[{"volume":24,"acknowledgement":"We thank C.U.T. Hellen for critically reading the manuscript. The MALDI MS facility and CLSM became available to us in the framework of Moscow State University Development Programs PNG 5.13 and PNR 5.13.\r\nThis work was funded by the Russian Science Foundation, grant numbers 19-14-00010 and 22-14-00071.","ddc":["580"],"date_updated":"2024-01-10T13:41:10Z","citation":{"short":"A. Teplova, A.A. Pigidanov, M.V. Serebryakova, S.A. Golyshev, R.A. Galiullina, N.V. Chichkova, A.B. Vartapetian, International Journal of Molecular Sciences 24 (2023).","mla":"Teplova, Anastasiia, et al. “Phytaspase Is Capable of Detaching the Endoplasmic Reticulum Retrieval Signal from Tobacco Calreticulin-3.” <i>International Journal of Molecular Sciences</i>, vol. 24, no. 22, 16527, MDPI, 2023, doi:<a href=\"https://doi.org/10.3390/ijms242216527\">10.3390/ijms242216527</a>.","ista":"Teplova A, Pigidanov AA, Serebryakova MV, Golyshev SA, Galiullina RA, Chichkova NV, Vartapetian AB. 2023. Phytaspase Is capable of detaching the endoplasmic reticulum retrieval signal from tobacco calreticulin-3. International Journal of Molecular Sciences. 24(22), 16527.","ama":"Teplova A, Pigidanov AA, Serebryakova MV, et al. Phytaspase Is capable of detaching the endoplasmic reticulum retrieval signal from tobacco calreticulin-3. <i>International Journal of Molecular Sciences</i>. 2023;24(22). doi:<a href=\"https://doi.org/10.3390/ijms242216527\">10.3390/ijms242216527</a>","apa":"Teplova, A., Pigidanov, A. A., Serebryakova, M. V., Golyshev, S. A., Galiullina, R. A., Chichkova, N. V., &#38; Vartapetian, A. B. (2023). Phytaspase Is capable of detaching the endoplasmic reticulum retrieval signal from tobacco calreticulin-3. <i>International Journal of Molecular Sciences</i>. MDPI. <a href=\"https://doi.org/10.3390/ijms242216527\">https://doi.org/10.3390/ijms242216527</a>","ieee":"A. Teplova <i>et al.</i>, “Phytaspase Is capable of detaching the endoplasmic reticulum retrieval signal from tobacco calreticulin-3,” <i>International Journal of Molecular Sciences</i>, vol. 24, no. 22. MDPI, 2023.","chicago":"Teplova, Anastasiia, Artemii A. Pigidanov, Marina V. Serebryakova, Sergei A. Golyshev, Raisa A. Galiullina, Nina V. Chichkova, and Andrey B. Vartapetian. “Phytaspase Is Capable of Detaching the Endoplasmic Reticulum Retrieval Signal from Tobacco Calreticulin-3.” <i>International Journal of Molecular Sciences</i>. MDPI, 2023. <a href=\"https://doi.org/10.3390/ijms242216527\">https://doi.org/10.3390/ijms242216527</a>."},"year":"2023","isi":1,"external_id":{"pmid":["38003717"],"isi":["001113792600001"]},"doi":"10.3390/ijms242216527","day":"01","abstract":[{"lang":"eng","text":"Soluble chaperones residing in the endoplasmic reticulum (ER) play vitally important roles in folding and quality control of newly synthesized proteins that transiently pass through the ER en route to their final destinations. These soluble residents of the ER are themselves endowed with an ER retrieval signal that enables the cell to bring the escaped residents back from the Golgi. Here, by using purified proteins, we showed that Nicotiana tabacum phytaspase, a plant aspartate-specific protease, introduces two breaks at the C-terminus of the N. tabacum ER resident calreticulin-3. These cleavages resulted in removal of either a dipeptide or a hexapeptide from the C-terminus of calreticulin-3 encompassing part or all of the ER retrieval signal. Consistently, expression of the calreticulin-3 derivative mimicking the phytaspase cleavage product in Nicotiana benthamiana cells demonstrated loss of the ER accumulation of the protein. Notably, upon its escape from the ER, calreticulin-3 was further processed by an unknown protease(s) to generate the free N-terminal (N) domain of calreticulin-3, which was ultimately secreted into the apoplast. Our study thus identified a specific proteolytic enzyme capable of precise detachment of the ER retrieval signal from a plant ER resident protein, with implications for the further fate of the escaped resident."}],"quality_controlled":"1","file_date_updated":"2024-01-10T13:39:42Z","publisher":"MDPI","article_type":"original","_id":"14776","pmid":1,"author":[{"id":"e3736151-106c-11ec-b916-c2558e2762c6","last_name":"Teplova","first_name":"Anastasiia","full_name":"Teplova, Anastasiia"},{"full_name":"Pigidanov, Artemii A.","first_name":"Artemii A.","last_name":"Pigidanov"},{"last_name":"Serebryakova","first_name":"Marina V.","full_name":"Serebryakova, Marina V."},{"full_name":"Golyshev, Sergei A.","first_name":"Sergei A.","last_name":"Golyshev"},{"full_name":"Galiullina, Raisa A.","last_name":"Galiullina","first_name":"Raisa A."},{"last_name":"Chichkova","first_name":"Nina V.","full_name":"Chichkova, Nina V."},{"first_name":"Andrey B.","last_name":"Vartapetian","full_name":"Vartapetian, Andrey B."