---
_id: '1210'
abstract:
- lang: eng
text: Mechanisms for cell protection are essential for survival of multicellular
organisms. In plants, the apical hook, which is transiently formed in darkness
when the germinating seedling penetrates towards the soil surface, plays such
protective role and shields the vitally important shoot apical meristem and cotyledons
from damage. The apical hook is formed by bending of the upper hypocotyl soon
after germination, and it is maintained in a closed stage while the hypocotyl
continues to penetrate through the soil and rapidly opens when exposed to light
in proximity of the soil surface. To uncover the complex molecular network orchestrating
this spatiotemporally tightly coordinated process, monitoring of the apical hook
development in real time is indispensable. Here we describe an imaging platform
that enables high-resolution kinetic analysis of this dynamic developmental process.
© Springer Science+Business Media New York 2017.
acknowledgement: "We thank Herman \r\nHöfte \r\n, Todor Asenov, Robert Hauschield,
and \r\nMarcal Gallemi for help with the establishment of the real-time
\ \r\nimaging platform and technical support. This work was supported \r\nby the
Czech Science Foundation (GA13-39982S) to Eva Benková. \r\nDominique Van Der
\ Straeten acknowledges the Research \r\nFoundation Flanders for fi\r\n
\ nancial support (G.0656.13N). Dajo \r\nSmet holds a PhD fellowship of the
Research Foundation Flanders. "
alternative_title:
- Methods in Molecular Biology
author:
- first_name: Qiang
full_name: Zhu, Qiang
id: 40A4B9E6-F248-11E8-B48F-1D18A9856A87
last_name: Zhu
- first_name: Petra
full_name: Žádníková, Petra
last_name: Žádníková
- first_name: Dajo
full_name: Smet, Dajo
last_name: Smet
- first_name: Dominique
full_name: Van Der Straeten, Dominique
last_name: Van Der Straeten
- first_name: Eva
full_name: Benková, Eva
id: 38F4F166-F248-11E8-B48F-1D18A9856A87
last_name: Benková
orcid: 0000-0002-8510-9739
citation:
ama: 'Zhu Q, Žádníková P, Smet D, Van Der Straeten D, Benková E. Real time analysis
of the apical hook development. In: Plant Hormones. Vol 1497. Humana Press;
2016:1-8. doi:10.1007/978-1-4939-6469-7_1'
apa: Zhu, Q., Žádníková, P., Smet, D., Van Der Straeten, D., & Benková, E. (2016).
Real time analysis of the apical hook development. In Plant Hormones (Vol.
1497, pp. 1–8). Humana Press. https://doi.org/10.1007/978-1-4939-6469-7_1
chicago: Zhu, Qiang, Petra Žádníková, Dajo Smet, Dominique Van Der Straeten, and
Eva Benková. “Real Time Analysis of the Apical Hook Development.” In Plant
Hormones, 1497:1–8. Humana Press, 2016. https://doi.org/10.1007/978-1-4939-6469-7_1.
ieee: Q. Zhu, P. Žádníková, D. Smet, D. Van Der Straeten, and E. Benková, “Real
time analysis of the apical hook development,” in Plant Hormones, vol.
1497, Humana Press, 2016, pp. 1–8.
ista: 'Zhu Q, Žádníková P, Smet D, Van Der Straeten D, Benková E. 2016.Real time
analysis of the apical hook development. In: Plant Hormones. Methods in Molecular
Biology, vol. 1497, 1–8.'
mla: Zhu, Qiang, et al. “Real Time Analysis of the Apical Hook Development.” Plant
Hormones, vol. 1497, Humana Press, 2016, pp. 1–8, doi:10.1007/978-1-4939-6469-7_1.
short: Q. Zhu, P. Žádníková, D. Smet, D. Van Der Straeten, E. Benková, in:, Plant
Hormones, Humana Press, 2016, pp. 1–8.
date_created: 2018-12-11T11:50:44Z
date_published: 2016-11-19T00:00:00Z
date_updated: 2021-01-12T06:49:07Z
day: '19'
department:
- _id: EvBe
doi: 10.1007/978-1-4939-6469-7_1
intvolume: ' 1497'
language:
- iso: eng
month: '11'
oa_version: None
page: 1 - 8
publication: Plant Hormones
publication_status: published
publisher: Humana Press
publist_id: '6135'
quality_controlled: '1'
scopus_import: 1
status: public
title: Real time analysis of the apical hook development
type: book_chapter
user_id: 3E5EF7F0-F248-11E8-B48F-1D18A9856A87
volume: 1497
year: '2016'
...
---
_id: '1212'
abstract:
- lang: eng
text: 'Plants adjust their growth according to gravity. Gravitropism involves gravity
perception, signal transduction, and asymmetric growth response, with organ bending
as a consequence [1]. Asymmetric growth results from the asymmetric distribution
of the plant-specific signaling molecule auxin [2] that is generated by lateral
transport, mediated in the hypocotyl predominantly by the auxin transporter PIN-FORMED3
(PIN3) [3–5]. Gravity stimulation polarizes PIN3 to the bottom sides of endodermal
cells, correlating with increased auxin accumulation in adjacent tissues at the
lower side of the stimulated organ, where auxin induces cell elongation and, hence,
organ bending. A curvature response allows the hypocotyl to resume straight growth
at a defined angle [6], implying that at some point auxin symmetry is restored
to prevent overbending. Here, we present initial insights into cellular and molecular
mechanisms that lead to the termination of the tropic response. We identified
an auxin feedback on PIN3 polarization as underlying mechanism that restores symmetry
of the PIN3-dependent auxin flow. Thus, two mechanistically distinct PIN3 polarization
events redirect auxin fluxes at different time points of the gravity response:
first, gravity-mediated redirection of PIN3-mediated auxin flow toward the lower
hypocotyl side, where auxin gradually accumulates and promotes growth, and later
PIN3 polarization to the opposite cell side, depleting this auxin maximum to end
the bending. Accordingly, genetic or pharmacological interference with the late
PIN3 polarization prevents termination of the response and leads to hypocotyl
overbending. This observation reveals a role of auxin feedback on PIN polarity
in the termination of the tropic response. © 2016 Elsevier Ltd'
acknowledgement: "We thank Dr. Jie Li (Key Laboratory of Plant Molecular Physiology,
Chinese Academy of Science, China) for the pPIN3::PIN3-GFP/DII::VENUS line and Martine
De Cock for help in preparing the manuscript. This work was supported by the European
Research Council (project ERC-2011-StG-20101109-PSDP), by the Czech Science Foundation
GAČR (GA13-40637S) to J.F., and by the Ministry of Education, Youth and Sports of
the Czech Republic under the project CEITEC 2020 (LQ1601) to H.S.R. H.R. is indebted
to the Agency for Innovation by Science and Technology (IWT) for a predoctoral fellowship.\r\n"
author:
- first_name: Hana
full_name: Rakusová, Hana
last_name: Rakusová
- first_name: Mohamad
full_name: Abbas, Mohamad
id: 47E8FC1C-F248-11E8-B48F-1D18A9856A87
last_name: Abbas
- first_name: Huibin
full_name: Han, Huibin
id: 31435098-F248-11E8-B48F-1D18A9856A87
last_name: Han
- first_name: Siyuan
full_name: Song, Siyuan
last_name: Song
- first_name: Hélène
full_name: Robert, Hélène
last_name: Robert
- first_name: Jirí
full_name: Friml, Jirí
id: 4159519E-F248-11E8-B48F-1D18A9856A87
last_name: Friml
orcid: 0000-0002-8302-7596
citation:
ama: Rakusová H, Abbas M, Han H, Song S, Robert H, Friml J. Termination of shoot
gravitropic responses by auxin feedback on PIN3 polarity. Current Biology.
2016;26(22):3026-3032. doi:10.1016/j.cub.2016.08.067
apa: Rakusová, H., Abbas, M., Han, H., Song, S., Robert, H., & Friml, J. (2016).
Termination of shoot gravitropic responses by auxin feedback on PIN3 polarity.
Current Biology. Cell Press. https://doi.org/10.1016/j.cub.2016.08.067
chicago: Rakusová, Hana, Mohamad Abbas, Huibin Han, Siyuan Song, Hélène Robert,
and Jiří Friml. “Termination of Shoot Gravitropic Responses by Auxin Feedback
on PIN3 Polarity.” Current Biology. Cell Press, 2016. https://doi.org/10.1016/j.cub.2016.08.067.
ieee: H. Rakusová, M. Abbas, H. Han, S. Song, H. Robert, and J. Friml, “Termination
of shoot gravitropic responses by auxin feedback on PIN3 polarity,” Current
Biology, vol. 26, no. 22. Cell Press, pp. 3026–3032, 2016.
ista: Rakusová H, Abbas M, Han H, Song S, Robert H, Friml J. 2016. Termination of
shoot gravitropic responses by auxin feedback on PIN3 polarity. Current Biology.
26(22), 3026–3032.
mla: Rakusová, Hana, et al. “Termination of Shoot Gravitropic Responses by Auxin
Feedback on PIN3 Polarity.” Current Biology, vol. 26, no. 22, Cell Press,
2016, pp. 3026–32, doi:10.1016/j.cub.2016.08.067.
short: H. Rakusová, M. Abbas, H. Han, S. Song, H. Robert, J. Friml, Current Biology
26 (2016) 3026–3032.
date_created: 2018-12-11T11:50:44Z
date_published: 2016-11-21T00:00:00Z
date_updated: 2021-01-12T06:49:08Z
day: '21'
ddc:
- '581'
department:
- _id: JiFr
doi: 10.1016/j.cub.2016.08.067
ec_funded: 1
file:
- access_level: open_access
checksum: 79ed2498185a027cf51a8f88100379e6
content_type: application/pdf
creator: system
date_created: 2018-12-12T10:09:33Z
date_updated: 2020-07-14T12:44:39Z
file_id: '4757'
file_name: IST-2018-1008-v1+1_Rakusova_CurrBiol_2016_proof.pdf
file_size: 5391923
relation: main_file
file_date_updated: 2020-07-14T12:44:39Z
has_accepted_license: '1'
intvolume: ' 26'
issue: '22'
language:
- iso: eng
month: '11'
oa: 1
oa_version: Submitted Version
page: 3026 - 3032
project:
- _id: 25716A02-B435-11E9-9278-68D0E5697425
call_identifier: FP7
grant_number: '282300'
name: Polarity and subcellular dynamics in plants
publication: Current Biology
publication_status: published
publisher: Cell Press
publist_id: '6138'
pubrep_id: '1008'
quality_controlled: '1'
scopus_import: 1
status: public
title: Termination of shoot gravitropic responses by auxin feedback on PIN3 polarity
type: journal_article
user_id: 3E5EF7F0-F248-11E8-B48F-1D18A9856A87
volume: 26
year: '2016'
...
---
_id: '1214'
abstract:
- lang: eng
text: 'With the accelerated development of robot technologies, optimal control becomes
one of the central themes of research. In traditional approaches, the controller,
by its internal functionality, finds appropriate actions on the basis of the history
of sensor values, guided by the goals, intentions, objectives, learning schemes,
and so forth. While very successful with classical robots, these methods run into
severe difficulties when applied to soft robots, a new field of robotics with
large interest for human-robot interaction. We claim that a novel controller paradigm
opens new perspective for this field. This paper applies a recently developed
neuro controller with differential extrinsic synaptic plasticity to a muscle-tendon
driven arm-shoulder system from the Myorobotics toolkit. In the experiments, we
observe a vast variety of self-organized behavior patterns: when left alone, the
arm realizes pseudo-random sequences of different poses. By applying physical
forces, the system can be entrained into definite motion patterns like wiping
a table. Most interestingly, after attaching an object, the controller gets in
a functional resonance with the object''s internal dynamics, starting to shake
spontaneously bottles half-filled with water or sensitively driving an attached
pendulum into a circular mode. When attached to the crank of a wheel the neural
system independently develops to rotate it. In this way, the robot discovers affordances
of objects its body is interacting with.'
acknowledgement: RD thanks for the hospitality at the Max-Planck-Institute and for
helpful discussions with Nihat Ay and Keyan Zahedi.
article_number: '7759138'
author:
- first_name: Georg S
full_name: Martius, Georg S
id: 3A276B68-F248-11E8-B48F-1D18A9856A87
last_name: Martius
- first_name: Raphael
full_name: Hostettler, Raphael
last_name: Hostettler
- first_name: Alois
full_name: Knoll, Alois
last_name: Knoll
- first_name: Ralf
full_name: Der, Ralf
last_name: Der
citation:
ama: 'Martius GS, Hostettler R, Knoll A, Der R. Compliant control for soft robots:
Emergent behavior of a tendon driven anthropomorphic arm. In: Vol 2016-November.
