---
_id: '14776'
abstract:
- lang: eng
  text: Soluble chaperones residing in the endoplasmic reticulum (ER) play vitally
    important roles in folding and quality control of newly synthesized proteins that
    transiently pass through the ER en route to their final destinations. These soluble
    residents of the ER are themselves endowed with an ER retrieval signal that enables
    the cell to bring the escaped residents back from the Golgi. Here, by using purified
    proteins, we showed that Nicotiana tabacum phytaspase, a plant aspartate-specific
    protease, introduces two breaks at the C-terminus of the N. tabacum ER resident
    calreticulin-3. These cleavages resulted in removal of either a dipeptide or a
    hexapeptide from the C-terminus of calreticulin-3 encompassing part or all of
    the ER retrieval signal. Consistently, expression of the calreticulin-3 derivative
    mimicking the phytaspase cleavage product in Nicotiana benthamiana cells demonstrated
    loss of the ER accumulation of the protein. Notably, upon its escape from the
    ER, calreticulin-3 was further processed by an unknown protease(s) to generate
    the free N-terminal (N) domain of calreticulin-3, which was ultimately secreted
    into the apoplast. Our study thus identified a specific proteolytic enzyme capable
    of precise detachment of the ER retrieval signal from a plant ER resident protein,
    with implications for the further fate of the escaped resident.
acknowledgement: "We thank C.U.T. Hellen for critically reading the manuscript. The
  MALDI MS facility and CLSM became available to us in the framework of Moscow State
  University Development Programs PNG 5.13 and PNR 5.13.\r\nThis work was funded by
  the Russian Science Foundation, grant numbers 19-14-00010 and 22-14-00071."
article_number: '16527'
article_processing_charge: Yes
article_type: original
author:
- first_name: Anastasiia
  full_name: Teplova, Anastasiia
  id: e3736151-106c-11ec-b916-c2558e2762c6
  last_name: Teplova
- first_name: Artemii A.
  full_name: Pigidanov, Artemii A.
  last_name: Pigidanov
- first_name: Marina V.
  full_name: Serebryakova, Marina V.
  last_name: Serebryakova
- first_name: Sergei A.
  full_name: Golyshev, Sergei A.
  last_name: Golyshev
- first_name: Raisa A.
  full_name: Galiullina, Raisa A.
  last_name: Galiullina
- first_name: Nina V.
  full_name: Chichkova, Nina V.
  last_name: Chichkova
- first_name: Andrey B.
  full_name: Vartapetian, Andrey B.
  last_name: Vartapetian
citation:
  ama: Teplova A, Pigidanov AA, Serebryakova MV, et al. Phytaspase Is capable of detaching
    the endoplasmic reticulum retrieval signal from tobacco calreticulin-3. <i>International
    Journal of Molecular Sciences</i>. 2023;24(22). doi:<a href="https://doi.org/10.3390/ijms242216527">10.3390/ijms242216527</a>
  apa: Teplova, A., Pigidanov, A. A., Serebryakova, M. V., Golyshev, S. A., Galiullina,
    R. A., Chichkova, N. V., &#38; Vartapetian, A. B. (2023). Phytaspase Is capable
    of detaching the endoplasmic reticulum retrieval signal from tobacco calreticulin-3.
    <i>International Journal of Molecular Sciences</i>. MDPI. <a href="https://doi.org/10.3390/ijms242216527">https://doi.org/10.3390/ijms242216527</a>
  chicago: Teplova, Anastasiia, Artemii A. Pigidanov, Marina V. Serebryakova, Sergei
    A. Golyshev, Raisa A. Galiullina, Nina V. Chichkova, and Andrey B. Vartapetian.
    “Phytaspase Is Capable of Detaching the Endoplasmic Reticulum Retrieval Signal
    from Tobacco Calreticulin-3.” <i>International Journal of Molecular Sciences</i>.
    MDPI, 2023. <a href="https://doi.org/10.3390/ijms242216527">https://doi.org/10.3390/ijms242216527</a>.
  ieee: A. Teplova <i>et al.</i>, “Phytaspase Is capable of detaching the endoplasmic
    reticulum retrieval signal from tobacco calreticulin-3,” <i>International Journal
    of Molecular Sciences</i>, vol. 24, no. 22. MDPI, 2023.
  ista: Teplova A, Pigidanov AA, Serebryakova MV, Golyshev SA, Galiullina RA, Chichkova
    NV, Vartapetian AB. 2023. Phytaspase Is capable of detaching the endoplasmic reticulum
    retrieval signal from tobacco calreticulin-3. International Journal of Molecular
    Sciences. 24(22), 16527.
  mla: Teplova, Anastasiia, et al. “Phytaspase Is Capable of Detaching the Endoplasmic
    Reticulum Retrieval Signal from Tobacco Calreticulin-3.” <i>International Journal
    of Molecular Sciences</i>, vol. 24, no. 22, 16527, MDPI, 2023, doi:<a href="https://doi.org/10.3390/ijms242216527">10.3390/ijms242216527</a>.
  short: A. Teplova, A.A. Pigidanov, M.V. Serebryakova, S.A. Golyshev, R.A. Galiullina,
    N.V. Chichkova, A.B. Vartapetian, International Journal of Molecular Sciences
    24 (2023).
date_created: 2024-01-10T09:24:35Z
date_published: 2023-11-01T00:00:00Z
date_updated: 2024-01-10T13:41:10Z
day: '01'
ddc:
- '580'
department:
- _id: JiFr
doi: 10.3390/ijms242216527
external_id:
  isi:
  - '001113792600001'
  pmid:
  - '38003717'
file:
- access_level: open_access
  checksum: 4df7d206ba022b7f54eff1f0aec1659a
  content_type: application/pdf
  creator: dernst
  date_created: 2024-01-10T13:39:42Z
  date_updated: 2024-01-10T13:39:42Z
  file_id: '14791'
  file_name: 2023_IJMS_Teplova.pdf
  file_size: 2637784
  relation: main_file
  success: 1
file_date_updated: 2024-01-10T13:39:42Z
has_accepted_license: '1'
intvolume: '        24'
isi: 1
issue: '22'
keyword:
- Inorganic Chemistry
- Organic Chemistry
- Physical and Theoretical Chemistry
- Computer Science Applications
- Spectroscopy
- Molecular Biology
- General Medicine
- Catalysis
language:
- iso: eng
month: '11'
oa: 1
oa_version: Published Version
pmid: 1
publication: International Journal of Molecular Sciences
publication_identifier:
  issn:
  - 1422-0067
publication_status: published
publisher: MDPI
quality_controlled: '1'
status: public
title: Phytaspase Is capable of detaching the endoplasmic reticulum retrieval signal
  from tobacco calreticulin-3
tmp:
  image: /images/cc_by.png
  legal_code_url: https://creativecommons.org/licenses/by/4.0/legalcode
  name: Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)
  short: CC BY (4.0)
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 24
year: '2023'
...
---
_id: '12919'
abstract:
- lang: eng
  text: We report the visible light photocatalytic cleavage of trityl thioethers or
    ethers under pH-neutral conditions. The method results in the formation of the
    respective symmetrical disulfides and alcohols in moderate to excellent yield.