}],"issue":"22","publication_status":"published","department":[{"_id":"JiFr"}],"date_created":"2024-01-10T09:24:35Z","article_processing_charge":"Yes","title":"Phytaspase Is capable of detaching the endoplasmic reticulum retrieval signal from tobacco calreticulin-3","intvolume":"        24","file":[{"content_type":"application/pdf","file_name":"2023_IJMS_Teplova.pdf","date_updated":"2024-01-10T13:39:42Z","checksum":"4df7d206ba022b7f54eff1f0aec1659a","file_size":2637784,"date_created":"2024-01-10T13:39:42Z","creator":"dernst","file_id":"14791","relation":"main_file","access_level":"open_access","success":1}],"status":"public","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","tmp":{"legal_code_url":"https://creativecommons.org/licenses/by/4.0/legalcode","short":"CC BY (4.0)","image":"/images/cc_by.png","name":"Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)"},"date_published":"2023-11-01T00:00:00Z","type":"journal_article","publication_identifier":{"issn":["1422-0067"]},"oa":1,"language":[{"iso":"eng"}],"keyword":["Inorganic Chemistry","Organic Chemistry","Physical and Theoretical Chemistry","Computer Science Applications","Spectroscopy","Molecular Biology","General Medicine","Catalysis"],"publication":"International Journal of Molecular Sciences","has_accepted_license":"1","oa_version":"Published Version","month":"11","article_number":"16527"},{"_id":"12919","scopus_import":"1","author":[{"last_name":"Murakami","first_name":"Sho","full_name":"Murakami, Sho"},{"last_name":"Brudy","first_name":"Cosima","full_name":"Brudy, Cosima"},{"full_name":"Bachmann, Moritz","first_name":"Moritz","last_name":"Bachmann"},{"full_name":"Takemoto, Yoshiji","last_name":"Takemoto","first_name":"Yoshiji"},{"id":"93e5e5b2-0da6-11ed-8a41-af589a024726","full_name":"Pieber, Bartholomäus","orcid":"0000-0001-8689-388X","last_name":"Pieber","first_name":"Bartholomäus"}],"issue":"09","publication_status":"published","date_created":"2023-05-08T08:25:08Z","article_processing_charge":"No","title":"Photocatalytic cleavage of trityl protected thiols and alcohols","intvolume":"        55","page":"1367-1374","quality_controlled":"1","publisher":"Georg Thieme Verlag","article_type":"original","date_updated":"2023-05-15T08:43:50Z","year":"2023","citation":{"apa":"Murakami, S., Brudy, C., Bachmann, M., Takemoto, Y., &#38; Pieber, B. (2023). Photocatalytic cleavage of trityl protected thiols and alcohols. <i>Synthesis</i>. Georg Thieme Verlag. <a href=\"https://doi.org/10.1055/a-1979-5933\">https://doi.org/10.1055/a-1979-5933</a>","ama":"Murakami S, Brudy C, Bachmann M, Takemoto Y, Pieber B. Photocatalytic cleavage of trityl protected thiols and alcohols. <i>Synthesis</i>. 2023;55(09):1367-1374. doi:<a href=\"https://doi.org/10.1055/a-1979-5933\">10.1055/a-1979-5933</a>","chicago":"Murakami, Sho, Cosima Brudy, Moritz Bachmann, Yoshiji Takemoto, and Bartholomäus Pieber. “Photocatalytic Cleavage of Trityl Protected Thiols and Alcohols.” <i>Synthesis</i>. Georg Thieme Verlag, 2023. <a href=\"https://doi.org/10.1055/a-1979-5933\">https://doi.org/10.1055/a-1979-5933</a>.","ieee":"S. Murakami, C. Brudy, M. Bachmann, Y. Takemoto, and B. Pieber, “Photocatalytic cleavage of trityl protected thiols and alcohols,” <i>Synthesis</i>, vol. 55, no. 09. Georg Thieme Verlag, pp. 1367–1374, 2023.","mla":"Murakami, Sho, et al. “Photocatalytic Cleavage of Trityl Protected Thiols and Alcohols.” <i>Synthesis</i>, vol. 55, no. 09, Georg Thieme Verlag, 2023, pp. 1367–74, doi:<a href=\"https://doi.org/10.1055/a-1979-5933\">10.1055/a-1979-5933</a>.","short":"S. Murakami, C. Brudy, M. Bachmann, Y. Takemoto, B. Pieber, Synthesis 55 (2023) 1367–1374.","ista":"Murakami S, Brudy C, Bachmann M, Takemoto Y, Pieber B. 2023. Photocatalytic cleavage of trityl protected thiols and alcohols. Synthesis. 55(09), 1367–1374."},"doi":"10.1055/a-1979-5933","day":"01","abstract":[{"lang":"eng","text":"We report the visible light photocatalytic cleavage of trityl thioethers or ethers under pH-neutral conditions. The method results in the formation of the respective symmetrical disulfides and alcohols in moderate to excellent yield. The protocol only requires the addition of a suitable photocatalyst and light rendering it orthogonal to several functionalities, including acid labile protective groups. The same conditions can be used to directly convert trityl-protected thiols into unsymmetrical disulfides or selenosulfides, and to cleave trityl resins in solid phase organic synthesis."}],"volume":55,"extern":"1","publication":"Synthesis","oa_version":"None","month":"05","language":[{"iso":"eng"}],"keyword":["Organic Chemistry","Catalysis"],"date_published":"2023-05-01T00:00:00Z","type":"journal_article","publication_identifier":{"eissn":["1437-210X"],"issn":["0039-7881"]},"status":"public","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87"},{"status":"public","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","main_file_link":[{"open_access":"1","url":"https://doi.org/10.1002/chem.202202967"}],"oa":1,"publication_identifier":{"eissn":["1521-3765"],"issn":["0947-6539"]},"date_published":"2023-01-18T00:00:00Z","type":"journal_article","language":[{"iso":"eng"}],"keyword":["General Chemistry","Catalysis","Organic Chemistry"],"month":"01","article_number":"e202202967","oa_version":"Published Version","publication":"Chemistry – A European Journal","extern":"1","volume":29,"abstract":[{"lang":"eng","text":"The multicomponent approach allows to incorporate several functionalities into a single covalent organic framework (COF) and consequently allows the construction of bifunctional materials for cooperative catalysis. The well-defined structure of such multicomponent COFs is furthermore ideally suited for structure-activity relationship studies. We report a series of multicomponent COFs that contain acridine- and 2,2’-bipyridine linkers connected through 1,3,5-benzenetrialdehyde derivatives. The acridine motif is responsible for broad light absorption, while the bipyridine unit enables complexation of nickel catalysts. These features enable the usage of the framework materials as catalysts for light-mediated carbon−heteroatom cross-couplings. Variation of the node units shows that the catalytic activity correlates to the keto-enamine tautomer isomerism. This allows switching between high charge-carrier mobility and persistent, localized charge-separated species depending on the nodes, a tool to tailor the materials for specific reactions. Moreover, nickel-loaded COFs are recyclable and catalyze cross-couplings even using red light irradiation."