Yuan","full_name":"Yu, Yuan"},{"id":"BB243B88-D767-11E9-B658-BC13E6697425","first_name":"Seungho","last_name":"Lee","orcid":"0000-0002-6962-8598","full_name":"Lee, Seungho"},{"id":"9E331C2E-9F27-11E9-AE48-5033E6697425","orcid":"0000-0002-9515-4277","full_name":"Chang, Cheng","first_name":"Cheng","last_name":"Chang"},{"first_name":"Jérémy","last_name":"David","full_name":"David, Jérémy"},{"id":"a5fc9bc3-feff-11ea-93fe-e8015a3c7e9d","first_name":"Tanmoy","last_name":"Ghosh","full_name":"Ghosh, Tanmoy"},{"first_name":"Maria Chiara","last_name":"Spadaro","full_name":"Spadaro, Maria Chiara"},{"full_name":"Xie, Chenyang","first_name":"Chenyang","last_name":"Xie"},{"last_name":"Cojocaru-Mirédin","first_name":"Oana","full_name":"Cojocaru-Mirédin, Oana"},{"full_name":"Arbiol, Jordi","last_name":"Arbiol","first_name":"Jordi"},{"last_name":"Ibáñez","first_name":"Maria","full_name":"Ibáñez, Maria","orcid":"0000-0001-5013-2843","id":"43C61214-F248-11E8-B48F-1D18A9856A87"}],"issue":"1","acknowledgement":"This work was financially supported by IST Austria and the Werner Siemens Foundation. Y.L. acknowledges funding from the European Union’s Horizon 2020 research and innovation program under the Marie Sklodowska-Curie grant agreement No. 754411. S.L. and M.C. received funding from the European Union’s Horizon 2020 research and innovation program under the Marie Skłodowska-Curie Grant Agreement No. 665385. J.D. acknowledges funding from the European Union’s Horizon 2020 research and innovation program under the Marie Sklodowska-Curie grant agreement no. 665919 (P-SPHERE) cofunded by Severo Ochoa Programme. C.C. acknowledges funding from the FWF “Lise Meitner Fellowship” grant agreement M 2889-N. Y.Y. and O.C.-M. acknowledge the financial support from DFG within the project SFB 917: Nanoswitches. M.C.S. received funding from the European Union’s Horizon 2020 research and innovation programme under the Marie Skłodowska-Curie grant agreement No. 754510 (PROBIST) and the Severo Ochoa programme. J.D. received funding from the European Union’s Horizon 2020 research and innovation programme under the Marie Sklodowska-Curie grant agreement No. 665919 (P-SPHERE) cofunded by Severo Ochoa Programme. The ICN2 is funded by the CERCA Program/Generalitat de Catalunya and by the Severo Ochoa program of the Spanish Ministry of Economy, Industry, and Competitiveness (MINECO, grant no. SEV-2017-0706). ICN2 acknowledges funding from Generalitat de Catalunya 2017 SGR 327 and the Spanish MINECO project NANOGEN (PID2020-116093RB-C43). This project received funding from the European Union’s Horizon 2020 research and innovation program under grant agreement No. 823717-ESTEEM3. The FIB sample preparation was conducted in the LMA-INA-Universidad de Zaragoza.","volume":16,"ddc":["540"],"doi":"10.1021/acsnano.1c06720","day":"25","abstract":[{"lang":"eng","text":"SnSe has emerged as one of the most promising materials for thermoelectric energy conversion due to its extraordinary performance in its single-crystal form and its low-cost constituent elements. However, to achieve an economic impact, the polycrystalline counterpart needs to replicate the performance of the single crystal. Herein, we optimize the thermoelectric performance of polycrystalline SnSe produced by consolidating solution-processed and surface-engineered SnSe particles. In particular, the SnSe particles are coated with CdSe molecular complexes that crystallize during the sintering process, forming CdSe nanoparticles. The presence of CdSe nanoparticles inhibits SnSe grain growth during the consolidation step due to Zener pinning, yielding a material with a high density of grain boundaries. Moreover, the resulting SnSe–CdSe nanocomposites present a large number of defects at different length scales, which significantly reduce the thermal conductivity. The produced SnSe–CdSe nanocomposites exhibit thermoelectric figures of merit up to 2.2 at 786 K, which is among the highest reported for solution-processed SnSe."}],"date_updated":"2023-08-02T14:41:05Z","citation":{"ista":"Liu Y, Calcabrini M, Yu Y, Lee S, Chang C, David J, Ghosh T, Spadaro MC, Xie C, Cojocaru-Mirédin O, Arbiol J, Ibáñez M. 2022. Defect engineering in solution-processed polycrystalline SnSe leads to high thermoelectric performance. ACS Nano. 16(1), 78–88.","short":"Y. Liu, M. Calcabrini, Y. Yu, S. Lee, C. Chang, J. David, T. Ghosh, M.C. Spadaro, C. Xie, O. Cojocaru-Mirédin, J. Arbiol, M. Ibáñez, ACS Nano 16 (2022) 78–88.","mla":"Liu, Yu, et al. “Defect Engineering in Solution-Processed Polycrystalline SnSe Leads to High Thermoelectric Performance.” <i>ACS Nano</i>, vol. 16, no. 1, American Chemical Society , 2022, pp. 78–88, doi:<a href=\"https://doi.org/10.1021/acsnano.1c06720\">10.1021/acsnano.1c06720</a>.","ieee":"Y. Liu <i>et al.</i>, “Defect engineering in solution-processed polycrystalline SnSe leads to high thermoelectric performance,” <i>ACS Nano</i>, vol. 16, no. 1. American Chemical Society , pp. 78–88, 2022.","chicago":"Liu, Yu, Mariano Calcabrini, Yuan Yu, Seungho Lee, Cheng Chang, Jérémy David, Tanmoy Ghosh, et al. “Defect Engineering in Solution-Processed Polycrystalline SnSe Leads to High Thermoelectric Performance.” <i>ACS Nano</i>. American Chemical Society , 2022. <a href=\"https://doi.org/10.1021/acsnano.1c06720\">https://doi.org/10.1021/acsnano.1c06720</a>.","apa":"Liu, Y., Calcabrini, M., Yu, Y., Lee, S., Chang, C., David, J., … Ibáñez, M. (2022). Defect engineering in solution-processed polycrystalline SnSe leads to high thermoelectric performance. <i>ACS Nano</i>. American Chemical Society . <a href=\"https://doi.org/10.1021/acsnano.1c06720\">https://doi.org/10.1021/acsnano.1c06720</a>","ama":"Liu Y, Calcabrini M, Yu Y, et al. Defect engineering in solution-processed polycrystalline SnSe leads to high thermoelectric performance. <i>ACS Nano</i>. 