---
_id: '11985'
abstract:
- lang: eng
text: Hydrocodone, a high value active pharmaceutical ingredient (API), is usually
produced in a semisynthetic pathway from morphine, codeine or thebaine. The latter
alkaloid is an attractive precursor as it is not used as a remedy itself. The
key step in this production route is a selective olefin reduction forming 8,14-dihydrothebaine
which can be subsequently hydrolyzed to yield hydrocodone. Unfortunately, standard
hydrogenation procedures cannot be applied due to severe selectivity problems.
A transfer hydrogenation using in situ generated diimide is the only known alternative
to achieve a selective transformation. The most (atom) economic generation of
this highly unstable reducing agent is by oxidizing hydrazine hydrate (N2H4·H2O)
with O2. In the past, this route was “forbidden” on an industrial scale due to
its enormous explosion potential in batch. A continuous high-temperature/high-pressure
methodology allows an efficient, safe, and scalable processing of the hazardous
reaction mixture. The industrially relevant reduction was achieved by using four
consecutive liquid feeds (of N2H4·H2O) and residence time units, resulting in
a highly selective reduction within less than 1 h.
article_processing_charge: No
article_type: original
author:
- first_name: Bartholomäus
full_name: Pieber, Bartholomäus
id: 93e5e5b2-0da6-11ed-8a41-af589a024726
last_name: Pieber
orcid: 0000-0001-8689-388X
- first_name: D. Phillip
full_name: Cox, D. Phillip
last_name: Cox
- first_name: C. Oliver
full_name: Kappe, C. Oliver
last_name: Kappe
citation:
ama: Pieber B, Cox DP, Kappe CO. Selective olefin reduction in thebaine using hydrazine
hydrate and O₂ under intensified continuous flow conditions. Organic Process
Research and Development. 2016;20(2):376-385. doi:10.1021/acs.oprd.5b00370
apa: Pieber, B., Cox, D. P., & Kappe, C. O. (2016). Selective olefin reduction
in thebaine using hydrazine hydrate and O₂ under intensified continuous flow conditions.
Organic Process Research and Development. American Chemical Society. https://doi.org/10.1021/acs.oprd.5b00370
chicago: Pieber, Bartholomäus, D. Phillip Cox, and C. Oliver Kappe. “Selective Olefin
Reduction in Thebaine Using Hydrazine Hydrate and O₂ under Intensified Continuous
Flow Conditions.” Organic Process Research and Development. American Chemical
Society, 2016. https://doi.org/10.1021/acs.oprd.5b00370.
ieee: B. Pieber, D. P. Cox, and C. O. Kappe, “Selective olefin reduction in thebaine
using hydrazine hydrate and O₂ under intensified continuous flow conditions,”
Organic Process Research and Development, vol. 20, no. 2. American Chemical
Society, pp. 376–385, 2016.
ista: Pieber B, Cox DP, Kappe CO. 2016. Selective olefin reduction in thebaine using
hydrazine hydrate and O₂ under intensified continuous flow conditions. Organic
Process Research and Development. 20(2), 376–385.
mla: Pieber, Bartholomäus, et al. “Selective Olefin Reduction in Thebaine Using
Hydrazine Hydrate and O₂ under Intensified Continuous Flow Conditions.” Organic
Process Research and Development, vol. 20, no. 2, American Chemical Society,
2016, pp. 376–85, doi:10.1021/acs.oprd.5b00370.
short: B. Pieber, D.P. Cox, C.O. Kappe, Organic Process Research and Development
20 (2016) 376–385.
date_created: 2022-08-25T11:34:28Z
date_published: 2016-02-19T00:00:00Z
date_updated: 2023-02-21T10:10:26Z
day: '19'
doi: 10.1021/acs.oprd.5b00370
extern: '1'
intvolume: ' 20'
issue: '2'
language:
- iso: eng
month: '02'
oa_version: None
page: 376-385
publication: Organic Process Research and Development
publication_identifier:
eissn:
- 1520-586X
issn:
- 1083-6160
publication_status: published
publisher: American Chemical Society
quality_controlled: '1'
scopus_import: '1'
status: public
title: Selective olefin reduction in thebaine using hydrazine hydrate and O₂ under
intensified continuous flow conditions
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 20
year: '2016'
...
---
_id: '11988'
abstract:
- lang: eng
text: A continuous Bucherer–Bergs hydantoin synthesis utilizing intensified conditions
is reported. The methodology is characterized by a two-feed flow approach to independently
feed the organic substrate and the aqueous reagent solution. The increased interfacial
area of the biphasic reaction mixture and the lack of headspace enabled almost
quantitative conversions within ca. 30 minutes at 120 °C and 20 bar even for unpolar
starting materials. In addition, a selective N(3)-monoalkylation of the resulting
heterocycles under batch microwave conditions is reported yielding potential acetylcholinesterase
inhibitors.
article_processing_charge: No
article_type: letter_note
author:
- first_name: C.
full_name: Kappe, C.
last_name: Kappe
- first_name: Julia
full_name: Monteiro, Julia
last_name: Monteiro
- first_name: Bartholomäus
full_name: Pieber, Bartholomäus
id: 93e5e5b2-0da6-11ed-8a41-af589a024726
last_name: Pieber
orcid: 0000-0001-8689-388X
- first_name: Arlene
full_name: Corrêa, Arlene
last_name: Corrêa
citation:
ama: 'Kappe C, Monteiro J, Pieber B, Corrêa A. Continuous synthesis of hydantoins:
Intensifying the Bucherer–Bergs reaction. Synlett. 2016;27(01):83-87. doi:10.1055/s-0035-1560317'
apa: 'Kappe, C., Monteiro, J., Pieber, B., & Corrêa, A. (2016). Continuous synthesis
of hydantoins: Intensifying the Bucherer–Bergs reaction. Synlett. Georg
Thieme Verlag. https://doi.org/10.1055/s-0035-1560317'
chicago: 'Kappe, C., Julia Monteiro, Bartholomäus Pieber, and Arlene Corrêa. “Continuous
Synthesis of Hydantoins: Intensifying the Bucherer–Bergs Reaction.” Synlett.
Georg Thieme Verlag, 2016. https://doi.org/10.1055/s-0035-1560317.'
ieee: 'C. Kappe, J. Monteiro, B. Pieber, and A. Corrêa, “Continuous synthesis of
hydantoins: Intensifying the Bucherer–Bergs reaction,” Synlett, vol. 27,
no. 01. Georg Thieme Verlag, pp. 83–87, 2016.'
ista: 'Kappe C, Monteiro J, Pieber B, Corrêa A. 2016. Continuous synthesis of hydantoins:
Intensifying the Bucherer–Bergs reaction. Synlett. 27(01), 83–87.'
mla: 'Kappe, C., et al. “Continuous Synthesis of Hydantoins: Intensifying the Bucherer–Bergs
Reaction.” Synlett, vol. 27, no. 01, Georg Thieme Verlag, 2016, pp. 83–87,
doi:10.1055/s-0035-1560317.'
short: C. Kappe, J. Monteiro, B. Pieber, A. Corrêa, Synlett 27 (2016) 83–87.
date_created: 2022-08-25T11:52:22Z
date_published: 2016-01-04T00:00:00Z
date_updated: 2023-02-21T10:10:33Z
day: '04'
doi: 10.1055/s-0035-1560317
extern: '1'
intvolume: ' 27'
issue: '01'
language:
- iso: eng
month: '01'
oa_version: None
page: 83-87
publication: Synlett
publication_identifier:
eissn:
- 1437-2096
issn:
- 0936-5214
publication_status: published
publisher: Georg Thieme Verlag
quality_controlled: '1'
scopus_import: '1'
status: public
title: 'Continuous synthesis of hydantoins: Intensifying the Bucherer–Bergs reaction'
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 27
year: '2016'
...
---
_id: '1200'
acknowledgement: C.H. acknowledges generous support from the ISTFELLOW program.
author:
- first_name: Christian
full_name: Hilbe, Christian
id: 2FDF8F3C-F248-11E8-B48F-1D18A9856A87
last_name: Hilbe
orcid: 0000-0001-5116-955X
- first_name: Arne
full_name: Traulsen, Arne
last_name: Traulsen
citation:
ama: 'Hilbe C, Traulsen A. Only the combination of mathematics and agent based simulations
can leverage the full potential of evolutionary modeling: Comment on “Evolutionary
game theory using agent-based methods” by C. Adami, J. Schossau and A. Hintze.
Physics of Life Reviews. 2016;19:29-31. doi:10.1016/j.plrev.2016.10.004'
apa: 'Hilbe, C., & Traulsen, A. (2016). Only the combination of mathematics
and agent based simulations can leverage the full potential of evolutionary modeling:
Comment on “Evolutionary game theory using agent-based methods” by C. Adami, J.
Schossau and A. Hintze. Physics of Life Reviews. Elsevier. https://doi.org/10.1016/j.plrev.2016.10.004'
chicago: 'Hilbe, Christian, and Arne Traulsen. “Only the Combination of Mathematics
and Agent Based Simulations Can Leverage the Full Potential of Evolutionary Modeling:
Comment on ‘Evolutionary Game Theory Using Agent-Based Methods’ by C. Adami, J.
Schossau and A. Hintze.” Physics of Life Reviews. Elsevier, 2016. https://doi.org/10.1016/j.plrev.2016.10.004.'
ieee: 'C. Hilbe and A. Traulsen, “Only the combination of mathematics and agent
based simulations can leverage the full potential of evolutionary modeling: Comment
on ‘Evolutionary game theory using agent-based methods’ by C. Adami, J. Schossau
and A. Hintze,” Physics of Life Reviews, vol. 19. Elsevier, pp. 29–31,
2016.'
ista: 'Hilbe C, Traulsen A. 2016. Only the combination of mathematics and agent
based simulations can leverage the full potential of evolutionary modeling: Comment
on “Evolutionary game theory using agent-based methods” by C. Adami, J. Schossau
and A. Hintze. Physics of Life Reviews. 19, 29–31.'
mla: 'Hilbe, Christian, and Arne Traulsen. “Only the Combination of Mathematics
and Agent Based Simulations Can Leverage the Full Potential of Evolutionary Modeling:
Comment on ‘Evolutionary Game Theory Using Agent-Based Methods’ by C. Adami, J.