    The protocol only requires the addition of a suitable photocatalyst and light
    rendering it orthogonal to several functionalities, including acid labile protective
    groups. The same conditions can be used to directly convert trityl-protected thiols
    into unsymmetrical disulfides or selenosulfides, and to cleave trityl resins in
    solid phase organic synthesis.
article_processing_charge: No
article_type: original
author:
- first_name: Sho
  full_name: Murakami, Sho
  last_name: Murakami
- first_name: Cosima
  full_name: Brudy, Cosima
  last_name: Brudy
- first_name: Moritz
  full_name: Bachmann, Moritz
  last_name: Bachmann
- first_name: Yoshiji
  full_name: Takemoto, Yoshiji
  last_name: Takemoto
- first_name: Bartholomäus
  full_name: Pieber, Bartholomäus
  id: 93e5e5b2-0da6-11ed-8a41-af589a024726
  last_name: Pieber
  orcid: 0000-0001-8689-388X
citation:
  ama: Murakami S, Brudy C, Bachmann M, Takemoto Y, Pieber B. Photocatalytic cleavage
    of trityl protected thiols and alcohols. <i>Synthesis</i>. 2023;55(09):1367-1374.
    doi:<a href="https://doi.org/10.1055/a-1979-5933">10.1055/a-1979-5933</a>
  apa: Murakami, S., Brudy, C., Bachmann, M., Takemoto, Y., &#38; Pieber, B. (2023).
    Photocatalytic cleavage of trityl protected thiols and alcohols. <i>Synthesis</i>.
    Georg Thieme Verlag. <a href="https://doi.org/10.1055/a-1979-5933">https://doi.org/10.1055/a-1979-5933</a>
  chicago: Murakami, Sho, Cosima Brudy, Moritz Bachmann, Yoshiji Takemoto, and Bartholomäus
    Pieber. “Photocatalytic Cleavage of Trityl Protected Thiols and Alcohols.” <i>Synthesis</i>.
    Georg Thieme Verlag, 2023. <a href="https://doi.org/10.1055/a-1979-5933">https://doi.org/10.1055/a-1979-5933</a>.
  ieee: S. Murakami, C. Brudy, M. Bachmann, Y. Takemoto, and B. Pieber, “Photocatalytic
    cleavage of trityl protected thiols and alcohols,” <i>Synthesis</i>, vol. 55,
    no. 09. Georg Thieme Verlag, pp. 1367–1374, 2023.
  ista: Murakami S, Brudy C, Bachmann M, Takemoto Y, Pieber B. 2023. Photocatalytic
    cleavage of trityl protected thiols and alcohols. Synthesis. 55(09), 1367–1374.
  mla: Murakami, Sho, et al. “Photocatalytic Cleavage of Trityl Protected Thiols and
    Alcohols.” <i>Synthesis</i>, vol. 55, no. 09, Georg Thieme Verlag, 2023, pp. 1367–74,
    doi:<a href="https://doi.org/10.1055/a-1979-5933">10.1055/a-1979-5933</a>.
  short: S. Murakami, C. Brudy, M. Bachmann, Y. Takemoto, B. Pieber, Synthesis 55
    (2023) 1367–1374.
date_created: 2023-05-08T08:25:08Z
date_published: 2023-05-01T00:00:00Z
date_updated: 2023-05-15T08:43:50Z
day: '01'
doi: 10.1055/a-1979-5933
extern: '1'
intvolume: '        55'
issue: '09'
keyword:
- Organic Chemistry
- Catalysis
language:
- iso: eng
month: '05'
oa_version: None
page: 1367-1374
publication: Synthesis
publication_identifier:
  eissn:
  - 1437-210X
  issn:
  - 0039-7881
publication_status: published
publisher: Georg Thieme Verlag
quality_controlled: '1'
scopus_import: '1'
status: public
title: Photocatalytic cleavage of trityl protected thiols and alcohols
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 55
year: '2023'
...
---
_id: '12920'
abstract:
- lang: eng
  text: The multicomponent approach allows to incorporate several functionalities
    into a single covalent organic framework (COF) and consequently allows the construction
    of bifunctional materials for cooperative catalysis. The well-defined structure
    of such multicomponent COFs is furthermore ideally suited for structure-activity
    relationship studies. We report a series of multicomponent COFs that contain acridine-
    and 2,2’-bipyridine linkers connected through 1,3,5-benzenetrialdehyde derivatives.
    The acridine motif is responsible for broad light absorption, while the bipyridine
    unit enables complexation of nickel catalysts. These features enable the usage
    of the framework materials as catalysts for light-mediated carbon−heteroatom cross-couplings.
    Variation of the node units shows that the catalytic activity correlates to the
    keto-enamine tautomer isomerism. This allows switching between high charge-carrier
    mobility and persistent, localized charge-separated species depending on the nodes,
    a tool to tailor the materials for specific reactions. Moreover, nickel-loaded
    COFs are recyclable and catalyze cross-couplings even using red light irradiation.
article_number: e202202967
article_processing_charge: No
article_type: original
author:
- first_name: Michael
  full_name: Traxler, Michael
  last_name: Traxler
- first_name: Susanne
  full_name: Reischauer, Susanne
  last_name: Reischauer
- first_name: Sarah
  full_name: Vogl, Sarah
  last_name: Vogl
- first_name: Jérôme
  full_name: Roeser, Jérôme
  last_name: Roeser
- first_name: Jabor
  full_name: Rabeah, Jabor
  last_name: Rabeah
- first_name: Christopher
  full_name: Penschke, Christopher
  last_name: Penschke
- first_name: Peter
  full_name: Saalfrank, Peter
  last_name: Saalfrank
- first_name: Bartholomäus
  full_name: Pieber, Bartholomäus
  id: 93e5e5b2-0da6-11ed-8a41-af589a024726
  last_name: Pieber
  orcid: 0000-0001-8689-388X
- first_name: Arne
  full_name: Thomas, Arne
  last_name: Thomas
citation:
  ama: Traxler M, Reischauer S, Vogl S, et al. Programmable photocatalytic activity
    of multicomponent covalent organic frameworks used as metallaphotocatalysts. <i>Chemistry
    – A European Journal</i>. 2023;29(4). doi:<a href="https://doi.org/10.1002/chem.202202967">10.1002/chem.202202967</a>
  apa: Traxler, M., Reischauer, S., Vogl, S., Roeser, J., Rabeah, J., Penschke, C.,
    … Thomas, A. (2023). Programmable photocatalytic activity of multicomponent covalent
    organic frameworks used as metallaphotocatalysts. <i>Chemistry – A European Journal</i>.
    Wiley. <a href="https://doi.org/10.1002/chem.202202967">https://doi.org/10.1002/chem.202202967</a>
  chicago: Traxler, Michael, Susanne Reischauer, Sarah Vogl, Jérôme Roeser, Jabor
    Rabeah, Christopher Penschke, Peter Saalfrank, Bartholomäus Pieber, and Arne Thomas.
    “Programmable Photocatalytic Activity of Multicomponent Covalent Organic Frameworks
    Used as Metallaphotocatalysts.” <i>Chemistry – A European Journal</i>. Wiley,
    2023. <a href="https://doi.org/10.1002/chem.202202967">https://doi.org/10.1002/chem.202202967</a>.
  ieee: M. Traxler <i>et al.</i>, “Programmable photocatalytic activity of multicomponent
    covalent organic frameworks used as metallaphotocatalysts,” <i>Chemistry – A European
    Journal</i>, vol. 29, no. 4. Wiley, 2023.
  ista: Traxler M, Reischauer S, Vogl S, Roeser J, Rabeah J, Penschke C, Saalfrank
    P, Pieber B, Thomas A. 2023. Programmable photocatalytic activity of multicomponent
    covalent organic frameworks used as metallaphotocatalysts. Chemistry – A European
    Journal. 29(4), e202202967.
  mla: Traxler, Michael, et al. “Programmable Photocatalytic Activity of Multicomponent
    Covalent Organic Frameworks Used as Metallaphotocatalysts.” <i>Chemistry – A European
    Journal</i>, vol. 29, no. 4, e202202967, Wiley, 2023, doi:<a href="https://doi.org/10.1002/chem.202202967">10.1002/chem.202202967</a>.
  short: M. Traxler, S. Reischauer, S. Vogl, J. Roeser, J. Rabeah, C. Penschke, P.