2022;16(1):78-88. doi:<a href=\"https://doi.org/10.1021/acsnano.1c06720\">10.1021/acsnano.1c06720</a>"},"year":"2022","isi":1,"external_id":{"isi":["000767223400008"],"pmid":["34549956"]}},{"day":"01","doi":"10.1016/j.cej.2021.133837","abstract":[{"text":"A versatile, scalable, room temperature and surfactant-free route for the synthesis of metal chalcogenide nanoparticles in aqueous solution is detailed here for the production of PbS and Cu-doped PbS nanoparticles. Subsequently, nanoparticles are annealed in a reducing atmosphere to remove surface oxide, and consolidated into dense polycrystalline materials by means of spark plasma sintering. By characterizing the transport properties of the sintered material, we observe the annealing step and the incorporation of Cu to play a key role in promoting the thermoelectric performance of PbS. The presence of Cu allows improving the electrical conductivity by increasing the charge carrier concentration and simultaneously maintaining a large charge carrier mobility, which overall translates into record power factors at ambient temperature, 2.3 mWm-1K−2. Simultaneously, the lattice thermal conductivity decreases with the introduction of Cu, leading to a record high ZT = 0.37 at room temperature and ZT = 1.22 at 773 K. Besides, a record average ZTave = 0.76 is demonstrated in the temperature range 320–773 K for n-type Pb0.955Cu0.045S.","lang":"eng"}],"citation":{"ista":"Li M, Liu Y, Zhang Y, Chang C, Zhang T, Yang D, Xiao K, Arbiol J, Ibáñez M, Cabot A. 2022. Room temperature aqueous-based synthesis of copper-doped lead sulfide nanoparticles for thermoelectric application. Chemical Engineering Journal. 433, 133837.","short":"M. Li, Y. Liu, Y. Zhang, C. Chang, T. Zhang, D. Yang, K. Xiao, J. Arbiol, M. Ibáñez, A. Cabot, Chemical Engineering Journal 433 (2022).","mla":"Li, Mengyao, et al. “Room Temperature Aqueous-Based Synthesis of Copper-Doped Lead Sulfide Nanoparticles for Thermoelectric Application.” <i>Chemical Engineering Journal</i>, vol. 433, 133837, Elsevier, 2022, doi:<a href=\"https://doi.org/10.1016/j.cej.2021.133837\">10.1016/j.cej.2021.133837</a>.","chicago":"Li, Mengyao, Yu Liu, Yu Zhang, Cheng Chang, Ting Zhang, Dawei Yang, Ke Xiao, Jordi Arbiol, Maria Ibáñez, and Andreu Cabot. “Room Temperature Aqueous-Based Synthesis of Copper-Doped Lead Sulfide Nanoparticles for Thermoelectric Application.” <i>Chemical Engineering Journal</i>. Elsevier, 2022. <a href=\"https://doi.org/10.1016/j.cej.2021.133837\">https://doi.org/10.1016/j.cej.2021.133837</a>.","ieee":"M. Li <i>et al.</i>, “Room temperature aqueous-based synthesis of copper-doped lead sulfide nanoparticles for thermoelectric application,” <i>Chemical Engineering Journal</i>, vol. 433. Elsevier, 2022.","ama":"Li M, Liu Y, Zhang Y, et al. Room temperature aqueous-based synthesis of copper-doped lead sulfide nanoparticles for thermoelectric application. <i>Chemical Engineering Journal</i>. 2022;433. doi:<a href=\"https://doi.org/10.1016/j.cej.2021.133837\">10.1016/j.cej.2021.133837</a>","apa":"Li, M., Liu, Y., Zhang, Y., Chang, C., Zhang, T., Yang, D., … Cabot, A. (2022). Room temperature aqueous-based synthesis of copper-doped lead sulfide nanoparticles for thermoelectric application. <i>Chemical Engineering Journal</i>. Elsevier. <a href=\"https://doi.org/10.1016/j.cej.2021.133837\">https://doi.org/10.1016/j.cej.2021.133837</a>"},"year":"2022","date_updated":"2023-10-03T10:14:34Z","external_id":{"isi":["000773425200006"]},"isi":1,"volume":433,"acknowledgement":"This work was supported by the European Regional Development Funds. MYL, YZ, DWY and KX thank the China Scholarship Council for scholarship support. YL acknowledges funding from the European Union's Horizon 2020 research and innovation program under the Marie Sklodowska-Curie grant agreement No. 754411 and the funding for scientific research startup of Hefei University of Technology (No. 13020-03712021049). MI acknowledges funding from IST Austria and the Werner Siemens Foundation. CC acknowledges funding from the FWF “Lise Meitner Fellowship” grant agreement M 2889-N. TZ has received funding from the CSC-UAB PhD scholarship program. ICN2 acknowledges funding from Generalitat de Catalunya 2017 SGR 327. ICN2 thanks support from the project NANOGEN (PID2020-116093RB-C43), funded by MCIN/ AEI/10.13039/501100011033/. ICN2 is supported by the Severo Ochoa program from Spanish MINECO (Grant No. SEV-2017-0706) and is funded by the CERCA Programme / Generalitat de Catalunya. Part of the present work has been performed in the framework of Universitat Autònoma de Barcelona Materials Science PhD program.","date_created":"2021-12-19T23:01:33Z","article_processing_charge":"No","department":[{"_id":"MaIb"}],"publication_status":"published","intvolume":"       433","title":"Room temperature aqueous-based synthesis of copper-doped lead sulfide nanoparticles for thermoelectric