Schossau and A. Hintze.” Physics of Life Reviews, vol. 19, Elsevier, 2016,
pp. 29–31, doi:10.1016/j.plrev.2016.10.004.'
short: C. Hilbe, A. Traulsen, Physics of Life Reviews 19 (2016) 29–31.
date_created: 2018-12-11T11:50:40Z
date_published: 2016-12-01T00:00:00Z
date_updated: 2021-01-12T06:49:03Z
day: '01'
ddc:
- '530'
department:
- _id: KrCh
doi: 10.1016/j.plrev.2016.10.004
ec_funded: 1
file:
- access_level: open_access
checksum: 95e6dc78278334b99dacbf8822509364
content_type: application/pdf
creator: system
date_created: 2018-12-12T10:11:02Z
date_updated: 2020-07-14T12:44:39Z
file_id: '4855'
file_name: IST-2017-798-v1+1_comment_adami.pdf
file_size: 171352
relation: main_file
file_date_updated: 2020-07-14T12:44:39Z
has_accepted_license: '1'
intvolume: ' 19'
language:
- iso: eng
month: '12'
oa: 1
oa_version: Submitted Version
page: 29 - 31
project:
- _id: 25681D80-B435-11E9-9278-68D0E5697425
call_identifier: FP7
grant_number: '291734'
name: International IST Postdoc Fellowship Programme
publication: Physics of Life Reviews
publication_status: published
publisher: Elsevier
publist_id: '6150'
pubrep_id: '798'
quality_controlled: '1'
scopus_import: 1
status: public
title: 'Only the combination of mathematics and agent based simulations can leverage
the full potential of evolutionary modeling: Comment on “Evolutionary game theory
using agent-based methods” by C. Adami, J. Schossau and A. Hintze'
tmp:
image: /images/cc_by_nc_nd.png
legal_code_url: https://creativecommons.org/licenses/by-nc-nd/4.0/legalcode
name: Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International
(CC BY-NC-ND 4.0)
short: CC BY-NC-ND (4.0)
type: journal_article
user_id: 3E5EF7F0-F248-11E8-B48F-1D18A9856A87
volume: 19
year: '2016'
...
---
_id: '1201'
abstract:
- lang: eng
text: In this issue of Cell, Skau et al. show that the formin FMN2 organizes a perinuclear
actin cytoskeleton that protects the nucleus and its genomic content of migrating
cells squeezing through small spaces.
author:
- first_name: Jörg
full_name: Renkawitz, Jörg
id: 3F0587C8-F248-11E8-B48F-1D18A9856A87
last_name: Renkawitz
orcid: 0000-0003-2856-3369
- first_name: Michael K
full_name: Sixt, Michael K
id: 41E9FBEA-F248-11E8-B48F-1D18A9856A87
last_name: Sixt
orcid: 0000-0002-6620-9179
citation:
ama: Renkawitz J, Sixt MK. Formin’ a nuclear protection. Cell. 2016;167(6):1448-1449.
doi:10.1016/j.cell.2016.11.024
apa: Renkawitz, J., & Sixt, M. K. (2016). Formin’ a nuclear protection. Cell.
Cell Press. https://doi.org/10.1016/j.cell.2016.11.024
chicago: Renkawitz, Jörg, and Michael K Sixt. “Formin’ a Nuclear Protection.” Cell.
Cell Press, 2016. https://doi.org/10.1016/j.cell.2016.11.024.
ieee: J. Renkawitz and M. K. Sixt, “Formin’ a nuclear protection,” Cell,
vol. 167, no. 6. Cell Press, pp. 1448–1449, 2016.
ista: Renkawitz J, Sixt MK. 2016. Formin’ a nuclear protection. Cell. 167(6), 1448–1449.
mla: Renkawitz, Jörg, and Michael K. Sixt. “Formin’ a Nuclear Protection.” Cell,
vol. 167, no. 6, Cell Press, 2016, pp. 1448–49, doi:10.1016/j.cell.2016.11.024.
short: J. Renkawitz, M.K. Sixt, Cell 167 (2016) 1448–1449.
date_created: 2018-12-11T11:50:41Z
date_published: 2016-12-01T00:00:00Z
date_updated: 2021-01-12T06:49:03Z
day: '01'
department:
- _id: MiSi
doi: 10.1016/j.cell.2016.11.024
intvolume: ' 167'
issue: '6'
language:
- iso: eng
month: '12'
oa_version: None
page: 1448 - 1449
publication: Cell
publication_status: published
publisher: Cell Press
publist_id: '6149'
quality_controlled: '1'
scopus_import: 1
status: public
title: Formin’ a nuclear protection
type: journal_article
user_id: 3E5EF7F0-F248-11E8-B48F-1D18A9856A87
volume: 167
year: '2016'
...
---
_id: '1202'
acknowledgement: The authors thank Sophie A.O. Armitage and Jan N. Offenborn for helpful
comments on the figures, and two anonymous reviewers for their helpful comments.
The project was funded by the Deutsche Forschungsgemeinschaft (DFG, KU 1929/4-2)
within the priority programme SPP 1399 “Host–Parasite Coevolution”.
author:
- first_name: Barbara
full_name: Milutinovic, Barbara
id: 2CDC32B8-F248-11E8-B48F-1D18A9856A87
last_name: Milutinovic
orcid: 0000-0002-8214-4758
- first_name: Robert
full_name: Peuß, Robert
last_name: Peuß
- first_name: Kevin
full_name: Ferro, Kevin
last_name: Ferro
- first_name: Joachim
full_name: Kurtz, Joachim
last_name: Kurtz
citation:
ama: 'Milutinovic B, Peuß R, Ferro K, Kurtz J. Immune priming in arthropods: an
update focusing on the red flour beetle. Zoology . 2016;119(4):254-261.
doi:10.1016/j.zool.2016.03.006'
apa: 'Milutinovic, B., Peuß, R., Ferro, K., & Kurtz, J. (2016). Immune priming
in arthropods: an update focusing on the red flour beetle. Zoology . Elsevier.
https://doi.org/10.1016/j.zool.2016.03.006'
chicago: 'Milutinovic, Barbara, Robert Peuß, Kevin Ferro, and Joachim Kurtz. “Immune
Priming in Arthropods: An Update Focusing on the Red Flour Beetle.” Zoology
. Elsevier, 2016. https://doi.org/10.1016/j.zool.2016.03.006.'
ieee: 'B. Milutinovic, R. Peuß, K. Ferro, and J. Kurtz, “Immune priming in arthropods:
an update focusing on the red flour beetle,” Zoology , vol. 119, no. 4.
Elsevier, pp. 254–261, 2016.'
ista: 'Milutinovic B, Peuß R, Ferro K, Kurtz J. 2016. Immune priming in arthropods:
an update focusing on the red flour beetle. Zoology . 119(4), 254–261.'
mla: 'Milutinovic, Barbara, et al. “Immune Priming in Arthropods: An Update Focusing
on the Red Flour Beetle.” Zoology , vol. 119, no. 4, Elsevier, 2016, pp.
254–61, doi:10.1016/j.zool.2016.03.006.'
short: B. Milutinovic, R. Peuß, K. Ferro, J. Kurtz, Zoology 119 (2016) 254–261.
date_created: 2018-12-11T11:50:41Z
date_published: 2016-08-01T00:00:00Z
date_updated: 2021-01-12T06:49:03Z
day: '01'
ddc:
- '570'
department:
- _id: SyCr
doi: 10.1016/j.zool.2016.03.006
file:
- access_level: open_access
checksum: 8396d5bd95f9c4295857162f902afabf
content_type: application/pdf
creator: kschuh
date_created: 2019-01-25T13:00:20Z
date_updated: 2020-07-14T12:44:39Z
file_id: '5885'
file_name: 2016_Elsevier_Milutinovic.pdf
file_size: 1473211
relation: main_file
file_date_updated: 2020-07-14T12:44:39Z
has_accepted_license: '1'
intvolume: ' 119'
issue: '4'
language:
- iso: eng
month: '08'
oa: 1
oa_version: Published Version
page: 254 - 261
project:
- _id: 25DAF0B2-B435-11E9-9278-68D0E5697425
grant_number: CR-118/3-1
name: Host-Parasite Coevolution
publication: 'Zoology '
publication_status: published
publisher: Elsevier
publist_id: '6147'
quality_controlled: '1'
scopus_import: 1
status: public
title: 'Immune priming in arthropods: an update focusing on the red flour beetle'
tmp:
image: /images/cc_by_nc_nd.png
legal_code_url: https://creativecommons.org/licenses/by-nc-nd/4.0/legalcode
name: Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International
(CC BY-NC-ND 4.0)
short: CC BY-NC-ND (4.0)
type: journal_article
user_id: 3E5EF7F0-F248-11E8-B48F-1D18A9856A87
volume: 119
year: '2016'
...
---
_id: '1203'
abstract:
- lang: eng
text: Haemophilus haemolyticus has been recently discovered to have the potential
to cause invasive disease. It is closely related to nontypeable Haemophilus influenzae
(NT H. influenzae). NT H. influenzae and H. haemolyticus are often misidentified
because none of the existing tests targeting the known phenotypes of H. haemolyticus
are able to specifically identify H. haemolyticus. Through comparative genomic
analysis of H. haemolyticus and NT H. influenzae, we identified genes unique to
H. haemolyticus that can be used as targets for the identification of H. haemolyticus.
A real-time PCR targeting purT (encoding phosphoribosylglycinamide formyltransferase
2 in the purine synthesis pathway) was developed and evaluated. The lower limit
of detection was 40 genomes/PCR; the sensitivity and specificity in detecting
H. haemolyticus were 98.9% and 97%, respectively. To improve the discrimination
of H. haemolyticus and NT H. influenzae, a testing scheme combining two targets
(H. haemolyticus purT and H. influenzae hpd, encoding protein D lipoprotein) was
also evaluated and showed 96.7% sensitivity and 98.2% specificity for the identification
of H. haemolyticus and 92.8% sensitivity and 100% specificity for the identification
of H. influenzae, respectively. The dual-target testing scheme can be used for
the diagnosis and surveillance of infection and disease caused by H. haemolyticus
and NT H. influenzae.
acknowledgement: We are grateful to ABCs for providing strains and the Bacterial Meningitis
Laboratory for technical support.
author:
- first_name: Fang
full_name: Hu, Fang
last_name: Hu
- first_name: Lavanya
full_name: Rishishwar, Lavanya
last_name: Rishishwar
- first_name: Ambily
full_name: Sivadas, Ambily
last_name: Sivadas
- first_name: Gabriel
full_name: Mitchell, Gabriel
id: 315BCD80-F248-11E8-B48F-1D18A9856A87
last_name: Mitchell
- first_name: Jordan
full_name: King, Jordan
last_name: King
- first_name: Timothy
full_name: Murphy, Timothy
last_name: Murphy
- first_name: Janet
full_name: Gilsdorf, Janet
last_name: Gilsdorf
- first_name: Leonard
full_name: Mayer, Leonard
last_name: Mayer
- first_name: Xin
full_name: Wang, Xin
last_name: Wang
citation:
ama: Hu F, Rishishwar L, Sivadas A, et al. Comparative genomic analysis of Haemophilus
haemolyticus and nontypeable Haemophilus influenzae and a new testing scheme for
their discrimination. Journal of Clinical Microbiology. 2016;54(12):3010-3017.
doi:10.1128/JCM.01511-16
apa: Hu, F., Rishishwar, L., Sivadas, A., Mitchell, G., King, J., Murphy, T., …
Wang, X. (2016). Comparative genomic analysis of Haemophilus haemolyticus and
nontypeable Haemophilus influenzae and a new testing scheme for their discrimination.