    Saalfrank, B. Pieber, A. Thomas, Chemistry – A European Journal 29 (2023).
date_created: 2023-05-08T08:25:34Z
date_published: 2023-01-18T00:00:00Z
date_updated: 2023-05-15T08:39:24Z
day: '18'
doi: 10.1002/chem.202202967
extern: '1'
intvolume: '        29'
issue: '4'
keyword:
- General Chemistry
- Catalysis
- Organic Chemistry
language:
- iso: eng
main_file_link:
- open_access: '1'
  url: https://doi.org/10.1002/chem.202202967
month: '01'
oa: 1
oa_version: Published Version
publication: Chemistry – A European Journal
publication_identifier:
  eissn:
  - 1521-3765
  issn:
  - 0947-6539
publication_status: published
publisher: Wiley
quality_controlled: '1'
scopus_import: '1'
status: public
title: Programmable photocatalytic activity of multicomponent covalent organic frameworks
  used as metallaphotocatalysts
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 29
year: '2023'
...
---
_id: '12921'
abstract:
- lang: eng
  text: Visible-light photocatalysis provides numerous useful methodologies for synthetic
    organic chemistry. However, the mechanisms of these reactions are often not fully
    understood. Common mechanistic experiments mainly aim to characterize excited
    state properties of photocatalysts and their interaction with other species. Recently,
    in situ reaction monitoring using dedicated techniques was shown to be well-suited
    for the identification of intermediates and to obtain kinetic insights, thereby
    providing more holistic pictures of the reactions of interest. This minireview
    surveys these technologies and discusses selected examples where reaction monitoring
    was used to elucidate the mechanism of photocatalytic reactions.
article_number: e202201583
article_processing_charge: No
article_type: original
author:
- first_name: Amiera
  full_name: Madani, Amiera
  last_name: Madani
- first_name: Bartholomäus
  full_name: Pieber, Bartholomäus
  id: 93e5e5b2-0da6-11ed-8a41-af589a024726
  last_name: Pieber
  orcid: 0000-0001-8689-388X
citation:
  ama: Madani A, Pieber B. In situ reaction monitoring in photocatalytic organic synthesis.
    <i>ChemCatChem</i>. 2023;15(7). doi:<a href="https://doi.org/10.1002/cctc.202201583">10.1002/cctc.202201583</a>
  apa: Madani, A., &#38; Pieber, B. (2023). In situ reaction monitoring in photocatalytic
    organic synthesis. <i>ChemCatChem</i>. Wiley. <a href="https://doi.org/10.1002/cctc.202201583">https://doi.org/10.1002/cctc.202201583</a>
  chicago: Madani, Amiera, and Bartholomäus Pieber. “In Situ Reaction Monitoring in
    Photocatalytic Organic Synthesis.” <i>ChemCatChem</i>. Wiley, 2023. <a href="https://doi.org/10.1002/cctc.202201583">https://doi.org/10.1002/cctc.202201583</a>.
  ieee: A. Madani and B. Pieber, “In situ reaction monitoring in photocatalytic organic
    synthesis,” <i>ChemCatChem</i>, vol. 15, no. 7. Wiley, 2023.
  ista: Madani A, Pieber B. 2023. In situ reaction monitoring in photocatalytic organic
    synthesis. ChemCatChem. 15(7), e202201583.
  mla: Madani, Amiera, and Bartholomäus Pieber. “In Situ Reaction Monitoring in Photocatalytic
    Organic Synthesis.” <i>ChemCatChem</i>, vol. 15, no. 7, e202201583, Wiley, 2023,
    doi:<a href="https://doi.org/10.1002/cctc.202201583">10.1002/cctc.202201583</a>.
  short: A. Madani, B. Pieber, ChemCatChem 15 (2023).
date_created: 2023-05-08T08:25:55Z
date_published: 2023-04-06T00:00:00Z
date_updated: 2023-05-15T08:35:48Z
day: '06'
doi: 10.1002/cctc.202201583
extern: '1'
intvolume: '        15'
issue: '7'
keyword:
- Inorganic Chemistry
- Organic Chemistry
- Physical and Theoretical Chemistry
- Catalysis
language:
- iso: eng
main_file_link:
- open_access: '1'
  url: https://doi.org/10.1002/cctc.202201583
month: '04'
oa: 1
oa_version: Published Version
publication: ChemCatChem
publication_identifier:
  eissn:
  - 1867-3899
  issn:
  - 1867-3880
publication_status: published
publisher: Wiley
quality_controlled: '1'
scopus_import: '1'
status: public
title: In situ reaction monitoring in photocatalytic organic synthesis
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 15
year: '2023'
...
---
_id: '12939'
abstract:
- lang: eng
  text: 'Linear tetrapyrroles, called phyllobilins, are obtained as major catabolites
    upon chlorophyll degradation. Primarily, colorless phylloleucobilins featuring
    four deconjugated pyrrole units were identified. Their yellow counterparts, phylloxanthobilins,
    were discovered more recently. Although the two catabolites differ only by one
    double bond, physicochemical properties are very distinct. Moreover, the presence
    of the double bond seems to enhance physiologically relevant bioactivities: in
    contrast to phylloleucobilin, we identified a potent anti-proliferative activity
    for a phylloxanthobilin, and show that this natural product induces apoptotic
    cell death and a cell cycle arrest in cancer cells. Interestingly, upon modifying
    inactive phylloleucobilin by esterification, an anti-proliferative activity can
    be observed that increases with the chain lengths of the alkyl esters. We provide
    first evidence for anti-cancer activity of phyllobilins, report a novel plant
    source for a phylloxanthobilin, and by using paper spray MS, show that these bioactive
    yellow chlorophyll catabolites are more prevalent in Nature than previously assumed.'
article_processing_charge: No
article_type: original
author:
- first_name: Cornelia A.
  full_name: Karg, Cornelia A.
  last_name: Karg
- first_name: Pengyu
  full_name: Wang, Pengyu
  last_name: Wang
- first_name: Florian
  full_name: Kluibenschedl, Florian
  id: 7499e70e-eb2c-11ec-b98b-f925648bc9d9
  last_name: Kluibenschedl
- first_name: Thomas
  full_name: Müller, Thomas
  last_name: Müller
- first_name: Lars
  full_name: Allmendinger, Lars
  last_name: Allmendinger
- first_name: Angelika M.
  full_name: Vollmar, Angelika M.
  last_name: Vollmar
- first_name: Simone
  full_name: Moser, Simone
  last_name: Moser
citation:
  ama: Karg CA, Wang P, Kluibenschedl F, et al. Phylloxanthobilins are abundant linear
    tetrapyrroles from chlorophyll breakdown with activities against cancer cells.