application","scopus_import":"1","_id":"10566","author":[{"full_name":"Li, Mengyao","last_name":"Li","first_name":"Mengyao"},{"full_name":"Liu, Yu","orcid":"0000-0001-7313-6740","last_name":"Liu","first_name":"Yu","id":"2A70014E-F248-11E8-B48F-1D18A9856A87"},{"full_name":"Zhang, Yu","last_name":"Zhang","first_name":"Yu"},{"orcid":"0000-0002-9515-4277","full_name":"Chang, Cheng","first_name":"Cheng","last_name":"Chang","id":"9E331C2E-9F27-11E9-AE48-5033E6697425"},{"first_name":"Ting","last_name":"Zhang","full_name":"Zhang, Ting"},{"full_name":"Yang, Dawei","last_name":"Yang","first_name":"Dawei"},{"first_name":"Ke","last_name":"Xiao","full_name":"Xiao, Ke"},{"full_name":"Arbiol, Jordi","last_name":"Arbiol","first_name":"Jordi"},{"id":"43C61214-F248-11E8-B48F-1D18A9856A87","full_name":"Ibáñez, Maria","orcid":"0000-0001-5013-2843","last_name":"Ibáñez","first_name":"Maria"},{"first_name":"Andreu","last_name":"Cabot","full_name":"Cabot, Andreu"}],"publisher":"Elsevier","article_type":"original","ec_funded":1,"quality_controlled":"1","publication_identifier":{"issn":["1385-8947"]},"oa":1,"type":"journal_article","date_published":"2022-04-01T00:00:00Z","main_file_link":[{"url":"https://ddd.uab.cat/pub/artpub/2022/270830/10.1016j.cej.2021.133837.pdf","open_access":"1"}],"status":"public","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","project":[{"_id":"260C2330-B435-11E9-9278-68D0E5697425","call_identifier":"H2020","name":"ISTplus - Postdoctoral Fellowships","grant_number":"754411"},{"grant_number":"M02889","name":"Bottom-up Engineering for Thermoelectric Applications","_id":"9B8804FC-BA93-11EA-9121-9846C619BF3A"},{"name":"HighTE: The Werner Siemens Laboratory for the High Throughput Discovery of Semiconductors for Waste Heat Recovery","_id":"9B8F7476-BA93-11EA-9121-9846C619BF3A"}],"oa_version":"Submitted Version","article_number":"133837","month":"04","publication":"Chemical Engineering Journal","language":[{"iso":"eng"}]},{"month":"05","oa_version":"Submitted Version","publication":"Nano Research","language":[{"iso":"eng"}],"keyword":["interfacial assembly","colloidal nanocrystal","superlattice","inkjet printing"],"oa":1,"publication_identifier":{"issn":["1998-0124"],"eissn":["1998-0000"]},"date_published":"2022-05-01T00:00:00Z","type":"journal_article","user_id":"4359f0d1-fa6c-11eb-b949-802e58b17ae8","status":"public","main_file_link":[{"url":"https://www.osti.gov/biblio/1837946","open_access":"1"}],"title":"Inkjet printing of epitaxially connected nanocrystal superlattices","intvolume":"        15","publication_status":"published","department":[{"_id":"MaIb"}],"article_processing_charge":"No","date_created":"2022-01-02T23:01:34Z","author":[{"first_name":"Daniel","last_name":"Balazs","orcid":"0000-0001-7597-043X","full_name":"Balazs, Daniel","id":"302BADF6-85FC-11EA-9E3B-B9493DDC885E"},{"full_name":"Erkan, N. Deniz","last_name":"Erkan","first_name":"N. Deniz"},{"full_name":"Quien, Michelle","last_name":"Quien","first_name":"Michelle"},{"full_name":"Hanrath, Tobias","last_name":"Hanrath","first_name":"Tobias"}],"issue":"5","_id":"10587","scopus_import":"1","article_type":"original","publisher":"Springer Nature","page":"4536–4543","quality_controlled":"1","abstract":[{"text":"Access to a blossoming library of colloidal nanomaterials provides building blocks for complex assembled materials. The journey to bring these prospects to fruition stands to benefit from the application of advanced processing methods. Epitaxially connected nanocrystal (or quantum dot) superlattices present a captivating model system for mesocrystals with intriguing emergent properties. The conventional processing approach to creating these materials involves assembling and attaching the constituent nanocrystals at the interface between two immiscible fluids. Processing small liquid volumes of the colloidal nanocrystal solution involves several complexities arising from the concurrent spreading, evaporation, assembly, and attachment. The ability of inkjet printers to deliver small (typically picoliter) liquid volumes with precise positioning is attractive to advance fundamental insights into the processing science, and thereby potentially enable new routes to incorporate the epitaxially connected superlattices into technology platforms. In this study, we identified the processing window of opportunity, including nanocrystal ink formulation and printing approach to enable delivery of colloidal nanocrystals from an inkjet nozzle onto the surface of a sessile droplet of the immiscible subphase. We demonstrate how inkjet printing can be scaled-down to enable the fabrication of epitaxially connected superlattices on patterned sub-millimeter droplets. We anticipate that insights from this work will spur on future advances to enable more mechanistic insights into the assembly processes and new avenues to create high-fidelity superlattices.","lang":"eng"}],"doi":"10.1007/s12274-021-4022-7","day":"01","isi":1,"external_id":{"isi":["000735340300001"]},"date_updated":"2023-08-02T13:47:21Z","citation":{"mla":"Balazs, Daniel, et al. “Inkjet Printing of Epitaxially Connected Nanocrystal Superlattices.” <i>Nano Research</i>, vol. 15, no. 5, Springer Nature, 2022, pp. 4536–4543, doi:<a href=\"https://doi.org/10.1007/s12274-021-4022-7\">10.1007/s12274-021-4022-7</a>.","short":"D. Balazs, N.D. Erkan, M. Quien, T. Hanrath, Nano Research 15 (2022) 4536–4543.","ista":"Balazs D, Erkan ND, Quien M, Hanrath T. 2022. Inkjet printing of epitaxially connected nanocrystal superlattices. Nano Research. 