Journal of Clinical Microbiology. American Society for Microbiology. https://doi.org/10.1128/JCM.01511-16
chicago: Hu, Fang, Lavanya Rishishwar, Ambily Sivadas, Gabriel Mitchell, Jordan
King, Timothy Murphy, Janet Gilsdorf, Leonard Mayer, and Xin Wang. “Comparative
Genomic Analysis of Haemophilus Haemolyticus and Nontypeable Haemophilus Influenzae
and a New Testing Scheme for Their Discrimination.” Journal of Clinical Microbiology.
American Society for Microbiology, 2016. https://doi.org/10.1128/JCM.01511-16.
ieee: F. Hu et al., “Comparative genomic analysis of Haemophilus haemolyticus
and nontypeable Haemophilus influenzae and a new testing scheme for their discrimination,”
Journal of Clinical Microbiology, vol. 54, no. 12. American Society for
Microbiology, pp. 3010–3017, 2016.
ista: Hu F, Rishishwar L, Sivadas A, Mitchell G, King J, Murphy T, Gilsdorf J, Mayer
L, Wang X. 2016. Comparative genomic analysis of Haemophilus haemolyticus and
nontypeable Haemophilus influenzae and a new testing scheme for their discrimination.
Journal of Clinical Microbiology. 54(12), 3010–3017.
mla: Hu, Fang, et al. “Comparative Genomic Analysis of Haemophilus Haemolyticus
and Nontypeable Haemophilus Influenzae and a New Testing Scheme for Their Discrimination.”
Journal of Clinical Microbiology, vol. 54, no. 12, American Society for
Microbiology, 2016, pp. 3010–17, doi:10.1128/JCM.01511-16.
short: F. Hu, L. Rishishwar, A. Sivadas, G. Mitchell, J. King, T. Murphy, J. Gilsdorf,
L. Mayer, X. Wang, Journal of Clinical Microbiology 54 (2016) 3010–3017.
date_created: 2018-12-11T11:50:41Z
date_published: 2016-12-01T00:00:00Z
date_updated: 2021-01-12T06:49:04Z
day: '01'
department:
- _id: GaTk
doi: 10.1128/JCM.01511-16
intvolume: ' 54'
issue: '12'
language:
- iso: eng
main_file_link:
- open_access: '1'
url: https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5121393/
month: '12'
oa: 1
oa_version: Submitted Version
page: 3010 - 3017
publication: Journal of Clinical Microbiology
publication_status: published
publisher: American Society for Microbiology
publist_id: '6146'
quality_controlled: '1'
scopus_import: 1
status: public
title: Comparative genomic analysis of Haemophilus haemolyticus and nontypeable Haemophilus
influenzae and a new testing scheme for their discrimination
type: journal_article
user_id: 3E5EF7F0-F248-11E8-B48F-1D18A9856A87
volume: 54
year: '2016'
...
---
_id: '1204'
abstract:
- lang: eng
text: In science, as in life, "surprises" can be adequately appreciated
only in the presence of a null model, what we expect a priori. In physics, theories
sometimes express the values of dimensionless physical constants as combinations
of mathematical constants like π or e. The inverse problem also arises, whereby
the measured value of a physical constant admits a "surprisingly" simple
approximation in terms of well-known mathematical constants. Can we estimate the
probability for this to be a mere coincidence, rather than an inkling of some
theory? We answer the question in the most naive form.
author:
- first_name: Ariel
full_name: Amir, Ariel
last_name: Amir
- first_name: Mikhail
full_name: Lemeshko, Mikhail
id: 37CB05FA-F248-11E8-B48F-1D18A9856A87
last_name: Lemeshko
orcid: 0000-0002-6990-7802
- first_name: Tadashi
full_name: Tokieda, Tadashi
last_name: Tokieda
citation:
ama: Amir A, Lemeshko M, Tokieda T. Surprises in numerical expressions of physical
constants. American Mathematical Monthly. 2016;123(6):609-612. doi:10.4169/amer.math.monthly.123.6.609
apa: Amir, A., Lemeshko, M., & Tokieda, T. (2016). Surprises in numerical expressions
of physical constants. American Mathematical Monthly. Mathematical Association
of America. https://doi.org/10.4169/amer.math.monthly.123.6.609
chicago: Amir, Ariel, Mikhail Lemeshko, and Tadashi Tokieda. “Surprises in Numerical
Expressions of Physical Constants.” American Mathematical Monthly. Mathematical
Association of America, 2016. https://doi.org/10.4169/amer.math.monthly.123.6.609.
ieee: A. Amir, M. Lemeshko, and T. Tokieda, “Surprises in numerical expressions
of physical constants,” American Mathematical Monthly, vol. 123, no. 6.
Mathematical Association of America, pp. 609–612, 2016.
ista: Amir A, Lemeshko M, Tokieda T. 2016. Surprises in numerical expressions of
physical constants. American Mathematical Monthly. 123(6), 609–612.
mla: Amir, Ariel, et al. “Surprises in Numerical Expressions of Physical Constants.”
American Mathematical Monthly, vol. 123, no. 6, Mathematical Association
of America, 2016, pp. 609–12, doi:10.4169/amer.math.monthly.123.6.609.
short: A. Amir, M. Lemeshko, T. Tokieda, American Mathematical Monthly 123 (2016)
609–612.
date_created: 2018-12-11T11:50:42Z
date_published: 2016-06-01T00:00:00Z
date_updated: 2021-01-12T06:49:04Z
day: '01'
department:
- _id: MiLe
doi: 10.4169/amer.math.monthly.123.6.609
intvolume: ' 123'
issue: '6'
language:
- iso: eng
main_file_link:
- open_access: '1'
url: https://arxiv.org/abs/1603.00299
month: '06'
oa: 1
oa_version: Preprint
page: 609 - 612
publication: American Mathematical Monthly
publication_status: published
publisher: Mathematical Association of America
publist_id: '6143'
quality_controlled: '1'
scopus_import: 1
status: public
title: Surprises in numerical expressions of physical constants
type: journal_article
user_id: 3E5EF7F0-F248-11E8-B48F-1D18A9856A87
volume: 123
year: '2016'
...
---
_id: '1205'
abstract:
- lang: eng
text: In this paper, we present a formal model-driven engineering approach to establishing
a safety-assured implementation of Multifunction vehicle bus controller (MVBC)
based on the generic reference models and requirements described in the International
Electrotechnical Commission (IEC) standard IEC-61375. First, the generic models
described in IEC-61375 are translated into a network of timed automata, and some
safety requirements tested in IEC-61375 are formalized as timed computation tree
logic (TCTL) formulas. With the help of Uppaal, we check and debug whether the
timed automata satisfy the formulas or not. Within this step, several logic inconsistencies
in the original standard are detected and corrected. Then, we apply the tool Times
to generate C code from the verified model, which was later synthesized into a
real MVBC chip. Finally, the runtime verification tool RMOR is applied to verify
some safety requirements at the implementation level. We set up a real platform
with worldwide mostly used MVBC D113, and verify the correctness and the scalability
of the synthesized MVBC chip more comprehensively. The errors in the standard
has been confirmed and the resulted MVBC has been deployed in real train communication
network.
acknowledgement: "This research is sponsored in part by NSFC Program (No. 91218302,
No. 61527812), National Science and Technology Major Project (No. 2016ZX01038101),
Tsinghua University Initiative Scientific Research Program (20131089331), MIIT IT
funds (Research and application of TCN key technologies) of China, and the National
Key Technology R&D Program (No. 2015BAG14B01-02), Austrian Science Fund (FWF) under
grants S11402-N23 (RiSE/SHiNE) and Z211-N23.\r\n"
alternative_title:
- LNCS
author:
- first_name: Yu
full_name: Jiang, Yu
last_name: Jiang
- first_name: Han
full_name: Liu, Han
last_name: Liu
- first_name: Houbing
full_name: Song, Houbing
last_name: Song
- first_name: Hui
full_name: Kong, Hui
id: 3BDE25AA-F248-11E8-B48F-1D18A9856A87
last_name: Kong
orcid: 0000-0002-3066-6941
- first_name: Ming
full_name: Gu, Ming
last_name: Gu
- first_name: Jiaguang
full_name: Sun, Jiaguang
last_name: Sun
- first_name: Lui
full_name: Sha, Lui
last_name: Sha
citation:
ama: 'Jiang Y, Liu H, Song H, et al. Safety assured formal model driven design of
the multifunction vehicle bus controller. In: Vol 9995. Springer; 2016:757-763.
doi:10.1007/978-3-319-48989-6_47'
apa: 'Jiang, Y., Liu, H., Song, H., Kong, H., Gu, M., Sun, J., & Sha, L. (2016).