    <i>European Journal of Organic Chemistry</i>. 2020;2020(29):4499-4509. doi:<a
    href="https://doi.org/10.1002/ejoc.202000692">10.1002/ejoc.202000692</a>
  apa: Karg, C. A., Wang, P., Kluibenschedl, F., Müller, T., Allmendinger, L., Vollmar,
    A. M., &#38; Moser, S. (2020). Phylloxanthobilins are abundant linear tetrapyrroles
    from chlorophyll breakdown with activities against cancer cells. <i>European Journal
    of Organic Chemistry</i>. Wiley. <a href="https://doi.org/10.1002/ejoc.202000692">https://doi.org/10.1002/ejoc.202000692</a>
  chicago: Karg, Cornelia A., Pengyu Wang, Florian Kluibenschedl, Thomas Müller, Lars
    Allmendinger, Angelika M. Vollmar, and Simone Moser. “Phylloxanthobilins Are Abundant
    Linear Tetrapyrroles from Chlorophyll Breakdown with Activities against Cancer
    Cells.” <i>European Journal of Organic Chemistry</i>. Wiley, 2020. <a href="https://doi.org/10.1002/ejoc.202000692">https://doi.org/10.1002/ejoc.202000692</a>.
  ieee: C. A. Karg <i>et al.</i>, “Phylloxanthobilins are abundant linear tetrapyrroles
    from chlorophyll breakdown with activities against cancer cells,” <i>European
    Journal of Organic Chemistry</i>, vol. 2020, no. 29. Wiley, pp. 4499–4509, 2020.
  ista: Karg CA, Wang P, Kluibenschedl F, Müller T, Allmendinger L, Vollmar AM, Moser
    S. 2020. Phylloxanthobilins are abundant linear tetrapyrroles from chlorophyll
    breakdown with activities against cancer cells. European Journal of Organic Chemistry.
    2020(29), 4499–4509.
  mla: Karg, Cornelia A., et al. “Phylloxanthobilins Are Abundant Linear Tetrapyrroles
    from Chlorophyll Breakdown with Activities against Cancer Cells.” <i>European
    Journal of Organic Chemistry</i>, vol. 2020, no. 29, Wiley, 2020, pp. 4499–509,
    doi:<a href="https://doi.org/10.1002/ejoc.202000692">10.1002/ejoc.202000692</a>.
  short: C.A. Karg, P. Wang, F. Kluibenschedl, T. Müller, L. Allmendinger, A.M. Vollmar,
    S. Moser, European Journal of Organic Chemistry 2020 (2020) 4499–4509.
date_created: 2023-05-10T14:49:30Z
date_published: 2020-08-09T00:00:00Z
date_updated: 2023-05-15T07:57:14Z
day: '09'
doi: 10.1002/ejoc.202000692
extern: '1'
intvolume: '      2020'
issue: '29'
keyword:
- Organic Chemistry
- Physical and Theoretical Chemistry
language:
- iso: eng
main_file_link:
- open_access: '1'
  url: https://doi.org/10.1002/ejoc.202000692
month: '08'
oa: 1
oa_version: Published Version
page: 4499-4509
publication: European Journal of Organic Chemistry
publication_identifier:
  issn:
  - 1434-193X
  - 1099-0690
publication_status: published
publisher: Wiley
quality_controlled: '1'
scopus_import: '1'
status: public
title: Phylloxanthobilins are abundant linear tetrapyrroles from chlorophyll breakdown
  with activities against cancer cells
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 2020
year: '2020'
...
---
_id: '13369'
abstract:
- lang: eng
  text: Arylazopyrazoles represent a new family of molecular photoswitches characterized
    by a near-quantitative conversion between two states and long thermal half-lives
    of the metastable state. Here, we investigated the behavior of a model arylazopyrazole
    in the presence of a self-assembled cage based on Pd–imidazole coordination. Owing
    to its high water solubility, the cage can solubilize the E isomer of arylazopyrazole,
    which, by itself, is not soluble in water. NMR spectroscopy and X-ray crystallography
    have independently demonstrated that each cage can encapsulate two molecules of
    E-arylazopyrazole. UV-induced switching to the Z isomer was accompanied by the
    release of one of the two guests from the cage and the formation of a 1:1 cage/Z-arylazopyrazole
    inclusion complex. DFT calculations suggest that this process involves a dramatic
    change in the conformation of the cage. Back-isomerization was induced with green
    light and resulted in the initial 1:2 cage/E-arylazopyrazole complex. This back-isomerization
    reaction also proceeded in the dark, with a rate significantly higher than in
    the absence of the cage.
article_processing_charge: No
article_type: original
author:
- first_name: Anton I
  full_name: Hanopolskyi, Anton I
  last_name: Hanopolskyi
- first_name: Soumen
  full_name: De, Soumen
  last_name: De
- first_name: Michał J
  full_name: Białek, Michał J
  last_name: Białek
- first_name: Yael
  full_name: Diskin-Posner, Yael
  last_name: Diskin-Posner
- first_name: Liat
  full_name: Avram, Liat
  last_name: Avram
- first_name: Moran
  full_name: Feller, Moran
  last_name: Feller
- first_name: Rafal
  full_name: Klajn, Rafal
  id: 8e84690e-1e48-11ed-a02b-a1e6fb8bb53b
  last_name: Klajn
citation:
  ama: Hanopolskyi AI, De S, Białek MJ, et al. Reversible switching of arylazopyrazole
    within a metal–organic cage. <i>Beilstein Journal of Organic Chemistry</i>. 2019;15:2398-2407.
    doi:<a href="https://doi.org/10.3762/bjoc.15.232">10.3762/bjoc.15.232</a>
  apa: Hanopolskyi, A. I., De, S., Białek, M. J., Diskin-Posner, Y., Avram, L., Feller,
    M., &#38; Klajn, R. (2019). Reversible switching of arylazopyrazole within a metal–organic
    cage. <i>Beilstein Journal of Organic Chemistry</i>. Beilstein Institut. <a href="https://doi.org/10.3762/bjoc.15.232">https://doi.org/10.3762/bjoc.15.232</a>
  chicago: Hanopolskyi, Anton I, Soumen De, Michał J Białek, Yael Diskin-Posner, Liat
    Avram, Moran Feller, and Rafal Klajn. “Reversible Switching of Arylazopyrazole
    within a Metal–Organic Cage.” <i>Beilstein Journal of Organic Chemistry</i>. Beilstein
    Institut, 2019. <a href="https://doi.org/10.3762/bjoc.15.232">https://doi.org/10.3762/bjoc.15.232</a>.
  ieee: A. I. Hanopolskyi <i>et al.</i>, “Reversible switching of arylazopyrazole
    within a metal–organic cage,” <i>Beilstein Journal of Organic Chemistry</i>, vol.
    15. Beilstein Institut, pp. 2398–2407, 2019.
  ista: Hanopolskyi AI, De S, Białek MJ, Diskin-Posner Y, Avram L, Feller M, Klajn
    R. 2019. Reversible switching of arylazopyrazole within a metal–organic cage.
    Beilstein Journal of Organic Chemistry. 15, 2398–2407.
  mla: Hanopolskyi, Anton I., et al. “Reversible Switching of Arylazopyrazole within
    a Metal–Organic Cage.” <i>Beilstein Journal of Organic Chemistry</i>, vol. 15,
    Beilstein Institut, 2019, pp. 2398–407, doi:<a href="https://doi.org/10.3762/bjoc.15.232">10.3762/bjoc.15.232</a>.
  short: A.I. Hanopolskyi, S. De, M.J. Białek, Y. Diskin-Posner, L. Avram, M. Feller,
    R. Klajn, Beilstein Journal of Organic Chemistry 15 (2019) 2398–2407.
date_created: 2023-08-01T09:38:06Z
date_published: 2019-10-10T00:00:00Z
date_updated: 2023-08-07T10:34:56Z
day: '10'
doi: 10.3762/bjoc.15.232
extern: '1'
external_id:
  pmid:
  - '31666874'
intvolume: '        15'
keyword:
- Organic Chemistry
language:
- iso: eng
main_file_link:
- open_access: '1'
  url: https://doi.org/10.3762/bjoc.15.232
month: '10'
oa: 1
oa_version: Published Version
page: 2398-2407
pmid: 1
publication: Beilstein Journal of Organic Chemistry
publication_identifier:
  eissn:
  - 1860-5397
publication_status: published
publisher: Beilstein Institut
quality_controlled: '1'
scopus_import: '1'
status: public
title: Reversible switching of arylazopyrazole within a metal–organic cage
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 15
year: '2019'
...
