[{"degree_awarded":"PhD","status":"public","project":[{"_id":"2564DBCA-B435-11E9-9278-68D0E5697425","call_identifier":"H2020","name":"International IST Doctoral Program","grant_number":"665385"}],"ec_funded":1,"date_published":"2023-04-28T00:00:00Z","year":"2023","related_material":{"record":[{"status":"public","relation":"part_of_dissertation","id":"10806"},{"id":"10042","status":"public","relation":"part_of_dissertation"},{"id":"12237","status":"public","relation":"part_of_dissertation"},{"id":"9118","status":"public","relation":"part_of_dissertation"},{"relation":"part_of_dissertation","status":"public","id":"10123"}]},"page":"82","ddc":["546","541"],"alternative_title":["ISTA Thesis"],"article_processing_charge":"No","doi":"10.15479/at:ista:12885","publisher":"Institute of Science and Technology Austria","_id":"12885","date_updated":"2023-08-14T07:25:26Z","type":"dissertation","oa":1,"language":[{"iso":"eng"}],"citation":{"mla":"Calcabrini, Mariano. <i>Nanoparticle-Based Semiconductor Solids: From Synthesis to Consolidation</i>. Institute of Science and Technology Austria, 2023, doi:<a href=\"https://doi.org/10.15479/at:ista:12885\">10.15479/at:ista:12885</a>.","apa":"Calcabrini, M. (2023). <i>Nanoparticle-based semiconductor solids: From synthesis to consolidation</i>. Institute of Science and Technology Austria. <a href=\"https://doi.org/10.15479/at:ista:12885\">https://doi.org/10.15479/at:ista:12885</a>","chicago":"Calcabrini, Mariano. “Nanoparticle-Based Semiconductor Solids: From Synthesis to Consolidation.” Institute of Science and Technology Austria, 2023. <a href=\"https://doi.org/10.15479/at:ista:12885\">https://doi.org/10.15479/at:ista:12885</a>.","ista":"Calcabrini M. 2023. Nanoparticle-based semiconductor solids: From synthesis to consolidation. Institute of Science and Technology Austria.","short":"M. Calcabrini, Nanoparticle-Based Semiconductor Solids: From Synthesis to Consolidation, Institute of Science and Technology Austria, 2023.","ieee":"M. Calcabrini, “Nanoparticle-based semiconductor solids: From synthesis to consolidation,” Institute of Science and Technology Austria, 2023.","ama":"Calcabrini M. Nanoparticle-based semiconductor solids: From synthesis to consolidation. 2023. doi:<a href=\"https://doi.org/10.15479/at:ista:12885\">10.15479/at:ista:12885</a>"},"user_id":"8b945eb4-e2f2-11eb-945a-df72226e66a9","supervisor":[{"full_name":"Ibáñez, Maria","id":"43C61214-F248-11E8-B48F-1D18A9856A87","last_name":"Ibáñez","orcid":"0000-0001-5013-2843","first_name":"Maria"}],"month":"04","department":[{"_id":"GradSch"},{"_id":"MaIb"}],"file":[{"file_size":99627036,"date_created":"2023-05-02T07:43:18Z","date_updated":"2023-05-02T07:43:18Z","creator":"mcalcabr","file_id":"12887","file_name":"Thesis_Calcabrini.docx","access_level":"closed","content_type":"application/vnd.openxmlformats-officedocument.wordprocessingml.document","relation":"source_file","checksum":"9347b0e09425f56fdcede5d3528404dc"},{"file_id":"12888","date_updated":"2023-05-02T07:42:45Z","creator":"mcalcabr","file_size":8742220,"date_created":"2023-05-02T07:42:45Z","checksum":"2d188b76621086cd384f0b9264b0a576","relation":"main_file","content_type":"application/pdf","access_level":"open_access","file_name":"Thesis_Calcabrini_pdfa.pdf","success":1}],"has_accepted_license":"1","acknowledged_ssus":[{"_id":"EM-Fac"},{"_id":"NanoFab"}],"abstract":[{"lang":"eng","text":"High-performance semiconductors rely upon precise control of heat and charge transport. This can be achieved by precisely engineering defects in polycrystalline solids. There are multiple approaches to preparing such polycrystalline semiconductors, and the transformation of solution-processed colloidal nanoparticles is appealing because colloidal nanoparticles combine low cost with structural and compositional tunability along with rich surface chemistry. However, the multiple processes from nanoparticle synthesis to the final bulk nanocomposites are very complex. They involve nanoparticle purification, post-synthetic modifications, and finally consolidation (thermal treatments and densification). All these properties dictate the final material’s composition and microstructure, ultimately affecting its functional properties. This thesis explores the synthesis, surface chemistry and consolidation of colloidal semiconductor nanoparticles into dense solids. In particular, the transformations that take place during these processes, and their effect on the material’s transport properties are evaluated. "}],"file_date_updated":"2023-05-02T07:43:18Z","publication_status":"published","publication_identifier":{"issn":["2663-337X"],"isbn":["978-3-99078-028-2"]},"day":"28","author":[{"id":"45D7531A-F248-11E8-B48F-1D18A9856A87","full_name":"Calcabrini, Mariano","last_name":"Calcabrini","orcid":"0000-0003-4566-5877","first_name":"Mariano"}],"title":"Nanoparticle-based semiconductor solids: From synthesis to consolidation","oa_version":"Published Version","date_created":"2023-05-02T07:58:57Z"},{"language":[{"iso":"eng"}],"oa":1,"user_id":"4359f0d1-fa6c-11eb-b949-802e58b17ae8","issue":"1","citation":{"ama":"Liu Y, Calcabrini M, Yu Y, et al. Defect engineering in solution-processed polycrystalline SnSe leads to high thermoelectric performance. <i>ACS Nano</i>. 