Safety assured formal model driven design of the multifunction vehicle bus controller
(Vol. 9995, pp. 757–763). Presented at the FM: International Symposium on Formal
Methods, Limassol, Cyprus: Springer. https://doi.org/10.1007/978-3-319-48989-6_47'
chicago: Jiang, Yu, Han Liu, Houbing Song, Hui Kong, Ming Gu, Jiaguang Sun, and
Lui Sha. “Safety Assured Formal Model Driven Design of the Multifunction Vehicle
Bus Controller,” 9995:757–63. Springer, 2016. https://doi.org/10.1007/978-3-319-48989-6_47.
ieee: 'Y. Jiang et al., “Safety assured formal model driven design of the
multifunction vehicle bus controller,” presented at the FM: International Symposium
on Formal Methods, Limassol, Cyprus, 2016, vol. 9995, pp. 757–763.'
ista: 'Jiang Y, Liu H, Song H, Kong H, Gu M, Sun J, Sha L. 2016. Safety assured
formal model driven design of the multifunction vehicle bus controller. FM: International
Symposium on Formal Methods, LNCS, vol. 9995, 757–763.'
mla: Jiang, Yu, et al. Safety Assured Formal Model Driven Design of the Multifunction
Vehicle Bus Controller. Vol. 9995, Springer, 2016, pp. 757–63, doi:10.1007/978-3-319-48989-6_47.
short: Y. Jiang, H. Liu, H. Song, H. Kong, M. Gu, J. Sun, L. Sha, in:, Springer,
2016, pp. 757–763.
conference:
end_date: 2016-11-11
location: Limassol, Cyprus
name: 'FM: International Symposium on Formal Methods'
start_date: 2016-11-09
date_created: 2018-12-11T11:50:42Z
date_published: 2016-11-08T00:00:00Z
date_updated: 2023-09-18T08:12:48Z
day: '08'
ddc:
- '004'
department:
- _id: ToHe
doi: 10.1007/978-3-319-48989-6_47
file:
- access_level: open_access
checksum: fea0b3fae9a2a42e8bfec59840e30d8c
content_type: application/pdf
creator: system
date_created: 2018-12-12T10:08:13Z
date_updated: 2020-07-14T12:44:39Z
file_id: '4673'
file_name: IST-2017-783-v1+1_FM-Safety-Assured-Development-of-MVBC.pdf
file_size: 281501
relation: main_file
file_date_updated: 2020-07-14T12:44:39Z
has_accepted_license: '1'
intvolume: ' 9995'
language:
- iso: eng
month: '11'
oa: 1
oa_version: Submitted Version
page: 757 - 763
project:
- _id: 25832EC2-B435-11E9-9278-68D0E5697425
call_identifier: FWF
grant_number: S 11407_N23
name: Rigorous Systems Engineering
- _id: 25F42A32-B435-11E9-9278-68D0E5697425
call_identifier: FWF
grant_number: Z211
name: The Wittgenstein Prize
publication_status: published
publisher: Springer
publist_id: '6144'
pubrep_id: '783'
quality_controlled: '1'
related_material:
record:
- id: '434'
relation: later_version
status: public
scopus_import: 1
status: public
title: Safety assured formal model driven design of the multifunction vehicle bus
controller
type: conference
user_id: 3E5EF7F0-F248-11E8-B48F-1D18A9856A87
volume: 9995
year: '2016'
...
---
_id: '1206'
abstract:
- lang: eng
text: We study a polar molecule immersed in a superfluid environment, such as a
helium nanodroplet or a Bose–Einstein condensate, in the presence of a strong
electrostatic field. We show that coupling of the molecular pendular motion, induced
by the field, to the fluctuating bath leads to formation of pendulons—spherical
harmonic librators dressed by a field of many-particle excitations. We study the
behavior of the pendulon in a broad range of molecule–bath and molecule–field
interaction strengths, and reveal that its spectrum features a series of instabilities
which are absent in the field-free case of the angulon quasiparticle. Furthermore,
we show that an external field allows to fine-tune the positions of these instabilities
in the molecular rotational spectrum. This opens the door to detailed experimental
studies of redistribution of orbital angular momentum in many-particle systems.
© 2016 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
author:
- first_name: Elena
full_name: Redchenko, Elena
id: 2C21D6E8-F248-11E8-B48F-1D18A9856A87
last_name: Redchenko
- first_name: Mikhail
full_name: Lemeshko, Mikhail
id: 37CB05FA-F248-11E8-B48F-1D18A9856A87
last_name: Lemeshko
orcid: 0000-0002-6990-7802
citation:
ama: Redchenko E, Lemeshko M. Libration of strongly oriented polar molecules inside
a superfluid. ChemPhysChem. 2016;17(22):3649-3654. doi:10.1002/cphc.201601042
apa: Redchenko, E., & Lemeshko, M. (2016). Libration of strongly oriented polar
molecules inside a superfluid. ChemPhysChem. Wiley-Blackwell. https://doi.org/10.1002/cphc.201601042
chicago: Redchenko, Elena, and Mikhail Lemeshko. “Libration of Strongly Oriented
Polar Molecules inside a Superfluid.” ChemPhysChem. Wiley-Blackwell, 2016.
https://doi.org/10.1002/cphc.201601042.
ieee: E. Redchenko and M. Lemeshko, “Libration of strongly oriented polar molecules
inside a superfluid,” ChemPhysChem, vol. 17, no. 22. Wiley-Blackwell, pp.
3649–3654, 2016.
ista: Redchenko E, Lemeshko M. 2016. Libration of strongly oriented polar molecules
inside a superfluid. ChemPhysChem. 17(22), 3649–3654.
mla: Redchenko, Elena, and Mikhail Lemeshko. “Libration of Strongly Oriented Polar
Molecules inside a Superfluid.” ChemPhysChem, vol. 17, no. 22, Wiley-Blackwell,
2016, pp. 3649–54, doi:10.1002/cphc.201601042.
short: E. Redchenko, M. Lemeshko, ChemPhysChem 17 (2016) 3649–3654.
date_created: 2018-12-11T11:50:43Z
date_published: 2016-09-18T00:00:00Z
date_updated: 2021-01-12T06:49:05Z
day: '18'
department:
- _id: JoFi
- _id: MiLe
doi: 10.1002/cphc.201601042
ec_funded: 1
intvolume: ' 17'
issue: '22'
language:
- iso: eng
main_file_link:
- open_access: '1'
url: https://arxiv.org/abs/1609.08161
month: '09'
oa: 1
oa_version: Preprint
page: 3649 - 3654
project:
- _id: 2564DBCA-B435-11E9-9278-68D0E5697425
call_identifier: H2020
grant_number: '665385'
name: International IST Doctoral Program
publication: ChemPhysChem
publication_status: published
publisher: Wiley-Blackwell
publist_id: '6140'
quality_controlled: '1'
scopus_import: 1
status: public
title: Libration of strongly oriented polar molecules inside a superfluid
type: journal_article
user_id: 3E5EF7F0-F248-11E8-B48F-1D18A9856A87
volume: 17
year: '2016'
...
---
_id: '1209'
abstract:
- lang: eng
text: 'NADH-ubiquinone oxidoreductase (complex I) is the largest (∼1 MDa) and the
least characterized complex of the mitochondrial electron transport chain. Because
of the ease of sample availability, previous work has focused almost exclusively
on bovine complex I. However, only medium resolution structural analyses of this
complex have been reported. Working with other mammalian complex I homologues
is a potential approach for overcoming these limitations. Due to the inherent
difficulty of expressing large membrane protein complexes, screening of complex
I homologues is limited to large mammals reared for human consumption. The high
sequence identity among these available sources may preclude the benefits of screening.
Here, we report the characterization of complex I purified from Ovis aries (ovine)
heart mitochondria. All 44 unique subunits of the intact complex were identified
by mass spectrometry. We identified differences in the subunit composition of
subcomplexes of ovine complex I as compared with bovine, suggesting differential
stability of inter-subunit interactions within the complex. Furthermore, the 42-kDa
subunit, which is easily lost from the bovine enzyme, remains tightly bound to
ovine complex I. Additionally, we developed a novel purification protocol for
highly active and stable mitochondrial complex I using the branched-chain detergent
lauryl maltose neopentyl glycol. Our data demonstrate that, although closely related,
significant differences exist between the biochemical properties of complex I
prepared from ovine and bovine mitochondria and that ovine complex I represents
a suitable alternative target for further structural studies. '
acknowledgement: "J.A.S supported in part by a Medical Research D.G.Council UK Ph.D.
fellowship.\r\nThis work was supported in part by European Union's 2020 Research
and Innovation Program under Grant 701309. \r\n"
author:
- first_name: James A
full_name: Letts, James A
id: 322DA418-F248-11E8-B48F-1D18A9856A87
last_name: Letts
orcid: 0000-0002-9864-3586
- first_name: Gianluca
full_name: Degliesposti, Gianluca
last_name: Degliesposti
- first_name: Karol
full_name: Fiedorczuk, Karol
id: 5BFF67CE-02D1-11E9-B11A-A5A4D7DFFFD0
last_name: Fiedorczuk
- first_name: Mark
full_name: Skehel, Mark
last_name: Skehel
- first_name: Leonid A
full_name: Sazanov, Leonid A
id: 338D39FE-F248-11E8-B48F-1D18A9856A87
last_name: Sazanov
orcid: 0000-0002-0977-7989
citation:
ama: Letts JA, Degliesposti G, Fiedorczuk K, Skehel M, Sazanov LA. Purification
of ovine respiratory complex i results in a highly active and stable preparation.
Journal of Biological Chemistry. 2016;291(47):24657-24675. doi:10.1074/jbc.M116.735142
apa: Letts, J. A., Degliesposti, G., Fiedorczuk, K., Skehel, M., & Sazanov,
L. A. (2016). Purification of ovine respiratory complex i results in a highly
active and stable preparation. Journal of Biological Chemistry. American
Society for Biochemistry and Molecular Biology. https://doi.org/10.1074/jbc.M116.735142
chicago: Letts, James A, Gianluca Degliesposti, Karol Fiedorczuk, Mark Skehel, and
Leonid A Sazanov. “Purification of Ovine Respiratory Complex i Results in a Highly
Active and Stable Preparation.” Journal of Biological Chemistry. American
Society for Biochemistry and Molecular Biology, 2016. https://doi.org/10.1074/jbc.M116.735142.
ieee: J. A. Letts, G. Degliesposti, K. Fiedorczuk, M. Skehel, and L. A. Sazanov,
“Purification of ovine respiratory complex i results in a highly active and stable
preparation,” Journal of Biological Chemistry, vol. 291, no. 47. American
Society for Biochemistry and Molecular Biology, pp. 24657–24675, 2016.
ista: Letts JA, Degliesposti G, Fiedorczuk K, Skehel M, Sazanov LA. 2016. Purification
of ovine respiratory complex i results in a highly active and stable preparation.
Journal of Biological Chemistry. 291(47), 24657–24675.
mla: Letts, James A., et al. “Purification of Ovine Respiratory Complex i Results
in a Highly Active and Stable Preparation.” Journal of Biological Chemistry,
vol. 291, no. 47, American Society for Biochemistry and Molecular Biology, 2016,
pp. 24657–75, doi:10.1074/jbc.M116.735142.
short: J.A. Letts, G. Degliesposti, K. Fiedorczuk, M. Skehel, L.A. Sazanov, Journal
of Biological Chemistry 291 (2016) 24657–24675.
date_created: 2018-12-11T11:50:44Z
date_published: 2016-11-18T00:00:00Z
date_updated: 2021-01-12T06:49:06Z
day: '18'
department:
- _id: LeSa
doi: 10.1074/jbc.M116.735142
ec_funded: 1
intvolume: ' 291'
issue: '47'
language:
- iso: eng
main_file_link:
- open_access: '1'
url: https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5114416/
month: '11'
oa: 1
oa_version: Submitted Version
page: 24657 - 24675
project:
- _id: 2593EBD6-B435-11E9-9278-68D0E5697425
name: Atomic-Resolution Structures of Mitochondrial Respiratory Chain Supercomplexes
(FEBS)
- _id: 2590DB08-B435-11E9-9278-68D0E5697425
call_identifier: H2020
grant_number: '701309'
name: Atomic-Resolution Structures of Mitochondrial Respiratory Chain Supercomplexes
(H2020)
publication: Journal of Biological Chemistry
publication_status: published
publisher: American Society for Biochemistry and Molecular Biology
publist_id: '6139'
quality_controlled: '1'
scopus_import: 1
status: public
title: Purification of ovine respiratory complex i results in a highly active and
stable preparation
type: journal_article
user_id: 3E5EF7F0-F248-11E8-B48F-1D18A9856A87
volume: 291
year: '2016'
...