---
_id: '13379'
article_number: '1700827'
article_processing_charge: No
article_type: letter_note
author:
- first_name: David
  full_name: Bléger, David
  last_name: Bléger
- first_name: Rafal
  full_name: Klajn, Rafal
  id: 8e84690e-1e48-11ed-a02b-a1e6fb8bb53b
  last_name: Klajn
citation:
  ama: Bléger D, Klajn R. Integrating macromolecules with molecular switches. <i>Macromolecular
    Rapid Communications</i>. 2018;39(1). doi:<a href="https://doi.org/10.1002/marc.201700827">10.1002/marc.201700827</a>
  apa: Bléger, D., &#38; Klajn, R. (2018). Integrating macromolecules with molecular
    switches. <i>Macromolecular Rapid Communications</i>. Wiley. <a href="https://doi.org/10.1002/marc.201700827">https://doi.org/10.1002/marc.201700827</a>
  chicago: Bléger, David, and Rafal Klajn. “Integrating Macromolecules with Molecular
    Switches.” <i>Macromolecular Rapid Communications</i>. Wiley, 2018. <a href="https://doi.org/10.1002/marc.201700827">https://doi.org/10.1002/marc.201700827</a>.
  ieee: D. Bléger and R. Klajn, “Integrating macromolecules with molecular switches,”
    <i>Macromolecular Rapid Communications</i>, vol. 39, no. 1. Wiley, 2018.
  ista: Bléger D, Klajn R. 2018. Integrating macromolecules with molecular switches.
    Macromolecular Rapid Communications. 39(1), 1700827.
  mla: Bléger, David, and Rafal Klajn. “Integrating Macromolecules with Molecular
    Switches.” <i>Macromolecular Rapid Communications</i>, vol. 39, no. 1, 1700827,
    Wiley, 2018, doi:<a href="https://doi.org/10.1002/marc.201700827">10.1002/marc.201700827</a>.
  short: D. Bléger, R. Klajn, Macromolecular Rapid Communications 39 (2018).
date_created: 2023-08-01T09:40:48Z
date_published: 2018-01-08T00:00:00Z
date_updated: 2023-08-07T11:16:49Z
day: '08'
doi: 10.1002/marc.201700827
extern: '1'
external_id:
  pmid:
  - '29314396'
intvolume: '        39'
issue: '1'
keyword:
- Materials Chemistry
- Polymers and Plastics
- Organic Chemistry
language:
- iso: eng
main_file_link:
- open_access: '1'
  url: https://doi.org/10.1002/marc.201700827
month: '01'
oa: 1
oa_version: Published Version
pmid: 1
publication: Macromolecular Rapid Communications
publication_identifier:
  eissn:
  - 1521-3927
  issn:
  - 1022-1336
publication_status: published
publisher: Wiley
quality_controlled: '1'
scopus_import: '1'
status: public
title: Integrating macromolecules with molecular switches
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 39
year: '2018'
...
---
_id: '13383'
abstract:
- lang: eng
  text: Two novel donor–acceptor Stenhouse adducts (DASAs) featuring the catechol
    moiety were synthesized and characterized. Both compounds bind strongly to the
    surfaces of magnetite nanoparticles. An adrenaline-derived DASA renders the particles
    insoluble in all common solvents, likely because of poor solvation of the zwitterionic
    isomer generated on the nanoparticle surfaces. Well-soluble nanoparticles were
    successfully obtained using dopamine-derived DASA equipped with a long alkyl chain.
    Upon its attachment to nanoparticles, this DASA undergoes an irreversible decoloration
    reaction owing to the formation of the zwitterionic form. The reaction follows
    first-order kinetics and proceeds more rapidly on large nanoparticles. Interestingly,
    decoloration can be suppressed in the presence of free DASA molecules in solution
    or at high nanoparticle concentrations.
article_processing_charge: No
article_type: original
author:
- first_name: Johannes
  full_name: Ahrens, Johannes
  last_name: Ahrens
- first_name: Tong
  full_name: Bian, Tong
  last_name: Bian
- first_name: Tom
  full_name: Vexler, Tom
  last_name: Vexler
- first_name: Rafal
  full_name: Klajn, Rafal
  id: 8e84690e-1e48-11ed-a02b-a1e6fb8bb53b
  last_name: Klajn
citation:
  ama: Ahrens J, Bian T, Vexler T, Klajn R. Irreversible bleaching of donor-acceptor
    stenhouse adducts on the surfaces of magnetite nanoparticles. <i>ChemPhotoChem</i>.
    2017;1(5):230-236. doi:<a href="https://doi.org/10.1002/cptc.201700009">10.1002/cptc.201700009</a>
  apa: Ahrens, J., Bian, T., Vexler, T., &#38; Klajn, R. (2017). Irreversible bleaching
    of donor-acceptor stenhouse adducts on the surfaces of magnetite nanoparticles.
    <i>ChemPhotoChem</i>. Wiley. <a href="https://doi.org/10.1002/cptc.201700009">https://doi.org/10.1002/cptc.201700009</a>
  chicago: Ahrens, Johannes, Tong Bian, Tom Vexler, and Rafal Klajn. “Irreversible
    Bleaching of Donor-Acceptor Stenhouse Adducts on the Surfaces of Magnetite Nanoparticles.”
    <i>ChemPhotoChem</i>. Wiley, 2017. <a href="https://doi.org/10.1002/cptc.201700009">https://doi.org/10.1002/cptc.201700009</a>.
  ieee: J. Ahrens, T. Bian, T. Vexler, and R. Klajn, “Irreversible bleaching of donor-acceptor
    stenhouse adducts on the surfaces of magnetite nanoparticles,” <i>ChemPhotoChem</i>,
    vol. 1, no. 5. Wiley, pp. 230–236, 2017.
  ista: Ahrens J, Bian T, Vexler T, Klajn R. 2017. Irreversible bleaching of donor-acceptor
    stenhouse adducts on the surfaces of magnetite nanoparticles. ChemPhotoChem. 1(5),
    230–236.
  mla: Ahrens, Johannes, et al. “Irreversible Bleaching of Donor-Acceptor Stenhouse
    Adducts on the Surfaces of Magnetite Nanoparticles.” <i>ChemPhotoChem</i>, vol.