}],"doi":"10.1002/chem.202202967","day":"18","date_updated":"2023-05-15T08:39:24Z","year":"2023","citation":{"apa":"Traxler, M., Reischauer, S., Vogl, S., Roeser, J., Rabeah, J., Penschke, C., … Thomas, A. (2023). Programmable photocatalytic activity of multicomponent covalent organic frameworks used as metallaphotocatalysts. <i>Chemistry – A European Journal</i>. Wiley. <a href=\"https://doi.org/10.1002/chem.202202967\">https://doi.org/10.1002/chem.202202967</a>","ama":"Traxler M, Reischauer S, Vogl S, et al. Programmable photocatalytic activity of multicomponent covalent organic frameworks used as metallaphotocatalysts. <i>Chemistry – A European Journal</i>. 2023;29(4). doi:<a href=\"https://doi.org/10.1002/chem.202202967\">10.1002/chem.202202967</a>","ieee":"M. Traxler <i>et al.</i>, “Programmable photocatalytic activity of multicomponent covalent organic frameworks used as metallaphotocatalysts,” <i>Chemistry – A European Journal</i>, vol. 29, no. 4. Wiley, 2023.","chicago":"Traxler, Michael, Susanne Reischauer, Sarah Vogl, Jérôme Roeser, Jabor Rabeah, Christopher Penschke, Peter Saalfrank, Bartholomäus Pieber, and Arne Thomas. “Programmable Photocatalytic Activity of Multicomponent Covalent Organic Frameworks Used as Metallaphotocatalysts.” <i>Chemistry – A European Journal</i>. Wiley, 2023. <a href=\"https://doi.org/10.1002/chem.202202967\">https://doi.org/10.1002/chem.202202967</a>.","short":"M. Traxler, S. Reischauer, S. Vogl, J. Roeser, J. Rabeah, C. Penschke, P. Saalfrank, B. Pieber, A. Thomas, Chemistry – A European Journal 29 (2023).","mla":"Traxler, Michael, et al. “Programmable Photocatalytic Activity of Multicomponent Covalent Organic Frameworks Used as Metallaphotocatalysts.” <i>Chemistry – A European Journal</i>, vol. 29, no. 4, e202202967, Wiley, 2023, doi:<a href=\"https://doi.org/10.1002/chem.202202967\">10.1002/chem.202202967</a>.","ista":"Traxler M, Reischauer S, Vogl S, Roeser J, Rabeah J, Penschke C, Saalfrank P, Pieber B, Thomas A. 2023. Programmable photocatalytic activity of multicomponent covalent organic frameworks used as metallaphotocatalysts. Chemistry – A European Journal. 29(4), e202202967."},"article_type":"original","publisher":"Wiley","quality_controlled":"1","title":"Programmable photocatalytic activity of multicomponent covalent organic frameworks used as metallaphotocatalysts","intvolume":"        29","publication_status":"published","article_processing_charge":"No","date_created":"2023-05-08T08:25:34Z","author":[{"full_name":"Traxler, Michael","last_name":"Traxler","first_name":"Michael"},{"full_name":"Reischauer, Susanne","last_name":"Reischauer","first_name":"Susanne"},{"first_name":"Sarah","last_name":"Vogl","full_name":"Vogl, Sarah"},{"first_name":"Jérôme","last_name":"Roeser","full_name":"Roeser, Jérôme"},{"first_name":"Jabor","last_name":"Rabeah","full_name":"Rabeah, Jabor"},{"first_name":"Christopher","last_name":"Penschke","full_name":"Penschke, Christopher"},{"last_name":"Saalfrank","first_name":"Peter","full_name":"Saalfrank, Peter"},{"orcid":"0000-0001-8689-388X","full_name":"Pieber, Bartholomäus","first_name":"Bartholomäus","last_name":"Pieber","id":"93e5e5b2-0da6-11ed-8a41-af589a024726"},{"full_name":"Thomas, Arne","last_name":"Thomas","first_name":"Arne"}],"issue":"4","_id":"12920","scopus_import":"1"},{"title":"In situ reaction monitoring in photocatalytic organic synthesis","intvolume":"        15","publication_status":"published","article_processing_charge":"No","date_created":"2023-05-08T08:25:55Z","author":[{"first_name":"Amiera","last_name":"Madani","full_name":"Madani, Amiera"},{"id":"93e5e5b2-0da6-11ed-8a41-af589a024726","orcid":"0000-0001-8689-388X","full_name":"Pieber, Bartholomäus","first_name":"Bartholomäus","last_name":"Pieber"}],"issue":"7","_id":"12921","scopus_import":"1","article_type":"original","publisher":"Wiley","quality_controlled":"1","abstract":[{"text":"Visible-light photocatalysis provides numerous useful methodologies for synthetic organic chemistry. However, the mechanisms of these reactions are often not fully understood. Common mechanistic experiments mainly aim to characterize excited state properties of photocatalysts and their interaction with other species. Recently, in situ reaction monitoring using dedicated techniques was shown to be well-suited for the identification of intermediates and to obtain kinetic insights, thereby providing more holistic pictures of the reactions of interest. This minireview surveys these technologies and discusses selected examples where reaction monitoring was used to elucidate the mechanism of photocatalytic reactions.","lang":"eng"}],"doi":"10.1002/cctc.202201583","day":"06","date_updated":"2023-05-15T08:35:48Z","citation":{"chicago":"Madani, Amiera, and Bartholomäus Pieber. “In Situ Reaction Monitoring in Photocatalytic Organic Synthesis.” <i>ChemCatChem</i>. Wiley, 2023. <a href=\"https://doi.org/10.1002/cctc.202201583\">https://doi.org/10.1002/cctc.202201583</a>.","ieee":"A. Madani and B. Pieber, “In situ reaction monitoring in photocatalytic organic synthesis,” <i>ChemCatChem</i>, vol. 15, no. 7. Wiley, 2023.","apa":"Madani, A., &#38; Pieber, B. (2023). In situ reaction monitoring in photocatalytic organic synthesis. <i>ChemCatChem</i>. Wiley. <a href=\"https://doi.org/10.1002/cctc.202201583\">https://doi.org/10.1002/cctc.202201583</a>","ama":"Madani A, Pieber B. In situ reaction monitoring in photocatalytic organic synthesis. <i>ChemCatChem</i>. 