---
_id: '1210'
abstract:
- lang: eng
text: Mechanisms for cell protection are essential for survival of multicellular
organisms. In plants, the apical hook, which is transiently formed in darkness
when the germinating seedling penetrates towards the soil surface, plays such
protective role and shields the vitally important shoot apical meristem and cotyledons
from damage. The apical hook is formed by bending of the upper hypocotyl soon
after germination, and it is maintained in a closed stage while the hypocotyl
continues to penetrate through the soil and rapidly opens when exposed to light
in proximity of the soil surface. To uncover the complex molecular network orchestrating
this spatiotemporally tightly coordinated process, monitoring of the apical hook
development in real time is indispensable. Here we describe an imaging platform
that enables high-resolution kinetic analysis of this dynamic developmental process.
© Springer Science+Business Media New York 2017.
acknowledgement: "We thank Herman \r\nHöfte \r\n, Todor Asenov, Robert Hauschield,
and \r\nMarcal Gallemi for help with the establishment of the real-time
\ \r\nimaging platform and technical support. This work was supported \r\nby the
Czech Science Foundation (GA13-39982S) to Eva Benková. \r\nDominique Van Der
\ Straeten acknowledges the Research \r\nFoundation Flanders for fi\r\n
\ nancial support (G.0656.13N). Dajo \r\nSmet holds a PhD fellowship of the
Research Foundation Flanders. "
alternative_title:
- Methods in Molecular Biology
author:
- first_name: Qiang
full_name: Zhu, Qiang
id: 40A4B9E6-F248-11E8-B48F-1D18A9856A87
last_name: Zhu
- first_name: Petra
full_name: Žádníková, Petra
last_name: Žádníková
- first_name: Dajo
full_name: Smet, Dajo
last_name: Smet
- first_name: Dominique
full_name: Van Der Straeten, Dominique
last_name: Van Der Straeten
- first_name: Eva
full_name: Benková, Eva
id: 38F4F166-F248-11E8-B48F-1D18A9856A87
last_name: Benková
orcid: 0000-0002-8510-9739
citation:
ama: 'Zhu Q, Žádníková P, Smet D, Van Der Straeten D, Benková E. Real time analysis
of the apical hook development. In: Plant Hormones. Vol 1497. Humana Press;
2016:1-8. doi:10.1007/978-1-4939-6469-7_1'
apa: Zhu, Q., Žádníková, P., Smet, D., Van Der Straeten, D., & Benková, E. (2016).
Real time analysis of the apical hook development. In Plant Hormones (Vol.
1497, pp. 1–8). Humana Press. https://doi.org/10.1007/978-1-4939-6469-7_1
chicago: Zhu, Qiang, Petra Žádníková, Dajo Smet, Dominique Van Der Straeten, and
Eva Benková. “Real Time Analysis of the Apical Hook Development.” In Plant
Hormones, 1497:1–8. Humana Press, 2016. https://doi.org/10.1007/978-1-4939-6469-7_1.
ieee: Q. Zhu, P. Žádníková, D. Smet, D. Van Der Straeten, and E. Benková, “Real
time analysis of the apical hook development,” in Plant Hormones, vol.
1497, Humana Press, 2016, pp. 1–8.
ista: 'Zhu Q, Žádníková P, Smet D, Van Der Straeten D, Benková E. 2016.Real time
analysis of the apical hook development. In: Plant Hormones. Methods in Molecular
Biology, vol. 1497, 1–8.'
mla: Zhu, Qiang, et al. “Real Time Analysis of the Apical Hook Development.” Plant
Hormones, vol. 1497, Humana Press, 2016, pp. 1–8, doi:10.1007/978-1-4939-6469-7_1.
short: Q. Zhu, P. Žádníková, D. Smet, D. Van Der Straeten, E. Benková, in:, Plant
Hormones, Humana Press, 2016, pp. 1–8.
date_created: 2018-12-11T11:50:44Z
date_published: 2016-11-19T00:00:00Z
date_updated: 2021-01-12T06:49:07Z
day: '19'
department:
- _id: EvBe
doi: 10.1007/978-1-4939-6469-7_1
intvolume: ' 1497'
language:
- iso: eng
month: '11'
oa_version: None
page: 1 - 8
publication: Plant Hormones
publication_status: published
publisher: Humana Press
publist_id: '6135'
quality_controlled: '1'
scopus_import: 1
status: public
title: Real time analysis of the apical hook development
type: book_chapter
user_id: 3E5EF7F0-F248-11E8-B48F-1D18A9856A87
volume: 1497
year: '2016'
...
---
_id: '1212'
abstract:
- lang: eng
text: 'Plants adjust their growth according to gravity. Gravitropism involves gravity
perception, signal transduction, and asymmetric growth response, with organ bending
as a consequence [1]. Asymmetric growth results from the asymmetric distribution
of the plant-specific signaling molecule auxin [2] that is generated by lateral
transport, mediated in the hypocotyl predominantly by the auxin transporter PIN-FORMED3
(PIN3) [3–5]. Gravity stimulation polarizes PIN3 to the bottom sides of endodermal
cells, correlating with increased auxin accumulation in adjacent tissues at the
lower side of the stimulated organ, where auxin induces cell elongation and, hence,
organ bending. A curvature response allows the hypocotyl to resume straight growth
at a defined angle [6], implying that at some point auxin symmetry is restored
to prevent overbending. Here, we present initial insights into cellular and molecular
mechanisms that lead to the termination of the tropic response. We identified
an auxin feedback on PIN3 polarization as underlying mechanism that restores symmetry
of the PIN3-dependent auxin flow. Thus, two mechanistically distinct PIN3 polarization
events redirect auxin fluxes at different time points of the gravity response:
first, gravity-mediated redirection of PIN3-mediated auxin flow toward the lower
hypocotyl side, where auxin gradually accumulates and promotes growth, and later
PIN3 polarization to the opposite cell side, depleting this auxin maximum to end
the bending. Accordingly, genetic or pharmacological interference with the late
PIN3 polarization prevents termination of the response and leads to hypocotyl
overbending. This observation reveals a role of auxin feedback on PIN polarity
in the termination of the tropic response. © 2016 Elsevier Ltd'
acknowledgement: "We thank Dr. Jie Li (Key Laboratory of Plant Molecular Physiology,
Chinese Academy of Science, China) for the pPIN3::PIN3-GFP/DII::VENUS line and Martine
De Cock for help in preparing the manuscript. This work was supported by the European
Research Council (project ERC-2011-StG-20101109-PSDP), by the Czech Science Foundation
GAČR (GA13-40637S) to J.F., and by the Ministry of Education, Youth and Sports of
the Czech Republic under the project CEITEC 2020 (LQ1601) to H.S.R. H.R. is indebted
to the Agency for Innovation by Science and Technology (IWT) for a predoctoral fellowship.\r\n"
author:
- first_name: Hana
full_name: Rakusová, Hana
last_name: Rakusová
- first_name: Mohamad
full_name: Abbas, Mohamad
id: 47E8FC1C-F248-11E8-B48F-1D18A9856A87
last_name: Abbas
- first_name: Huibin
full_name: Han, Huibin
id: 31435098-F248-11E8-B48F-1D18A9856A87
last_name: Han
- first_name: Siyuan
full_name: Song, Siyuan
last_name: Song
- first_name: Hélène
full_name: Robert, Hélène
last_name: Robert
- first_name: Jirí
full_name: Friml, Jirí
id: 4159519E-F248-11E8-B48F-1D18A9856A87
last_name: Friml
orcid: 0000-0002-8302-7596
citation:
ama: Rakusová H, Abbas M, Han H, Song S, Robert H, Friml J. Termination of shoot
gravitropic responses by auxin feedback on PIN3 polarity. Current Biology.
2016;26(22):3026-3032. doi:10.1016/j.cub.2016.08.067
apa: Rakusová, H., Abbas, M., Han, H., Song, S., Robert, H., & Friml, J. (2016).
Termination of shoot gravitropic responses by auxin feedback on PIN3 polarity.
Current Biology. Cell Press. https://doi.org/10.1016/j.cub.2016.08.067
chicago: Rakusová, Hana, Mohamad Abbas, Huibin Han, Siyuan Song, Hélène Robert,
and Jiří Friml. “Termination of Shoot Gravitropic Responses by Auxin Feedback
on PIN3 Polarity.” Current Biology. Cell Press, 2016. https://doi.org/10.1016/j.cub.2016.08.067.
ieee: H. Rakusová, M. Abbas, H. Han, S. Song, H. Robert, and J. Friml, “Termination
of shoot gravitropic responses by auxin feedback on PIN3 polarity,” Current
Biology, vol. 26, no. 22. Cell Press, pp. 3026–3032, 2016.
ista: Rakusová H, Abbas M, Han H, Song S, Robert H, Friml J. 2016. Termination of
shoot gravitropic responses by auxin feedback on PIN3 polarity. Current Biology.
26(22), 3026–3032.
mla: Rakusová, Hana, et al. “Termination of Shoot Gravitropic Responses by Auxin
Feedback on PIN3 Polarity.” Current Biology, vol. 26, no. 22, Cell Press,
2016, pp. 3026–32, doi:10.1016/j.cub.2016.08.067.
short: H. Rakusová, M. Abbas, H. Han, S. Song, H. Robert, J. Friml, Current Biology
26 (2016) 3026–3032.
date_created: 2018-12-11T11:50:44Z
date_published: 2016-11-21T00:00:00Z
date_updated: 2021-01-12T06:49:08Z
day: '21'
ddc:
- '581'
department:
- _id: JiFr
doi: 10.1016/j.cub.2016.08.067
ec_funded: 1
file:
- access_level: open_access
checksum: 79ed2498185a027cf51a8f88100379e6
content_type: application/pdf
creator: system
date_created: 2018-12-12T10:09:33Z
date_updated: 2020-07-14T12:44:39Z
file_id: '4757'
file_name: IST-2018-1008-v1+1_Rakusova_CurrBiol_2016_proof.pdf
file_size: 5391923
relation: main_file
file_date_updated: 2020-07-14T12:44:39Z
has_accepted_license: '1'
intvolume: ' 26'
issue: '22'
language:
- iso: eng
month: '11'
oa: 1
oa_version: Submitted Version
page: 3026 - 3032
project:
- _id: 25716A02-B435-11E9-9278-68D0E5697425
call_identifier: FP7
grant_number: '282300'
name: Polarity and subcellular dynamics in plants
publication: Current Biology
publication_status: published
publisher: Cell Press
publist_id: '6138'
pubrep_id: '1008'
quality_controlled: '1'
scopus_import: 1
status: public
title: Termination of shoot gravitropic responses by auxin feedback on PIN3 polarity
type: journal_article
user_id: 3E5EF7F0-F248-11E8-B48F-1D18A9856A87
volume: 26
year: '2016'
...