2022;16(1):78-88. doi:<a href=\"https://doi.org/10.1021/acsnano.1c06720\">10.1021/acsnano.1c06720</a>","short":"Y. Liu, M. Calcabrini, Y. Yu, S. Lee, C. Chang, J. David, T. Ghosh, M.C. Spadaro, C. Xie, O. Cojocaru-Mirédin, J. Arbiol, M. Ibáñez, ACS Nano 16 (2022) 78–88.","ieee":"Y. Liu <i>et al.</i>, “Defect engineering in solution-processed polycrystalline SnSe leads to high thermoelectric performance,” <i>ACS Nano</i>, vol. 16, no. 1. American Chemical Society , pp. 78–88, 2022.","chicago":"Liu, Yu, Mariano Calcabrini, Yuan Yu, Seungho Lee, Cheng Chang, Jérémy David, Tanmoy Ghosh, et al. “Defect Engineering in Solution-Processed Polycrystalline SnSe Leads to High Thermoelectric Performance.” <i>ACS Nano</i>. American Chemical Society , 2022. <a href=\"https://doi.org/10.1021/acsnano.1c06720\">https://doi.org/10.1021/acsnano.1c06720</a>.","ista":"Liu Y, Calcabrini M, Yu Y, Lee S, Chang C, David J, Ghosh T, Spadaro MC, Xie C, Cojocaru-Mirédin O, Arbiol J, Ibáñez M. 2022. Defect engineering in solution-processed polycrystalline SnSe leads to high thermoelectric performance. ACS Nano. 16(1), 78–88.","mla":"Liu, Yu, et al. “Defect Engineering in Solution-Processed Polycrystalline SnSe Leads to High Thermoelectric Performance.” <i>ACS Nano</i>, vol. 16, no. 1, American Chemical Society , 2022, pp. 78–88, doi:<a href=\"https://doi.org/10.1021/acsnano.1c06720\">10.1021/acsnano.1c06720</a>.","apa":"Liu, Y., Calcabrini, M., Yu, Y., Lee, S., Chang, C., David, J., … Ibáñez, M. (2022). Defect engineering in solution-processed polycrystalline SnSe leads to high thermoelectric performance. <i>ACS Nano</i>. American Chemical Society . <a href=\"https://doi.org/10.1021/acsnano.1c06720\">https://doi.org/10.1021/acsnano.1c06720</a>"},"month":"01","file":[{"file_id":"10808","date_created":"2022-03-02T16:17:29Z","file_size":9050764,"creator":"cchlebak","date_updated":"2022-03-02T16:17:29Z","relation":"main_file","checksum":"74f9c1aa5f95c0b992a4328e8e0247b4","success":1,"file_name":"2022_ACSNano_Liu.pdf","access_level":"open_access","content_type":"application/pdf"}],"department":[{"_id":"MaIb"}],"tmp":{"name":"Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)","legal_code_url":"https://creativecommons.org/licenses/by/4.0/legalcode","image":"/images/cc_by.png","short":"CC BY (4.0)"},"abstract":[{"lang":"eng","text":"SnSe has emerged as one of the most promising materials for thermoelectric energy conversion due to its extraordinary performance in its single-crystal form and its low-cost constituent elements. However, to achieve an economic impact, the polycrystalline counterpart needs to replicate the performance of the single crystal. Herein, we optimize the thermoelectric performance of polycrystalline SnSe produced by consolidating solution-processed and surface-engineered SnSe particles. In particular, the SnSe particles are coated with CdSe molecular complexes that crystallize during the sintering process, forming CdSe nanoparticles. The presence of CdSe nanoparticles inhibits SnSe grain growth during the consolidation step due to Zener pinning, yielding a material with a high density of grain boundaries. Moreover, the resulting SnSe–CdSe nanocomposites present a large number of defects at different length scales, which significantly reduce the thermal conductivity. The produced SnSe–CdSe nanocomposites exhibit thermoelectric figures of merit up to 2.2 at 786 K, which is among the highest reported for solution-processed SnSe."}],"intvolume":"        16","has_accepted_license":"1","publication_status":"published","publication_identifier":{"eissn":["1936-086X"],"issn":["1936-0851"]},"file_date_updated":"2022-03-02T16:17:29Z","oa_version":"Published Version","title":"Defect engineering in solution-processed polycrystalline SnSe leads to high thermoelectric performance","author":[{"full_name":"Liu, Yu","id":"2A70014E-F248-11E8-B48F-1D18A9856A87","last_name":"Liu","orcid":"0000-0001-7313-6740","first_name":"Yu"},{"first_name":"Mariano","last_name":"Calcabrini","full_name":"Calcabrini, Mariano","id":"45D7531A-F248-11E8-B48F-1D18A9856A87"},{"first_name":"Yuan","full_name":"Yu, Yuan","last_name":"Yu"},{"full_name":"Lee, Seungho","id":"BB243B88-D767-11E9-B658-BC13E6697425","last_name":"Lee","first_name":"Seungho","orcid":"0000-0002-6962-8598"},{"full_name":"Chang, Cheng","id":"9E331C2E-9F27-11E9-AE48-5033E6697425","last_name":"Chang","first_name":"Cheng","orcid":"0000-0002-9515-4277"},{"last_name":"David","full_name":"David, Jérémy","first_name":"Jérémy"},{"id":"a5fc9bc3-feff-11ea-93fe-e8015a3c7e9d","full_name":"Ghosh, Tanmoy","last_name":"Ghosh","first_name":"Tanmoy"},{"first_name":"Maria Chiara","last_name":"Spadaro","full_name":"Spadaro, Maria