2023;15(7). doi:<a href=\"https://doi.org/10.1002/cctc.202201583\">10.1002/cctc.202201583</a>","ista":"Madani A, Pieber B. 2023. In situ reaction monitoring in photocatalytic organic synthesis. ChemCatChem. 15(7), e202201583.","mla":"Madani, Amiera, and Bartholomäus Pieber. “In Situ Reaction Monitoring in Photocatalytic Organic Synthesis.” <i>ChemCatChem</i>, vol. 15, no. 7, e202201583, Wiley, 2023, doi:<a href=\"https://doi.org/10.1002/cctc.202201583\">10.1002/cctc.202201583</a>.","short":"A. Madani, B. Pieber, ChemCatChem 15 (2023)."},"year":"2023","extern":"1","volume":15,"month":"04","article_number":"e202201583","oa_version":"Published Version","publication":"ChemCatChem","language":[{"iso":"eng"}],"keyword":["Inorganic Chemistry","Organic Chemistry","Physical and Theoretical Chemistry","Catalysis"],"oa":1,"publication_identifier":{"issn":["1867-3880"],"eissn":["1867-3899"]},"date_published":"2023-04-06T00:00:00Z","type":"journal_article","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","status":"public","main_file_link":[{"url":"https://doi.org/10.1002/cctc.202201583","open_access":"1"}]},{"extern":"1","volume":2020,"date_updated":"2023-05-15T07:57:14Z","year":"2020","citation":{"ama":"Karg CA, Wang P, Kluibenschedl F, et al. Phylloxanthobilins are abundant linear tetrapyrroles from chlorophyll breakdown with activities against cancer cells. <i>European Journal of Organic Chemistry</i>. 2020;2020(29):4499-4509. doi:<a href=\"https://doi.org/10.1002/ejoc.202000692\">10.1002/ejoc.202000692</a>","apa":"Karg, C. A., Wang, P., Kluibenschedl, F., Müller, T., Allmendinger, L., Vollmar, A. M., &#38; Moser, S. (2020). Phylloxanthobilins are abundant linear tetrapyrroles from chlorophyll breakdown with activities against cancer cells. <i>European Journal of Organic Chemistry</i>. Wiley. <a href=\"https://doi.org/10.1002/ejoc.202000692\">https://doi.org/10.1002/ejoc.202000692</a>","chicago":"Karg, Cornelia A., Pengyu Wang, Florian Kluibenschedl, Thomas Müller, Lars Allmendinger, Angelika M. Vollmar, and Simone Moser. “Phylloxanthobilins Are Abundant Linear Tetrapyrroles from Chlorophyll Breakdown with Activities against Cancer Cells.” <i>European Journal of Organic Chemistry</i>. Wiley, 2020. <a href=\"https://doi.org/10.1002/ejoc.202000692\">https://doi.org/10.1002/ejoc.202000692</a>.","ieee":"C. A. Karg <i>et al.</i>, “Phylloxanthobilins are abundant linear tetrapyrroles from chlorophyll breakdown with activities against cancer cells,” <i>European Journal of Organic Chemistry</i>, vol. 2020, no. 29. Wiley, pp. 4499–4509, 2020.","mla":"Karg, Cornelia A., et al. “Phylloxanthobilins Are Abundant Linear Tetrapyrroles from Chlorophyll Breakdown with Activities against Cancer Cells.” <i>European Journal of Organic Chemistry</i>, vol. 2020, no. 29, Wiley, 2020, pp. 4499–509, doi:<a href=\"https://doi.org/10.1002/ejoc.202000692\">10.1002/ejoc.202000692</a>.","short":"C.A. Karg, P. Wang, F. Kluibenschedl, T. Müller, L. Allmendinger, A.M. Vollmar, S. Moser, European Journal of Organic Chemistry 2020 (2020) 4499–4509.","ista":"Karg CA, Wang P, Kluibenschedl F, Müller T, Allmendinger L, Vollmar AM, Moser S. 2020. Phylloxanthobilins are abundant linear tetrapyrroles from chlorophyll breakdown with activities against cancer cells. European Journal of Organic Chemistry. 2020(29), 4499–4509."},"abstract":[{"text":"Linear tetrapyrroles, called phyllobilins, are obtained as major catabolites upon chlorophyll degradation. Primarily, colorless phylloleucobilins featuring four deconjugated pyrrole units were identified. Their yellow counterparts, phylloxanthobilins, were discovered more recently. Although the two catabolites differ only by one double bond, physicochemical properties are very distinct. Moreover, the presence of the double bond seems to enhance physiologically relevant bioactivities: in contrast to phylloleucobilin, we identified a potent anti-proliferative activity for a phylloxanthobilin, and show that this natural product induces apoptotic cell death and a cell cycle arrest in cancer cells. Interestingly, upon modifying inactive phylloleucobilin by esterification, an anti-proliferative activity can be observed that increases with the chain lengths of the alkyl esters. We provide first evidence for anti-cancer activity of phyllobilins, report a novel plant source for a phylloxanthobilin, and by using paper spray MS, show that these bioactive yellow chlorophyll catabolites are more prevalent in Nature than previously assumed.","lang":"eng"}],"doi":"10.1002/ejoc.202000692","day":"09","page":"4499-4509","quality_controlled":"1","article_type":"original","publisher":"Wiley","author":[{"full_name":"Karg, Cornelia A.","last_name":"Karg","first_name":"Cornelia A."},{"full_name":"Wang, Pengyu","last_name":"Wang","first_name":"Pengyu"},{"last_name":"Kluibenschedl","first_name":"Florian","full_name":"Kluibenschedl, Florian","id":"7499e70e-eb2c-11ec-b98b-f925648bc9d9"},{"last_name":"Müller","first_name":"Thomas","full_name":"Müller, Thomas"},{"first_name":"Lars","last_name":"Allmendinger","full_name":"Allmendinger, Lars"},{"full_name":"Vollmar, Angelika M.","last_name":"Vollmar","first_name":"Angelika M."