15(5), 4536–4543.","ama":"Balazs D, Erkan ND, Quien M, Hanrath T. Inkjet printing of epitaxially connected nanocrystal superlattices. <i>Nano Research</i>. 2022;15(5):4536–4543. doi:<a href=\"https://doi.org/10.1007/s12274-021-4022-7\">10.1007/s12274-021-4022-7</a>","apa":"Balazs, D., Erkan, N. D., Quien, M., &#38; Hanrath, T. (2022). Inkjet printing of epitaxially connected nanocrystal superlattices. <i>Nano Research</i>. Springer Nature. <a href=\"https://doi.org/10.1007/s12274-021-4022-7\">https://doi.org/10.1007/s12274-021-4022-7</a>","chicago":"Balazs, Daniel, N. Deniz Erkan, Michelle Quien, and Tobias Hanrath. “Inkjet Printing of Epitaxially Connected Nanocrystal Superlattices.” <i>Nano Research</i>. Springer Nature, 2022. <a href=\"https://doi.org/10.1007/s12274-021-4022-7\">https://doi.org/10.1007/s12274-021-4022-7</a>.","ieee":"D. Balazs, N. D. Erkan, M. Quien, and T. Hanrath, “Inkjet printing of epitaxially connected nanocrystal superlattices,” <i>Nano Research</i>, vol. 15, no. 5. Springer Nature, pp. 4536–4543, 2022."},"year":"2022","acknowledgement":"This project was supported by the US Department of Energy through award (No. DE-SC0018026). The work was performed in part at the Cornell NanoScale Facility, a member of the National Nanotechnology Coordinated Infrastructure (NNCI), which is supported by the National Science Foundation (No. NNCI-1542081) and in part at the Cornell Center for Materials Research with funding from the NSF MRSEC program (No. DMR-1719875). The authors thank Beth Rhodes for the technical assistance with inkjet printing, and E. Peretz and Q. Wen for the early exploratory experiments.","volume":15},{"quality_controlled":"1","page":"4527-4541","article_type":"original","publisher":"Royal Society of Chemistry","issue":"11","author":[{"full_name":"Qin, Yongxin","last_name":"Qin","first_name":"Yongxin"},{"full_name":"Qin, Bingchao","last_name":"Qin","first_name":"Bingchao"},{"first_name":"Dongyang","last_name":"Wang","full_name":"Wang, Dongyang"},{"first_name":"Cheng","last_name":"Chang","orcid":"0000-0002-9515-4277","full_name":"Chang, Cheng","id":"9E331C2E-9F27-11E9-AE48-5033E6697425"},{"full_name":"Zhao, Li-Dong","last_name":"Zhao","first_name":"Li-Dong"}],"scopus_import":"1","_id":"12155","intvolume":"        15","title":"Solid-state cooling: Thermoelectrics","department":[{"_id":"MaIb"}],"article_processing_charge":"No","date_created":"2023-01-12T12:08:41Z","publication_status":"published","acknowledgement":"We acknowledge support from the National Key Research and Development Program of China (2018YFA0702100), the National Natural Science Foundation of China (51571007, 51772012, 52002011 and 52002042), the Basic Science Center Project of National Natural Science Foundation of China (51788104), Beijing Natural Science Foundation (JQ18004), 111 Project (B17002), and the National Science Fund for Distinguished Young Scholars (51925101).","volume":15,"external_id":{"isi":["000863642400001"]},"isi":1,"year":"2022","citation":{"apa":"Qin, Y., Qin, B., Wang, D., Chang, C., &#38; Zhao, L.-D. (2022). Solid-state cooling: Thermoelectrics. <i>Energy &#38; Environmental Science</i>. Royal Society of Chemistry. <a href=\"https://doi.org/10.1039/d2ee02408j\">https://doi.org/10.1039/d2ee02408j</a>","ama":"Qin Y, Qin B, Wang D, Chang C, Zhao L-D. Solid-state cooling: Thermoelectrics. <i>Energy &#38; Environmental Science</i>. 2022;15(11):4527-4541. doi:<a href=\"https://doi.org/10.1039/d2ee02408j\">10.1039/d2ee02408j</a>","ieee":"Y. Qin, B. Qin, D. Wang, C. Chang, and L.-D. Zhao, “Solid-state cooling: Thermoelectrics,” <i>Energy &#38; Environmental Science</i>, vol. 15, no. 11. Royal Society of Chemistry, pp. 4527–4541, 2022.","chicago":"Qin, Yongxin, Bingchao Qin, Dongyang Wang, Cheng Chang, and Li-Dong Zhao. “Solid-State Cooling: Thermoelectrics.” <i>Energy &#38; Environmental Science</i>. Royal Society of Chemistry, 2022. <a href=\"https://doi.org/10.1039/d2ee02408j\">https://doi.org/10.1039/d2ee02408j</a>.","mla":"Qin, Yongxin, et al. “Solid-State Cooling: Thermoelectrics.” <i>Energy &#38; Environmental Science</i>, vol. 15, no. 11, Royal Society of Chemistry, 2022, pp. 4527–41, doi:<a href=\"https://doi.org/10.1039/d2ee02408j\">10.1039/d2ee02408j</a>.","short":"Y. Qin, B. Qin, D. Wang, C. Chang, L.-D. Zhao, Energy &#38; Environmental Science 15 (2022) 4527–4541.","ista":"Qin Y, Qin B, Wang D, Chang C, Zhao L-D. 2022. Solid-state cooling: Thermoelectrics. Energy &#38; Environmental Science. 15(11), 4527–4541."},"date_updated":"2024-01-22T08:13:43Z","abstract":[{"text":"The growing demand of thermal management in various fields such as miniaturized 5G chips has motivated researchers to develop new and high-performance solid-state refrigeration technologies, typically including multicaloric and thermoelectric (TE) cooling. Among them, TE cooling has attracted huge attention owing to its advantages of rapid response, large cooling temperature difference, high stability, and tunable device size. Bi2Te3-based alloys have long been the only commercialized TE cooling materials, while novel systems SnSe and Mg3(Bi,Sb)2 have recently been discovered as potential candidates. However, challenges and problems still require to be summarized and further resolved for realizing better cooling performance. In this review, we systematically investigate TE cooling from its internal mechanism, crucial parameters, to device design and applications. Furthermore, we