IEEE; 2016. doi:10.1109/IROS.2016.7759138'
apa: 'Martius, G. S., Hostettler, R., Knoll, A., & Der, R. (2016). Compliant
control for soft robots: Emergent behavior of a tendon driven anthropomorphic
arm (Vol. 2016–November). Presented at the IEEE RSJ International Conference on
Intelligent Robots and Systems IROS , Daejeon, Korea: IEEE. https://doi.org/10.1109/IROS.2016.7759138'
chicago: 'Martius, Georg S, Raphael Hostettler, Alois Knoll, and Ralf Der. “Compliant
Control for Soft Robots: Emergent Behavior of a Tendon Driven Anthropomorphic
Arm,” Vol. 2016–November. IEEE, 2016. https://doi.org/10.1109/IROS.2016.7759138.'
ieee: 'G. S. Martius, R. Hostettler, A. Knoll, and R. Der, “Compliant control for
soft robots: Emergent behavior of a tendon driven anthropomorphic arm,” presented
at the IEEE RSJ International Conference on Intelligent Robots and Systems IROS
, Daejeon, Korea, 2016, vol. 2016–November.'
ista: 'Martius GS, Hostettler R, Knoll A, Der R. 2016. Compliant control for soft
robots: Emergent behavior of a tendon driven anthropomorphic arm. IEEE RSJ International
Conference on Intelligent Robots and Systems IROS vol. 2016–November, 7759138.'
mla: 'Martius, Georg S., et al. Compliant Control for Soft Robots: Emergent Behavior
of a Tendon Driven Anthropomorphic Arm. Vol. 2016–November, 7759138, IEEE,
2016, doi:10.1109/IROS.2016.7759138.'
short: G.S. Martius, R. Hostettler, A. Knoll, R. Der, in:, IEEE, 2016.
conference:
end_date: 2016-09-14
location: Daejeon, Korea
name: 'IEEE RSJ International Conference on Intelligent Robots and Systems IROS '
start_date: 2016-09-09
date_created: 2018-12-11T11:50:45Z
date_published: 2016-11-28T00:00:00Z
date_updated: 2021-01-12T06:49:08Z
day: '28'
department:
- _id: ChLa
- _id: GaTk
doi: 10.1109/IROS.2016.7759138
language:
- iso: eng
month: '11'
oa_version: None
publication_status: published
publisher: IEEE
publist_id: '6121'
quality_controlled: '1'
scopus_import: 1
status: public
title: 'Compliant control for soft robots: Emergent behavior of a tendon driven anthropomorphic
arm'
type: conference
user_id: 3E5EF7F0-F248-11E8-B48F-1D18A9856A87
volume: 2016-November
year: '2016'
...
---
_id: '261'
abstract:
- lang: eng
text: Let G = SL(2, R) ⋉R2 and Γ = SL(2, Z) ⋉Z2. Building on recent work of Strömbergsson,
we prove a rate of equidistribution for the orbits of a certain one-dimensional
unipotent flow of Γ\G, which projects to a closed horocycle in the unit tangent
bundle to the modular surface. We use this to answer a question of Elkies and
McMullen by making effective the convergence of the gap distribution of √n mod
1.
acknowledgement: The research leading to these results has received funding from the
European Research Council under the European Union’s Seventh Framework Programme
(FP/2007–2013)/ERC Grant Agreements 291147 and 306457.
author:
- first_name: Timothy D
full_name: Timothy Browning
id: 35827D50-F248-11E8-B48F-1D18A9856A87
last_name: Browning
orcid: 0000-0002-8314-0177
- first_name: Ilya
full_name: Vinogradov, Ilya
last_name: Vinogradov
citation:
ama: Browning TD, Vinogradov I. Effective ratner theorem for SL (2, R) ⋉R2 and gaps
in √n modulo 1. Journal of the London Mathematical Society. 2016;94(1):61-84.
doi:10.1112/jlms/jdw025
apa: Browning, T. D., & Vinogradov, I. (2016). Effective ratner theorem for
SL (2, R) ⋉R2 and gaps in √n modulo 1. Journal of the London Mathematical Society.
John Wiley and Sons Ltd. https://doi.org/10.1112/jlms/jdw025
chicago: Browning, Timothy D, and Ilya Vinogradov. “Effective Ratner Theorem for
SL (2, R) ⋉R2 and Gaps in √n modulo 1.” Journal of the London Mathematical
Society. John Wiley and Sons Ltd, 2016. https://doi.org/10.1112/jlms/jdw025.
ieee: T. D. Browning and I. Vinogradov, “Effective ratner theorem for SL (2, R)
⋉R2 and gaps in √n modulo 1,” Journal of the London Mathematical Society,
vol. 94, no. 1. John Wiley and Sons Ltd, pp. 61–84, 2016.
ista: Browning TD, Vinogradov I. 2016. Effective ratner theorem for SL (2, R) ⋉R2
and gaps in √n modulo 1. Journal of the London Mathematical Society. 94(1), 61–84.
mla: Browning, Timothy D., and Ilya Vinogradov. “Effective Ratner Theorem for SL
(2, R) ⋉R2 and Gaps in √n modulo 1.” Journal of the London Mathematical Society,
vol. 94, no. 1, John Wiley and Sons Ltd, 2016, pp. 61–84, doi:10.1112/jlms/jdw025.
short: T.D. Browning, I. Vinogradov, Journal of the London Mathematical Society
94 (2016) 61–84.
date_created: 2018-12-11T11:45:29Z
date_published: 2016-05-24T00:00:00Z
date_updated: 2021-01-12T06:58:33Z
day: '24'
doi: 10.1112/jlms/jdw025
extern: 1
intvolume: ' 94'
issue: '1'
month: '05'
page: 61 - 84
publication: Journal of the London Mathematical Society
publication_status: published
publisher: John Wiley and Sons Ltd
publist_id: '7641'
quality_controlled: 0
status: public
title: Effective ratner theorem for SL (2, R) ⋉R2 and gaps in √n modulo 1
type: journal_article
volume: 94
year: '2016'
...
---
_id: '262'
abstract:
- lang: eng
text: For any number field we calculate the exact proportion of rational numbers
which are everywhere locally a norm but not globally a norm from the number field.
acknowledgement: While working on this paper the first author was supported by ERC
grant 306457.
author:
- first_name: Timothy D
full_name: Timothy Browning
id: 35827D50-F248-11E8-B48F-1D18A9856A87
last_name: Browning
orcid: 0000-0002-8314-0177
- first_name: Rachel
full_name: Newton, Rachel
last_name: Newton
citation:
ama: Browning TD, Newton R. The proportion of failures of the Hasse norm principle.
Mathematika. 2016;62(2):337-347. doi:10.1112/S0025579315000261
apa: Browning, T. D., & Newton, R. (2016). The proportion of failures of the
Hasse norm principle. Mathematika. Cambridge University Press. https://doi.org/10.1112/S0025579315000261
chicago: Browning, Timothy D, and Rachel Newton. “The Proportion of Failures of
the Hasse Norm Principle.” Mathematika. Cambridge University Press, 2016.
https://doi.org/10.1112/S0025579315000261.
ieee: T. D. Browning and R. Newton, “The proportion of failures of the Hasse norm
principle,” Mathematika, vol. 62, no. 2. Cambridge University Press, pp.
337–347, 2016.
ista: Browning TD, Newton R. 2016. The proportion of failures of the Hasse norm
principle. Mathematika. 62(2), 337–347.
mla: Browning, Timothy D., and Rachel Newton. “The Proportion of Failures of the
Hasse Norm Principle.” Mathematika, vol. 62, no. 2, Cambridge University
Press, 2016, pp. 337–47, doi:10.1112/S0025579315000261.
short: T.D. Browning, R. Newton, Mathematika 62 (2016) 337–347.
date_created: 2018-12-11T11:45:29Z
date_published: 2016-01-22T00:00:00Z
date_updated: 2021-01-12T06:58:37Z
day: '22'
doi: 10.1112/S0025579315000261
extern: 1
intvolume: ' 62'
issue: '2'
main_file_link:
- open_access: '1'
url: https://arxiv.org/abs/1411.7775
month: '01'
oa: 1
page: 337 - 347
publication: Mathematika
publication_status: published
publisher: Cambridge University Press
publist_id: '7640'
quality_controlled: 0
status: public
title: The proportion of failures of the Hasse norm principle
type: journal_article
volume: 62
year: '2016'
...
---
_id: '263'
abstract:
- lang: eng
text: We count rational points of bounded height on the Cayley ruled cubic surface
and interpret the result in the context of general conjectures due to Batyrev
and Tschinkel.
acknowledgement: 'While working on this paper the first author was supported by an
IUF Junior and the second author was supported by ERC grant 306457. '
author:
- first_name: Régis
full_name: de la Bretèche, Régis
last_name: De La Bretèche
- first_name: Timothy D
full_name: Timothy Browning
id: 35827D50-F248-11E8-B48F-1D18A9856A87
last_name: Browning
orcid: 0000-0002-8314-0177
- first_name: Per
full_name: Salberger, Per
last_name: Salberger
citation:
ama: De La Bretèche R, Browning TD, Salberger P. Counting rational points on the
Cayley ruled cubic. European Journal of Mathematics. 2016;2(1):55-72. doi:10.1007/s40879-015-0049-1
apa: De La Bretèche, R., Browning, T. D., & Salberger, P. (2016). Counting rational
points on the Cayley ruled cubic. European Journal of Mathematics. Springer
Nature. https://doi.org/10.1007/s40879-015-0049-1
chicago: De La Bretèche, Régis, Timothy D Browning, and Per Salberger. “Counting
Rational Points on the Cayley Ruled Cubic.” European Journal of Mathematics.
Springer Nature, 2016. https://doi.org/10.1007/s40879-015-0049-1.
ieee: R. De La Bretèche, T. D. Browning, and P. Salberger, “Counting rational points
on the Cayley ruled cubic,” European Journal of Mathematics, vol. 2, no.
1. Springer Nature, pp. 55–72, 2016.
ista: De La Bretèche R, Browning TD, Salberger P. 2016. Counting rational points
on the Cayley ruled cubic. European Journal of Mathematics. 2(1), 55–72.
mla: De La Bretèche, Régis, et al. “Counting Rational Points on the Cayley Ruled
Cubic.” European Journal of Mathematics, vol. 2, no. 1, Springer Nature,
2016, pp. 55–72, doi:10.1007/s40879-015-0049-1.
short: R. De La Bretèche, T.D. Browning, P. Salberger, European Journal of Mathematics
2 (2016) 55–72.
date_created: 2018-12-11T11:45:30Z
date_published: 2016-03-01T00:00:00Z
date_updated: 2021-01-12T06:58:41Z
day: '01'
doi: 10.1007/s40879-015-0049-1
extern: 1
intvolume: ' 2'
issue: '1'
main_file_link:
- open_access: '1'
url: https://arxiv.org/abs/1410.3855
month: '03'
oa: 1
page: 55 - 72
publication: European Journal of Mathematics
publication_status: published
publisher: Springer Nature
publist_id: '7639'
quality_controlled: 0
status: public
title: Counting rational points on the Cayley ruled cubic
type: journal_article
volume: 2
year: '2016'
...
---
_id: '264'
abstract:
- lang: eng
text: Given a family of varieties over a number field, we determine conditions under
which there is a Brauer-Manin obstruction to weak approximation for 100% of the
fibres which are everywhere locally soluble.
acknowledgement: While working on this paper the second author was supported by ERC
grant 306457.
author:
- first_name: Maritn
full_name: Bright, Maritn J
last_name: Bright
- first_name: Timothy D
full_name: Timothy Browning
id: 35827D50-F248-11E8-B48F-1D18A9856A87
last_name: Browning
orcid: 0000-0002-8314-0177
- first_name: Daniel
full_name: Loughran, Daniel
last_name: Loughran
citation:
ama: Bright M, Browning TD, Loughran D. Failures of weak approximation in families.