Chiara"},{"full_name":"Xie, Chenyang","last_name":"Xie","first_name":"Chenyang"},{"full_name":"Cojocaru-Mirédin, Oana","last_name":"Cojocaru-Mirédin","first_name":"Oana"},{"first_name":"Jordi","last_name":"Arbiol","full_name":"Arbiol, Jordi"},{"full_name":"Ibáñez, Maria","id":"43C61214-F248-11E8-B48F-1D18A9856A87","last_name":"Ibáñez","orcid":"0000-0001-5013-2843","first_name":"Maria"}],"day":"25","scopus_import":"1","article_type":"original","date_created":"2021-09-24T07:55:12Z","volume":16,"project":[{"grant_number":"754411","name":"ISTplus - Postdoctoral Fellowships","call_identifier":"H2020","_id":"260C2330-B435-11E9-9278-68D0E5697425"},{"name":"International IST Doctoral Program","grant_number":"665385","call_identifier":"H2020","_id":"2564DBCA-B435-11E9-9278-68D0E5697425"},{"_id":"9B8F7476-BA93-11EA-9121-9846C619BF3A","name":"HighTE: The Werner Siemens Laboratory for the High Throughput Discovery of Semiconductors for Waste Heat Recovery"},{"grant_number":"M02889","name":"Bottom-up Engineering for Thermoelectric Applications","_id":"9B8804FC-BA93-11EA-9121-9846C619BF3A"}],"status":"public","publication":"ACS Nano","acknowledgement":"This work was financially supported by IST Austria and the Werner Siemens Foundation. Y.L. acknowledges funding from the European Union’s Horizon 2020 research and innovation program under the Marie Sklodowska-Curie grant agreement No. 754411. S.L. and M.C. received funding from the European Union’s Horizon 2020 research and innovation program under the Marie Skłodowska-Curie Grant Agreement No. 665385. J.D. acknowledges funding from the European Union’s Horizon 2020 research and innovation program under the Marie Sklodowska-Curie grant agreement no. 665919 (P-SPHERE) cofunded by Severo Ochoa Programme. C.C. acknowledges funding from the FWF “Lise Meitner Fellowship” grant agreement M 2889-N. Y.Y. and O.C.-M. acknowledge the financial support from DFG within the project SFB 917: Nanoswitches. M.C.S. received funding from the European Union’s Horizon 2020 research and innovation programme under the Marie Skłodowska-Curie grant agreement No. 754510 (PROBIST) and the Severo Ochoa programme. J.D. received funding from the European Union’s Horizon 2020 research and innovation programme under the Marie Sklodowska-Curie grant agreement No. 665919 (P-SPHERE) cofunded by Severo Ochoa Programme. The ICN2 is funded by the CERCA Program/Generalitat de Catalunya and by the Severo Ochoa program of the Spanish Ministry of Economy, Industry, and Competitiveness (MINECO, grant no. SEV-2017-0706). ICN2 acknowledges funding from Generalitat de Catalunya 2017 SGR 327 and the Spanish MINECO project NANOGEN (PID2020-116093RB-C43). This project received funding from the European Union’s Horizon 2020 research and innovation program under grant agreement No. 823717-ESTEEM3. The FIB sample preparation was conducted in the LMA-INA-Universidad de Zaragoza.","date_published":"2022-01-25T00:00:00Z","pmid":1,"ec_funded":1,"external_id":{"pmid":["34549956"],"isi":["000767223400008"]},"related_material":{"record":[{"id":"12885","status":"public","relation":"dissertation_contains"}]},"year":"2022","isi":1,"keyword":["tin selenide","nanocomposite","grain growth","Zener pinning","thermoelectricity","annealing","solution processing"],"ddc":["540"],"page":"78-88","quality_controlled":"1","publisher":"American Chemical Society ","doi":"10.1021/acsnano.1c06720","article_processing_charge":"Yes (via OA deal)","type":"journal_article","date_updated":"2023-08-02T14:41:05Z","_id":"10042"},{"user_id":"4359f0d1-fa6c-11eb-b949-802e58b17ae8","citation":{"ama":"Fiedler C, Kleinhanns T, Garcia M, Lee S, Calcabrini M, Ibáñez M. Solution-processed inorganic thermoelectric materials: Opportunities and challenges. <i>Chemistry of Materials</i>. 2022;34(19):8471-8489. doi:<a href=\"https://doi.org/10.1021/acs.chemmater.2c01967\">10.1021/acs.chemmater.2c01967</a>","short":"C. Fiedler, T. Kleinhanns, M. Garcia, S. Lee, M. Calcabrini, M. Ibáñez, Chemistry of Materials 34 (2022) 8471–8489.","ieee":"C. Fiedler, T. Kleinhanns, M. Garcia, S. Lee, M. Calcabrini, and M. Ibáñez, “Solution-processed inorganic thermoelectric materials: Opportunities and challenges,” <i>Chemistry of Materials</i>, vol. 34, no. 19. American Chemical Society, pp. 8471–8489, 2022.","ista":"Fiedler C, Kleinhanns T, Garcia M, Lee S, Calcabrini M, Ibáñez M. 2022. Solution-processed inorganic thermoelectric materials: Opportunities and challenges. Chemistry of Materials. 