---
_id: '1214'
abstract:
- lang: eng
text: 'With the accelerated development of robot technologies, optimal control becomes
one of the central themes of research. In traditional approaches, the controller,
by its internal functionality, finds appropriate actions on the basis of the history
of sensor values, guided by the goals, intentions, objectives, learning schemes,
and so forth. While very successful with classical robots, these methods run into
severe difficulties when applied to soft robots, a new field of robotics with
large interest for human-robot interaction. We claim that a novel controller paradigm
opens new perspective for this field. This paper applies a recently developed
neuro controller with differential extrinsic synaptic plasticity to a muscle-tendon
driven arm-shoulder system from the Myorobotics toolkit. In the experiments, we
observe a vast variety of self-organized behavior patterns: when left alone, the
arm realizes pseudo-random sequences of different poses. By applying physical
forces, the system can be entrained into definite motion patterns like wiping
a table. Most interestingly, after attaching an object, the controller gets in
a functional resonance with the object''s internal dynamics, starting to shake
spontaneously bottles half-filled with water or sensitively driving an attached
pendulum into a circular mode. When attached to the crank of a wheel the neural
system independently develops to rotate it. In this way, the robot discovers affordances
of objects its body is interacting with.'
acknowledgement: RD thanks for the hospitality at the Max-Planck-Institute and for
helpful discussions with Nihat Ay and Keyan Zahedi.
article_number: '7759138'
author:
- first_name: Georg S
full_name: Martius, Georg S
id: 3A276B68-F248-11E8-B48F-1D18A9856A87
last_name: Martius
- first_name: Raphael
full_name: Hostettler, Raphael
last_name: Hostettler
- first_name: Alois
full_name: Knoll, Alois
last_name: Knoll
- first_name: Ralf
full_name: Der, Ralf
last_name: Der
citation:
ama: 'Martius GS, Hostettler R, Knoll A, Der R. Compliant control for soft robots:
Emergent behavior of a tendon driven anthropomorphic arm. In: Vol 2016-November.
IEEE; 2016. doi:10.1109/IROS.2016.7759138'
apa: 'Martius, G. S., Hostettler, R., Knoll, A., & Der, R. (2016). Compliant
control for soft robots: Emergent behavior of a tendon driven anthropomorphic
arm (Vol. 2016–November). Presented at the IEEE RSJ International Conference on
Intelligent Robots and Systems IROS , Daejeon, Korea: IEEE. https://doi.org/10.1109/IROS.2016.7759138'
chicago: 'Martius, Georg S, Raphael Hostettler, Alois Knoll, and Ralf Der. “Compliant
Control for Soft Robots: Emergent Behavior of a Tendon Driven Anthropomorphic
Arm,” Vol. 2016–November. IEEE, 2016. https://doi.org/10.1109/IROS.2016.7759138.'
ieee: 'G. S. Martius, R. Hostettler, A. Knoll, and R. Der, “Compliant control for
soft robots: Emergent behavior of a tendon driven anthropomorphic arm,” presented
at the IEEE RSJ International Conference on Intelligent Robots and Systems IROS
, Daejeon, Korea, 2016, vol. 2016–November.'
ista: 'Martius GS, Hostettler R, Knoll A, Der R. 2016. Compliant control for soft
robots: Emergent behavior of a tendon driven anthropomorphic arm. IEEE RSJ International
Conference on Intelligent Robots and Systems IROS vol. 2016–November, 7759138.'
mla: 'Martius, Georg S., et al. Compliant Control for Soft Robots: Emergent Behavior
of a Tendon Driven Anthropomorphic Arm. Vol. 2016–November, 7759138, IEEE,
2016, doi:10.1109/IROS.2016.7759138.'
short: G.S. Martius, R. Hostettler, A. Knoll, R. Der, in:, IEEE, 2016.
conference:
end_date: 2016-09-14
location: Daejeon, Korea
name: 'IEEE RSJ International Conference on Intelligent Robots and Systems IROS '
start_date: 2016-09-09
date_created: 2018-12-11T11:50:45Z
date_published: 2016-11-28T00:00:00Z
date_updated: 2021-01-12T06:49:08Z
day: '28'
department:
- _id: ChLa
- _id: GaTk
doi: 10.1109/IROS.2016.7759138
language:
- iso: eng
month: '11'
oa_version: None
publication_status: published
publisher: IEEE
publist_id: '6121'
quality_controlled: '1'
scopus_import: 1
status: public
title: 'Compliant control for soft robots: Emergent behavior of a tendon driven anthropomorphic
arm'
type: conference
user_id: 3E5EF7F0-F248-11E8-B48F-1D18A9856A87
volume: 2016-November
year: '2016'
...
---
_id: '261'
abstract:
- lang: eng
text: Let G = SL(2, R) ⋉R2 and Γ = SL(2, Z) ⋉Z2. Building on recent work of Strömbergsson,
we prove a rate of equidistribution for the orbits of a certain one-dimensional
unipotent flow of Γ\G, which projects to a closed horocycle in the unit tangent
bundle to the modular surface. We use this to answer a question of Elkies and
McMullen by making effective the convergence of the gap distribution of √n mod
1.
acknowledgement: The research leading to these results has received funding from the
European Research Council under the European Union’s Seventh Framework Programme
(FP/2007–2013)/ERC Grant Agreements 291147 and 306457.
author:
- first_name: Timothy D
full_name: Timothy Browning
id: 35827D50-F248-11E8-B48F-1D18A9856A87
last_name: Browning
orcid: 0000-0002-8314-0177
- first_name: Ilya
full_name: Vinogradov, Ilya
last_name: Vinogradov
citation:
ama: Browning TD, Vinogradov I. Effective ratner theorem for SL (2, R) ⋉R2 and gaps
in √n modulo 1. Journal of the London Mathematical Society. 2016;94(1):61-84.
doi:10.1112/jlms/jdw025
apa: Browning, T. D., & Vinogradov, I. (2016). Effective ratner theorem for
SL (2, R) ⋉R2 and gaps in √n modulo 1. Journal of the London Mathematical Society.
John Wiley and Sons Ltd. https://doi.org/10.1112/jlms/jdw025
chicago: Browning, Timothy D, and Ilya Vinogradov. “Effective Ratner Theorem for
SL (2, R) ⋉R2 and Gaps in √n modulo 1.” Journal of the London Mathematical
Society. John Wiley and Sons Ltd, 2016. https://doi.org/10.1112/jlms/jdw025.
ieee: T. D. Browning and I. Vinogradov, “Effective ratner theorem for SL (2, R)
⋉R2 and gaps in √n modulo 1,” Journal of the London Mathematical Society,
vol. 94, no. 1. John Wiley and Sons Ltd, pp. 61–84, 2016.
ista: Browning TD, Vinogradov I. 2016. Effective ratner theorem for SL (2, R) ⋉R2
and gaps in √n modulo 1. Journal of the London Mathematical Society. 94(1), 61–84.
mla: Browning, Timothy D., and Ilya Vinogradov. “Effective Ratner Theorem for SL
(2, R) ⋉R2 and Gaps in √n modulo 1.” Journal of the London Mathematical Society,
vol. 94, no. 1, John Wiley and Sons Ltd, 2016, pp. 61–84, doi:10.1112/jlms/jdw025.
short: T.D. Browning, I. Vinogradov, Journal of the London Mathematical Society
94 (2016) 61–84.
date_created: 2018-12-11T11:45:29Z
date_published: 2016-05-24T00:00:00Z
date_updated: 2021-01-12T06:58:33Z
day: '24'
doi: 10.1112/jlms/jdw025
extern: 1
intvolume: ' 94'
issue: '1'
month: '05'
page: 61 - 84
publication: Journal of the London Mathematical Society
publication_status: published
publisher: John Wiley and Sons Ltd
publist_id: '7641'
quality_controlled: 0
status: public
title: Effective ratner theorem for SL (2, R) ⋉R2 and gaps in √n modulo 1
type: journal_article
volume: 94
year: '2016'
...
---
_id: '262'
abstract:
- lang: eng
text: For any number field we calculate the exact proportion of rational numbers
which are everywhere locally a norm but not globally a norm from the number field.
acknowledgement: While working on this paper the first author was supported by ERC
grant 306457.
author:
- first_name: Timothy D
full_name: Timothy Browning
id: 35827D50-F248-11E8-B48F-1D18A9856A87
last_name: Browning
orcid: 0000-0002-8314-0177
- first_name: Rachel
full_name: Newton, Rachel
last_name: Newton
citation:
ama: Browning TD, Newton R. The proportion of failures of the Hasse norm principle.
Mathematika. 2016;62(2):337-347. doi:10.1112/S0025579315000261
apa: Browning, T. D., & Newton, R. (2016). The proportion of failures of the
Hasse norm principle. Mathematika. Cambridge University Press. https://doi.org/10.1112/S0025579315000261
chicago: Browning, Timothy D, and Rachel Newton. “The Proportion of Failures of
the Hasse Norm Principle.” Mathematika. Cambridge University Press, 2016.
https://doi.org/10.1112/S0025579315000261.
ieee: T. D. Browning and R. Newton, “The proportion of failures of the Hasse norm
principle,” Mathematika, vol. 62, no. 2. Cambridge University Press, pp.
337–347, 2016.
ista: Browning TD, Newton R. 2016. The proportion of failures of the Hasse norm
principle. Mathematika. 62(2), 337–347.
mla: Browning, Timothy D., and Rachel Newton. “The Proportion of Failures of the
Hasse Norm Principle.” Mathematika, vol. 62, no. 2, Cambridge University
Press, 2016, pp. 337–47, doi:10.1112/S0025579315000261.
short: T.D. Browning, R. Newton, Mathematika 62 (2016) 337–347.
date_created: 2018-12-11T11:45:29Z
date_published: 2016-01-22T00:00:00Z
date_updated: 2021-01-12T06:58:37Z
day: '22'
doi: 10.1112/S0025579315000261
extern: 1
intvolume: ' 62'
issue: '2'
main_file_link:
- open_access: '1'
url: https://arxiv.org/abs/1411.7775
month: '01'
oa: 1
page: 337 - 347
publication: Mathematika
publication_status: published
publisher: Cambridge University Press
publist_id: '7640'
quality_controlled: 0
status: public
title: The proportion of failures of the Hasse norm principle
type: journal_article
volume: 62
year: '2016'
...