Compositio Mathematica. 2016;152(7):1435-1475. doi:10.1112/S0010437X16007405
apa: Bright, M., Browning, T. D., & Loughran, D. (2016). Failures of weak approximation
in families. Compositio Mathematica. Cambridge University Press. https://doi.org/10.1112/S0010437X16007405
chicago: Bright, Maritn, Timothy D Browning, and Daniel Loughran. “Failures of Weak
Approximation in Families.” Compositio Mathematica. Cambridge University
Press, 2016. https://doi.org/10.1112/S0010437X16007405.
ieee: M. Bright, T. D. Browning, and D. Loughran, “Failures of weak approximation
in families,” Compositio Mathematica, vol. 152, no. 7. Cambridge University
Press, pp. 1435–1475, 2016.
ista: Bright M, Browning TD, Loughran D. 2016. Failures of weak approximation in
families. Compositio Mathematica. 152(7), 1435–1475.
mla: Bright, Maritn, et al. “Failures of Weak Approximation in Families.” Compositio
Mathematica, vol. 152, no. 7, Cambridge University Press, 2016, pp. 1435–75,
doi:10.1112/S0010437X16007405.
short: M. Bright, T.D. Browning, D. Loughran, Compositio Mathematica 152 (2016)
1435–1475.
date_created: 2018-12-11T11:45:30Z
date_published: 2016-07-01T00:00:00Z
date_updated: 2021-01-12T06:58:45Z
day: '01'
doi: 10.1112/S0010437X16007405
extern: 1
intvolume: ' 152'
issue: '7'
main_file_link:
- open_access: '1'
url: https://arxiv.org/abs/1506.01817
month: '07'
oa: 1
page: 1435 - 1475
publication: Compositio Mathematica
publication_status: published
publisher: Cambridge University Press
publist_id: '7638'
quality_controlled: 0
status: public
title: Failures of weak approximation in families
type: journal_article
volume: 152
year: '2016'
...
---
_id: '363'
abstract:
- lang: eng
text: Lead halide perovskite materials have attracted significant attention in the
context of photovoltaics and other optoelectronic applications, and recently,
research efforts have been directed to nanostructured lead halide perovskites.
Collodial nanocrystals (NCs) of cesium lead halides (CsPbX3, X = Cl, Br, I) exhibit
bright photoluminescence, with emission tunable over the entire visible spectral
region. However, previous studies on CsPbX3 NCs did not address key aspects of
their chemistry and photophysics such as surface chemistry and quantitative light
absorption. Here, we elaborate on the synthesis of CsPbBr3 NCs and their surface
chemistry. In addition, the intrinsic absorption coefficient was determined experimentally
by combining elemental analysis with accurate optical absorption measurements.
1H solution nuclear magnetic resonance spectroscopy was used to characterize sample
purity, elucidate the surface chemistry, and evaluate the influence of purification
methods on the surface composition. We find that ligand binding to the NC surface
is highly dynamic, and therefore, ligands are easily lost during the isolation
and purification procedures. However, when a small amount of both oleic acid and
oleylamine is added, the NCs can be purified, maintaining optical, colloidal,
and material integrity. In addition, we find that a high amine content in the
ligand shell increases the quantum yield due to the improved binding of the carboxylic
acid.
article_processing_charge: No
author:
- first_name: Jonathan
full_name: De Roo, Jonathan
last_name: De Roo
- first_name: Maria
full_name: Ibáñez, Maria
id: 43C61214-F248-11E8-B48F-1D18A9856A87
last_name: Ibáñez
orcid: 0000-0001-5013-2843
- first_name: Pieter
full_name: Geiregat, Pieter
last_name: Geiregat
- first_name: Georgian
full_name: Nedelcu, Georgian
last_name: Nedelcu
- first_name: Willem
full_name: Walravens, Willem
last_name: Walravens
- first_name: Jorick
full_name: Maes, Jorick
last_name: Maes
- first_name: Jose
full_name: Martins, Jose
last_name: Martins
- first_name: Isabel
full_name: Van Driessche, Isabel
last_name: Van Driessche
- first_name: Maksym
full_name: Kovalenko, Maksym
last_name: Kovalenko
- first_name: Zeger
full_name: Hens, Zeger
last_name: Hens
citation:
ama: De Roo J, Ibáñez M, Geiregat P, et al. Highly dynamic ligand binding and light
absorption coefficient of cesium lead bromide perovskite nanocrystals. ACS
Nano. 2016;10(2):2071-2081. doi:10.1021/acsnano.5b06295
apa: De Roo, J., Ibáñez, M., Geiregat, P., Nedelcu, G., Walravens, W., Maes, J.,
… Hens, Z. (2016). Highly dynamic ligand binding and light absorption coefficient
of cesium lead bromide perovskite nanocrystals. ACS Nano. American Chemical
Society. https://doi.org/10.1021/acsnano.5b06295
chicago: De Roo, Jonathan, Maria Ibáñez, Pieter Geiregat, Georgian Nedelcu, Willem
Walravens, Jorick Maes, Jose Martins, Isabel Van Driessche, Maksym Kovalenko,
and Zeger Hens. “Highly Dynamic Ligand Binding and Light Absorption Coefficient
of Cesium Lead Bromide Perovskite Nanocrystals.” ACS Nano. American Chemical
Society, 2016. https://doi.org/10.1021/acsnano.5b06295.
ieee: J. De Roo et al., “Highly dynamic ligand binding and light absorption
coefficient of cesium lead bromide perovskite nanocrystals,” ACS Nano,
vol. 10, no. 2. American Chemical Society, pp. 2071–2081, 2016.
ista: De Roo J, Ibáñez M, Geiregat P, Nedelcu G, Walravens W, Maes J, Martins J,
Van Driessche I, Kovalenko M, Hens Z. 2016. Highly dynamic ligand binding and
light absorption coefficient of cesium lead bromide perovskite nanocrystals. ACS
Nano. 10(2), 2071–2081.
mla: De Roo, Jonathan, et al. “Highly Dynamic Ligand Binding and Light Absorption
Coefficient of Cesium Lead Bromide Perovskite Nanocrystals.” ACS Nano,
vol. 10, no. 2, American Chemical Society, 2016, pp. 2071–81, doi:10.1021/acsnano.5b06295.
short: J. De Roo, M. Ibáñez, P. Geiregat, G. Nedelcu, W. Walravens, J. Maes, J.
Martins, I. Van Driessche, M. Kovalenko, Z. Hens, ACS Nano 10 (2016) 2071–2081.
date_created: 2018-12-11T11:46:02Z
date_published: 2016-02-23T00:00:00Z
date_updated: 2021-01-12T07:44:46Z
day: '23'
doi: 10.1021/acsnano.5b06295
extern: '1'
intvolume: ' 10'
issue: '2'
language:
- iso: eng
month: '02'
oa_version: None
page: 2071 - 2081
publication: ACS Nano
publication_status: published
publisher: American Chemical Society
publist_id: '7464'
status: public
title: Highly dynamic ligand binding and light absorption coefficient of cesium lead
bromide perovskite nanocrystals
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 10
year: '2016'
...
---
_id: '364'
abstract:
- lang: eng
text: The development of highly active, low cost and stable electrocatalysts for
direct alcohol fuel cells remains a critical challenge. While Pd2Sn has been reported
as an excellent catalyst for the ethanol oxidation reaction (EOR), here we present
DFT analysis results showing the (100) and (001) facets of orthorhombic Pd2Sn
to be more favourable for the EOR than (010). Accordingly, using tri-n-octylphosphine,
oleylamine (OLA) and methylamine hydrochloride as size and shape directing agents,
we produced colloidal Pd2Sn nanorods (NRs) grown in the [010] direction. Such
Pd2Sn NRs, supported on graphitic carbon, showed excellent performance and stability
as an anode electrocatalyst for the EOR in alkaline media, exhibiting 3 times
and 10 times higher EOR current densities than that of Pd2Sn and Pd nanospheres,
respectively. We associate this improved performance with the favourable faceting
of the NRs.
author:
- first_name: Zhishan
full_name: Luo, Zhishan
last_name: Luo
- first_name: Jianmin
full_name: Lu, Jianmin
last_name: Lu
- first_name: Cristina
full_name: Flox, Cristina
last_name: Flox
- first_name: Raquel
full_name: Nafria, Raquel
last_name: Nafria
- first_name: Aziz
full_name: Genç, Aziz
last_name: Genç
- first_name: Jordi
full_name: Arbiol, Jordi
last_name: Arbiol
- first_name: Jordi
full_name: Llorca, Jordi
last_name: Llorca
- first_name: Maria
full_name: Ibanez Sabate, Maria
id: 43C61214-F248-11E8-B48F-1D18A9856A87
last_name: Ibanez Sabate
orcid: 0000-0001-5013-2843
- first_name: Joan
full_name: Morante, Joan
last_name: Morante
- first_name: Andreu
full_name: Cabot, Andreu
last_name: Cabot
citation:
ama: Luo Z, Lu J, Flox C, et al. Pd2Sn [010] nanorods as a highly active and stable
ethanol oxidation catalyst. Journal of Materials Chemistry A. 2016;4(42):16706-16713.
doi:10.1039/c6ta06430b
apa: Luo, Z., Lu, J., Flox, C., Nafria, R., Genç, A., Arbiol, J., … Cabot, A. (2016).
Pd2Sn [010] nanorods as a highly active and stable ethanol oxidation catalyst.
Journal of Materials Chemistry A. Royal Society of Chemistry. https://doi.org/10.1039/c6ta06430b
chicago: Luo, Zhishan, Jianmin Lu, Cristina Flox, Raquel Nafria, Aziz Genç, Jordi
Arbiol, Jordi Llorca, Maria Ibáñez, Joan Morante, and Andreu Cabot. “Pd2Sn [010]
Nanorods as a Highly Active and Stable Ethanol Oxidation Catalyst.” Journal
of Materials Chemistry A. Royal Society of Chemistry, 2016. https://doi.org/10.1039/c6ta06430b.
ieee: Z. Luo et al., “Pd2Sn [010] nanorods as a highly active and stable
ethanol oxidation catalyst,” Journal of Materials Chemistry A, vol. 4,
no. 42. Royal Society of Chemistry, pp. 16706–16713, 2016.
ista: Luo Z, Lu J, Flox C, Nafria R, Genç A, Arbiol J, Llorca J, Ibáñez M, Morante
J, Cabot A. 2016. Pd2Sn [010] nanorods as a highly active and stable ethanol oxidation
catalyst. Journal of Materials Chemistry A. 4(42), 16706–16713.
mla: Luo, Zhishan, et al. “Pd2Sn [010] Nanorods as a Highly Active and Stable Ethanol
Oxidation Catalyst.” Journal of Materials Chemistry A, vol. 4, no. 42,
Royal Society of Chemistry, 2016, pp. 16706–13, doi:10.1039/c6ta06430b.
short: Z. Luo, J. Lu, C. Flox, R. Nafria, A. Genç, J. Arbiol, J. Llorca, M. Ibáñez,
J. Morante, A. Cabot, Journal of Materials Chemistry A 4 (2016) 16706–16713.
date_created: 2018-12-11T11:46:02Z
date_published: 2016-10-05T00:00:00Z
date_updated: 2021-01-12T07:44:50Z
day: '05'
doi: 10.1039/c6ta06430b
extern: '1'
intvolume: ' 4'
issue: '42'
language:
- iso: eng
month: '10'
oa_version: None
page: 16706 - 16713
publication: Journal of Materials Chemistry A
publication_status: published
publisher: Royal Society of Chemistry
publist_id: '7465'
status: public
title: Pd2Sn [010] nanorods as a highly active and stable ethanol oxidation catalyst
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 4
year: '2016'
...
---
_id: '366'
abstract:
- lang: eng
text: Cesium lead halide (CsPbX3, X = Cl, Br, I) nanocrystals (NCs) offer exceptional
optical properties for several potential applications but their implementation
is hindered by a low chemical and structural stability and limited processability.
In the present work, we developed a new method to efficiently coat CsPbX3 NCs,
which resulted in their increased chemical and optical stability as well as processability.