34(19), 8471–8489.","chicago":"Fiedler, Christine, Tobias Kleinhanns, Maria Garcia, Seungho Lee, Mariano Calcabrini, and Maria Ibáñez. “Solution-Processed Inorganic Thermoelectric Materials: Opportunities and Challenges.” <i>Chemistry of Materials</i>. American Chemical Society, 2022. <a href=\"https://doi.org/10.1021/acs.chemmater.2c01967\">https://doi.org/10.1021/acs.chemmater.2c01967</a>.","mla":"Fiedler, Christine, et al. “Solution-Processed Inorganic Thermoelectric Materials: Opportunities and Challenges.” <i>Chemistry of Materials</i>, vol. 34, no. 19, American Chemical Society, 2022, pp. 8471–89, doi:<a href=\"https://doi.org/10.1021/acs.chemmater.2c01967\">10.1021/acs.chemmater.2c01967</a>.","apa":"Fiedler, C., Kleinhanns, T., Garcia, M., Lee, S., Calcabrini, M., &#38; Ibáñez, M. (2022). Solution-processed inorganic thermoelectric materials: Opportunities and challenges. <i>Chemistry of Materials</i>. American Chemical Society. <a href=\"https://doi.org/10.1021/acs.chemmater.2c01967\">https://doi.org/10.1021/acs.chemmater.2c01967</a>"},"issue":"19","language":[{"iso":"eng"}],"oa":1,"file":[{"file_size":10923495,"date_created":"2023-01-30T07:35:09Z","creator":"dernst","date_updated":"2023-01-30T07:35:09Z","file_id":"12434","file_name":"2022_ChemistryMaterials_Fiedler.pdf","success":1,"content_type":"application/pdf","access_level":"open_access","relation":"main_file","checksum":"f7143e44ab510519d1949099c3558532"}],"department":[{"_id":"MaIb"}],"month":"09","file_date_updated":"2023-01-30T07:35:09Z","publication_identifier":{"issn":["0897-4756"],"eissn":["1520-5002"]},"publication_status":"published","intvolume":"        34","tmp":{"name":"Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)","legal_code_url":"https://creativecommons.org/licenses/by/4.0/legalcode","image":"/images/cc_by.png","short":"CC BY (4.0)"},"abstract":[{"lang":"eng","text":"Thermoelectric technology requires synthesizing complex materials where not only the crystal structure but also other structural features such as defects, grain size and orientation, and interfaces must be controlled. To date, conventional solid-state techniques are unable to provide this level of control. Herein, we present a synthetic approach in which dense inorganic thermoelectric materials are produced by the consolidation of well-defined nanoparticle powders. The idea is that controlling the characteristics of the powder allows the chemical transformations that take place during consolidation to be guided, ultimately yielding inorganic solids with targeted features. Different from conventional methods, syntheses in solution can produce particles with unprecedented control over their size, shape, crystal structure, composition, and surface chemistry. However, to date, most works have focused only on the low-cost benefits of this strategy. In this perspective, we first cover the opportunities that solution processing of the powder offers, emphasizing the potential structural features that can be controlled by precisely engineering the inorganic core of the particle, the surface, and the organization of the particles before consolidation. We then discuss the challenges of this synthetic approach and more practical matters related to solution processing. Finally, we suggest some good practices for adequate knowledge transfer and improving reproducibility among different laboratories."}],"has_accepted_license":"1","date_created":"2023-01-16T09:51:26Z","article_type":"original","volume":34,"oa_version":"Published Version","title":"Solution-processed inorganic thermoelectric materials: Opportunities and challenges","scopus_import":"1","day":"20","author":[{"first_name":"Christine","id":"bd3fceba-dc74-11ea-a0a7-c17f71817366","full_name":"Fiedler, Christine","last_name":"Fiedler"},{"id":"8BD9DE16-AB3C-11E9-9C8C-2A03E6697425","full_name":"Kleinhanns, Tobias","last_name":"Kleinhanns","first_name":"Tobias"},{"last_name":"Garcia","full_name":"Garcia, Maria","id":"6e5c50b8-97dc-11ed-be98-b0a74c84cae0","first_name":"Maria"},{"first_name":"Seungho","orcid":"0000-0002-6962-8598","id":"BB243B88-D767-11E9-B658-BC13E6697425","full_name":"Lee, Seungho","last_name":"Lee"},{"last_name":"Calcabrini","full_name":"Calcabrini, Mariano","id":"45D7531A-F248-11E8-B48F-1D18A9856A87","first_name":"Mariano"},{"first_name":"Maria","orcid":"0000-0001-5013-2843","id":"43C61214-F248-11E8-B48F-1D18A9856A87","full_name":"Ibáñez, Maria","last_name":"Ibáñez"}],"date_published":"2022-09-20T00:00:00Z","acknowledgement":"This work was financially supported by ISTA and the Werner Siemens Foundation. M.C. has received funding from the European Union’s Horizon 2020 research and innovation program under the Marie Skłodowska-Curie Grant Agreement no. 665385.","ec_funded":1,"pmid":1,"publication":"Chemistry of Materials","status":"public","project":[{"_id":"2564DBCA-B435-11E9-9278-68D0E5697425","call_identifier":"H2020","name":"International IST Doctoral Program","grant_number":"665385"}],"keyword":["Materials Chemistry","General Chemical Engineering","General Chemistry"],"related_material":{"record":[{"status":"public","relation":"dissertation_contains","id":"12885"}]},"external_id":{"isi":["000917837600001"],"pmid":["36248227"]},"year":"2022","isi":1,"quality_controlled":"1","ddc":["540"],"page":"8471-8489","type":"journal_article","_id":"12237","date_updated":"2023-08-04T09:38:26Z","publisher":"American Chemical Society","article_processing_charge":"Yes (via OA deal)","doi":"10.1021/acs.chemmater.2c01967"},{"publication_status":"published","publication_identifier":{"eissn":["2691-3704"],"issn":["2691-3704"]},"file_date_updated":"2022-03-02T15:33:18Z","has_accepted_license":"1","tmp":{"name":"Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)","legal_code_url":"https://creativecommons.org/licenses/by/4.0/legalcode","image":"/images/cc_by.png","short":"CC