---
_id: '263'
abstract:
- lang: eng
text: We count rational points of bounded height on the Cayley ruled cubic surface
and interpret the result in the context of general conjectures due to Batyrev
and Tschinkel.
acknowledgement: 'While working on this paper the first author was supported by an
IUF Junior and the second author was supported by ERC grant 306457. '
author:
- first_name: Régis
full_name: de la Bretèche, Régis
last_name: De La Bretèche
- first_name: Timothy D
full_name: Timothy Browning
id: 35827D50-F248-11E8-B48F-1D18A9856A87
last_name: Browning
orcid: 0000-0002-8314-0177
- first_name: Per
full_name: Salberger, Per
last_name: Salberger
citation:
ama: De La Bretèche R, Browning TD, Salberger P. Counting rational points on the
Cayley ruled cubic. European Journal of Mathematics. 2016;2(1):55-72. doi:10.1007/s40879-015-0049-1
apa: De La Bretèche, R., Browning, T. D., & Salberger, P. (2016). Counting rational
points on the Cayley ruled cubic. European Journal of Mathematics. Springer
Nature. https://doi.org/10.1007/s40879-015-0049-1
chicago: De La Bretèche, Régis, Timothy D Browning, and Per Salberger. “Counting
Rational Points on the Cayley Ruled Cubic.” European Journal of Mathematics.
Springer Nature, 2016. https://doi.org/10.1007/s40879-015-0049-1.
ieee: R. De La Bretèche, T. D. Browning, and P. Salberger, “Counting rational points
on the Cayley ruled cubic,” European Journal of Mathematics, vol. 2, no.
1. Springer Nature, pp. 55–72, 2016.
ista: De La Bretèche R, Browning TD, Salberger P. 2016. Counting rational points
on the Cayley ruled cubic. European Journal of Mathematics. 2(1), 55–72.
mla: De La Bretèche, Régis, et al. “Counting Rational Points on the Cayley Ruled
Cubic.” European Journal of Mathematics, vol. 2, no. 1, Springer Nature,
2016, pp. 55–72, doi:10.1007/s40879-015-0049-1.
short: R. De La Bretèche, T.D. Browning, P. Salberger, European Journal of Mathematics
2 (2016) 55–72.
date_created: 2018-12-11T11:45:30Z
date_published: 2016-03-01T00:00:00Z
date_updated: 2021-01-12T06:58:41Z
day: '01'
doi: 10.1007/s40879-015-0049-1
extern: 1
intvolume: ' 2'
issue: '1'
main_file_link:
- open_access: '1'
url: https://arxiv.org/abs/1410.3855
month: '03'
oa: 1
page: 55 - 72
publication: European Journal of Mathematics
publication_status: published
publisher: Springer Nature
publist_id: '7639'
quality_controlled: 0
status: public
title: Counting rational points on the Cayley ruled cubic
type: journal_article
volume: 2
year: '2016'
...
---
_id: '264'
abstract:
- lang: eng
text: Given a family of varieties over a number field, we determine conditions under
which there is a Brauer-Manin obstruction to weak approximation for 100% of the
fibres which are everywhere locally soluble.
acknowledgement: While working on this paper the second author was supported by ERC
grant 306457.
author:
- first_name: Maritn
full_name: Bright, Maritn J
last_name: Bright
- first_name: Timothy D
full_name: Timothy Browning
id: 35827D50-F248-11E8-B48F-1D18A9856A87
last_name: Browning
orcid: 0000-0002-8314-0177
- first_name: Daniel
full_name: Loughran, Daniel
last_name: Loughran
citation:
ama: Bright M, Browning TD, Loughran D. Failures of weak approximation in families.
Compositio Mathematica. 2016;152(7):1435-1475. doi:10.1112/S0010437X16007405
apa: Bright, M., Browning, T. D., & Loughran, D. (2016). Failures of weak approximation
in families. Compositio Mathematica. Cambridge University Press. https://doi.org/10.1112/S0010437X16007405
chicago: Bright, Maritn, Timothy D Browning, and Daniel Loughran. “Failures of Weak
Approximation in Families.” Compositio Mathematica. Cambridge University
Press, 2016. https://doi.org/10.1112/S0010437X16007405.
ieee: M. Bright, T. D. Browning, and D. Loughran, “Failures of weak approximation
in families,” Compositio Mathematica, vol. 152, no. 7. Cambridge University
Press, pp. 1435–1475, 2016.
ista: Bright M, Browning TD, Loughran D. 2016. Failures of weak approximation in
families. Compositio Mathematica. 152(7), 1435–1475.
mla: Bright, Maritn, et al. “Failures of Weak Approximation in Families.” Compositio
Mathematica, vol. 152, no. 7, Cambridge University Press, 2016, pp. 1435–75,
doi:10.1112/S0010437X16007405.
short: M. Bright, T.D. Browning, D. Loughran, Compositio Mathematica 152 (2016)
1435–1475.
date_created: 2018-12-11T11:45:30Z
date_published: 2016-07-01T00:00:00Z
date_updated: 2021-01-12T06:58:45Z
day: '01'
doi: 10.1112/S0010437X16007405
extern: 1
intvolume: ' 152'
issue: '7'
main_file_link:
- open_access: '1'
url: https://arxiv.org/abs/1506.01817
month: '07'
oa: 1
page: 1435 - 1475
publication: Compositio Mathematica
publication_status: published
publisher: Cambridge University Press
publist_id: '7638'
quality_controlled: 0
status: public
title: Failures of weak approximation in families
type: journal_article
volume: 152
year: '2016'
...
---
_id: '363'
abstract:
- lang: eng
text: Lead halide perovskite materials have attracted significant attention in the
context of photovoltaics and other optoelectronic applications, and recently,
research efforts have been directed to nanostructured lead halide perovskites.
Collodial nanocrystals (NCs) of cesium lead halides (CsPbX3, X = Cl, Br, I) exhibit
bright photoluminescence, with emission tunable over the entire visible spectral
region. However, previous studies on CsPbX3 NCs did not address key aspects of
their chemistry and photophysics such as surface chemistry and quantitative light
absorption. Here, we elaborate on the synthesis of CsPbBr3 NCs and their surface
chemistry. In addition, the intrinsic absorption coefficient was determined experimentally
by combining elemental analysis with accurate optical absorption measurements.
1H solution nuclear magnetic resonance spectroscopy was used to characterize sample
purity, elucidate the surface chemistry, and evaluate the influence of purification
methods on the surface composition. We find that ligand binding to the NC surface
is highly dynamic, and therefore, ligands are easily lost during the isolation
and purification procedures. However, when a small amount of both oleic acid and
oleylamine is added, the NCs can be purified, maintaining optical, colloidal,
and material integrity. In addition, we find that a high amine content in the
ligand shell increases the quantum yield due to the improved binding of the carboxylic
acid.
article_processing_charge: No
author:
- first_name: Jonathan
full_name: De Roo, Jonathan
last_name: De Roo
- first_name: Maria
full_name: Ibáñez, Maria
id: 43C61214-F248-11E8-B48F-1D18A9856A87
last_name: Ibáñez
orcid: 0000-0001-5013-2843
- first_name: Pieter
full_name: Geiregat, Pieter
last_name: Geiregat
- first_name: Georgian
full_name: Nedelcu, Georgian
last_name: Nedelcu
- first_name: Willem
full_name: Walravens, Willem
last_name: Walravens
- first_name: Jorick
full_name: Maes, Jorick
last_name: Maes
- first_name: Jose
full_name: Martins, Jose
last_name: Martins
- first_name: Isabel
full_name: Van Driessche, Isabel
last_name: Van Driessche
- first_name: Maksym
full_name: Kovalenko, Maksym
last_name: Kovalenko
- first_name: Zeger
full_name: Hens, Zeger
last_name: Hens
citation:
ama: De Roo J, Ibáñez M, Geiregat P, et al. Highly dynamic ligand binding and light
absorption coefficient of cesium lead bromide perovskite nanocrystals. ACS
Nano. 2016;10(2):2071-2081. doi:10.1021/acsnano.5b06295
apa: De Roo, J., Ibáñez, M., Geiregat, P., Nedelcu, G., Walravens, W., Maes, J.,
… Hens, Z. (2016). Highly dynamic ligand binding and light absorption coefficient
of cesium lead bromide perovskite nanocrystals. ACS Nano. American Chemical
Society. https://doi.org/10.1021/acsnano.5b06295
chicago: De Roo, Jonathan, Maria Ibáñez, Pieter Geiregat, Georgian Nedelcu, Willem
Walravens, Jorick Maes, Jose Martins, Isabel Van Driessche, Maksym Kovalenko,
and Zeger Hens. “Highly Dynamic Ligand Binding and Light Absorption Coefficient
of Cesium Lead Bromide Perovskite Nanocrystals.” ACS Nano. American Chemical
Society, 2016. https://doi.org/10.1021/acsnano.5b06295.
ieee: J. De Roo et al., “Highly dynamic ligand binding and light absorption
coefficient of cesium lead bromide perovskite nanocrystals,” ACS Nano,
vol. 10, no. 2. American Chemical Society, pp. 2071–2081, 2016.
ista: De Roo J, Ibáñez M, Geiregat P, Nedelcu G, Walravens W, Maes J, Martins J,
Van Driessche I, Kovalenko M, Hens Z. 2016. Highly dynamic ligand binding and
light absorption coefficient of cesium lead bromide perovskite nanocrystals. ACS
Nano. 10(2), 2071–2081.
mla: De Roo, Jonathan, et al. “Highly Dynamic Ligand Binding and Light Absorption
Coefficient of Cesium Lead Bromide Perovskite Nanocrystals.” ACS Nano,
vol. 10, no. 2, American Chemical Society, 2016, pp. 2071–81, doi:10.1021/acsnano.5b06295.
short: J. De Roo, M. Ibáñez, P. Geiregat, G. Nedelcu, W. Walravens, J. Maes, J.
Martins, I. Van Driessche, M. Kovalenko, Z. Hens, ACS Nano 10 (2016) 2071–2081.
date_created: 2018-12-11T11:46:02Z
date_published: 2016-02-23T00:00:00Z
date_updated: 2021-01-12T07:44:46Z
day: '23'
doi: 10.1021/acsnano.5b06295
extern: '1'
intvolume: ' 10'
issue: '2'
language:
- iso: eng
month: '02'
oa_version: None
page: 2071 - 2081
publication: ACS Nano
publication_status: published
publisher: American Chemical Society
publist_id: '7464'
status: public
title: Highly dynamic ligand binding and light absorption coefficient of cesium lead
bromide perovskite nanocrystals
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 10
year: '2016'
...