The method is based on the incorporation of poly(maleic anhydride-alt-1-octadecene)
(PMA) into the synthesis of the perovskite NCs. The presence of PMA in the ligand
shell stabilizes the NCs by tightening the ligand binding, limiting in this way
the NC surface interaction with the surrounding media. We further show that these
NCs can be embedded in self-standing silicone/glass plates as down-conversion
filters for the fabrication of monochromatic green and white light emitting diodes
(LEDs) with narrow bandwidths and appealing color characteristics.
acknowledgement: This work was supported by the European Regional Development Funds,
the Framework 7 program under project UNION (FP7-NMP-2012-310250) and HI-LED (FP7-ICT-2013-11-
619912), as well as the Spanish MINECO Projects BOOSTER (ENE2013-46624-C4-3-R) and
AMALIE (TEC2012-38901- C02-01). M.M. thanks the Spanish MINECO for financial support
through the Juan de la Cierva-formacion program. A.G. and J.A. acknowledge funding
from Generalitat de Catalunya 2014 SGR 1638 and the Spanish MINECO MAT2014-51480-
ERC (e-ATOM) and Severo Ochoa Excellence Program. We would like to thank Pablo Guardia
for fruitful discussions.
author:
- first_name: Michaela
full_name: Meyn, Michaela
last_name: Meyn
- first_name: Mariano
full_name: Perálvarez, Mariano
last_name: Perálvarez
- first_name: Amelie
full_name: Heuer Jungemann, Amelie
last_name: Heuer Jungemann
- first_name: Wim
full_name: Hertog, Wim
last_name: Hertog
- first_name: Maria
full_name: Ibanez Sabate, Maria
id: 43C61214-F248-11E8-B48F-1D18A9856A87
last_name: Ibanez Sabate
orcid: 0000-0001-5013-2843
- first_name: Raquel
full_name: Nafria, Raquel
last_name: Nafria
- first_name: Aziz
full_name: Genç, Aziz
last_name: Genç
- first_name: Jordi
full_name: Arbiol, Jordi
last_name: Arbiol
- first_name: Maksym
full_name: Kovalenko, Maksym
last_name: Kovalenko
- first_name: Josep
full_name: Carreras, Josep
last_name: Carreras
- first_name: Andreu
full_name: Cabot, Andreu
last_name: Cabot
- first_name: Antonios
full_name: Kanaras, Antonios
last_name: Kanaras
citation:
ama: Meyn M, Perálvarez M, Heuer Jungemann A, et al. Polymer enhanced stability
of inorganic perovskite nanocrystals and their application in color conversion
LEDs. ACS Applied Materials and Interfaces. 2016;8(30):19579-19586. doi:10.1021/acsami.6b02529
apa: Meyn, M., Perálvarez, M., Heuer Jungemann, A., Hertog, W., Ibáñez, M., Nafria,
R., … Kanaras, A. (2016). Polymer enhanced stability of inorganic perovskite nanocrystals
and their application in color conversion LEDs. ACS Applied Materials and Interfaces.
American Chemical Society. https://doi.org/10.1021/acsami.6b02529
chicago: Meyn, Michaela, Mariano Perálvarez, Amelie Heuer Jungemann, Wim Hertog,
Maria Ibáñez, Raquel Nafria, Aziz Genç, et al. “Polymer Enhanced Stability of
Inorganic Perovskite Nanocrystals and Their Application in Color Conversion LEDs.”
ACS Applied Materials and Interfaces. American Chemical Society, 2016.
https://doi.org/10.1021/acsami.6b02529.
ieee: M. Meyn et al., “Polymer enhanced stability of inorganic perovskite
nanocrystals and their application in color conversion LEDs,” ACS Applied Materials
and Interfaces, vol. 8, no. 30. American Chemical Society, pp. 19579–19586,
2016.
ista: Meyn M, Perálvarez M, Heuer Jungemann A, Hertog W, Ibáñez M, Nafria R, Genç
A, Arbiol J, Kovalenko M, Carreras J, Cabot A, Kanaras A. 2016. Polymer enhanced
stability of inorganic perovskite nanocrystals and their application in color
conversion LEDs. ACS Applied Materials and Interfaces. 8(30), 19579–19586.
mla: Meyn, Michaela, et al. “Polymer Enhanced Stability of Inorganic Perovskite
Nanocrystals and Their Application in Color Conversion LEDs.” ACS Applied Materials
and Interfaces, vol. 8, no. 30, American Chemical Society, 2016, pp. 19579–86,
doi:10.1021/acsami.6b02529.
short: M. Meyn, M. Perálvarez, A. Heuer Jungemann, W. Hertog, M. Ibáñez, R. Nafria,
A. Genç, J. Arbiol, M. Kovalenko, J. Carreras, A. Cabot, A. Kanaras, ACS Applied
Materials and Interfaces 8 (2016) 19579–19586.
date_created: 2018-12-11T11:46:03Z
date_published: 2016-07-25T00:00:00Z
date_updated: 2021-01-12T07:44:58Z
day: '25'
doi: 10.1021/acsami.6b02529
extern: '1'
intvolume: ' 8'
issue: '30'
language:
- iso: eng
main_file_link:
- open_access: '1'
url: https://eprints.soton.ac.uk/398581/
month: '07'
oa: 1
oa_version: None
page: 19579 - 19586
publication: ACS Applied Materials and Interfaces
publication_status: published
publisher: American Chemical Society
publist_id: '7460'
status: public
title: Polymer enhanced stability of inorganic perovskite nanocrystals and their application
in color conversion LEDs
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 8
year: '2016'
...
---
_id: '367'
abstract:
- lang: eng
text: 'The functional properties of quaternary I2–II–IV–VI4 nanomaterials, with
potential interest in various technological fields, are highly sensitive to compositional
variations, which is a challenging parameter to adjust. Here we demonstrate the
presence of phosphonic acids to aid controlling the reactivity of the II element
monomer to be incorporated in quaternary Cu2ZnSnSe4 nanoparticles and thus to
provide a more reliable way to adjust the final nanoparticle metal ratios. Furthermore,
we demonstrate the composition control in such multivalence nanoparticles to allow
modifying charge carrier concentrations in nanomaterials produced from the assembly
of these building blocks. '
article_processing_charge: No
author:
- first_name: Maria
full_name: Ibáñez, Maria
id: 43C61214-F248-11E8-B48F-1D18A9856A87
last_name: Ibáñez
orcid: 0000-0001-5013-2843
- first_name: Taisiia
full_name: Berestok, Taisiia
last_name: Berestok
- first_name: Oleksandr
full_name: Dobrozhan, Oleksandr
last_name: Dobrozhan
- first_name: Aaron
full_name: Lalonde, Aaron
last_name: Lalonde
- first_name: Victor
full_name: Izquierdo Roca, Victor
last_name: Izquierdo Roca
- first_name: Alexey
full_name: Shavel, Alexey
last_name: Shavel
- first_name: Alejandro
full_name: Pérez Rodríguez, Alejandro
last_name: Pérez Rodríguez
- first_name: G Jeffrey
full_name: Snyder, G Jeffrey
last_name: Snyder
- first_name: Andreu
full_name: Cabot, Andreu
last_name: Cabot
citation:
ama: Ibáñez M, Berestok T, Dobrozhan O, et al. Phosphonic acids aid composition
adjustment in the synthesis of Cu2+xZn1−xSnSe4−y nanoparticles. Journal of
Nanoparticle Research. 2016;18(8). doi:10.1007/s11051-016-3545-4
apa: Ibáñez, M., Berestok, T., Dobrozhan, O., Lalonde, A., Izquierdo Roca, V., Shavel,
A., … Cabot, A. (2016). Phosphonic acids aid composition adjustment in the synthesis
of Cu2+xZn1−xSnSe4−y nanoparticles. Journal of Nanoparticle Research. Springer.
https://doi.org/10.1007/s11051-016-3545-4
chicago: Ibáñez, Maria, Taisiia Berestok, Oleksandr Dobrozhan, Aaron Lalonde, Victor
Izquierdo Roca, Alexey Shavel, Alejandro Pérez Rodríguez, G Jeffrey Snyder, and
Andreu Cabot. “Phosphonic Acids Aid Composition Adjustment in the Synthesis of
Cu2+xZn1−xSnSe4−y Nanoparticles.” Journal of Nanoparticle Research. Springer,
2016. https://doi.org/10.1007/s11051-016-3545-4.
ieee: M. Ibáñez et al., “Phosphonic acids aid composition adjustment in the
synthesis of Cu2+xZn1−xSnSe4−y nanoparticles,” Journal of Nanoparticle Research,
vol. 18, no. 8. Springer, 2016.
ista: Ibáñez M, Berestok T, Dobrozhan O, Lalonde A, Izquierdo Roca V, Shavel A,
Pérez Rodríguez A, Snyder GJ, Cabot A. 2016. Phosphonic acids aid composition
adjustment in the synthesis of Cu2+xZn1−xSnSe4−y nanoparticles. Journal of Nanoparticle
Research. 18(8).
mla: Ibáñez, Maria, et al. “Phosphonic Acids Aid Composition Adjustment in the Synthesis
of Cu2+xZn1−xSnSe4−y Nanoparticles.” Journal of Nanoparticle Research,
vol. 18, no. 8, Springer, 2016, doi:10.1007/s11051-016-3545-4.
short: M. Ibáñez, T. Berestok, O. Dobrozhan, A. Lalonde, V. Izquierdo Roca, A. Shavel,
A. Pérez Rodríguez, G.J. Snyder, A. Cabot, Journal of Nanoparticle Research 18
(2016).
date_created: 2018-12-11T11:46:04Z
date_published: 2016-08-11T00:00:00Z
date_updated: 2021-01-12T07:45:02Z
day: '11'
doi: 10.1007/s11051-016-3545-4
extern: '1'
intvolume: ' 18'
issue: '8'
language:
- iso: eng
month: '08'
oa_version: None
publication: Journal of Nanoparticle Research
publication_status: published
publisher: Springer
publist_id: '7461'
status: public
title: Phosphonic acids aid composition adjustment in the synthesis of Cu2+xZn1−xSnSe4−y
nanoparticles
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 18
year: '2016'
...
---
_id: '368'
abstract:
- lang: eng
text: The control of the phase distribution in multicomponent nanomaterials is critical
to optimize their catalytic performance. In this direction, while impressive advances
have been achieved in the past decade in the synthesis of multicomponent nanoparticles
and nanocomposites, element rearrangement during catalyst activation has been
frequently overseen. Here, we present a facile galvanic replacement-based procedure
to synthesize Co@Cu nanoparticles with narrow size and composition distributions.
We further characterize their phase arrangement before and after catalytic activation.
When oxidized at 350 °C in air to remove organics, Co@Cu core-shell nanostructures
oxidize to polycrystalline CuO-Co3O4 nanoparticles with randomly distributed CuO
and Co3O4 crystallites. During a posterior reduction treatment in H2 atmosphere,
Cu precipitates in a metallic core and Co migrates to the nanoparticle surface
to form Cu@Co core-shell nanostructures. The catalytic behavior of such Cu@Co
nanoparticles supported on mesoporous silica was further analyzed toward CO2 hydrogenation
in real working conditions.
acknowledgement: The research was supported by the European Regional Development Funds
and the Spanish MICINN projects CSD2009-00050, MAT2014-52416-P, and ENE2013-46624-C4-3-R.
M.I. thanks AGAUR for her Beatriu de Pino?s postdoctoral grant 2013 BP-A00344. J.A.
and A.G. acknowledge the funding from the Spanish MINECO Severo Ochoa Excellence
Program and Generalitat de Catalunya 2014SGR1638.
article_processing_charge: No
author:
- first_name: Raquel
full_name: Nafria, Raquel
last_name: Nafria
- first_name: Aziz
full_name: Genç, Aziz
last_name: Genç
- first_name: Maria
full_name: Ibáñez, Maria
id: 43C61214-F248-11E8-B48F-1D18A9856A87
last_name: Ibáñez
orcid: 0000-0001-5013-2843
- first_name: Jprdi
full_name: Arbiol, Jprdi
last_name: Arbiol
- first_name: Pilar
full_name: Ramírez De La Piscina, Pilar
last_name: Ramírez De La Piscina
- first_name: Narcís
full_name: Homs, Narcís
last_name: Homs
- first_name: Andreu
full_name: Cabot, Andreu
last_name: Cabot
citation:
ama: Nafria R, Genç A, Ibáñez M, et al. Co Cu nanoparticles synthesis by galvanic
replacement and phase rearrangement during catalytic activation. Langmuir.
2016;32(9):2267-2276. doi:10.1021/acs.langmuir.5b04622
apa: Nafria, R., Genç, A., Ibáñez, M., Arbiol, J., Ramírez De La Piscina, P., Homs,
N., & Cabot, A. (2016). Co Cu nanoparticles synthesis by galvanic replacement
and phase rearrangement during catalytic activation. Langmuir. American
Chemical Society. https://doi.org/10.1021/acs.langmuir.5b04622
chicago: Nafria, Raquel, Aziz Genç, Maria Ibáñez, Jprdi Arbiol, Pilar Ramírez De
La Piscina, Narcís Homs, and Andreu Cabot. “Co Cu Nanoparticles Synthesis by Galvanic
Replacement and Phase Rearrangement during Catalytic Activation.” Langmuir.