    1, no. 5, Wiley, 2017, pp. 230–36, doi:<a href="https://doi.org/10.1002/cptc.201700009">10.1002/cptc.201700009</a>.
  short: J. Ahrens, T. Bian, T. Vexler, R. Klajn, ChemPhotoChem 1 (2017) 230–236.
date_created: 2023-08-01T09:41:43Z
date_published: 2017-05-01T00:00:00Z
date_updated: 2023-08-07T12:08:05Z
day: '01'
doi: 10.1002/cptc.201700009
extern: '1'
intvolume: '         1'
issue: '5'
keyword:
- Organic Chemistry
- Physical and Theoretical Chemistry
- Analytical Chemistry
language:
- iso: eng
month: '05'
oa_version: None
page: 230-236
publication: ChemPhotoChem
publication_identifier:
  eissn:
  - 2367-0932
publication_status: published
publisher: Wiley
quality_controlled: '1'
scopus_import: '1'
status: public
title: Irreversible bleaching of donor-acceptor stenhouse adducts on the surfaces
  of magnetite nanoparticles
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 1
year: '2017'
...
---
_id: '13405'
abstract:
- lang: eng
  text: We report a method for preparing electrode–molecule–electrode junctions that
    incorporate nonsymmetrical azobenzene dithiols. Our approach is based on sequential
    deprotection of thiol moieties originally carrying two different protecting groups.
    The azobenzene derivatives retained their switching properties within monolayers
    and permitted the photocontrol of electrical conductance.
article_processing_charge: No
article_type: original
author:
- first_name: Tal
  full_name: Ely, Tal
  last_name: Ely
- first_name: Sanjib
  full_name: Das, Sanjib
  last_name: Das
- first_name: Wenjie
  full_name: Li, Wenjie
  last_name: Li
- first_name: Pintu
  full_name: Kundu, Pintu
  last_name: Kundu
- first_name: Einat
  full_name: Tirosh, Einat
  last_name: Tirosh
- first_name: David
  full_name: Cahen, David
  last_name: Cahen
- first_name: Ayelet
  full_name: Vilan, Ayelet
  last_name: Vilan
- first_name: Rafal
  full_name: Klajn, Rafal
  id: 8e84690e-1e48-11ed-a02b-a1e6fb8bb53b
  last_name: Klajn
citation:
  ama: Ely T, Das S, Li W, et al. Photocontrol of electrical conductance with a nonsymmetrical
    azobenzene dithiol. <i>Synlett</i>. 2013;24(18):2370-2374. doi:<a href="https://doi.org/10.1055/s-0033-1340087">10.1055/s-0033-1340087</a>
  apa: Ely, T., Das, S., Li, W., Kundu, P., Tirosh, E., Cahen, D., … Klajn, R. (2013).
    Photocontrol of electrical conductance with a nonsymmetrical azobenzene dithiol.
    <i>Synlett</i>. Georg Thieme Verlag. <a href="https://doi.org/10.1055/s-0033-1340087">https://doi.org/10.1055/s-0033-1340087</a>
  chicago: Ely, Tal, Sanjib Das, Wenjie Li, Pintu Kundu, Einat Tirosh, David Cahen,
    Ayelet Vilan, and Rafal Klajn. “Photocontrol of Electrical Conductance with a
    Nonsymmetrical Azobenzene Dithiol.” <i>Synlett</i>. Georg Thieme Verlag, 2013.
    <a href="https://doi.org/10.1055/s-0033-1340087">https://doi.org/10.1055/s-0033-1340087</a>.
  ieee: T. Ely <i>et al.</i>, “Photocontrol of electrical conductance with a nonsymmetrical
    azobenzene dithiol,” <i>Synlett</i>, vol. 24, no. 18. Georg Thieme Verlag, pp.
    2370–2374, 2013.
  ista: Ely T, Das S, Li W, Kundu P, Tirosh E, Cahen D, Vilan A, Klajn R. 2013. Photocontrol
    of electrical conductance with a nonsymmetrical azobenzene dithiol. Synlett. 24(18),
    2370–2374.
  mla: Ely, Tal, et al. “Photocontrol of Electrical Conductance with a Nonsymmetrical
    Azobenzene Dithiol.” <i>Synlett</i>, vol. 24, no. 18, Georg Thieme Verlag, 2013,
    pp. 2370–74, doi:<a href="https://doi.org/10.1055/s-0033-1340087">10.1055/s-0033-1340087</a>.
  short: T. Ely, S. Das, W. Li, P. Kundu, E. Tirosh, D. Cahen, A. Vilan, R. Klajn,
    Synlett 24 (2013) 2370–2374.
date_created: 2023-08-01T09:47:17Z
date_published: 2013-10-22T00:00:00Z
date_updated: 2023-08-08T07:47:35Z
day: '22'
doi: 10.1055/s-0033-1340087
extern: '1'
intvolume: '        24'
issue: '18'
keyword:
- Organic Chemistry
language:
- iso: eng
month: '10'
oa_version: None
page: 2370-2374
publication: Synlett
publication_identifier:
  eissn:
  - 1437-2096
  issn:
  - 0936-5214
publication_status: published
publisher: Georg Thieme Verlag
quality_controlled: '1'
scopus_import: '1'
status: public
title: Photocontrol of electrical conductance with a nonsymmetrical azobenzene dithiol
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 24
year: '2013'
...
---
_id: '10392'
abstract:
- lang: eng
  text: Protonated formylmetallocenes [M(C5H5)(C5H4-CHOH)]+ (M = Fe, Ru) and their
    isomers have been studied at the BP86 and B3LYP levels of density functional theory.
    Oxygen-protonated isomers are the most stable forms in each case, with a plethora
    of ring- or metal-protonated species at least ca. 14 and 10 kcal/mol higher in
    energy for M = Fe and Ru, respectively. The computed rotational barriers around
    the C−C bond connecting the cyclopentadienyl and protonated formyl moieties, ca.
    18 kcal/mol, are indicative of substantial conjugation between these moieties.
    Some of the ring- and iron-protonated species are models for possible intermediates
    in Friedel–Crafts acylation of ferrocene, and the computations provide further
    evidence that exo attack is clearly favored over endo attack of the electrophile
    in this reaction. The structures of the most stable mono- and diprotonated formylferrocenes
    are corroborated by the good agreement between GIAO-B3LYP-computed and experimental
    NMR chemical shifts.
acknowledgement: M.B. wishes to thank Prof. W. Thiel and the Max-Planck-Institut für
  Kohlenforschung for continuing support. A Humboldt fellowship for V.V. is gratefully
  acknowledged. Computations were performed on Compaq XP1000 and ES40 workstations
  as well as on an Intel Xeon PC cluster at the MPI Mülheim. A.S. thanks the Computing
  Center of the University of Zagreb SRCE for allocating computer time on the Isabella
  cluster.
article_processing_charge: No
article_type: original
author:
- first_name: Anđela
  full_name: Šarić, Anđela
  id: bf63d406-f056-11eb-b41d-f263a6566d8b
  last_name: Šarić
  orcid: 0000-0002-7854-2139
- first_name: Valerije
  full_name: Vrček, Valerije
  last_name: Vrček
- first_name: Michael
  full_name: Bühl, Michael
  last_name: Bühl
citation:
  ama: Šarić A, Vrček V, Bühl M. Density functional study of protonated formylmetallocenes.