BY (4.0)"},"intvolume":"         1","abstract":[{"text":"Ligands are a fundamental part of nanocrystals. They control and direct nanocrystal syntheses and provide colloidal stability. Bound ligands also affect the nanocrystals’ chemical reactivity and electronic structure. Surface chemistry is thus crucial to understand nanocrystal properties and functionality. Here, we investigate the synthesis of metal oxide nanocrystals (CeO2-x, ZnO, and NiO) from metal nitrate precursors, in the presence of oleylamine ligands. Surprisingly, the nanocrystals are capped exclusively with a fatty acid instead of oleylamine. Analysis of the reaction mixtures with nuclear magnetic resonance spectroscopy revealed several reaction byproducts and intermediates that are common to the decomposition of Ce, Zn, Ni, and Zr nitrate precursors. Our evidence supports the oxidation of alkylamine and formation of a carboxylic acid, thus unraveling this counterintuitive surface chemistry.","lang":"eng"}],"volume":1,"article_type":"original","date_created":"2022-03-02T15:24:16Z","author":[{"first_name":"Mariano","last_name":"Calcabrini","full_name":"Calcabrini, Mariano","id":"45D7531A-F248-11E8-B48F-1D18A9856A87"},{"first_name":"Dietger","last_name":"Van den Eynden","full_name":"Van den Eynden, Dietger"},{"first_name":"Sergi","last_name":"Sanchez Ribot","id":"ddae5a59-f6e0-11ea-865d-d9dc61e77a2a","full_name":"Sanchez Ribot, Sergi"},{"first_name":"Rohan","full_name":"Pokratath, Rohan","last_name":"Pokratath"},{"full_name":"Llorca, Jordi","last_name":"Llorca","first_name":"Jordi"},{"first_name":"Jonathan","last_name":"De Roo","full_name":"De Roo, Jonathan"},{"full_name":"Ibáñez, Maria","id":"43C61214-F248-11E8-B48F-1D18A9856A87","last_name":"Ibáñez","orcid":"0000-0001-5013-2843","first_name":"Maria"}],"day":"22","title":"Ligand conversion in nanocrystal synthesis: The oxidation of alkylamines to fatty acids by nitrate","oa_version":"Published Version","issue":"11","citation":{"short":"M. Calcabrini, D. Van den Eynden, S. Sanchez Ribot, R. Pokratath, J. Llorca, J. De Roo, M. Ibáñez, JACS Au 1 (2021) 1898–1903.","ieee":"M. Calcabrini <i>et al.</i>, “Ligand conversion in nanocrystal synthesis: The oxidation of alkylamines to fatty acids by nitrate,” <i>JACS Au</i>, vol. 1, no. 11. American Chemical Society, pp. 1898–1903, 2021.","ama":"Calcabrini M, Van den Eynden D, Sanchez Ribot S, et al. Ligand conversion in nanocrystal synthesis: The oxidation of alkylamines to fatty acids by nitrate. <i>JACS Au</i>. 2021;1(11):1898-1903. doi:<a href=\"https://doi.org/10.1021/jacsau.1c00349\">10.1021/jacsau.1c00349</a>","mla":"Calcabrini, Mariano, et al. “Ligand Conversion in Nanocrystal Synthesis: The Oxidation of Alkylamines to Fatty Acids by Nitrate.” <i>JACS Au</i>, vol. 1, no. 11, American Chemical Society, 2021, pp. 1898–903, doi:<a href=\"https://doi.org/10.1021/jacsau.1c00349\">10.1021/jacsau.1c00349</a>.","apa":"Calcabrini, M., Van den Eynden, D., Sanchez Ribot, S., Pokratath, R., Llorca, J., De Roo, J., &#38; Ibáñez, M. (2021). Ligand conversion in nanocrystal synthesis: The oxidation of alkylamines to fatty acids by nitrate. <i>JACS Au</i>. American Chemical Society. <a href=\"https://doi.org/10.1021/jacsau.1c00349\">https://doi.org/10.1021/jacsau.1c00349</a>","ista":"Calcabrini M, Van den Eynden D, Sanchez Ribot S, Pokratath R, Llorca J, De Roo J, Ibáñez M. 2021. Ligand conversion in nanocrystal synthesis: The oxidation of alkylamines to fatty acids by nitrate. JACS Au. 1(11), 1898–1903.","chicago":"Calcabrini, Mariano, Dietger Van den Eynden, Sergi Sanchez Ribot, Rohan Pokratath, Jordi Llorca, Jonathan De Roo, and Maria Ibáñez. “Ligand Conversion in Nanocrystal Synthesis: The Oxidation of Alkylamines to Fatty Acids by Nitrate.” <i>JACS Au</i>. American Chemical Society, 2021. <a href=\"https://doi.org/10.1021/jacsau.1c00349\">https://doi.org/10.1021/jacsau.1c00349</a>."},"user_id":"8b945eb4-e2f2-11eb-945a-df72226e66a9","oa":1,"language":[{"iso":"eng"}],"department":[{"_id":"MaIb"}],"file":[{"date_updated":"2022-03-02T15:33:18Z","creator":"cchlebak","file_size":1257973,"date_created":"2022-03-02T15:33:18Z","file_id":"10807","content_type":"application/pdf","access_level":"open_access","file_name":"2021_JACSAu_Calcabrini.pdf","success":1,"checksum":"1c66a35369e911312a359111420318a9","relation":"main_file"}],"month":"11","quality_controlled":"1","page":"1898-1903","ddc":["540"],"date_updated":"2023-05-05T08:45:36Z","_id":"10806","type":"journal_article","doi":"10.1021/jacsau.1c00349","article_processing_charge":"Yes (via OA deal)","publisher":"American Chemical Society","ec_funded":1,"date_published":"2021-11-22T00:00:00Z","acknowledgement":"This work was financially supported by IST Austria and the Werner Siemens Foundation. M.C. has received funding from the European Union’s Horizon 2020 research and innovation programme under the Marie Skłodowska-Curie Grant