American Chemical Society, 2016. https://doi.org/10.1021/acs.langmuir.5b04622.
ieee: R. Nafria et al., “Co Cu nanoparticles synthesis by galvanic replacement
and phase rearrangement during catalytic activation,” Langmuir, vol. 32,
no. 9. American Chemical Society, pp. 2267–2276, 2016.
ista: Nafria R, Genç A, Ibáñez M, Arbiol J, Ramírez De La Piscina P, Homs N, Cabot
A. 2016. Co Cu nanoparticles synthesis by galvanic replacement and phase rearrangement
during catalytic activation. Langmuir. 32(9), 2267–2276.
mla: Nafria, Raquel, et al. “Co Cu Nanoparticles Synthesis by Galvanic Replacement
and Phase Rearrangement during Catalytic Activation.” Langmuir, vol. 32,
no. 9, American Chemical Society, 2016, pp. 2267–76, doi:10.1021/acs.langmuir.5b04622.
short: R. Nafria, A. Genç, M. Ibáñez, J. Arbiol, P. Ramírez De La Piscina, N. Homs,
A. Cabot, Langmuir 32 (2016) 2267–2276.
date_created: 2018-12-11T11:46:04Z
date_published: 2016-03-08T00:00:00Z
date_updated: 2021-01-12T07:45:05Z
day: '08'
doi: 10.1021/acs.langmuir.5b04622
extern: '1'
intvolume: ' 32'
issue: '9'
language:
- iso: eng
month: '03'
oa_version: None
page: 2267 - 2276
publication: Langmuir
publication_status: published
publisher: American Chemical Society
publist_id: '7462'
status: public
title: Co Cu nanoparticles synthesis by galvanic replacement and phase rearrangement
during catalytic activation
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 32
year: '2016'
...
---
_id: '369'
abstract:
- lang: eng
text: The efficient conversion between thermal and electrical energy by means of
durable, silent and scalable solid-state thermoelectric devices has been a long
standing goal. While nanocrystalline materials have already led to substantially
higher thermoelectric efficiencies, further improvements are expected to arise
from precise chemical engineering of nanoscale building blocks and interfaces.
Here we present a simple and versatile bottom-up strategy based on the assembly
of colloidal nanocrystals to produce consolidated yet nanostructured thermoelectric
materials. In the case study on the PbS-Ag system, Ag nanodomains not only contribute
to block phonon propagation, but also provide electrons to the PbS host semiconductor
and reduce the PbS intergrain energy barriers for charge transport. Thus, PbS-Ag
nanocomposites exhibit reduced thermal conductivities and higher charge carrier
concentrations and mobilities than PbS nanomaterial. Such improvements of the
material transport properties provide thermoelectric figures of merit up to 1.7
at 850 K.
author:
- first_name: Maria
full_name: Ibanez Sabate, Maria
id: 43C61214-F248-11E8-B48F-1D18A9856A87
last_name: Ibanez Sabate
orcid: 0000-0001-5013-2843
- first_name: Zhishan
full_name: Luo, Zhishan
last_name: Luo
- first_name: Azoz
full_name: Genç, Azoz
last_name: Genç
- first_name: Laura
full_name: Piveteau, Laura
last_name: Piveteau
- first_name: Silvia
full_name: Ortega, Silvia
last_name: Ortega
- first_name: Doris
full_name: Cadavid, Doris
last_name: Cadavid
- first_name: Oleksandr
full_name: Dobrozhan, Oleksandr
last_name: Dobrozhan
- first_name: Yu
full_name: Liu, Yu
id: 2A70014E-F248-11E8-B48F-1D18A9856A87
last_name: Liu
orcid: 0000-0001-7313-6740
- first_name: Maarten
full_name: Nachtegaal, Maarten
last_name: Nachtegaal
- first_name: Mona
full_name: Zebarjadi, Mona
last_name: Zebarjadi
- first_name: Jordi
full_name: Arbiol, Jordi
last_name: Arbiol
- first_name: Maksym
full_name: Kovalenko, Maksym
last_name: Kovalenko
- first_name: Andreu
full_name: Cabot, Andreu
last_name: Cabot
citation:
ama: Ibáñez M, Luo Z, Genç A, et al. High performance thermoelectric nanocomposites
from nanocrystal building blocks. Nature Communications. 2016;7. doi:doi:10.1038/ncomms10766
apa: Ibáñez, M., Luo, Z., Genç, A., Piveteau, L., Ortega, S., Cadavid, D., … Cabot,
A. (2016). High performance thermoelectric nanocomposites from nanocrystal building
blocks. Nature Communications. Nature Publishing Group. https://doi.org/doi:10.1038/ncomms10766
chicago: Ibáñez, Maria, Zhishan Luo, Azoz Genç, Laura Piveteau, Silvia Ortega, Doris
Cadavid, Oleksandr Dobrozhan, et al. “High Performance Thermoelectric Nanocomposites
from Nanocrystal Building Blocks.” Nature Communications. Nature Publishing
Group, 2016. https://doi.org/doi:10.1038/ncomms10766.
ieee: M. Ibáñez et al., “High performance thermoelectric nanocomposites from
nanocrystal building blocks,” Nature Communications, vol. 7. Nature Publishing
Group, 2016.
ista: Ibáñez M, Luo Z, Genç A, Piveteau L, Ortega S, Cadavid D, Dobrozhan O, Liu
Y, Nachtegaal M, Zebarjadi M, Arbiol J, Kovalenko M, Cabot A. 2016. High performance
thermoelectric nanocomposites from nanocrystal building blocks. Nature Communications.
7.
mla: Ibáñez, Maria, et al. “High Performance Thermoelectric Nanocomposites from
Nanocrystal Building Blocks.” Nature Communications, vol. 7, Nature Publishing
Group, 2016, doi:doi:10.1038/ncomms10766.
short: M. Ibáñez, Z. Luo, A. Genç, L. Piveteau, S. Ortega, D. Cadavid, O. Dobrozhan,
Y. Liu, M. Nachtegaal, M. Zebarjadi, J. Arbiol, M. Kovalenko, A. Cabot, Nature
Communications 7 (2016).
date_created: 2018-12-11T11:46:04Z
date_published: 2016-03-07T00:00:00Z
date_updated: 2021-01-12T07:48:59Z
day: '07'
doi: doi:10.1038/ncomms10766
extern: '1'
intvolume: ' 7'
language:
- iso: eng
month: '03'
oa_version: None
publication: Nature Communications
publication_status: published
publisher: Nature Publishing Group
publist_id: '7463'
status: public
title: High performance thermoelectric nanocomposites from nanocrystal building blocks
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 7
year: '2016'
...
---
_id: '370'
abstract:
- lang: eng
text: Copper-based chalcogenides that comprise abundant, low-cost, and environmental
friendly elements are excellent materials for a number of energy conversion applications,
including photovoltaics, photocatalysis, and thermoelectrics (TE). In such applications,
the use of solution-processed nanocrystals (NCs) to produce thin films or bulk
nanomaterials has associated several potential advantages, such as high material
yield and throughput, and composition control with unmatched spatial resolution
and cost. Here we report on the production of Cu3SbSe4 (CASe) NCs with tuned amounts
of Sn and Bi dopants. After proper ligand removal, as monitored by nuclear magnetic
resonance and infrared spectroscopy, these NCs were used to produce dense CASe
bulk nanomaterials for solid state TE energy conversion. By adjusting the amount
of extrinsic dopants, dimensionless TE figures of merit (ZT) up to 1.26 at 673
K were reached. Such high ZT values are related to an optimized carrier concentration
by Sn doping, a minimized lattice thermal conductivity due to efficient phonon
scattering at point defects and grain boundaries, and to an increase of the Seebeck
coefficient obtained by a modification of the electronic band structure with Bi
doping. Nanomaterials were further employed to fabricate ring-shaped TE generators
to be coupled to hot pipes, which provided 20 mV and 1 mW per TE element when
exposed to a 160 °C temperature gradient. The simple design and good thermal contact
associated with the ring geometry and the potential low cost of the material solution
processing may allow the fabrication of TE generators with short payback times.
author:
- first_name: Yu
full_name: Liu, Yu
id: 2A70014E-F248-11E8-B48F-1D18A9856A87
last_name: Liu
orcid: 0000-0001-7313-6740
- first_name: Gregorio
full_name: García, Gregorio
last_name: García
- first_name: Silvia
full_name: Ortega, Silvia
last_name: Ortega
- first_name: Doris
full_name: Cadavid, Doris
last_name: Cadavid
- first_name: Pablo
full_name: Palacios, Pablo
last_name: Palacios
- first_name: Jinyu
full_name: Lu, Jinyu
last_name: Lu
- first_name: Maria
full_name: Ibanez, Maria
last_name: Ibanez
- first_name: Lili
full_name: Xi, Lili
last_name: Xi
- first_name: Jonathan
full_name: De Roo, Jonathan
last_name: De Roo
- first_name: Antonio
full_name: López, Antonio
last_name: López
- first_name: Sara
full_name: Márti Sánchez, Sara
last_name: Márti Sánchez
- first_name: Ignasi
full_name: Cabezas, Ignasi
last_name: Cabezas
- first_name: Maria
full_name: De La Mata, Maria
last_name: De La Mata
- first_name: Zhishan
full_name: Luo, Zhishan
last_name: Luo
- first_name: Chaocha
full_name: Dun, Chaocha
last_name: Dun
- first_name: Oleksandr
full_name: Dobrozhan, Oleksandr
last_name: Dobrozhan
- first_name: David
full_name: Carroll, David
last_name: Carroll
- first_name: Wenging
full_name: Zhang, Wenging
last_name: Zhang
- first_name: José
full_name: Martins, José
last_name: Martins
- first_name: Mksym
full_name: Kovalenko, Mksym
last_name: Kovalenko
- first_name: Jordi
full_name: Arbiol, Jordi
last_name: Arbiol
- first_name: German
full_name: Noriega, German
last_name: Noriega
- first_name: Jiming
full_name: Song, Jiming
last_name: Song
- first_name: Perla
full_name: Wahnón, Perla
last_name: Wahnón
- first_name: Andreu
full_name: Cabot, Andreu
last_name: Cabot
citation:
ama: Liu Y, García G, Ortega S, et al. Solution based synthesis and processing of
Sn and Bi doped Cu inf 3 inf SbSe inf 4 inf nanocrystals nanomaterials and ring
shaped thermoelectric generators. Journal of Materials Chemistry A. 2016;5(6):2592-2602.
doi:10.1039/C6TA08467B
apa: Liu, Y., García, G., Ortega, S., Cadavid, D., Palacios, P., Lu, J., … Cabot,
A. (2016). Solution based synthesis and processing of Sn and Bi doped Cu inf 3
inf SbSe inf 4 inf nanocrystals nanomaterials and ring shaped thermoelectric generators.