summarize the current optimization strategies for existing TE cooling materials, and finally provide some personal prospects especially the material-planification concept on future research on establishing better TE cooling.","lang":"eng"}],"day":"01","doi":"10.1039/d2ee02408j","keyword":["Pollution","Nuclear Energy and Engineering","Renewable Energy","Sustainability and the Environment","Environmental Chemistry"],"language":[{"iso":"eng"}],"publication":"Energy & Environmental Science","month":"11","oa_version":"None","status":"public","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","related_material":{"link":[{"relation":"erratum","url":"https://doi.org/10.1039/d3ee90067c"}]},"type":"journal_article","date_published":"2022-11-01T00:00:00Z","publication_identifier":{"eissn":["1754-5706"],"issn":["1754-5692"]}},{"keyword":["General Materials Science"],"language":[{"iso":"eng"}],"publication":"ACS Applied Materials & Interfaces","oa_version":"None","month":"10","status":"public","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","type":"journal_article","date_published":"2022-10-14T00:00:00Z","publication_identifier":{"eissn":["1944-8252"],"issn":["1944-8244"]},"quality_controlled":"1","page":"48212-48219","publisher":"American Chemical Society","article_type":"original","scopus_import":"1","pmid":1,"_id":"12236","issue":"42","author":[{"full_name":"Wang, Xiang","last_name":"Wang","first_name":"Xiang"},{"full_name":"Zuo, Yong","last_name":"Zuo","first_name":"Yong"},{"last_name":"Horta","first_name":"Sharona","full_name":"Horta, Sharona","id":"03a7e858-01b1-11ec-8b71-99ae6c4a05bc"},{"first_name":"Ren","last_name":"He","full_name":"He, Ren"},{"full_name":"Yang, Linlin","last_name":"Yang","first_name":"Linlin"},{"first_name":"Ahmad","last_name":"Ostovari Moghaddam","full_name":"Ostovari Moghaddam, Ahmad"},{"id":"43C61214-F248-11E8-B48F-1D18A9856A87","full_name":"Ibáñez, Maria","orcid":"0000-0001-5013-2843","last_name":"Ibáñez","first_name":"Maria"},{"full_name":"Qi, Xueqiang","first_name":"Xueqiang","last_name":"Qi"},{"last_name":"Cabot","first_name":"Andreu","full_name":"Cabot, Andreu"}],"date_created":"2023-01-16T09:51:10Z","department":[{"_id":"MaIb"}],"article_processing_charge":"No","publication_status":"published","intvolume":"        14","title":"CoFeNiMnZnB as a high-entropy metal boride to boost the oxygen evolution reaction","volume":14,"acknowledgement":"This work was supported by the Spanish MCIN project COMBENERGY (PID2019-105490RB-C32). X.W. and L.Y. thank the China Scholarship Council (CSC) for the scholarship support.","year":"2022","citation":{"ista":"Wang X, Zuo Y, Horta S, He R, Yang L, Ostovari Moghaddam A, Ibáñez M, Qi X, Cabot A. 2022. CoFeNiMnZnB as a high-entropy metal boride to boost the oxygen evolution reaction. ACS Applied Materials &#38; Interfaces. 14(42), 48212–48219.","short":"X. Wang, Y. Zuo, S. Horta, R. He, L. Yang, A. Ostovari Moghaddam, M. Ibáñez, X. Qi, A. Cabot, ACS Applied Materials &#38; Interfaces 14 (2022) 48212–48219.","mla":"Wang, Xiang, et al. “CoFeNiMnZnB as a High-Entropy Metal Boride to Boost the Oxygen Evolution Reaction.” <i>ACS Applied Materials &#38; Interfaces</i>, vol. 14, no. 42, American Chemical Society, 2022, pp. 48212–19, doi:<a href=\"https://doi.org/10.1021/acsami.2c11627\">10.1021/acsami.2c11627</a>.","ieee":"X. Wang <i>et al.</i>, “CoFeNiMnZnB as a high-entropy metal boride to boost the oxygen evolution reaction,” <i>ACS Applied Materials &#38; Interfaces</i>, vol. 14, no. 42. American Chemical Society, pp. 48212–48219, 2022.","chicago":"Wang, Xiang, Yong Zuo, Sharona Horta, Ren He, Linlin Yang, Ahmad Ostovari Moghaddam, Maria Ibáñez, Xueqiang Qi, and Andreu Cabot. “CoFeNiMnZnB as a High-Entropy Metal Boride to Boost the Oxygen Evolution Reaction.” <i>ACS Applied Materials &#38; Interfaces</i>. American Chemical Society, 2022. <a href=\"https://doi.org/10.1021/acsami.2c11627\">https://doi.org/10.1021/acsami.2c11627</a>.","ama":"Wang X, Zuo Y, Horta S, et al. CoFeNiMnZnB as a high-entropy metal boride to boost the oxygen evolution reaction. <i>ACS Applied Materials &#38; Interfaces</i>. 2022;14(42):48212-48219. doi:<a href=\"https://doi.org/10.1021/acsami.2c11627\">10.1021/acsami.2c11627</a>","apa":"Wang, X., Zuo, Y., Horta, S., He, R., Yang, L., Ostovari Moghaddam, A., … Cabot, A. (2022). CoFeNiMnZnB as a high-entropy metal boride to boost the oxygen evolution reaction. <i>ACS Applied Materials &#38; Interfaces</i>. American Chemical Society. <a href=\"https://doi.org/10.1021/acsami.2c11627\">https://doi.org/10.1021/acsami.2c11627</a>"},"date_updated":"2023-10-04T08:28:14Z","external_id":{"isi":["000873782700001"],"pmid":["36239982"]},"isi":1,"day":"14","doi":"10.1021/acsami.2c11627","abstract":[{"text":"High-entropy materials offer numerous advantages as catalysts, including a flexible composition to tune the catalytic activity and selectivity and a large variety of adsorption/reaction sites for multistep or multiple reactions. Herein, we report on the synthesis, properties, and electrocatalytic performance of an amorphous high-entropy boride based on abundant transition metals, CoFeNiMnZnB. This metal boride provides excellent performance toward the oxygen evolution reaction (OER), including a low overpotential of 261 mV at 10 mA cm–2, a reduced Tafel slope of 56.8 mV dec–1, and very high stability. The outstanding OER performance of CoFeNiMnZnB is attributed to the