Agreement No. 665385. The work was also financially supported by University of Basel, SNSF NCCR Molecular Systems Engineering (project number: 182895) and SNSF R’equip (project number: 189622). J.L. is a Serra Húnter Fellow and is grateful to ICREA Academia program and MICINN/FEDER RTI2018-093996-B-C31 and GC 2017 SGR 128 projects.","project":[{"call_identifier":"H2020","grant_number":"665385","name":"International IST Doctoral Program","_id":"2564DBCA-B435-11E9-9278-68D0E5697425"},{"name":"HighTE: The Werner Siemens Laboratory for the High Throughput Discovery of Semiconductors for Waste Heat Recovery","_id":"9B8F7476-BA93-11EA-9121-9846C619BF3A"},{"name":"IST Austria Open Access Fund","_id":"B67AFEDC-15C9-11EA-A837-991A96BB2854"}],"publication":"JACS Au","status":"public","keyword":["general medicine"],"year":"2021","related_material":{"link":[{"url":"https://doi.org/10.26434/chemrxiv-2021-cn2fr","relation":"earlier_version"}],"record":[{"relation":"dissertation_contains","status":"public","id":"12885"}]}},{"file":[{"checksum":"6fa7374bf8b95fdfe6e6c595322a6689","relation":"main_file","access_level":"open_access","content_type":"application/pdf","success":1,"file_name":"2021_ACSEnergyLetters_Calcabrini.pdf","file_id":"9155","creator":"dernst","date_updated":"2021-02-17T07:36:52Z","file_size":5071201,"date_created":"2021-02-17T07:36:52Z"}],"department":[{"_id":"MaIb"}],"month":"01","user_id":"4359f0d1-fa6c-11eb-b949-802e58b17ae8","issue":"2","citation":{"mla":"Calcabrini, Mariano, et al. “Exploiting the Lability of Metal Halide Perovskites for Doping Semiconductor Nanocomposites.” <i>ACS Energy Letters</i>, vol. 6, no. 2, American Chemical Society, 2021, pp. 581–87, doi:<a href=\"https://doi.org/10.1021/acsenergylett.0c02448\">10.1021/acsenergylett.0c02448</a>.","apa":"Calcabrini, M., Genc, A., Liu, Y., Kleinhanns, T., Lee, S., Dirin, D. N., … Ibáñez, M. (2021). Exploiting the lability of metal halide perovskites for doping semiconductor nanocomposites. <i>ACS Energy Letters</i>. American Chemical Society. <a href=\"https://doi.org/10.1021/acsenergylett.0c02448\">https://doi.org/10.1021/acsenergylett.0c02448</a>","ista":"Calcabrini M, Genc A, Liu Y, Kleinhanns T, Lee S, Dirin DN, Akkerman QA, Kovalenko MV, Arbiol J, Ibáñez M. 2021. Exploiting the lability of metal halide perovskites for doping semiconductor nanocomposites. ACS Energy Letters. 6(2), 581–587.","chicago":"Calcabrini, Mariano, Aziz Genc, Yu Liu, Tobias Kleinhanns, Seungho Lee, Dmitry N. Dirin, Quinten A. Akkerman, Maksym V. Kovalenko, Jordi Arbiol, and Maria Ibáñez. “Exploiting the Lability of Metal Halide Perovskites for Doping Semiconductor Nanocomposites.” <i>ACS Energy Letters</i>. American Chemical Society, 2021. <a href=\"https://doi.org/10.1021/acsenergylett.0c02448\">https://doi.org/10.1021/acsenergylett.0c02448</a>.","short":"M. Calcabrini, A. Genc, Y. Liu, T. Kleinhanns, S. Lee, D.N. Dirin, Q.A. Akkerman, M.V. Kovalenko, J. Arbiol, M. Ibáñez, ACS Energy Letters 6 (2021) 581–587.","ieee":"M. Calcabrini <i>et al.</i>, “Exploiting the lability of metal halide perovskites for doping semiconductor nanocomposites,” <i>ACS Energy Letters</i>, vol. 6, no. 2. American Chemical Society, pp. 581–587, 2021.","ama":"Calcabrini M, Genc A, Liu Y, et al. Exploiting the lability of metal halide perovskites for doping semiconductor nanocomposites. <i>ACS Energy Letters</i>. 2021;6(2):581-587. doi:<a href=\"https://doi.org/10.1021/acsenergylett.0c02448\">10.1021/acsenergylett.0c02448</a>"},"language":[{"iso":"eng"}],"oa":1,"article_type":"original","date_created":"2021-02-14T23:01:14Z","volume":6,"oa_version":"Published Version","title":"Exploiting the lability of metal halide perovskites for doping semiconductor nanocomposites","author":[{"last_name":"Calcabrini","id":"45D7531A-F248-11E8-B48F-1D18A9856A87","full_name":"Calcabrini, Mariano","first_name":"Mariano"},{"first_name":"Aziz","last_name":"Genc","full_name":"Genc, Aziz"},{"first_name":"Yu","orcid":"0000-0001-7313-6740","full_name":"Liu, Yu","id":"2A70014E-F248-11E8-B48F-1D18A9856A87","last_name":"Liu"},{"first_name":"Tobias","last_name":"Kleinhanns","id":"8BD9DE16-AB3C-11E9-9C8C-2A03E6697425","full_name":"Kleinhanns, Tobias"},{"orcid":"0000-0002-6962-8598","first_name":"Seungho","full_name":"Lee, Seungho","id":"BB243B88-D767-11E9-B658-BC13E6697425","last_name":"Lee"},{"first_name":"Dmitry N.","full_name":"Dirin, Dmitry N.","last_name":"Dirin"},{"last_name":"Akkerman","full_name":"Akkerman, Quinten A.","first_name":"Quinten A."},{"last_name":"Kovalenko","full_name":"Kovalenko, Maksym V.","first_name":"Maksym V."