Journal of Materials Chemistry A. Royal Society of Chemistry. https://doi.org/10.1039/C6TA08467B
chicago: Liu, Yu, Gregorio García, Silvia Ortega, Doris Cadavid, Pablo Palacios,
Jinyu Lu, Maria Ibanez, et al. “Solution Based Synthesis and Processing of Sn
and Bi Doped Cu Inf 3 Inf SbSe Inf 4 Inf Nanocrystals Nanomaterials and Ring Shaped
Thermoelectric Generators.” Journal of Materials Chemistry A. Royal Society
of Chemistry, 2016. https://doi.org/10.1039/C6TA08467B.
ieee: Y. Liu et al., “Solution based synthesis and processing of Sn and Bi
doped Cu inf 3 inf SbSe inf 4 inf nanocrystals nanomaterials and ring shaped thermoelectric
generators,” Journal of Materials Chemistry A, vol. 5, no. 6. Royal Society
of Chemistry, pp. 2592–2602, 2016.
ista: Liu Y, García G, Ortega S, Cadavid D, Palacios P, Lu J, Ibanez M, Xi L, De
Roo J, López A, Márti Sánchez S, Cabezas I, De La Mata M, Luo Z, Dun C, Dobrozhan
O, Carroll D, Zhang W, Martins J, Kovalenko M, Arbiol J, Noriega G, Song J, Wahnón
P, Cabot A. 2016. Solution based synthesis and processing of Sn and Bi doped Cu
inf 3 inf SbSe inf 4 inf nanocrystals nanomaterials and ring shaped thermoelectric
generators. Journal of Materials Chemistry A. 5(6), 2592–2602.
mla: Liu, Yu, et al. “Solution Based Synthesis and Processing of Sn and Bi Doped
Cu Inf 3 Inf SbSe Inf 4 Inf Nanocrystals Nanomaterials and Ring Shaped Thermoelectric
Generators.” Journal of Materials Chemistry A, vol. 5, no. 6, Royal Society
of Chemistry, 2016, pp. 2592–602, doi:10.1039/C6TA08467B.
short: Y. Liu, G. García, S. Ortega, D. Cadavid, P. Palacios, J. Lu, M. Ibanez,
L. Xi, J. De Roo, A. López, S. Márti Sánchez, I. Cabezas, M. De La Mata, Z. Luo,
C. Dun, O. Dobrozhan, D. Carroll, W. Zhang, J. Martins, M. Kovalenko, J. Arbiol,
G. Noriega, J. Song, P. Wahnón, A. Cabot, Journal of Materials Chemistry A 5 (2016)
2592–2602.
date_created: 2018-12-11T11:46:05Z
date_published: 2016-12-19T00:00:00Z
date_updated: 2021-01-12T07:51:34Z
day: '19'
doi: 10.1039/C6TA08467B
extern: '1'
intvolume: ' 5'
issue: '6'
language:
- iso: eng
month: '12'
oa_version: None
page: 2592 - 2602
publication: Journal of Materials Chemistry A
publication_status: published
publisher: Royal Society of Chemistry
publist_id: '7457'
status: public
title: Solution based synthesis and processing of Sn and Bi doped Cu inf 3 inf SbSe
inf 4 inf nanocrystals nanomaterials and ring shaped thermoelectric generators
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 5
year: '2016'
...
---
_id: '371'
abstract:
- lang: eng
text: The design and engineering of earth-abundant catalysts that are both cost-effective
and highly active for water splitting are crucial challenges in a number of energy
conversion and storage technologies. In this direction, herein we report the synthesis
of Fe3O4@NiFexOy core-shell nanoheterostructures and the characterization of their
electrocatalytic performance toward the oxygen evolution reaction (OER). Such
nanoparticles (NPs) were produced by a two-step synthesis procedure involving
the colloidal synthesis of Fe3O4 nanocubes with a defective shell and the posterior
diffusion of nickel cations within this defective shell. Fe3O4@NiFexOy NPs were
subsequently spin-coated over ITO-covered glass and their electrocatalytic activity
toward water oxidation in carbonate electrolyte was characterized. Fe3O4@NiFexOy
catalysts reached current densities above 1 mA/cm2 with a 410 mV overpotential
and Tafel slopes of 48 mV/dec, which is among the best electrocatalytic performances
reported in carbonate electrolyte.
acknowledgement: "This work was supported by the European Regional Development Funds
and the Spanish MINECO project BOOSTER, TNT-FUELS, e-TNT, Severo Ochoa Program (MINECO,
Grant SEV-2013-0295), and PEC?CO2. Z.L. thanks the China Scholarship Council for
scholarship support. P.G. acknowledges the People Programme (Marie Curie Actions)
of the FP7/2007-2013 European Union Program (TECNIOspring grant agreement no. 600388)
and the Agency for Business Competitiveness of the Government of Catalonia, ACCIO.
M.I. thanks AGAUR for Beatriu de Pinos postdoctoral grant (2013 BP-A00344).\r\n\r\n"
author:
- first_name: Zhishan
full_name: Luo, Zhishan
last_name: Luo
- first_name: Sara
full_name: Márti Sánchez, Sara
last_name: Márti Sánchez
- first_name: Raquel
full_name: Nafria, Raquel
last_name: Nafria
- first_name: Gihan
full_name: Joshua, Gihan
last_name: Joshua
- first_name: Maria
full_name: De La Mata, Maria
last_name: De La Mata
- first_name: Pablo
full_name: Guardia, Pablo
last_name: Guardia
- first_name: Christina
full_name: Flox, Christina
last_name: Flox
- first_name: Carlos
full_name: Martínez Boubeta, Carlos
last_name: Martínez Boubeta
- first_name: Konstantinos
full_name: Simeonidis, Konstantinos
last_name: Simeonidis
- first_name: Jordi
full_name: Llorca, Jordi
last_name: Llorca
- first_name: Joan
full_name: Morante, Joan
last_name: Morante
- first_name: Jordi
full_name: Arbiol, Jordi
last_name: Arbiol
- first_name: Maria
full_name: Ibanez Sabate, Maria
id: 43C61214-F248-11E8-B48F-1D18A9856A87
last_name: Ibanez Sabate
orcid: 0000-0001-5013-2843
- first_name: Andreu
full_name: Cabot, Andreu
last_name: Cabot
citation:
ama: Luo Z, Márti Sánchez S, Nafria R, et al. Fe3O4@NiFexOy nanoparticles with enhanced
electrocatalytic properties for oxygen evolution in carbonate electrolyte. ACS
Applied Materials and Interfaces. 2016;8(43):29461-29469. doi:10.1021/acsami.6b09888
apa: Luo, Z., Márti Sánchez, S., Nafria, R., Joshua, G., De La Mata, M., Guardia,
P., … Cabot, A. (2016). Fe3O4@NiFexOy nanoparticles with enhanced electrocatalytic
properties for oxygen evolution in carbonate electrolyte. ACS Applied Materials
and Interfaces. American Chemical Society. https://doi.org/10.1021/acsami.6b09888
chicago: Luo, Zhishan, Sara Márti Sánchez, Raquel Nafria, Gihan Joshua, Maria De
La Mata, Pablo Guardia, Christina Flox, et al. “Fe3O4@NiFexOy Nanoparticles with
Enhanced Electrocatalytic Properties for Oxygen Evolution in Carbonate Electrolyte.”
ACS Applied Materials and Interfaces. American Chemical Society, 2016.
https://doi.org/10.1021/acsami.6b09888.
ieee: Z. Luo et al., “Fe3O4@NiFexOy nanoparticles with enhanced electrocatalytic
properties for oxygen evolution in carbonate electrolyte,” ACS Applied Materials
and Interfaces, vol. 8, no. 43. American Chemical Society, pp. 29461–29469,
2016.
ista: Luo Z, Márti Sánchez S, Nafria R, Joshua G, De La Mata M, Guardia P, Flox
C, Martínez Boubeta C, Simeonidis K, Llorca J, Morante J, Arbiol J, Ibáñez M,
Cabot A. 2016. Fe3O4@NiFexOy nanoparticles with enhanced electrocatalytic properties
for oxygen evolution in carbonate electrolyte. ACS Applied Materials and Interfaces.
8(43), 29461–29469.
mla: Luo, Zhishan, et al. “Fe3O4@NiFexOy Nanoparticles with Enhanced Electrocatalytic
Properties for Oxygen Evolution in Carbonate Electrolyte.” ACS Applied Materials
and Interfaces, vol. 8, no. 43, American Chemical Society, 2016, pp. 29461–69,
doi:10.1021/acsami.6b09888.
short: Z. Luo, S. Márti Sánchez, R. Nafria, G. Joshua, M. De La Mata, P. Guardia,
C. Flox, C. Martínez Boubeta, K. Simeonidis, J. Llorca, J. Morante, J. Arbiol,
M. Ibáñez, A. Cabot, ACS Applied Materials and Interfaces 8 (2016) 29461–29469.
date_created: 2018-12-11T11:46:05Z
date_published: 2016-11-02T00:00:00Z
date_updated: 2021-01-12T07:51:38Z
day: '02'
doi: 10.1021/acsami.6b09888
extern: '1'
intvolume: ' 8'
issue: '43'
language:
- iso: eng
month: '11'
oa_version: None
page: 29461 - 29469
publication: ACS Applied Materials and Interfaces
publication_status: published
publisher: American Chemical Society
publist_id: '7458'
status: public
title: Fe3O4@NiFexOy nanoparticles with enhanced electrocatalytic properties for oxygen
evolution in carbonate electrolyte
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 8
year: '2016'
...
---
_id: '372'
abstract:
- lang: eng
text: 'The optimization of a material functionality requires both the rational design
and precise engineering of its structural and chemical parameters. In this work,
we show how colloidal chemistry is an excellent synthetic choice for the synthesis
of novel ternary nanostructured chalcogenides, containing exclusively noble metals,
with tailored morphology and composition and with potential application in the
energy conversion field. Specifically, the Ag-Au-Se system has been explored from
a synthetic point of view, which leads to a set of Ag2Se-based hybrid and ternary
nanoparticles including the room temperature synthesis of the rare ternary Ag3AuSe2
fischesserite phase. An in-depth structural and chemical characterization of all
nanomaterials has been performed, which proofed especially useful for unravelling
the reaction mechanism behind the formation of the ternary phase in solution.
The work is complemented with the thermal and electric characterization of a ternary
Ag-Au-Se nanocomposite with promising results: we found that the use of the ternary
nanocomposite represents a clear improvement in terms of thermoelectric energy
conversion as compared to a binary Ag-Se nanocomposite analogue. '
acknowledgement: We acknowledge financial support from the Spanish MINECO through
CTQ2012-32247, CTQ2015-68370-P, and ENE2015-63969-R and from the Generalitat de
Catalunya through 2014 SGR 129. A.F. acknowledges the Spanish MINECO for a Ramon
y Cajal Fellowship (RYC-2010-05821). J.L. is a Serra Hunter Fellow and is grateful
to ICREA Academia program. At IREC, work was supported by European Regional Development
Funds and the Framework 7 program under project UNION (FP7-NMP 310250). M.I. thanks
AGAUR for their Beatriu de Pinos postdoctoral grant. M.V.K. acknowledges partial
financial support by the European Union (EU) via FP7 ERC Starting Grant 2012 (Project
NANOSOLID, GA No. 306733). L.P. acknowledges support from the Scholarship Fund of
the Swiss Chemical Industry (SSCI). The Swiss Light Source is thanked for the provision
of beamtime at the SuperXAS beamline.
author:
- first_name: Mariona
full_name: Dalmases, Mariona
last_name: Dalmases
- first_name: Maria
full_name: Ibanez Sabate, Maria
id: 43C61214-F248-11E8-B48F-1D18A9856A87
last_name: Ibanez Sabate
orcid: 0000-0001-5013-2843
- first_name: Paul
full_name: Torruella, Paul
last_name: Torruella
- first_name: Victor
full_name: Fernàndez Altable, Victor
last_name: Fernàndez Altable
- first_name: Luis
full_name: López Conesa, Luis
last_name: López Conesa
- first_name: Doris
full_name: Cadavid, Doris
last_name: Cadavid
- first_name: Laura
full_name: Piveteau, Laura
last_name: Piveteau
- first_name: Maarten
full_name: Nachtegaal, Maarten
last_name: Nachtegaal
- first_name: Jordi
full_name: Llorca, Jordi
last_name: Llorca
- first_name: Maria
full_name: Ruiz González, Maria
last_name: Ruiz González
- first_name: Sònia
full_name: Estradé, Sònia
last_name: Estradé
- first_name: Francesca
full_name: Peiró, Francesca
last_name: Peiró
- first_name: Maksym
full_name: Kovalenko, Maksym
last_name: Kovalenko
- first_name: Andreu
full_name: Cabot, Andreu
last_name: Cabot
- first_name: Albert
full_name: Figuerola, Albert
last_name: Figuerola
citation:
ama: Dalmases M, Ibáñez M, Torruella P, et al. Synthesis and thermoelectric properties
of noble metal ternary chalcogenide systems of Ag Au Se in the forms of alloyed
nanoparticles and colloidal nanoheterostructures. Chemistry of Materials.
2016;28(19):7017-7028. doi:10.1021/acs.chemmater.6b02845
apa: Dalmases, M., Ibáñez, M., Torruella, P., Fernàndez Altable, V., López Conesa,
L., Cadavid, D., … Figuerola, A. (2016). Synthesis and thermoelectric properties
of noble metal ternary chalcogenide systems of Ag Au Se in the forms of alloyed
nanoparticles and colloidal nanoheterostructures. Chemistry of Materials.