synergistic interactions between the different metals, the leaching of Zn ions, the generation of oxygen vacancies, and the in situ formation of an amorphous oxyhydroxide at the CoFeNiMnZnB surface during the OER.","lang":"eng"}]},{"intvolume":"        34","title":"Solution-processed inorganic thermoelectric materials: Opportunities and challenges","date_created":"2023-01-16T09:51:26Z","department":[{"_id":"MaIb"}],"article_processing_charge":"Yes (via OA deal)","publication_status":"published","issue":"19","author":[{"id":"bd3fceba-dc74-11ea-a0a7-c17f71817366","first_name":"Christine","last_name":"Fiedler","full_name":"Fiedler, Christine"},{"id":"8BD9DE16-AB3C-11E9-9C8C-2A03E6697425","first_name":"Tobias","last_name":"Kleinhanns","full_name":"Kleinhanns, Tobias"},{"id":"6e5c50b8-97dc-11ed-be98-b0a74c84cae0","first_name":"Maria","last_name":"Garcia","full_name":"Garcia, Maria"},{"id":"BB243B88-D767-11E9-B658-BC13E6697425","orcid":"0000-0002-6962-8598","full_name":"Lee, Seungho","first_name":"Seungho","last_name":"Lee"},{"full_name":"Calcabrini, Mariano","first_name":"Mariano","last_name":"Calcabrini","id":"45D7531A-F248-11E8-B48F-1D18A9856A87"},{"first_name":"Maria","last_name":"Ibáñez","orcid":"0000-0001-5013-2843","full_name":"Ibáñez, Maria","id":"43C61214-F248-11E8-B48F-1D18A9856A87"}],"scopus_import":"1","_id":"12237","pmid":1,"article_type":"original","publisher":"American Chemical Society","file_date_updated":"2023-01-30T07:35:09Z","quality_controlled":"1","ec_funded":1,"page":"8471-8489","abstract":[{"lang":"eng","text":"Thermoelectric technology requires synthesizing complex materials where not only the crystal structure but also other structural features such as defects, grain size and orientation, and interfaces must be controlled. To date, conventional solid-state techniques are unable to provide this level of control. Herein, we present a synthetic approach in which dense inorganic thermoelectric materials are produced by the consolidation of well-defined nanoparticle powders. The idea is that controlling the characteristics of the powder allows the chemical transformations that take place during consolidation to be guided, ultimately yielding inorganic solids with targeted features. Different from conventional methods, syntheses in solution can produce particles with unprecedented control over their size, shape, crystal structure, composition, and surface chemistry. However, to date, most works have focused only on the low-cost benefits of this strategy. In this perspective, we first cover the opportunities that solution processing of the powder offers, emphasizing the potential structural features that can be controlled by precisely engineering the inorganic core of the particle, the surface, and the organization of the particles before consolidation. We then discuss the challenges of this synthetic approach and more practical matters related to solution processing. Finally, we suggest some good practices for adequate knowledge transfer and improving reproducibility among different laboratories."}],"day":"20","doi":"10.1021/acs.chemmater.2c01967","external_id":{"pmid":["36248227"],"isi":["000917837600001"]},"isi":1,"citation":{"apa":"Fiedler, C., Kleinhanns, T., Garcia, M., Lee, S., Calcabrini, M., &#38; Ibáñez, M. (2022). Solution-processed inorganic thermoelectric materials: Opportunities and challenges. <i>Chemistry of Materials</i>. American Chemical Society. <a href=\"https://doi.org/10.1021/acs.chemmater.2c01967\">https://doi.org/10.1021/acs.chemmater.2c01967</a>","ama":"Fiedler C, Kleinhanns T, Garcia M, Lee S, Calcabrini M, Ibáñez M. Solution-processed inorganic thermoelectric materials: Opportunities and challenges. <i>Chemistry of Materials</i>. 2022;34(19):8471-8489. doi:<a href=\"https://doi.org/10.1021/acs.chemmater.2c01967\">10.1021/acs.chemmater.2c01967</a>","ieee":"C. Fiedler, T. Kleinhanns, M. Garcia, S. Lee, M. Calcabrini, and M. Ibáñez, “Solution-processed inorganic thermoelectric materials: Opportunities and challenges,” <i>Chemistry of Materials</i>, vol. 34, no. 19. American Chemical Society, pp. 8471–8489, 2022.","chicago":"Fiedler, Christine, Tobias Kleinhanns, Maria Garcia, Seungho Lee, Mariano Calcabrini, and Maria Ibáñez. “Solution-Processed Inorganic Thermoelectric Materials: Opportunities and Challenges.” <i>Chemistry of Materials</i>. American Chemical Society, 2022. <a href=\"https://doi.org/10.1021/acs.chemmater.2c01967\">https://doi.org/10.1021/acs.chemmater.2c01967</a>.","mla":"Fiedler, Christine, et al. “Solution-Processed Inorganic Thermoelectric Materials: Opportunities and Challenges.” <i>Chemistry of Materials</i>, vol. 34, no. 19, American Chemical Society, 2022, pp. 8471–89, doi:<a href=\"https://doi.org/10.1021/acs.chemmater.2c01967\">10.1021/acs.chemmater.2c01967</a>.","short":"C. Fiedler, T. Kleinhanns, M. Garcia, S. Lee, M. Calcabrini, M. Ibáñez, Chemistry of Materials 34 (2022) 8471–8489.","ista":"Fiedler C, Kleinhanns T, Garcia M, Lee S, Calcabrini M, Ibáñez M. 2022. Solution-processed inorganic thermoelectric materials: Opportunities and challenges. Chemistry of Materials. 34(19), 8471–8489."