},{"first_name":"Jordi","full_name":"Arbiol, Jordi","last_name":"Arbiol"},{"first_name":"Maria","orcid":"0000-0001-5013-2843","id":"43C61214-F248-11E8-B48F-1D18A9856A87","full_name":"Ibáñez, Maria","last_name":"Ibáñez"}],"scopus_import":"1","day":"20","publication_status":"published","publication_identifier":{"eissn":["2380-8195"]},"file_date_updated":"2021-02-17T07:36:52Z","abstract":[{"text":"Cesium lead halides have intrinsically unstable crystal lattices and easily transform within perovskite and nonperovskite structures. In this work, we explore the conversion of the perovskite CsPbBr3 into Cs4PbBr6 in the presence of PbS at 450 °C to produce doped nanocrystal-based composites with embedded Cs4PbBr6 nanoprecipitates. We show that PbBr2 is extracted from CsPbBr3 and diffuses into the PbS lattice with a consequent increase in the concentration of free charge carriers. This new doping strategy enables the adjustment of the density of charge carriers between 1019 and 1020 cm–3, and it may serve as a general strategy for doping other nanocrystal-based semiconductors.","lang":"eng"}],"tmp":{"name":"Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)","legal_code_url":"https://creativecommons.org/licenses/by/4.0/legalcode","image":"/images/cc_by.png","short":"CC BY (4.0)"},"intvolume":"         6","has_accepted_license":"1","external_id":{"isi":["000619803400036"]},"related_material":{"record":[{"relation":"dissertation_contains","status":"public","id":"12885"}]},"year":"2021","isi":1,"date_published":"2021-01-20T00:00:00Z","acknowledgement":"M.C. has received funding from the European Union’s Horizon 2020 research and innovation programme under the Marie Skłodowska-Curie Grant Agreement No. 665385. ICN2\r\nacknowledges funding from Generalitat de Catalunya 2017 SGR 327. ICN2 is supported by the Severo Ochoa program from Spanish MINECO (Grant No. SEV-2017-0706) and is funded by the CERCA Programme/Generalitat de Catalunya. This project has received funding from the European Union’s Horizon 2020 research and innovation programme under grant agreement No 823717 − ESTEEM3. M.V.K. acknowledges the support by the European Research Council under the Horizon 2020 Framework Program (ERC Consolidator Grant SCALEHALO\r\nGrant Agreement No. 819740) and by FET-OPEN project no. 862656 (DROP-IT).","ec_funded":1,"project":[{"call_identifier":"H2020","name":"International IST Doctoral Program","grant_number":"665385","_id":"2564DBCA-B435-11E9-9278-68D0E5697425"}],"status":"public","publication":"ACS Energy Letters","type":"journal_article","date_updated":"2023-08-07T13:46:00Z","_id":"9118","publisher":"American Chemical Society","doi":"10.1021/acsenergylett.0c02448","article_processing_charge":"Yes (via OA deal)","quality_controlled":"1","ddc":["540"],"page":"581-587"},{"oa":1,"language":[{"iso":"eng"}],"issue":"52","citation":{"mla":"Liu, Yu, et al. “The Importance of Surface Adsorbates in Solution‐processed Thermoelectric Materials: The Case of SnSe.” <i>Advanced Materials</i>, vol. 33, no. 52, 2106858, Wiley, 2021, doi:<a href=\"https://doi.org/10.1002/adma.202106858\">10.1002/adma.202106858</a>.","apa":"Liu, Y., Calcabrini, M., Yu, Y., Genç, A., Chang, C., Costanzo, T., … Ibáñez, M. (2021). The importance of surface adsorbates in solution‐processed thermoelectric materials: The case of SnSe. <i>Advanced Materials</i>. Wiley. <a href=\"https://doi.org/10.1002/adma.202106858\">https://doi.org/10.1002/adma.202106858</a>","chicago":"Liu, Yu, Mariano Calcabrini, Yuan Yu, Aziz Genç, Cheng Chang, Tommaso Costanzo, Tobias Kleinhanns, et al. “The Importance of Surface Adsorbates in Solution‐processed Thermoelectric Materials: The Case of SnSe.” <i>Advanced Materials</i>. Wiley, 2021. <a href=\"https://doi.org/10.1002/adma.202106858\">https://doi.org/10.1002/adma.202106858</a>.","ista":"Liu Y, Calcabrini M, Yu Y, Genç A, Chang C, Costanzo T, Kleinhanns T, Lee S, Llorca J, Cojocaru‐Mirédin O, Ibáñez M. 2021. The importance of surface adsorbates in solution‐processed thermoelectric materials: The case of SnSe. Advanced Materials. 33(52), 2106858.","short":"Y. Liu, M. Calcabrini, Y. Yu, A. Genç, C. Chang, T. Costanzo, T. Kleinhanns, S. Lee, J. Llorca, O. Cojocaru‐Mirédin, M. Ibáñez, Advanced Materials 33 (2021).","ieee":"Y. Liu <i>et al.</i>, “The importance of surface adsorbates in solution‐processed thermoelectric materials: The case of SnSe,” <i>Advanced Materials</i>, vol. 33, no. 52. Wiley, 2021.","ama":"Liu Y, Calcabrini M, Yu Y, et al. The importance of surface adsorbates in solution‐processed thermoelectric materials: The case of SnSe. <i>Advanced Materials</i>. 2021;33(52). doi:<a href=\"https://doi.org/10.1002/adma.202106858\">10.1002/adma.202106858</a>"},"user_id":"4359f0d1-fa6c-11eb-b949-802e58b17ae8","month":"12","department":[{"_id":"EM-Fac"},{"_id":"MaIb"}],"article_number":"2106858","file":[{"relation":"main_file","checksum":"990bccc527c64d85cf1c97885110b5f4","success":1,"file_name":"2021_AdvancedMaterials_Liu.pdf","access_level":"open_access","content_type":"application/pdf","file_id":"10720","date_created":"2022-02-03T13:16:14Z","file_size":5595666,"date_updated":"2022-02-03T13:16:14Z","creator":"cchlebak"}],"has_accepted_license":"1","abstract":[{"text":"Solution synthesis of particles emerged as an alternative to prepare thermoelectric materials with less demanding processing conditions than conventional solid-state synthetic methods. However, solution synthesis generally involves the presence of additional