},{"last_name":"Moser","first_name":"Simone","full_name":"Moser, Simone"}],"issue":"29","_id":"12939","scopus_import":"1","title":"Phylloxanthobilins are abundant linear tetrapyrroles from chlorophyll breakdown with activities against cancer cells","intvolume":"      2020","publication_status":"published","article_processing_charge":"No","date_created":"2023-05-10T14:49:30Z","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","status":"public","main_file_link":[{"open_access":"1","url":"https://doi.org/10.1002/ejoc.202000692"}],"date_published":"2020-08-09T00:00:00Z","type":"journal_article","oa":1,"publication_identifier":{"issn":["1434-193X","1099-0690"]},"language":[{"iso":"eng"}],"keyword":["Organic Chemistry","Physical and Theoretical Chemistry"],"publication":"European Journal of Organic Chemistry","month":"08","oa_version":"Published Version"},{"keyword":["Organic Chemistry"],"language":[{"iso":"eng"}],"publication":"Beilstein Journal of Organic Chemistry","oa_version":"Published Version","month":"10","main_file_link":[{"open_access":"1","url":"https://doi.org/10.3762/bjoc.15.232"}],"user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","status":"public","type":"journal_article","date_published":"2019-10-10T00:00:00Z","publication_identifier":{"eissn":["1860-5397"]},"oa":1,"quality_controlled":"1","page":"2398-2407","publisher":"Beilstein Institut","article_type":"original","scopus_import":"1","pmid":1,"_id":"13369","author":[{"full_name":"Hanopolskyi, Anton I","last_name":"Hanopolskyi","first_name":"Anton I"},{"first_name":"Soumen","last_name":"De","full_name":"De, Soumen"},{"full_name":"Białek, Michał J","first_name":"Michał J","last_name":"Białek"},{"first_name":"Yael","last_name":"Diskin-Posner","full_name":"Diskin-Posner, Yael"},{"last_name":"Avram","first_name":"Liat","full_name":"Avram, Liat"},{"full_name":"Feller, Moran","first_name":"Moran","last_name":"Feller"},{"full_name":"Klajn, Rafal","first_name":"Rafal","last_name":"Klajn","id":"8e84690e-1e48-11ed-a02b-a1e6fb8bb53b"}],"article_processing_charge":"No","date_created":"2023-08-01T09:38:06Z","publication_status":"published","intvolume":"        15","title":"Reversible switching of arylazopyrazole within a metal–organic cage","volume":15,"extern":"1","citation":{"ista":"Hanopolskyi AI, De S, Białek MJ, Diskin-Posner Y, Avram L, Feller M, Klajn R. 2019. Reversible switching of arylazopyrazole within a metal–organic cage. Beilstein Journal of Organic Chemistry. 15, 2398–2407.","mla":"Hanopolskyi, Anton I., et al. “Reversible Switching of Arylazopyrazole within a Metal–Organic Cage.” <i>Beilstein Journal of Organic Chemistry</i>, vol. 15, Beilstein Institut, 2019, pp. 2398–407, doi:<a href=\"https://doi.org/10.3762/bjoc.15.232\">10.3762/bjoc.15.232</a>.","short":"A.I. Hanopolskyi, S. De, M.J. Białek, Y. Diskin-Posner, L. Avram, M. Feller, R. Klajn, Beilstein Journal of Organic Chemistry 15 (2019) 2398–2407.","ieee":"A. I. Hanopolskyi <i>et al.</i>, “Reversible switching of arylazopyrazole within a metal–organic cage,” <i>Beilstein Journal of Organic Chemistry</i>, vol. 15. Beilstein Institut, pp. 2398–2407, 2019.","chicago":"Hanopolskyi, Anton I, Soumen De, Michał J Białek, Yael Diskin-Posner, Liat Avram, Moran Feller, and Rafal Klajn. “Reversible Switching of Arylazopyrazole within a Metal–Organic Cage.” <i>Beilstein Journal of Organic Chemistry</i>. Beilstein Institut, 2019. <a href=\"https://doi.org/10.3762/bjoc.15.232\">https://doi.org/10.3762/bjoc.15.232</a>.","ama":"Hanopolskyi AI, De S, Białek MJ, et al. Reversible switching of arylazopyrazole within a metal–organic cage. <i>Beilstein Journal of Organic Chemistry</i>. 2019;15:2398-2407. doi:<a href=\"https://doi.org/10.3762/bjoc.15.232\">10.3762/bjoc.15.232</a>","apa":"Hanopolskyi, A. I., De, S., Białek, M. J., Diskin-Posner, Y., Avram, L., Feller, M., &#38; Klajn, R. (2019). Reversible switching of arylazopyrazole within a metal–organic cage. <i>Beilstein Journal of Organic Chemistry</i>. Beilstein Institut. <a href=\"https://doi.org/10.3762/bjoc.15.232\">https://doi.org/10.3762/bjoc.15.232</a>"},"year":"2019","date_updated":"2023-08-07T10:34:56Z","external_id":{"pmid":["31666874"]},"day":"10","doi":"10.3762/bjoc.15.232","abstract":[{"text":"Arylazopyrazoles represent a new family of molecular photoswitches characterized by a near-quantitative conversion between two states and long thermal half-lives of the metastable state. Here, we investigated the behavior of a model arylazopyrazole in the presence of a self-assembled cage based on Pd–imidazole coordination. Owing to its high water solubility, the cage can solubilize the E isomer of arylazopyrazole, which, by itself, is not soluble in water. NMR spectroscopy and X-ray crystallography have independently demonstrated that each cage can encapsulate two molecules of E-arylazopyrazole. UV-induced switching to the Z isomer was accompanied by the release of one of the two guests from the cage and the formation of a 1:1 cage/Z-arylazopyrazole inclusion complex. DFT calculations suggest that this process involves a dramatic change in the conformation of the cage. Back-isomerization was induced with green light and resulted in the initial 1:2 cage/E-arylazopyrazole complex. This back-isomerization reaction also proceeded in the dark, with a rate significantly higher than in the absence of the cage.","lang":"eng"}]},{"pmid":1,"_id":"13379","scopus_import":"1","author":[{"full_name":"Bléger, David","first_name":"David","last_name":"Bléger"},{"full_name":"Klajn, Rafal","last_name":"Klajn","first_name":"Rafal","id":"8e84690e-1e48-11ed-a02b-a1e6fb8bb53b"}],"issue":"1","publication_status":"published","date_created":"2023-08-01T09:40:48Z","article_processing_charge":"No","title":"Integrating macromolecules with molecular switches","intvolume":"        39","quality_controlled":"1","publisher":"Wiley","article_type":"letter_note","date_updated":"2023-08-07T11:16:49Z","year":"2018","citation":{"ieee":"D. Bléger and R. Klajn, “Integrating macromolecules with molecular switches,” <i>Macromolecular Rapid Communications</i>, vol. 39, no. 1. Wiley, 2018.","chicago":"Bléger, David, and Rafal Klajn. “Integrating Macromolecules with Molecular Switches.” <i>Macromolecular Rapid Communications</i>. Wiley, 2018. <a href=\"https://doi.org/10.1002/marc.201700827\">https://doi.org/10.1002/marc.201700827</a>.","ama":"Bléger D, Klajn R. Integrating macromolecules with molecular switches. <i>Macromolecular Rapid Communications</i>. 