---
_id: '364'
abstract:
- lang: eng
text: The development of highly active, low cost and stable electrocatalysts for
direct alcohol fuel cells remains a critical challenge. While Pd2Sn has been reported
as an excellent catalyst for the ethanol oxidation reaction (EOR), here we present
DFT analysis results showing the (100) and (001) facets of orthorhombic Pd2Sn
to be more favourable for the EOR than (010). Accordingly, using tri-n-octylphosphine,
oleylamine (OLA) and methylamine hydrochloride as size and shape directing agents,
we produced colloidal Pd2Sn nanorods (NRs) grown in the [010] direction. Such
Pd2Sn NRs, supported on graphitic carbon, showed excellent performance and stability
as an anode electrocatalyst for the EOR in alkaline media, exhibiting 3 times
and 10 times higher EOR current densities than that of Pd2Sn and Pd nanospheres,
respectively. We associate this improved performance with the favourable faceting
of the NRs.
author:
- first_name: Zhishan
full_name: Luo, Zhishan
last_name: Luo
- first_name: Jianmin
full_name: Lu, Jianmin
last_name: Lu
- first_name: Cristina
full_name: Flox, Cristina
last_name: Flox
- first_name: Raquel
full_name: Nafria, Raquel
last_name: Nafria
- first_name: Aziz
full_name: Genç, Aziz
last_name: Genç
- first_name: Jordi
full_name: Arbiol, Jordi
last_name: Arbiol
- first_name: Jordi
full_name: Llorca, Jordi
last_name: Llorca
- first_name: Maria
full_name: Ibanez Sabate, Maria
id: 43C61214-F248-11E8-B48F-1D18A9856A87
last_name: Ibanez Sabate
orcid: 0000-0001-5013-2843
- first_name: Joan
full_name: Morante, Joan
last_name: Morante
- first_name: Andreu
full_name: Cabot, Andreu
last_name: Cabot
citation:
ama: Luo Z, Lu J, Flox C, et al. Pd2Sn [010] nanorods as a highly active and stable
ethanol oxidation catalyst. Journal of Materials Chemistry A. 2016;4(42):16706-16713.
doi:10.1039/c6ta06430b
apa: Luo, Z., Lu, J., Flox, C., Nafria, R., Genç, A., Arbiol, J., … Cabot, A. (2016).
Pd2Sn [010] nanorods as a highly active and stable ethanol oxidation catalyst.
Journal of Materials Chemistry A. Royal Society of Chemistry. https://doi.org/10.1039/c6ta06430b
chicago: Luo, Zhishan, Jianmin Lu, Cristina Flox, Raquel Nafria, Aziz Genç, Jordi
Arbiol, Jordi Llorca, Maria Ibáñez, Joan Morante, and Andreu Cabot. “Pd2Sn [010]
Nanorods as a Highly Active and Stable Ethanol Oxidation Catalyst.” Journal
of Materials Chemistry A. Royal Society of Chemistry, 2016. https://doi.org/10.1039/c6ta06430b.
ieee: Z. Luo et al., “Pd2Sn [010] nanorods as a highly active and stable
ethanol oxidation catalyst,” Journal of Materials Chemistry A, vol. 4,
no. 42. Royal Society of Chemistry, pp. 16706–16713, 2016.
ista: Luo Z, Lu J, Flox C, Nafria R, Genç A, Arbiol J, Llorca J, Ibáñez M, Morante
J, Cabot A. 2016. Pd2Sn [010] nanorods as a highly active and stable ethanol oxidation
catalyst. Journal of Materials Chemistry A. 4(42), 16706–16713.
mla: Luo, Zhishan, et al. “Pd2Sn [010] Nanorods as a Highly Active and Stable Ethanol
Oxidation Catalyst.” Journal of Materials Chemistry A, vol. 4, no. 42,
Royal Society of Chemistry, 2016, pp. 16706–13, doi:10.1039/c6ta06430b.
short: Z. Luo, J. Lu, C. Flox, R. Nafria, A. Genç, J. Arbiol, J. Llorca, M. Ibáñez,
J. Morante, A. Cabot, Journal of Materials Chemistry A 4 (2016) 16706–16713.
date_created: 2018-12-11T11:46:02Z
date_published: 2016-10-05T00:00:00Z
date_updated: 2021-01-12T07:44:50Z
day: '05'
doi: 10.1039/c6ta06430b
extern: '1'
intvolume: ' 4'
issue: '42'
language:
- iso: eng
month: '10'
oa_version: None
page: 16706 - 16713
publication: Journal of Materials Chemistry A
publication_status: published
publisher: Royal Society of Chemistry
publist_id: '7465'
status: public
title: Pd2Sn [010] nanorods as a highly active and stable ethanol oxidation catalyst
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 4
year: '2016'
...
---
_id: '366'
abstract:
- lang: eng
text: Cesium lead halide (CsPbX3, X = Cl, Br, I) nanocrystals (NCs) offer exceptional
optical properties for several potential applications but their implementation
is hindered by a low chemical and structural stability and limited processability.
In the present work, we developed a new method to efficiently coat CsPbX3 NCs,
which resulted in their increased chemical and optical stability as well as processability.
The method is based on the incorporation of poly(maleic anhydride-alt-1-octadecene)
(PMA) into the synthesis of the perovskite NCs. The presence of PMA in the ligand
shell stabilizes the NCs by tightening the ligand binding, limiting in this way
the NC surface interaction with the surrounding media. We further show that these
NCs can be embedded in self-standing silicone/glass plates as down-conversion
filters for the fabrication of monochromatic green and white light emitting diodes
(LEDs) with narrow bandwidths and appealing color characteristics.
acknowledgement: This work was supported by the European Regional Development Funds,
the Framework 7 program under project UNION (FP7-NMP-2012-310250) and HI-LED (FP7-ICT-2013-11-
619912), as well as the Spanish MINECO Projects BOOSTER (ENE2013-46624-C4-3-R) and
AMALIE (TEC2012-38901- C02-01). M.M. thanks the Spanish MINECO for financial support
through the Juan de la Cierva-formacion program. A.G. and J.A. acknowledge funding
from Generalitat de Catalunya 2014 SGR 1638 and the Spanish MINECO MAT2014-51480-
ERC (e-ATOM) and Severo Ochoa Excellence Program. We would like to thank Pablo Guardia
for fruitful discussions.
author:
- first_name: Michaela
full_name: Meyn, Michaela
last_name: Meyn
- first_name: Mariano
full_name: Perálvarez, Mariano
last_name: Perálvarez
- first_name: Amelie
full_name: Heuer Jungemann, Amelie
last_name: Heuer Jungemann
- first_name: Wim
full_name: Hertog, Wim
last_name: Hertog
- first_name: Maria
full_name: Ibanez Sabate, Maria
id: 43C61214-F248-11E8-B48F-1D18A9856A87
last_name: Ibanez Sabate
orcid: 0000-0001-5013-2843
- first_name: Raquel
full_name: Nafria, Raquel
last_name: Nafria
- first_name: Aziz
full_name: Genç, Aziz
last_name: Genç
- first_name: Jordi
full_name: Arbiol, Jordi
last_name: Arbiol
- first_name: Maksym
full_name: Kovalenko, Maksym
last_name: Kovalenko
- first_name: Josep
full_name: Carreras, Josep
last_name: Carreras
- first_name: Andreu
full_name: Cabot, Andreu
last_name: Cabot
- first_name: Antonios
full_name: Kanaras, Antonios
last_name: Kanaras
citation:
ama: Meyn M, Perálvarez M, Heuer Jungemann A, et al. Polymer enhanced stability
of inorganic perovskite nanocrystals and their application in color conversion
LEDs. ACS Applied Materials and Interfaces. 2016;8(30):19579-19586. doi:10.1021/acsami.6b02529
apa: Meyn, M., Perálvarez, M., Heuer Jungemann, A., Hertog, W., Ibáñez, M., Nafria,
R., … Kanaras, A. (2016). Polymer enhanced stability of inorganic perovskite nanocrystals
and their application in color conversion LEDs. ACS Applied Materials and Interfaces.
American Chemical Society. https://doi.org/10.1021/acsami.6b02529
chicago: Meyn, Michaela, Mariano Perálvarez, Amelie Heuer Jungemann, Wim Hertog,
Maria Ibáñez, Raquel Nafria, Aziz Genç, et al. “Polymer Enhanced Stability of
Inorganic Perovskite Nanocrystals and Their Application in Color Conversion LEDs.”
ACS Applied Materials and Interfaces. American Chemical Society, 2016.
https://doi.org/10.1021/acsami.6b02529.
ieee: M. Meyn et al., “Polymer enhanced stability of inorganic perovskite
nanocrystals and their application in color conversion LEDs,” ACS Applied Materials
and Interfaces, vol. 8, no. 30. American Chemical Society, pp. 19579–19586,
2016.
ista: Meyn M, Perálvarez M, Heuer Jungemann A, Hertog W, Ibáñez M, Nafria R, Genç
A, Arbiol J, Kovalenko M, Carreras J, Cabot A, Kanaras A. 2016. Polymer enhanced
stability of inorganic perovskite nanocrystals and their application in color
conversion LEDs. ACS Applied Materials and Interfaces. 8(30), 19579–19586.
mla: Meyn, Michaela, et al. “Polymer Enhanced Stability of Inorganic Perovskite
Nanocrystals and Their Application in Color Conversion LEDs.” ACS Applied Materials
and Interfaces, vol. 8, no. 30, American Chemical Society, 2016, pp. 19579–86,
doi:10.1021/acsami.6b02529.
short: M. Meyn, M. Perálvarez, A. Heuer Jungemann, W. Hertog, M. Ibáñez, R. Nafria,
A. Genç, J. Arbiol, M. Kovalenko, J. Carreras, A. Cabot, A. Kanaras, ACS Applied
Materials and Interfaces 8 (2016) 19579–19586.
date_created: 2018-12-11T11:46:03Z
date_published: 2016-07-25T00:00:00Z
date_updated: 2021-01-12T07:44:58Z
day: '25'
doi: 10.1021/acsami.6b02529
extern: '1'
intvolume: ' 8'
issue: '30'
language:
- iso: eng
main_file_link:
- open_access: '1'
url: https://eprints.soton.ac.uk/398581/
month: '07'
oa: 1
oa_version: None
page: 19579 - 19586
publication: ACS Applied Materials and Interfaces
publication_status: published
publisher: American Chemical Society
publist_id: '7460'
status: public
title: Polymer enhanced stability of inorganic perovskite nanocrystals and their application
in color conversion LEDs
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 8
year: '2016'
...