},"year":"2022","date_updated":"2023-08-04T09:38:26Z","ddc":["540"],"acknowledgement":"This work was financially supported by ISTA and the Werner Siemens Foundation. M.C. has received funding from the European Union’s Horizon 2020 research and innovation program under the Marie Skłodowska-Curie Grant Agreement no. 665385.","volume":34,"month":"09","project":[{"grant_number":"665385","name":"International IST Doctoral Program","_id":"2564DBCA-B435-11E9-9278-68D0E5697425","call_identifier":"H2020"}],"oa_version":"Published Version","has_accepted_license":"1","publication":"Chemistry of Materials","keyword":["Materials Chemistry","General Chemical Engineering","General Chemistry"],"language":[{"iso":"eng"}],"oa":1,"publication_identifier":{"eissn":["1520-5002"],"issn":["0897-4756"]},"type":"journal_article","date_published":"2022-09-20T00:00:00Z","tmp":{"legal_code_url":"https://creativecommons.org/licenses/by/4.0/legalcode","short":"CC BY (4.0)","image":"/images/cc_by.png","name":"Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)"},"status":"public","related_material":{"record":[{"relation":"dissertation_contains","id":"12885","status":"public"}]},"user_id":"4359f0d1-fa6c-11eb-b949-802e58b17ae8","file":[{"file_size":10923495,"checksum":"f7143e44ab510519d1949099c3558532","date_created":"2023-01-30T07:35:09Z","file_name":"2022_ChemistryMaterials_Fiedler.pdf","content_type":"application/pdf","date_updated":"2023-01-30T07:35:09Z","access_level":"open_access","relation":"main_file","success":1,"creator":"dernst","file_id":"12434"}]},{"file":[{"checksum":"1c66a35369e911312a359111420318a9","file_size":1257973,"date_created":"2022-03-02T15:33:18Z","file_name":"2021_JACSAu_Calcabrini.pdf","content_type":"application/pdf","date_updated":"2022-03-02T15:33:18Z","relation":"main_file","access_level":"open_access","success":1,"creator":"cchlebak","file_id":"10807"}],"status":"public","related_material":{"record":[{"relation":"dissertation_contains","id":"12885","status":"public"}],"link":[{"relation":"earlier_version","url":"https://doi.org/10.26434/chemrxiv-2021-cn2fr"}]},"user_id":"8b945eb4-e2f2-11eb-945a-df72226e66a9","publication_identifier":{"eissn":["2691-3704"],"issn":["2691-3704"]},"oa":1,"tmp":{"legal_code_url":"https://creativecommons.org/licenses/by/4.0/legalcode","short":"CC BY (4.0)","image":"/images/cc_by.png","name":"Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)"},"date_published":"2021-11-22T00:00:00Z","type":"journal_article","language":[{"iso":"eng"}],"keyword":["general medicine"],"oa_version":"Published Version","project":[{"grant_number":"665385","name":"International IST Doctoral Program","_id":"2564DBCA-B435-11E9-9278-68D0E5697425","call_identifier":"H2020"},{"_id":"9B8F7476-BA93-11EA-9121-9846C619BF3A","name":"HighTE: The Werner Siemens Laboratory for the High Throughput Discovery of Semiconductors for Waste Heat Recovery"},{"_id":"B67AFEDC-15C9-11EA-A837-991A96BB2854","name":"IST Austria Open Access Fund"}],"month":"11","publication":"JACS Au","has_accepted_license":"1","acknowledgement":"This work was financially supported by IST Austria and the Werner Siemens Foundation. M.C. has received funding from the European Union’s Horizon 2020 research and innovation programme under the Marie Skłodowska-Curie Grant Agreement No. 665385. The work was also financially supported by University of Basel, SNSF NCCR Molecular Systems Engineering (project number: 182895) and SNSF R’equip (project number: 189622). J.L. is a Serra Húnter Fellow and is grateful to ICREA Academia program and MICINN/FEDER RTI2018-093996-B-C31 and GC 2017 SGR 128 projects.","volume":1,"ddc":["540"],"doi":"10.1021/jacsau.1c00349","day":"22","abstract":[{"lang":"eng","text":"Ligands are a fundamental part of nanocrystals. They control and direct nanocrystal syntheses and provide colloidal stability. Bound ligands also affect the nanocrystals’ chemical reactivity and electronic structure. Surface chemistry is thus crucial to understand nanocrystal properties and functionality. Here, we investigate the synthesis of metal oxide nanocrystals (CeO2-x, ZnO, and NiO) from metal nitrate precursors, in the presence of oleylamine ligands. Surprisingly, the nanocrystals are capped exclusively with a fatty acid instead of oleylamine. Analysis of the reaction mixtures with nuclear magnetic resonance spectroscopy revealed several reaction byproducts and intermediates that are common to the decomposition of Ce, Zn, Ni, and Zr nitrate precursors. Our evidence supports the oxidation of alkylamine and formation of a carboxylic acid, thus unraveling this counterintuitive surface chemistry."}],"date_updated":"2023-05-05T08:45:36Z","citation":{"ista":"Calcabrini M, Van den Eynden D, Sanchez Ribot S, Pokratath R, Llorca J, De Roo J, Ibáñez M. 2021. Ligand conversion in nanocrystal synthesis: The oxidation of alkylamines to fatty acids by nitrate. JACS Au. 1(11), 1898–1903.","mla":"Calcabrini, Mariano, et al. “Ligand Conversion in Nanocrystal Synthesis: The Oxidation of Alkylamines to Fatty Acids by Nitrate.” <i>JACS Au</i>, vol. 1, no. 11, American Chemical Society, 2021, pp. 1898–903, doi:<a href=\"https://doi.org/10.1021/jacsau.1c00349\">10.1021/jacsau.1c00349</a>.","short":"M. Calcabrini, D. Van den Eynden, S. Sanchez Ribot, R. Pokratath, J. Llorca, J. De Roo, M. Ibáñez, JACS Au 1 (2021) 1898–1903.","chicago":"Calcabrini, Mariano, Dietger Van den Eynden, Sergi Sanchez Ribot, Rohan Pokratath, Jordi Llorca, Jonathan De Roo, and Maria Ibáñez. “Ligand Conversion in Nanocrystal Synthesis: The Oxidation of Alkylamines to Fatty Acids by Nitrate.” <i>JACS Au</i>. American Chemical Society, 2021. <a href=\"https://doi.org/10.1021/jacsau.1c00349\">https://doi.org/10.1021/jacsau.1c00349</a>.","ieee":"M. Calcabrini <i>et al.