2018;39(1). doi:<a href=\"https://doi.org/10.1002/marc.201700827\">10.1002/marc.201700827</a>","apa":"Bléger, D., &#38; Klajn, R. (2018). Integrating macromolecules with molecular switches. <i>Macromolecular Rapid Communications</i>. Wiley. <a href=\"https://doi.org/10.1002/marc.201700827\">https://doi.org/10.1002/marc.201700827</a>","ista":"Bléger D, Klajn R. 2018. Integrating macromolecules with molecular switches. Macromolecular Rapid Communications. 39(1), 1700827.","mla":"Bléger, David, and Rafal Klajn. “Integrating Macromolecules with Molecular Switches.” <i>Macromolecular Rapid Communications</i>, vol. 39, no. 1, 1700827, Wiley, 2018, doi:<a href=\"https://doi.org/10.1002/marc.201700827\">10.1002/marc.201700827</a>.","short":"D. Bléger, R. Klajn, Macromolecular Rapid Communications 39 (2018)."},"external_id":{"pmid":["29314396"]},"doi":"10.1002/marc.201700827","day":"08","volume":39,"extern":"1","publication":"Macromolecular Rapid Communications","oa_version":"Published Version","month":"01","article_number":"1700827","language":[{"iso":"eng"}],"keyword":["Materials Chemistry","Polymers and Plastics","Organic Chemistry"],"date_published":"2018-01-08T00:00:00Z","type":"journal_article","publication_identifier":{"issn":["1022-1336"],"eissn":["1521-3927"]},"oa":1,"main_file_link":[{"open_access":"1","url":"https://doi.org/10.1002/marc.201700827"}],"user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","status":"public"},{"publication":"ChemPhotoChem","oa_version":"None","month":"05","keyword":["Organic Chemistry","Physical and Theoretical Chemistry","Analytical Chemistry"],"language":[{"iso":"eng"}],"type":"journal_article","date_published":"2017-05-01T00:00:00Z","publication_identifier":{"eissn":["2367-0932"]},"user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","status":"public","scopus_import":"1","_id":"13383","issue":"5","author":[{"first_name":"Johannes","last_name":"Ahrens","full_name":"Ahrens, Johannes"},{"first_name":"Tong","last_name":"Bian","full_name":"Bian, Tong"},{"first_name":"Tom","last_name":"Vexler","full_name":"Vexler, Tom"},{"last_name":"Klajn","first_name":"Rafal","full_name":"Klajn, Rafal","id":"8e84690e-1e48-11ed-a02b-a1e6fb8bb53b"}],"article_processing_charge":"No","date_created":"2023-08-01T09:41:43Z","publication_status":"published","intvolume":"         1","title":"Irreversible bleaching of donor-acceptor stenhouse adducts on the surfaces of magnetite nanoparticles","quality_controlled":"1","page":"230-236","publisher":"Wiley","article_type":"original","year":"2017","citation":{"ieee":"J. Ahrens, T. Bian, T. Vexler, and R. Klajn, “Irreversible bleaching of donor-acceptor stenhouse adducts on the surfaces of magnetite nanoparticles,” <i>ChemPhotoChem</i>, vol. 1, no. 5. Wiley, pp. 230–236, 2017.","chicago":"Ahrens, Johannes, Tong Bian, Tom Vexler, and Rafal Klajn. “Irreversible Bleaching of Donor-Acceptor Stenhouse Adducts on the Surfaces of Magnetite Nanoparticles.” <i>ChemPhotoChem</i>. Wiley, 2017. <a href=\"https://doi.org/10.1002/cptc.201700009\">https://doi.org/10.1002/cptc.201700009</a>.","apa":"Ahrens, J., Bian, T., Vexler, T., &#38; Klajn, R. (2017). Irreversible bleaching of donor-acceptor stenhouse adducts on the surfaces of magnetite nanoparticles. <i>ChemPhotoChem</i>. Wiley. <a href=\"https://doi.org/10.1002/cptc.201700009\">https://doi.org/10.1002/cptc.201700009</a>","ama":"Ahrens J, Bian T, Vexler T, Klajn R. Irreversible bleaching of donor-acceptor stenhouse adducts on the surfaces of magnetite nanoparticles. <i>ChemPhotoChem</i>. 2017;1(5):230-236. doi:<a href=\"https://doi.org/10.1002/cptc.201700009\">10.1002/cptc.201700009</a>","ista":"Ahrens J, Bian T, Vexler T, Klajn R. 2017. Irreversible bleaching of donor-acceptor stenhouse adducts on the surfaces of magnetite nanoparticles. ChemPhotoChem. 1(5), 230–236.","short":"J. Ahrens, T. Bian, T. Vexler, R. Klajn, ChemPhotoChem 1 (2017) 230–236.","mla":"Ahrens, Johannes, et al. “Irreversible Bleaching of Donor-Acceptor Stenhouse Adducts on the Surfaces of Magnetite Nanoparticles.” <i>ChemPhotoChem</i>, vol. 1, no. 5, Wiley, 2017, pp. 230–36, doi:<a href=\"https://doi.org/10.1002/cptc.201700009\">10.1002/cptc.201700009</a>."},"date_updated":"2023-08-07T12:08:05Z","day":"01","doi":"10.1002/cptc.201700009","abstract":[{"lang":"eng","text":"Two novel donor–acceptor Stenhouse adducts (DASAs) featuring the catechol moiety were synthesized and characterized. Both compounds bind strongly to the surfaces of magnetite nanoparticles. An adrenaline-derived DASA renders the particles insoluble in all common solvents, likely because of poor solvation of the zwitterionic isomer generated on the nanoparticle surfaces. Well-soluble nanoparticles were successfully obtained using dopamine-derived DASA equipped with a long alkyl chain. Upon its attachment to nanoparticles, this DASA undergoes an irreversible decoloration reaction owing to the formation of the zwitterionic form. The reaction follows first-order kinetics and proceeds more rapidly on large nanoparticles. Interestingly, decoloration can be suppressed in the presence of free DASA molecules in solution or at high nanoparticle concentrations."