    <i>Organometallics</i>. 2008;27(3):394-401. doi:<a href="https://doi.org/10.1021/om700916f">10.1021/om700916f</a>
  apa: Šarić, A., Vrček, V., &#38; Bühl, M. (2008). Density functional study of protonated
    formylmetallocenes. <i>Organometallics</i>. American Chemical Society. <a href="https://doi.org/10.1021/om700916f">https://doi.org/10.1021/om700916f</a>
  chicago: Šarić, Anđela, Valerije Vrček, and Michael Bühl. “Density Functional Study
    of Protonated Formylmetallocenes.” <i>Organometallics</i>. American Chemical Society,
    2008. <a href="https://doi.org/10.1021/om700916f">https://doi.org/10.1021/om700916f</a>.
  ieee: A. Šarić, V. Vrček, and M. Bühl, “Density functional study of protonated formylmetallocenes,”
    <i>Organometallics</i>, vol. 27, no. 3. American Chemical Society, pp. 394–401,
    2008.
  ista: Šarić A, Vrček V, Bühl M. 2008. Density functional study of protonated formylmetallocenes.
    Organometallics. 27(3), 394–401.
  mla: Šarić, Anđela, et al. “Density Functional Study of Protonated Formylmetallocenes.”
    <i>Organometallics</i>, vol. 27, no. 3, American Chemical Society, 2008, pp. 394–401,
    doi:<a href="https://doi.org/10.1021/om700916f">10.1021/om700916f</a>.
  short: A. Šarić, V. Vrček, M. Bühl, Organometallics 27 (2008) 394–401.
date_created: 2021-11-29T15:31:06Z
date_published: 2008-01-15T00:00:00Z
date_updated: 2021-11-30T08:04:44Z
day: '15'
doi: 10.1021/om700916f
extern: '1'
intvolume: '        27'
issue: '3'
keyword:
- Inorganic Chemistry
- Organic Chemistry
- Physical and Theoretical Chemistry
language:
- iso: eng
main_file_link:
- url: https://pubs.acs.org/doi/10.1021/om700916f
month: '01'
oa_version: None
page: 394-401
publication: Organometallics
publication_identifier:
  eissn:
  - 1520-6041
  issn:
  - 0276-7333
publication_status: published
publisher: American Chemical Society
quality_controlled: '1'
scopus_import: '1'
status: public
title: Density functional study of protonated formylmetallocenes
type: journal_article
user_id: 8b945eb4-e2f2-11eb-945a-df72226e66a9
volume: 27
year: '2008'
...
---
_id: '13433'
abstract:
- lang: eng
  text: Self-assembled monolayers (SAMs) of alkane thiols on gold and other metals
    are versatile constructs with which to study interfacial phenomena and reactions
    at surfaces. Surface properties of SAMs - e.g., wettability, stability in diverse
    environments, propensity to interact with or to resist adsorption of macromolecules
    -- depend on and can be controlled flexibly by the properties of the functional
    (head) groups in the w position of the alkyl chain. SAMs provide a basis for many
    important scientific and technological applications, ranging from micropatterning
    methods, through sensing, to biological recognition. Despite their importance,
    the literature on SAMs and the synthesis of molecules that constitute them remains
    scattered and often conflicting. The purpose of this Review is (i) to summarize
    the applications and physical properties of SAMs and (ii) to systematize the strategies
    of synthesis of ω-functionalized alkane thiols. Generic retrosynthetic scheme
    is developed that allows efficient synthetic planning. Issues related to the selection
    of appropriate protecting groups and the ways of introduction of the thiol functionality
    are discussed in detail, and illustrated with examples of syntheses of several
    complex alkane thiols.
article_processing_charge: No
article_type: original
author:
- first_name: Dariusz
  full_name: Witt, Dariusz
  last_name: Witt
- first_name: Rafal
  full_name: Klajn, Rafal
  id: 8e84690e-1e48-11ed-a02b-a1e6fb8bb53b
  last_name: Klajn
- first_name: Piotr
  full_name: Barski, Piotr
  last_name: Barski
- first_name: Bartosz
  full_name: Grzybowski, Bartosz
  last_name: Grzybowski
citation:
  ama: Witt D, Klajn R, Barski P, Grzybowski B. Applications, properties and synthesis
    of w-functionalized n-alkanethiols and disulfides - the building blocks of self-assembled
    monolayers. <i>Current Organic Chemistry</i>. 2005;8(18):1763-1797. doi:<a href="https://doi.org/10.2174/1385272043369421">10.2174/1385272043369421</a>
  apa: Witt, D., Klajn, R., Barski, P., &#38; Grzybowski, B. (2005). Applications,
    properties and synthesis of w-functionalized n-alkanethiols and disulfides - the
    building blocks of self-assembled monolayers. <i>Current Organic Chemistry</i>.
    Bentham Science. <a href="https://doi.org/10.2174/1385272043369421">https://doi.org/10.2174/1385272043369421</a>
  chicago: Witt, Dariusz, Rafal Klajn, Piotr Barski, and Bartosz Grzybowski. “Applications,
    Properties and Synthesis of w-Functionalized n-Alkanethiols and Disulfides - the
    Building Blocks of Self-Assembled Monolayers.” <i>Current Organic Chemistry</i>.
    Bentham Science, 2005. <a href="https://doi.org/10.2174/1385272043369421">https://doi.org/10.2174/1385272043369421</a>.
  ieee: D. Witt, R. Klajn, P. Barski, and B. Grzybowski, “Applications, properties
    and synthesis of w-functionalized n-alkanethiols and disulfides - the building
    blocks of self-assembled monolayers,” <i>Current Organic Chemistry</i>, vol. 8,
    no. 18. Bentham Science, pp. 1763–1797, 2005.
  ista: Witt D, Klajn R, Barski P, Grzybowski B. 2005. Applications, properties and
    synthesis of w-functionalized n-alkanethiols and disulfides - the building blocks
    of self-assembled monolayers. Current Organic Chemistry. 8(18), 1763–1797.
  mla: Witt, Dariusz, et al. “Applications, Properties and Synthesis of w-Functionalized
    n-Alkanethiols and Disulfides - the Building Blocks of Self-Assembled Monolayers.”
    <i>Current Organic Chemistry</i>, vol. 8, no. 18, Bentham Science, 2005, pp. 1763–97,
    doi:<a href="https://doi.org/10.2174/1385272043369421">10.2174/1385272043369421</a>.
  short: D. Witt, R. Klajn, P. Barski, B. Grzybowski, Current Organic Chemistry 8
    (2005) 1763–1797.
date_created: 2023-08-01T10:38:58Z
date_published: 2005-12-01T00:00:00Z
date_updated: 2023-08-08T12:39:52Z
day: '01'
doi: 10.2174/1385272043369421
extern: '1'
intvolume: '         8'
issue: '18'
keyword:
- Organic Chemistry
language:
- iso: eng
month: '12'
oa_version: None
page: 1763-1797
publication: Current Organic Chemistry
publication_identifier:
  eissn:
  - 1875-5348
  issn:
  - 1385-2728
publication_status: published
publisher: Bentham Science
quality_controlled: '1'
scopus_import: '1'
status: public
title: Applications, properties and synthesis of w-functionalized n-alkanethiols and
  disulfides - the building blocks of self-assembled monolayers
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 8
year: '2005'
...
---
_id: '13436'
abstract:
- lang: eng
  text: Cross-metathesis reactions of α,β-unsaturated sulfones and sulfoxides in the
    presence of molybdenum and ruthenium pre-catalysts were tested. A selective metahesis
    reaction was achieved between functionalized terminal olefins and vinyl sulfones
    by using the ‘second generation’ ruthenium catalysts 1c–h while the highly active
    Schrock catalyst 1b was found to be functional group incompatible with vinyl sulfones.
    The cross-metathesis products were isolated in good yields with an excellent (E)-selectivity.