</i>, “Ligand conversion in nanocrystal synthesis: The oxidation of alkylamines to fatty acids by nitrate,” <i>JACS Au</i>, vol. 1, no. 11. American Chemical Society, pp. 1898–1903, 2021.","apa":"Calcabrini, M., Van den Eynden, D., Sanchez Ribot, S., Pokratath, R., Llorca, J., De Roo, J., &#38; Ibáñez, M. (2021). Ligand conversion in nanocrystal synthesis: The oxidation of alkylamines to fatty acids by nitrate. <i>JACS Au</i>. American Chemical Society. <a href=\"https://doi.org/10.1021/jacsau.1c00349\">https://doi.org/10.1021/jacsau.1c00349</a>","ama":"Calcabrini M, Van den Eynden D, Sanchez Ribot S, et al. Ligand conversion in nanocrystal synthesis: The oxidation of alkylamines to fatty acids by nitrate. <i>JACS Au</i>. 2021;1(11):1898-1903. doi:<a href=\"https://doi.org/10.1021/jacsau.1c00349\">10.1021/jacsau.1c00349</a>"},"year":"2021","publisher":"American Chemical Society","article_type":"original","page":"1898-1903","quality_controlled":"1","ec_funded":1,"file_date_updated":"2022-03-02T15:33:18Z","publication_status":"published","article_processing_charge":"Yes (via OA deal)","department":[{"_id":"MaIb"}],"date_created":"2022-03-02T15:24:16Z","title":"Ligand conversion in nanocrystal synthesis: The oxidation of alkylamines to fatty acids by nitrate","intvolume":"         1","_id":"10806","author":[{"id":"45D7531A-F248-11E8-B48F-1D18A9856A87","full_name":"Calcabrini, Mariano","last_name":"Calcabrini","first_name":"Mariano"},{"first_name":"Dietger","last_name":"Van den Eynden","full_name":"Van den Eynden, Dietger"},{"full_name":"Sanchez Ribot, Sergi","first_name":"Sergi","last_name":"Sanchez Ribot","id":"ddae5a59-f6e0-11ea-865d-d9dc61e77a2a"},{"full_name":"Pokratath, Rohan","first_name":"Rohan","last_name":"Pokratath"},{"first_name":"Jordi","last_name":"Llorca","full_name":"Llorca, Jordi"},{"last_name":"De Roo","first_name":"Jonathan","full_name":"De Roo, Jonathan"},{"id":"43C61214-F248-11E8-B48F-1D18A9856A87","first_name":"Maria","last_name":"Ibáñez","orcid":"0000-0001-5013-2843","full_name":"Ibáñez, Maria"}],"issue":"11"},{"keyword":["multidisciplinary"],"language":[{"iso":"eng"}],"publication":"Science","month":"02","oa_version":"None","user_id":"4359f0d1-fa6c-11eb-b949-802e58b17ae8","status":"public","type":"journal_article","date_published":"2021-02-12T00:00:00Z","publication_identifier":{"issn":["0036-8075"],"eissn":["1095-9203"]},"quality_controlled":"1","page":"678-679","article_type":"letter_note","publisher":"American Association for the Advancement of Science","issue":"6530","author":[{"id":"2A70014E-F248-11E8-B48F-1D18A9856A87","last_name":"Liu","first_name":"Yu","full_name":"Liu, Yu","orcid":"0000-0001-7313-6740"},{"last_name":"Ibáñez","first_name":"Maria","full_name":"Ibáñez, Maria","orcid":"0000-0001-5013-2843","id":"43C61214-F248-11E8-B48F-1D18A9856A87"}],"scopus_import":"1","_id":"10809","pmid":1,"intvolume":"       371","title":"Tidying up the mess","article_processing_charge":"No","department":[{"_id":"MaIb"}],"date_created":"2022-03-03T09:51:48Z","publication_status":"published","volume":371,"external_id":{"isi":["000617551600027"],"pmid":["33574201"]},"isi":1,"year":"2021","citation":{"ama":"Liu Y, Ibáñez M. Tidying up the mess. <i>Science</i>. 2021;371(6530):678-679. doi:<a href=\"https://doi.org/10.1126/science.abg0886\">10.1126/science.abg0886</a>","apa":"Liu, Y., &#38; Ibáñez, M. (2021). Tidying up the mess. <i>Science</i>. American Association for the Advancement of Science. <a href=\"https://doi.org/10.1126/science.abg0886\">https://doi.org/10.1126/science.abg0886</a>","chicago":"Liu, Yu, and Maria Ibáñez. “Tidying up the Mess.” <i>Science</i>. American Association for the Advancement of Science, 2021. <a href=\"https://doi.org/10.1126/science.abg0886\">https://doi.org/10.1126/science.abg0886</a>.","ieee":"Y. Liu and M. Ibáñez, “Tidying up the mess,” <i>Science</i>, vol. 371, no. 6530. American Association for the Advancement of Science, pp. 678–679, 2021.","mla":"Liu, Yu, and Maria Ibáñez. “Tidying up the Mess.” <i>Science</i>, vol. 371, no. 6530, American Association for the Advancement of Science, 2021, pp. 678–79, doi:<a href=\"https://doi.org/10.1126/science.abg0886\">10.1126/science.abg0886</a>.","short":"Y. Liu, M. Ibáñez, Science 371 (2021) 678–679.","ista":"Liu Y, Ibáñez M. 2021. Tidying up the mess. Science. 371(6530), 678–679."},"date_updated":"2023-08-17T07:00:35Z","abstract":[{"text":"Thermoelectric materials are engines that convert heat into an electrical current. Intuitively, the efficiency of this process depends on how many electrons (charge carriers) can move and how easily they do so, how much energy those moving electrons transport, and how easily the temperature gradient is maintained. In terms of material properties, an excellent thermoelectric material requires a high electrical conductivity σ, a high Seebeck coefficient S (a measure of the induced thermoelectric voltage as a function of temperature gradient), and a low thermal conductivity κ. The challenge is that these three properties are strongly interrelated in a conflicting manner (1). On page 722 of this issue, Roychowdhury et al. (2) have found a way to partially break these ties in silver antimony telluride (AgSbTe2) with the addition of cadmium (Cd) cations, which increase the ordering in this inherently disordered thermoelectric material.","lang":"eng"}],"day":"12","doi":"10.1126/science.abg0886"}]