}],"volume":1,"extern":"1"},{"publisher":"Georg Thieme Verlag","article_type":"original","page":"2370-2374","quality_controlled":"1","publication_status":"published","date_created":"2023-08-01T09:47:17Z","article_processing_charge":"No","title":"Photocontrol of electrical conductance with a nonsymmetrical azobenzene dithiol","intvolume":"        24","_id":"13405","scopus_import":"1","author":[{"full_name":"Ely, Tal","first_name":"Tal","last_name":"Ely"},{"first_name":"Sanjib","last_name":"Das","full_name":"Das, Sanjib"},{"last_name":"Li","first_name":"Wenjie","full_name":"Li, Wenjie"},{"last_name":"Kundu","first_name":"Pintu","full_name":"Kundu, Pintu"},{"last_name":"Tirosh","first_name":"Einat","full_name":"Tirosh, Einat"},{"full_name":"Cahen, David","last_name":"Cahen","first_name":"David"},{"full_name":"Vilan, Ayelet","last_name":"Vilan","first_name":"Ayelet"},{"last_name":"Klajn","first_name":"Rafal","full_name":"Klajn, Rafal","id":"8e84690e-1e48-11ed-a02b-a1e6fb8bb53b"}],"issue":"18","volume":24,"extern":"1","doi":"10.1055/s-0033-1340087","day":"22","abstract":[{"lang":"eng","text":"We report a method for preparing electrode–molecule–electrode junctions that incorporate nonsymmetrical azobenzene dithiols. Our approach is based on sequential deprotection of thiol moieties originally carrying two different protecting groups. The azobenzene derivatives retained their switching properties within monolayers and permitted the photocontrol of electrical conductance."}],"date_updated":"2023-08-08T07:47:35Z","year":"2013","citation":{"mla":"Ely, Tal, et al. “Photocontrol of Electrical Conductance with a Nonsymmetrical Azobenzene Dithiol.” <i>Synlett</i>, vol. 24, no. 18, Georg Thieme Verlag, 2013, pp. 2370–74, doi:<a href=\"https://doi.org/10.1055/s-0033-1340087\">10.1055/s-0033-1340087</a>.","short":"T. Ely, S. Das, W. Li, P. Kundu, E. Tirosh, D. Cahen, A. Vilan, R. Klajn, Synlett 24 (2013) 2370–2374.","ista":"Ely T, Das S, Li W, Kundu P, Tirosh E, Cahen D, Vilan A, Klajn R. 2013. Photocontrol of electrical conductance with a nonsymmetrical azobenzene dithiol. Synlett. 24(18), 2370–2374.","ama":"Ely T, Das S, Li W, et al. Photocontrol of electrical conductance with a nonsymmetrical azobenzene dithiol. <i>Synlett</i>. 2013;24(18):2370-2374. doi:<a href=\"https://doi.org/10.1055/s-0033-1340087\">10.1055/s-0033-1340087</a>","apa":"Ely, T., Das, S., Li, W., Kundu, P., Tirosh, E., Cahen, D., … Klajn, R. (2013). Photocontrol of electrical conductance with a nonsymmetrical azobenzene dithiol. <i>Synlett</i>. Georg Thieme Verlag. <a href=\"https://doi.org/10.1055/s-0033-1340087\">https://doi.org/10.1055/s-0033-1340087</a>","ieee":"T. Ely <i>et al.</i>, “Photocontrol of electrical conductance with a nonsymmetrical azobenzene dithiol,” <i>Synlett</i>, vol. 24, no. 18. Georg Thieme Verlag, pp. 2370–2374, 2013.","chicago":"Ely, Tal, Sanjib Das, Wenjie Li, Pintu Kundu, Einat Tirosh, David Cahen, Ayelet Vilan, and Rafal Klajn. “Photocontrol of Electrical Conductance with a Nonsymmetrical Azobenzene Dithiol.” <i>Synlett</i>. Georg Thieme Verlag, 2013. <a href=\"https://doi.org/10.1055/s-0033-1340087\">https://doi.org/10.1055/s-0033-1340087</a>."},"language":[{"iso":"eng"}],"keyword":["Organic Chemistry"],"oa_version":"None","month":"10","publication":"Synlett","status":"public","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","publication_identifier":{"issn":["0936-5214"],"eissn":["1437-2096"]},"date_published":"2013-10-22T00:00:00Z","type":"journal_article"},{"main_file_link":[{"url":"https://pubs.acs.org/doi/10.1021/om700916f"}],"status":"public","user_id":"8b945eb4-e2f2-11eb-945a-df72226e66a9","type":"journal_article","date_published":"2008-01-15T00:00:00Z","publication_identifier":{"eissn":["1520-6041"],"issn":["0276-7333"]},"keyword":["Inorganic Chemistry","Organic Chemistry","Physical and Theoretical Chemistry"],"language":[{"iso":"eng"}],"publication":"Organometallics","oa_version":"None","month":"01","acknowledgement":"M.B. wishes to thank Prof. W. Thiel and the Max-Planck-Institut für Kohlenforschung for continuing support. A Humboldt fellowship for V.V. is gratefully acknowledged. Computations were performed on Compaq XP1000 and ES40 workstations as well as on an Intel Xeon PC cluster at the MPI Mülheim. A.S. thanks the Computing Center of the University of Zagreb SRCE for allocating computer time on the Isabella cluster.","volume":27,"extern":"1","year":"2008","citation":{"ista":"Šarić A, Vrček V, Bühl M. 2008. Density functional study of protonated formylmetallocenes. Organometallics. 27(3), 394–401.","short":"A. Šarić, V. Vrček, M. Bühl, Organometallics 27 (2008) 394–401.","mla":"Šarić, Anđela, et al. “Density Functional Study of Protonated Formylmetallocenes.” <i>Organometallics</i>, vol. 27, no. 3, American Chemical Society, 2008, pp. 394–401, doi:<a href=\"https://doi.org/10.1021/om700916f\">10.1021/om700916f</a>.","chicago":"Šarić, Anđela, Valerije Vrček, and Michael Bühl. “Density Functional Study of Protonated Formylmetallocenes.” <i>Organometallics</i>. American Chemical Society, 2008. <a href=\"https://doi.org/10.1021/om700916f\">https://doi.org/10.1021/om700916f</a>.","ieee":"A. Šarić, V. Vrček, and M. Bühl, “Density functional study of protonated formylmetallocenes,” <i>Organometallics</i>, vol. 27, no. 3. American Chemical Society, pp. 394–401, 2008.","ama":"Šarić A, Vrček V, Bühl M. Density functional study of protonated formylmetallocenes. <i>Organometallics</i>. 