    Both the molybdenum and ruthenium-based complexes were, however, incompatible
    with α,β- and β,γ-unsaturated sulfoxides.
article_processing_charge: No
article_type: original
author:
- first_name: Anna
  full_name: Michrowska, Anna
  last_name: Michrowska
- first_name: Michał
  full_name: Bieniek, Michał
  last_name: Bieniek
- first_name: Mikhail
  full_name: Kim, Mikhail
  last_name: Kim
- first_name: Rafal
  full_name: Klajn, Rafal
  id: 8e84690e-1e48-11ed-a02b-a1e6fb8bb53b
  last_name: Klajn
- first_name: Karol
  full_name: Grela, Karol
  last_name: Grela
citation:
  ama: Michrowska A, Bieniek M, Kim M, Klajn R, Grela K. Cross-metathesis reaction
    of vinyl sulfones and sulfoxides. <i>Tetrahedron</i>. 2003;59(25):4525-4531. doi:<a
    href="https://doi.org/10.1016/s0040-4020(03)00682-3">10.1016/s0040-4020(03)00682-3</a>
  apa: Michrowska, A., Bieniek, M., Kim, M., Klajn, R., &#38; Grela, K. (2003). Cross-metathesis
    reaction of vinyl sulfones and sulfoxides. <i>Tetrahedron</i>. Elsevier. <a href="https://doi.org/10.1016/s0040-4020(03)00682-3">https://doi.org/10.1016/s0040-4020(03)00682-3</a>
  chicago: Michrowska, Anna, Michał Bieniek, Mikhail Kim, Rafal Klajn, and Karol Grela.
    “Cross-Metathesis Reaction of Vinyl Sulfones and Sulfoxides.” <i>Tetrahedron</i>.
    Elsevier, 2003. <a href="https://doi.org/10.1016/s0040-4020(03)00682-3">https://doi.org/10.1016/s0040-4020(03)00682-3</a>.
  ieee: A. Michrowska, M. Bieniek, M. Kim, R. Klajn, and K. Grela, “Cross-metathesis
    reaction of vinyl sulfones and sulfoxides,” <i>Tetrahedron</i>, vol. 59, no. 25.
    Elsevier, pp. 4525–4531, 2003.
  ista: Michrowska A, Bieniek M, Kim M, Klajn R, Grela K. 2003. Cross-metathesis reaction
    of vinyl sulfones and sulfoxides. Tetrahedron. 59(25), 4525–4531.
  mla: Michrowska, Anna, et al. “Cross-Metathesis Reaction of Vinyl Sulfones and Sulfoxides.”
    <i>Tetrahedron</i>, vol. 59, no. 25, Elsevier, 2003, pp. 4525–31, doi:<a href="https://doi.org/10.1016/s0040-4020(03)00682-3">10.1016/s0040-4020(03)00682-3</a>.
  short: A. Michrowska, M. Bieniek, M. Kim, R. Klajn, K. Grela, Tetrahedron 59 (2003)
    4525–4531.
date_created: 2023-08-01T10:39:34Z
date_published: 2003-06-16T00:00:00Z
date_updated: 2023-08-08T12:44:17Z
day: '16'
doi: 10.1016/s0040-4020(03)00682-3
extern: '1'
intvolume: '        59'
issue: '25'
keyword:
- Organic Chemistry
- Drug Discovery
- Biochemistry
language:
- iso: eng
month: '06'
oa_version: None
page: 4525-4531
publication: Tetrahedron
publication_identifier:
  eissn:
  - 1464-5416
  issn:
  - 0040-4020
publication_status: published
publisher: Elsevier
quality_controlled: '1'
scopus_import: '1'
status: public
title: Cross-metathesis reaction of vinyl sulfones and sulfoxides
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 59
year: '2003'
...
---
_id: '13437'
abstract:
- lang: eng
  text: Liquid/liquid Phase Transfer Catalysis (PTC) reaction of 4-chlorobutyronitrile
    with nonenolisable aldehydes leads via an addition-cyclisation reaction sequence
    to derivatives of tetrahydrofuran-3-carbonitrile.
article_processing_charge: No
article_type: letter_note
author:
- first_name: Mieczysław
  full_name: Macogonkosza, Mieczysław
  last_name: Macogonkosza
- first_name: Jacek
  full_name: Przyborowski, Jacek
  last_name: Przyborowski
- first_name: Rafal
  full_name: Klajn, Rafal
  id: 8e84690e-1e48-11ed-a02b-a1e6fb8bb53b
  last_name: Klajn
- first_name: Andrzej
  full_name: Kwast, Andrzej
  last_name: Kwast
citation:
  ama: Macogonkosza M, Przyborowski J, Klajn R, Kwast A. Simple synthesis of 2-substituted
    Tetrahydrofuran-3-carbonitriles. <i>Synlett</i>. 2000;2000(12):1773-1774. doi:<a
    href="https://doi.org/10.1055/s-2000-8670">10.1055/s-2000-8670</a>
  apa: Macogonkosza, M., Przyborowski, J., Klajn, R., &#38; Kwast, A. (2000). Simple
    synthesis of 2-substituted Tetrahydrofuran-3-carbonitriles. <i>Synlett</i>. Georg
    Thieme Verlag. <a href="https://doi.org/10.1055/s-2000-8670">https://doi.org/10.1055/s-2000-8670</a>
  chicago: Macogonkosza, Mieczysław, Jacek Przyborowski, Rafal Klajn, and Andrzej
    Kwast. “Simple Synthesis of 2-Substituted Tetrahydrofuran-3-Carbonitriles.” <i>Synlett</i>.
    Georg Thieme Verlag, 2000. <a href="https://doi.org/10.1055/s-2000-8670">https://doi.org/10.1055/s-2000-8670</a>.
  ieee: M. Macogonkosza, J. Przyborowski, R. Klajn, and A. Kwast, “Simple synthesis
    of 2-substituted Tetrahydrofuran-3-carbonitriles,” <i>Synlett</i>, vol. 2000,
    no. 12. Georg Thieme Verlag, pp. 1773–1774, 2000.
  ista: Macogonkosza M, Przyborowski J, Klajn R, Kwast A. 2000. Simple synthesis of
    2-substituted Tetrahydrofuran-3-carbonitriles. Synlett. 2000(12), 1773–1774.
  mla: Macogonkosza, Mieczysław, et al. “Simple Synthesis of 2-Substituted Tetrahydrofuran-3-Carbonitriles.”
    <i>Synlett</i>, vol. 2000, no. 12, Georg Thieme Verlag, 2000, pp. 1773–74, doi:<a
    href="https://doi.org/10.1055/s-2000-8670">10.1055/s-2000-8670</a>.
  short: M. Macogonkosza, J. Przyborowski, R. Klajn, A. Kwast, Synlett 2000 (2000)
    1773–1774.
date_created: 2023-08-01T10:39:48Z
date_published: 2000-12-01T00:00:00Z
date_updated: 2023-08-02T07:54:46Z
day: '01'
doi: 10.1055/s-2000-8670
extern: '1'
intvolume: '      2000'
issue: '12'
keyword:
- Organic Chemistry
language:
- iso: eng
month: '12'
oa_version: None
page: 1773-1774
publication: Synlett
publication_identifier:
  eissn:
  - 1437-2096
  issn:
  - 0936-5214
publication_status: published
publisher: Georg Thieme Verlag
quality_controlled: '1'
scopus_import: '1'
status: public
title: Simple synthesis of 2-substituted Tetrahydrofuran-3-carbonitriles
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 2000
year: '2000'
...