American Chemical Society. https://doi.org/10.1021/acs.chemmater.6b02845
chicago: Dalmases, Mariona, Maria Ibáñez, Paul Torruella, Victor Fernàndez Altable,
Luis López Conesa, Doris Cadavid, Laura Piveteau, et al. “Synthesis and Thermoelectric
Properties of Noble Metal Ternary Chalcogenide Systems of Ag Au Se in the Forms
of Alloyed Nanoparticles and Colloidal Nanoheterostructures.” Chemistry of
Materials. American Chemical Society, 2016. https://doi.org/10.1021/acs.chemmater.6b02845.
ieee: M. Dalmases et al., “Synthesis and thermoelectric properties of noble
metal ternary chalcogenide systems of Ag Au Se in the forms of alloyed nanoparticles
and colloidal nanoheterostructures,” Chemistry of Materials, vol. 28, no.
19. American Chemical Society, pp. 7017–7028, 2016.
ista: Dalmases M, Ibáñez M, Torruella P, Fernàndez Altable V, López Conesa L, Cadavid
D, Piveteau L, Nachtegaal M, Llorca J, Ruiz González M, Estradé S, Peiró F, Kovalenko
M, Cabot A, Figuerola A. 2016. Synthesis and thermoelectric properties of noble
metal ternary chalcogenide systems of Ag Au Se in the forms of alloyed nanoparticles
and colloidal nanoheterostructures. Chemistry of Materials. 28(19), 7017–7028.
mla: Dalmases, Mariona, et al. “Synthesis and Thermoelectric Properties of Noble
Metal Ternary Chalcogenide Systems of Ag Au Se in the Forms of Alloyed Nanoparticles
and Colloidal Nanoheterostructures.” Chemistry of Materials, vol. 28, no.
19, American Chemical Society, 2016, pp. 7017–28, doi:10.1021/acs.chemmater.6b02845.
short: M. Dalmases, M. Ibáñez, P. Torruella, V. Fernàndez Altable, L. López Conesa,
D. Cadavid, L. Piveteau, M. Nachtegaal, J. Llorca, M. Ruiz González, S. Estradé,
F. Peiró, M. Kovalenko, A. Cabot, A. Figuerola, Chemistry of Materials 28 (2016)
7017–7028.
date_created: 2018-12-11T11:46:06Z
date_published: 2016-10-11T00:00:00Z
date_updated: 2021-01-12T07:51:43Z
day: '11'
doi: 10.1021/acs.chemmater.6b02845
extern: '1'
intvolume: ' 28'
issue: '19'
language:
- iso: eng
month: '10'
oa_version: None
page: 7017 - 7028
publication: Chemistry of Materials
publication_status: published
publisher: American Chemical Society
publist_id: '7459'
status: public
title: Synthesis and thermoelectric properties of noble metal ternary chalcogenide
systems of Ag Au Se in the forms of alloyed nanoparticles and colloidal nanoheterostructures
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 28
year: '2016'
...
---
_id: '379'
abstract:
- lang: eng
text: Monodisperse Cu2ZnSnS4 (CZTS) nanocrystals (NCs), with quasi-spherical shape,
were prepared by a facile, high-yield, scalable, and high-concentration heat-up
procedure. The key parameters to minimize the NC size distribution were efficient
mixing and heat transfer in the reaction mixture through intensive argon bubbling
and improved control of the heating ramp stability. Optimized synthetic conditions
allowed the production of several grams of highly monodisperse CZTS NCs per batch,
with up to 5 wt % concentration in a crude solution and a yield above 90%.
article_processing_charge: No
author:
- first_name: Alexey
full_name: Shavel, Alexey
last_name: Shavel
- first_name: Maria
full_name: Ibáñez, Maria
id: 43C61214-F248-11E8-B48F-1D18A9856A87
last_name: Ibáñez
orcid: 0000-0001-5013-2843
- first_name: Zhishan
full_name: Luo, Zhishan
last_name: Luo
- first_name: Jonathan
full_name: De Roo, Jonathan
last_name: De Roo
- first_name: Alex
full_name: Carrete, Alex
last_name: Carrete
- first_name: Mirjana
full_name: Dimitrievska, Mirjana
last_name: Dimitrievska
- first_name: Aziz
full_name: Genç, Aziz
last_name: Genç
- first_name: Michaela
full_name: Meyns, Michaela
last_name: Meyns
- first_name: Alejandro
full_name: Pérez Rodríguez, Alejandro
last_name: Pérez Rodríguez
- first_name: Maksym
full_name: Kovalenko, Maksym
last_name: Kovalenko
- first_name: Jordi
full_name: Arbol, Jordi
last_name: Arbol
- first_name: Andreu
full_name: Cabot, Andreu
last_name: Cabot
citation:
ama: Shavel A, Ibáñez M, Luo Z, et al. Scalable heating-up synthesis of monodisperse
Cu2ZnSnS4 nanocrystals. Chemistry of Materials. 2016;28(3):720-726. doi:10.1021/acs.chemmater.5b03417
apa: Shavel, A., Ibáñez, M., Luo, Z., De Roo, J., Carrete, A., Dimitrievska, M.,
… Cabot, A. (2016). Scalable heating-up synthesis of monodisperse Cu2ZnSnS4 nanocrystals.
Chemistry of Materials. American Chemical Society. https://doi.org/10.1021/acs.chemmater.5b03417
chicago: Shavel, Alexey, Maria Ibáñez, Zhishan Luo, Jonathan De Roo, Alex Carrete,
Mirjana Dimitrievska, Aziz Genç, et al. “Scalable Heating-up Synthesis of Monodisperse
Cu2ZnSnS4 Nanocrystals.” Chemistry of Materials. American Chemical Society,
2016. https://doi.org/10.1021/acs.chemmater.5b03417.
ieee: A. Shavel et al., “Scalable heating-up synthesis of monodisperse Cu2ZnSnS4
nanocrystals,” Chemistry of Materials, vol. 28, no. 3. American Chemical
Society, pp. 720–726, 2016.
ista: Shavel A, Ibáñez M, Luo Z, De Roo J, Carrete A, Dimitrievska M, Genç A, Meyns
M, Pérez Rodríguez A, Kovalenko M, Arbol J, Cabot A. 2016. Scalable heating-up
synthesis of monodisperse Cu2ZnSnS4 nanocrystals. Chemistry of Materials. 28(3),
720–726.
mla: Shavel, Alexey, et al. “Scalable Heating-up Synthesis of Monodisperse Cu2ZnSnS4
Nanocrystals.” Chemistry of Materials, vol. 28, no. 3, American Chemical
Society, 2016, pp. 720–26, doi:10.1021/acs.chemmater.5b03417.
short: A. Shavel, M. Ibáñez, Z. Luo, J. De Roo, A. Carrete, M. Dimitrievska, A.
Genç, M. Meyns, A. Pérez Rodríguez, M. Kovalenko, J. Arbol, A. Cabot, Chemistry
of Materials 28 (2016) 720–726.
date_created: 2018-12-11T11:46:08Z
date_published: 2016-01-17T00:00:00Z
date_updated: 2021-01-12T07:52:13Z
day: '17'
doi: 10.1021/acs.chemmater.5b03417
extern: '1'
intvolume: ' 28'
issue: '3'
language:
- iso: eng
month: '01'
oa_version: None
page: 720 - 726
publication: Chemistry of Materials
publication_status: published
publisher: American Chemical Society
publist_id: '7450'
status: public
title: Scalable heating-up synthesis of monodisperse Cu2ZnSnS4 nanocrystals
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 28
year: '2016'
...
---
_id: '380'
abstract:
- lang: eng
text: Size and shape tunability and low-cost solution processability make colloidal
lead chalcogenide quantum dots (QDs) an emerging class of building blocks for
innovative photovoltaic, thermoelectric and optoelectronic devices. Lead chalcogenide
QDs are known to crystallize in the rock-salt structure, although with very different
atomic order and stoichiometry in the core and surface regions; however, there
exists no convincing prior identification of how extreme downsizing and surface-induced
ligand effects influence structural distortion. Using forefront X-ray scattering
techniques and density functional theory calculations, here we have identified
that, at sizes below 8 nm, PbS and PbSe QDs undergo a lattice distortion with
displacement of the Pb sublattice, driven by ligand-induced tensile strain. The
resulting permanent electric dipoles may have implications on the oriented attachment
of these QDs. Evidence is found for a Pb-deficient core and, in the as-synthesized
QDs, for a rhombic dodecahedral shape with nonpolar {110} facets. On varying the
nature of the surface ligands, differences in lattice strains are found.
acknowledgement: F.B. acknowledges University of Insubria for Junior Fellowship Grant
2013, M.V.K. acknowledges the European Union for financial support via FP7 ERC Starting
Grant 2012 (Project NANOSOLID, GA No. 306733), D.N.D. thanks the European Union
for Marie Curie Fellowship (PIIF-GA-2012-330524) and M.I. thanks AGAUR for her Beatriu
i Pinós post-doctoral grant (2013 BP-A 00344). Synchrotron XRPD data were collected
at the X04SA-MS Beamline of the Swiss Light Source. M. Döbeli is gratefully acknowledged
for taking RBS spectra. Electron microscopy was performed at the Scientific Center
for Optical and Electron Microscopy (ScopeM) at ETH Zürich. Computations were performed
using the BlueGene/Q supercomputer at the SciNet HPC Consortium provided through
the Southern Ontario Smart Computing Innovation Platform (SOSCIP). We thank N. Stadie
and J. Mason for reading the manuscript.
author:
- first_name: Federica
full_name: Bertolotti, Federica
last_name: Bertolotti
- first_name: Dmitry
full_name: Dirin, Dmitry
last_name: Dirin
- first_name: Maria
full_name: Ibanez Sabate, Maria
id: 43C61214-F248-11E8-B48F-1D18A9856A87
last_name: Ibanez Sabate
orcid: 0000-0001-5013-2843
- first_name: Frank
full_name: Krumreich, Frank
last_name: Krumreich
- first_name: Antonio
full_name: Cervellino, Antonio
last_name: Cervellino
- first_name: Ruggero
full_name: Frison, Ruggero
last_name: Frison
- first_name: Oleksandr
full_name: Voznyy, Oleksandr
last_name: Voznyy
- first_name: Edward
full_name: Sargent, Edward
last_name: Sargent
- first_name: Maksym
full_name: Kovalenko, Maksym
last_name: Kovalenko
- first_name: Antonietta
full_name: Guagliardi, Antonietta
last_name: Guagliardi
- first_name: Norberto
full_name: Masciocchi, Norberto
last_name: Masciocchi
citation:
ama: Bertolotti F, Dirin D, Ibáñez M, et al. Crystal symmetry breaking and role
of vacancies in colloidal lead chalcogenide quantum dots. Nature Materials.
2016;15:987-994. doi:10.1038/NMAT4661
apa: Bertolotti, F., Dirin, D., Ibáñez, M., Krumreich, F., Cervellino, A., Frison,
R., … Masciocchi, N. (2016). Crystal symmetry breaking and role of vacancies in
colloidal lead chalcogenide quantum dots. Nature Materials. Nature Publishing
Group. https://doi.org/10.1038/NMAT4661
chicago: Bertolotti, Federica, Dmitry Dirin, Maria Ibáñez, Frank Krumreich, Antonio
Cervellino, Ruggero Frison, Oleksandr Voznyy, et al. “Crystal Symmetry Breaking
and Role of Vacancies in Colloidal Lead Chalcogenide Quantum Dots.” Nature
Materials. Nature Publishing Group, 2016. https://doi.org/10.1038/NMAT4661.
ieee: F. Bertolotti et al., “Crystal symmetry breaking and role of vacancies
in colloidal lead chalcogenide quantum dots,” Nature Materials, vol. 15.
Nature Publishing Group, pp. 987–994, 2016.
ista: Bertolotti F, Dirin D, Ibáñez M, Krumreich F, Cervellino A, Frison R, Voznyy
O, Sargent E, Kovalenko M, Guagliardi A, Masciocchi N. 2016. Crystal symmetry
breaking and role of vacancies in colloidal lead chalcogenide quantum dots. Nature
Materials. 15, 987–994.
mla: Bertolotti, Federica, et al. “Crystal Symmetry Breaking and Role of Vacancies
in Colloidal Lead Chalcogenide Quantum Dots.” Nature Materials, vol. 15,
Nature Publishing Group, 2016, pp. 987–94, doi:10.1038/NMAT4661.
short: F. Bertolotti, D. Dirin, M. Ibáñez, F. Krumreich, A. Cervellino, R. Frison,
O. Voznyy, E. Sargent, M. Kovalenko, A. Guagliardi, N. Masciocchi, Nature Materials
15 (2016) 987–994.
date_created: 2018-12-11T11:46:08Z
date_published: 2016-06-13T00:00:00Z
date_updated: 2021-01-12T07:52:17Z
day: '13'
doi: 10.1038/NMAT4661
extern: '1'
intvolume: ' 15'
language:
- iso: eng
month: '06'
oa_version: None
page: 987 - 994
publication: Nature Materials
publication_status: published
publisher: Nature Publishing Group
publist_id: '7449'
status: public
title: Crystal symmetry breaking and role of vacancies in colloidal lead chalcogenide
quantum dots
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 15
year: '2016'
...