molecules or ions belonging to the precursors or added to enable solubility and/or regulate nucleation and growth. These molecules or ions can end up in the particles as surface adsorbates and interfere in the material properties. This work demonstrates that ionic adsorbates, in particular Na⁺ ions, are electrostatically adsorbed in SnSe particles synthesized in water and play a crucial role not only in directing the material nano/microstructure but also in determining the transport properties of the consolidated material. In dense pellets prepared by sintering SnSe particles, Na remains within the crystal lattice as dopant, in dislocations, precipitates, and forming grain boundary complexions. These results highlight the importance of considering all the possible unintentional impurities to establish proper structure-property relationships and control material properties in solution-processed thermoelectric materials.","lang":"eng"}],"tmp":{"name":"Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)","legal_code_url":"https://creativecommons.org/licenses/by/4.0/legalcode","image":"/images/cc_by.png","short":"CC BY (4.0)"},"intvolume":"        33","acknowledged_ssus":[{"_id":"EM-Fac"},{"_id":"NanoFab"}],"publication_status":"published","publication_identifier":{"eissn":["1521-4095"],"issn":["0935-9648"]},"file_date_updated":"2022-02-03T13:16:14Z","author":[{"orcid":"0000-0001-7313-6740","first_name":"Yu","full_name":"Liu, Yu","id":"2A70014E-F248-11E8-B48F-1D18A9856A87","last_name":"Liu"},{"orcid":"0000-0003-4566-5877","first_name":"Mariano","full_name":"Calcabrini, Mariano","id":"45D7531A-F248-11E8-B48F-1D18A9856A87","last_name":"Calcabrini"},{"first_name":"Yuan","full_name":"Yu, Yuan","last_name":"Yu"},{"full_name":"Genç, Aziz","last_name":"Genç","first_name":"Aziz"},{"first_name":"Cheng","orcid":"0000-0002-9515-4277","last_name":"Chang","full_name":"Chang, Cheng","id":"9E331C2E-9F27-11E9-AE48-5033E6697425"},{"last_name":"Costanzo","full_name":"Costanzo, Tommaso","id":"D93824F4-D9BA-11E9-BB12-F207E6697425","orcid":"0000-0001-9732-3815","first_name":"Tommaso"},{"first_name":"Tobias","full_name":"Kleinhanns, Tobias","id":"8BD9DE16-AB3C-11E9-9C8C-2A03E6697425","last_name":"Kleinhanns"},{"last_name":"Lee","id":"BB243B88-D767-11E9-B658-BC13E6697425","full_name":"Lee, Seungho","orcid":"0000-0002-6962-8598","first_name":"Seungho"},{"full_name":"Llorca, Jordi","last_name":"Llorca","first_name":"Jordi"},{"last_name":"Cojocaru‐Mirédin","full_name":"Cojocaru‐Mirédin, Oana","first_name":"Oana"},{"full_name":"Ibáñez, Maria","id":"43C61214-F248-11E8-B48F-1D18A9856A87","last_name":"Ibáñez","orcid":"0000-0001-5013-2843","first_name":"Maria"}],"day":"29","scopus_import":"1","title":"The importance of surface adsorbates in solution‐processed thermoelectric materials: The case of SnSe","oa_version":"Published Version","volume":33,"article_type":"original","date_created":"2021-10-11T20:07:24Z","project":[{"_id":"2564DBCA-B435-11E9-9278-68D0E5697425","name":"International IST Doctoral Program","grant_number":"665385","call_identifier":"H2020"},{"name":"ISTplus - Postdoctoral Fellowships","grant_number":"754411","call_identifier":"H2020","_id":"260C2330-B435-11E9-9278-68D0E5697425"},{"grant_number":"M02889","name":"Bottom-up Engineering for Thermoelectric Applications","_id":"9B8804FC-BA93-11EA-9121-9846C619BF3A"},{"_id":"9B8F7476-BA93-11EA-9121-9846C619BF3A","name":"HighTE: The Werner Siemens Laboratory for the High Throughput Discovery of Semiconductors for Waste Heat Recovery"}],"status":"public","publication":"Advanced Materials","pmid":1,"ec_funded":1,"date_published":"2021-12-29T00:00:00Z","acknowledgement":"Y.L. and M.C. contributed equally to this work. This research was supported by the Scientific Service Units (SSU) of IST Austria through resources provided by Electron Microscopy Facility (EMF) and the Nanofabrication Facility (NNF). This work was financially supported by IST Austria and the Werner Siemens Foundation. Y.L. acknowledges funding from the European Union's Horizon 2020 research and innovation program under the Marie Sklodowska-Curie grant agreement No. 754411. M.C. has received funding from the European Union's Horizon 2020 research and innovation program under the Marie Skłodowska-Curie Grant Agreement No. 665385. Y.Y. and O.C.-M. acknowledge the financial support from DFG within the project SFB 917: Nanoswitches. J.L. is a Serra Húnter Fellow and is grateful to ICREA Academia program. C.C. acknowledges funding from the FWF “Lise Meitner Fellowship” grant agreement M 2889-N.","isi":1,"year":"2021","external_id":{"pmid":["34626034"],"isi":["000709899300001"]},"related_material":{"record":[{"status":"public","relation":"dissertation_contains","id":"12885"}]},"keyword":["mechanical engineering","mechanics of materials","general materials science"],"ddc":["620"],"quality_controlled":"1","doi":"10.1002/adma.202106858","article_processing_charge":"Yes (via OA deal)","publisher":"Wiley","date_updated":"2023-08-14T07:25:27Z","_id":"10123","type":"journal_article"}]