[{"article_number":"e202300769","acknowledgement":"We gratefully acknowledge the Max-Planck Society and the Institute of Science and Technology Austria (ISTA) for generous financial support. We also thank the Deutsche Forschungsgemeinschaft (DFG, German Research Foundation) under Germany's Excellence Strategy – EXC 2008 – 390540038 – UniSysCat for funding. B.P. thanks the Boehringer Ingelheim Foundation for funding through the Plus 3 Perspectives Programme.","year":"2023","date_created":"2023-10-08T22:01:18Z","citation":{"chicago":"Baunis, Haralds, and Bartholomäus Pieber. “Formal Radical Deoxyfluorination of Oxalate-Activated Alcohols Triggered by the Selectfluor-DMAP Charge-Transfer Complex.” <i>European Journal of Organic Chemistry</i>. Wiley, 2023. <a href=\"https://doi.org/10.1002/ejoc.202300769\">https://doi.org/10.1002/ejoc.202300769</a>.","mla":"Baunis, Haralds, and Bartholomäus Pieber. “Formal Radical Deoxyfluorination of Oxalate-Activated Alcohols Triggered by the Selectfluor-DMAP Charge-Transfer Complex.” <i>European Journal of Organic Chemistry</i>, vol. 26, no. 42, e202300769, Wiley, 2023, doi:<a href=\"https://doi.org/10.1002/ejoc.202300769\">10.1002/ejoc.202300769</a>.","ista":"Baunis H, Pieber B. 2023. Formal radical deoxyfluorination of oxalate-activated alcohols triggered by the selectfluor-DMAP charge-transfer complex. European Journal of Organic Chemistry. 26(42), e202300769.","ieee":"H. Baunis and B. Pieber, “Formal radical deoxyfluorination of oxalate-activated alcohols triggered by the selectfluor-DMAP charge-transfer complex,” <i>European Journal of Organic Chemistry</i>, vol. 26, no. 42. Wiley, 2023.","ama":"Baunis H, Pieber B. Formal radical deoxyfluorination of oxalate-activated alcohols triggered by the selectfluor-DMAP charge-transfer complex. <i>European Journal of Organic Chemistry</i>. 2023;26(42). doi:<a href=\"https://doi.org/10.1002/ejoc.202300769\">10.1002/ejoc.202300769</a>","short":"H. Baunis, B. Pieber, European Journal of Organic Chemistry 26 (2023).","apa":"Baunis, H., &#38; Pieber, B. (2023). Formal radical deoxyfluorination of oxalate-activated alcohols triggered by the selectfluor-DMAP charge-transfer complex. <i>European Journal of Organic Chemistry</i>. Wiley. <a href=\"https://doi.org/10.1002/ejoc.202300769\">https://doi.org/10.1002/ejoc.202300769</a>"},"doi":"10.1002/ejoc.202300769","file_date_updated":"2024-01-30T14:04:44Z","article_type":"original","_id":"14409","ddc":["540"],"tmp":{"short":"CC BY-NC (4.0)","name":"Creative Commons Attribution-NonCommercial 4.0 International (CC BY-NC 4.0)","legal_code_url":"https://creativecommons.org/licenses/by-nc/4.0/legalcode","image":"/images/cc_by_nc.png"},"external_id":{"isi":["001072666500001"]},"abstract":[{"lang":"eng","text":"We present a photon- and metal-free approach for the radical fluorination of aliphatic oxalate-activated alcohols. The method relies on the spontaneous generation of the N-(chloromethyl)triethylenediamine radical dication, a potent single electron oxidant, from Selectfluor and 4-(dimethylamino)pyridine. The protocol is easily scalable and provides the desired fluorinated products within only a few minutes reaction time."}],"publication_status":"published","publisher":"Wiley","date_published":"2023-11-07T00:00:00Z","department":[{"_id":"BaPi"}],"quality_controlled":"1","volume":26,"isi":1,"has_accepted_license":"1","intvolume":"        26","scopus_import":"1","date_updated":"2024-01-30T14:05:14Z","oa":1,"issue":"42","article_processing_charge":"Yes (via OA deal)","title":"Formal radical deoxyfluorination of oxalate-activated alcohols triggered by the selectfluor-DMAP charge-transfer complex","publication":"European Journal of Organic Chemistry","language":[{"iso":"eng"}],"month":"11","publication_identifier":{"issn":["1434-193X"],"eissn":["1099-0690"]},"day":"07","oa_version":"Published Version","file":[{"access_level":"open_access","relation":"main_file","content_type":"application/pdf","file_size":3277622,"creator":"dernst","date_created":"2024-01-30T14:04:44Z","date_updated":"2024-01-30T14:04:44Z","success":1,"checksum":"e8ad7865acd94672e476f273ccf3d542","file_name":"2023_EurJOrgChem_Baunis.pdf","file_id":"14913"}],"user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","author":[{"full_name":"Baunis, Haralds","first_name":"Haralds","last_name":"Baunis","id":"2eea55ec-e8ec-11ed-86cb-d9c76787acfe"},{"id":"93e5e5b2-0da6-11ed-8a41-af589a024726","last_name":"Pieber","orcid":"0000-0001-8689-388X","first_name":"Bartholomäus","full_name":"Pieber, Bartholomäus"}],"status":"public","type":"journal_article"}]