---
_id: '381'
abstract:
- lang: eng
text: We present a high-yield and scalable colloidal synthesis to produce monodisperse
AgSbSe2 nanocrystals (NCs). Using nuclear magnetic resonance (NMR) spectroscopy,
we characterized the NC surface chemistry and demonstrate the presence of surfactants
in dynamic exchange, which controls the NC growth mechanism. In addition, these
NCs were electronically doped by introducing small amounts of bismuth. To demonstrate
the technological potential of such processed material, after ligand removal by
means of NaNH2, AgSbSe2 NCs were used as building blocks to produce thermoelectric
(TE) nanomaterials. A preliminary optimization of the doping concentration resulted
in a thermoelectric figure of merit (ZT) of 1.1 at 640 K, which is comparable
to the best ZT values obtained with a Pb- and Te-free material in this middle
temperature range, with the additional advantage of the high versatility and low
cost associated with solution processing technologies.
author:
- first_name: Yu
full_name: Liu, Yu
id: 2A70014E-F248-11E8-B48F-1D18A9856A87
last_name: Liu
orcid: 0000-0001-7313-6740
- first_name: Doris
full_name: Cadavid, Doris
last_name: Cadavid
- first_name: Maria
full_name: Ibanez Sabate, Maria
id: 43C61214-F248-11E8-B48F-1D18A9856A87
last_name: Ibanez Sabate
orcid: 0000-0001-5013-2843
- first_name: Jonathan
full_name: De Roo, Jonathan
last_name: De Roo
- first_name: Silvia
full_name: Ortega, Silvia
last_name: Ortega
- first_name: Oleksandr
full_name: Dobrozhan, Oleksandr
last_name: Dobrozhan
- first_name: Maksym
full_name: Kovalenko, Maksym
last_name: Kovalenko
- first_name: Andreu
full_name: Cabot, Andreu
last_name: Cabot
citation:
ama: 'Liu Y, Cadavid D, Ibáñez M, et al. Colloidal AgSbSe2 nanocrystals: surface
analysis, electronic doping and processing into thermoelectric nanomaterials.
Journal of Materials Chemistry C. 2016;4:4756-4762. doi:10.1039/c6tc00893c'
apa: 'Liu, Y., Cadavid, D., Ibáñez, M., De Roo, J., Ortega, S., Dobrozhan, O., …
Cabot, A. (2016). Colloidal AgSbSe2 nanocrystals: surface analysis, electronic
doping and processing into thermoelectric nanomaterials. Journal of Materials
Chemistry C. Royal Society of Chemistry. https://doi.org/10.1039/c6tc00893c'
chicago: 'Liu, Yu, Doris Cadavid, Maria Ibáñez, Jonathan De Roo, Silvia Ortega,
Oleksandr Dobrozhan, Maksym Kovalenko, and Andreu Cabot. “Colloidal AgSbSe2 Nanocrystals:
Surface Analysis, Electronic Doping and Processing into Thermoelectric Nanomaterials.”
Journal of Materials Chemistry C. Royal Society of Chemistry, 2016. https://doi.org/10.1039/c6tc00893c.'
ieee: 'Y. Liu et al., “Colloidal AgSbSe2 nanocrystals: surface analysis,
electronic doping and processing into thermoelectric nanomaterials,” Journal
of Materials Chemistry C, vol. 4. Royal Society of Chemistry, pp. 4756–4762,
2016.'
ista: 'Liu Y, Cadavid D, Ibáñez M, De Roo J, Ortega S, Dobrozhan O, Kovalenko M,
Cabot A. 2016. Colloidal AgSbSe2 nanocrystals: surface analysis, electronic doping
and processing into thermoelectric nanomaterials. Journal of Materials Chemistry
C. 4, 4756–4762.'
mla: 'Liu, Yu, et al. “Colloidal AgSbSe2 Nanocrystals: Surface Analysis, Electronic
Doping and Processing into Thermoelectric Nanomaterials.” Journal of Materials
Chemistry C, vol. 4, Royal Society of Chemistry, 2016, pp. 4756–62, doi:10.1039/c6tc00893c.'
short: Y. Liu, D. Cadavid, M. Ibáñez, J. De Roo, S. Ortega, O. Dobrozhan, M. Kovalenko,
A. Cabot, Journal of Materials Chemistry C 4 (2016) 4756–4762.
date_created: 2018-12-11T11:46:09Z
date_published: 2016-04-13T00:00:00Z
date_updated: 2021-01-12T07:52:22Z
day: '13'
doi: 10.1039/c6tc00893c
extern: '1'
intvolume: ' 4'
language:
- iso: eng
month: '04'
oa_version: None
page: 4756 - 4762
publication: Journal of Materials Chemistry C
publication_status: published
publisher: Royal Society of Chemistry
publist_id: '7448'
status: public
title: 'Colloidal AgSbSe2 nanocrystals: surface analysis, electronic doping and processing
into thermoelectric nanomaterials'
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 4
year: '2016'
...
---
_id: '382'
abstract:
- lang: eng
text: Mn3O4@CoMn2O4 nanoparticles (NPs) were produced at low temperature and ambient
atmosphere using a one-pot two-step synthesis protocol involving the cation exchange
of Mn by Co in preformed Mn3O4 NPs. Selecting the proper cobalt precursor, the
nucleation of CoxOy crystallites at the Mn3O4@CoMn2O4 surface could be simultaneously
promoted to form Mn3O4@CoMn2O4–CoxOy NPs. Such heterostructured NPs were investigated
for oxygen reduction and evolution reactions (ORR, OER) in alkaline solution.
Mn3O4@CoMn2O4–CoxOy NPs with [Co]/[Mn] = 1 showed low overpotentials of 0.31 V
at −3 mA·cm–2 and a small Tafel slope of 52 mV·dec–1 for ORR, and overpotentials
of 0.31 V at 10 mA·cm–2 and a Tafel slope of 81 mV·dec–1 for OER, thus outperforming
commercial Pt-, IrO2-based and previously reported transition metal oxides. This
cation-exchange-based synthesis protocol opens up a new approach to design novel
heterostructured NPs as efficient nonprecious metal bifunctional oxygen catalysts.
acknowledgement: his work was supported by the European Regional Development Funds
and the Spanish MINECO projects BOOSTER (ENE2013-46624-C4-3-R), TNT-FUELS (MAT2014-59961),
e-TNT (MAT2014-59961-C2-2-R) and PEC-CO2 (ENE2012- 3651). Z.L. and Y.L. thank the
China Scholarship Council for scholarship support. E.I. thanks AGAUR for his Ph.D.
grant (FI-2013-B-00769). M.I. thanks AGAUR for the Beatriu de Pinos postdoctoral
grant (2013 BP-A00344). S.M. acknowl- ́ edges funding from “Programa Internacional
de Becas ‘la Caixa’-Severo Ochoa”. J.L. is a Serra Hunter Fellow and is ́ grateful
to ICREA Academia program. We also acknowledge the funding from Generalitat de Catalunya
2014 SGR 1638.
author:
- first_name: Zhishan
full_name: Luo, Zhishan
last_name: Luo
- first_name: Erdem
full_name: Irtem, Erdem
last_name: Irtem
- first_name: Maria
full_name: Ibanez, Maria
last_name: Ibanez
- first_name: Raquel
full_name: Nafria, Raquel
last_name: Nafria
- first_name: Sara
full_name: Márti Sánchez, Sara
last_name: Márti Sánchez
- first_name: Aziz
full_name: Genç, Aziz
last_name: Genç
- first_name: Maria
full_name: De La Mata, Maria
last_name: De La Mata
- first_name: Yu
full_name: Liu, Yu
id: 2A70014E-F248-11E8-B48F-1D18A9856A87
last_name: Liu
orcid: 0000-0001-7313-6740
- first_name: Doris
full_name: Cadavid, Doris
last_name: Cadavid
- first_name: Jordi
full_name: Llorca, Jordi
last_name: Llorca
- first_name: Jordi
full_name: Arbiol, Jordi
last_name: Arbiol
- first_name: Teresa
full_name: Andreu, Teresa
last_name: Andreu
- first_name: Joan
full_name: Morante, Joan
last_name: Morante
- first_name: Andreu
full_name: Cabot, Andreu
last_name: Cabot
citation:
ama: 'Luo Z, Irtem E, Ibanez M, et al. Mn3O4@CoMn2O4–CoxOy nanoparticles: Partial
cation exchange synthesis and electrocatalytic properties toward the oxygen reduction
and evolution reactions. ACS Applied Materials and Interfaces. 2016;8:17435-17444.
doi:10.1021/acsami.6b02786'
apa: 'Luo, Z., Irtem, E., Ibanez, M., Nafria, R., Márti Sánchez, S., Genç, A., …
Cabot, A. (2016). Mn3O4@CoMn2O4–CoxOy nanoparticles: Partial cation exchange synthesis
and electrocatalytic properties toward the oxygen reduction and evolution reactions.
ACS Applied Materials and Interfaces. American Chemical Society. https://doi.org/10.1021/acsami.6b02786'
chicago: 'Luo, Zhishan, Erdem Irtem, Maria Ibanez, Raquel Nafria, Sara Márti Sánchez,
Aziz Genç, Maria De La Mata, et al. “Mn3O4@CoMn2O4–CoxOy Nanoparticles: Partial
Cation Exchange Synthesis and Electrocatalytic Properties toward the Oxygen Reduction
and Evolution Reactions.” ACS Applied Materials and Interfaces. American
Chemical Society, 2016. https://doi.org/10.1021/acsami.6b02786.'
ieee: 'Z. Luo et al., “Mn3O4@CoMn2O4–CoxOy nanoparticles: Partial cation
exchange synthesis and electrocatalytic properties toward the oxygen reduction
and evolution reactions,” ACS Applied Materials and Interfaces, vol. 8.
American Chemical Society, pp. 17435–17444, 2016.'
ista: 'Luo Z, Irtem E, Ibanez M, Nafria R, Márti Sánchez S, Genç A, De La Mata M,
Liu Y, Cadavid D, Llorca J, Arbiol J, Andreu T, Morante J, Cabot A. 2016. Mn3O4@CoMn2O4–CoxOy
nanoparticles: Partial cation exchange synthesis and electrocatalytic properties
toward the oxygen reduction and evolution reactions. ACS Applied Materials and
Interfaces. 8, 17435–17444.'
mla: 'Luo, Zhishan, et al. “Mn3O4@CoMn2O4–CoxOy Nanoparticles: Partial Cation Exchange
Synthesis and Electrocatalytic Properties toward the Oxygen Reduction and Evolution
Reactions.” ACS Applied Materials and Interfaces, vol. 8, American Chemical
Society, 2016, pp. 17435–44, doi:10.1021/acsami.6b02786.'
short: Z. Luo, E. Irtem, M. Ibanez, R. Nafria, S. Márti Sánchez, A. Genç, M. De
La Mata, Y. Liu, D. Cadavid, J. Llorca, J. Arbiol, T. Andreu, J. Morante, A. Cabot,
ACS Applied Materials and Interfaces 8 (2016) 17435–17444.
date_created: 2018-12-11T11:46:09Z
date_published: 2016-06-20T00:00:00Z
date_updated: 2021-01-12T07:52:26Z
day: '20'
doi: 10.1021/acsami.6b02786
extern: '1'
intvolume: ' 8'
language:
- iso: eng
month: '06'
oa_version: None
page: 17435 - 17444
publication: ACS Applied Materials and Interfaces
publication_status: published
publisher: American Chemical Society
publist_id: '7447'
status: public
title: 'Mn3O4@CoMn2O4–CoxOy nanoparticles: Partial cation exchange synthesis and electrocatalytic
properties toward the oxygen reduction and evolution reactions'
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 8
year: '2016'
...