2008;27(3):394-401. doi:<a href=\"https://doi.org/10.1021/om700916f\">10.1021/om700916f</a>","apa":"Šarić, A., Vrček, V., &#38; Bühl, M. (2008). Density functional study of protonated formylmetallocenes. <i>Organometallics</i>. American Chemical Society. <a href=\"https://doi.org/10.1021/om700916f\">https://doi.org/10.1021/om700916f</a>"},"date_updated":"2021-11-30T08:04:44Z","day":"15","doi":"10.1021/om700916f","abstract":[{"text":"Protonated formylmetallocenes [M(C5H5)(C5H4-CHOH)]+ (M = Fe, Ru) and their isomers have been studied at the BP86 and B3LYP levels of density functional theory. Oxygen-protonated isomers are the most stable forms in each case, with a plethora of ring- or metal-protonated species at least ca. 14 and 10 kcal/mol higher in energy for M = Fe and Ru, respectively. The computed rotational barriers around the C−C bond connecting the cyclopentadienyl and protonated formyl moieties, ca. 18 kcal/mol, are indicative of substantial conjugation between these moieties. Some of the ring- and iron-protonated species are models for possible intermediates in Friedel–Crafts acylation of ferrocene, and the computations provide further evidence that exo attack is clearly favored over endo attack of the electrophile in this reaction. The structures of the most stable mono- and diprotonated formylferrocenes are corroborated by the good agreement between GIAO-B3LYP-computed and experimental NMR chemical shifts.","lang":"eng"}],"quality_controlled":"1","page":"394-401","publisher":"American Chemical Society","article_type":"original","scopus_import":"1","_id":"10392","issue":"3","author":[{"full_name":"Šarić, Anđela","orcid":"0000-0002-7854-2139","last_name":"Šarić","first_name":"Anđela","id":"bf63d406-f056-11eb-b41d-f263a6566d8b"},{"full_name":"Vrček, Valerije","last_name":"Vrček","first_name":"Valerije"},{"first_name":"Michael","last_name":"Bühl","full_name":"Bühl, Michael"}],"date_created":"2021-11-29T15:31:06Z","article_processing_charge":"No","publication_status":"published","intvolume":"        27","title":"Density functional study of protonated formylmetallocenes"},{"oa_version":"None","month":"12","publication":"Current Organic Chemistry","language":[{"iso":"eng"}],"keyword":["Organic Chemistry"],"publication_identifier":{"eissn":["1875-5348"],"issn":["1385-2728"]},"date_published":"2005-12-01T00:00:00Z","type":"journal_article","status":"public","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","publication_status":"published","date_created":"2023-08-01T10:38:58Z","article_processing_charge":"No","title":"Applications, properties and synthesis of w-functionalized n-alkanethiols and disulfides - the building blocks of self-assembled monolayers","intvolume":"         8","_id":"13433","scopus_import":"1","author":[{"full_name":"Witt, Dariusz","first_name":"Dariusz","last_name":"Witt"},{"first_name":"Rafal","last_name":"Klajn","full_name":"Klajn, Rafal","id":"8e84690e-1e48-11ed-a02b-a1e6fb8bb53b"},{"last_name":"Barski","first_name":"Piotr","full_name":"Barski, Piotr"},{"last_name":"Grzybowski","first_name":"Bartosz","full_name":"Grzybowski, Bartosz"}],"issue":"18","publisher":"Bentham Science","article_type":"original","page":"1763-1797","quality_controlled":"1","doi":"10.2174/1385272043369421","day":"01","abstract":[{"text":"Self-assembled monolayers (SAMs) of alkane thiols on gold and other metals are versatile constructs with which to study interfacial phenomena and reactions at surfaces. Surface properties of SAMs - e.g., wettability, stability in diverse environments, propensity to interact with or to resist adsorption of macromolecules -- depend on and can be controlled flexibly by the properties of the functional (head) groups in the w position of the alkyl chain. SAMs provide a basis for many important scientific and technological applications, ranging from micropatterning methods, through sensing, to biological recognition. Despite their importance, the literature on SAMs and the synthesis of molecules that constitute them remains scattered and often conflicting. The purpose of this Review is (i) to summarize the applications and physical properties of SAMs and (ii) to systematize the strategies of synthesis of ω-functionalized alkane thiols. Generic retrosynthetic scheme is developed that allows efficient synthetic planning. Issues related to the selection of appropriate protecting groups and the ways of introduction of the thiol functionality are discussed in detail, and illustrated with examples of syntheses of several complex alkane thiols.","lang":"eng"}],"date_updated":"2023-08-08T12:39:52Z","year":"2005","citation":{"ieee":"D. Witt, R. Klajn, P. Barski, and B. Grzybowski, “Applications, properties and synthesis of w-functionalized n-alkanethiols and disulfides - the building blocks of self-assembled monolayers,” <i>Current Organic Chemistry</i>, vol. 8, no. 18. Bentham Science, pp. 1763–1797, 2005.","chicago":"Witt, Dariusz, Rafal Klajn, Piotr Barski, and Bartosz Grzybowski. “Applications, Properties and Synthesis of w-Functionalized n-Alkanethiols and Disulfides - the Building Blocks of Self-Assembled Monolayers.” <i>Current Organic Chemistry</i>. Bentham Science, 2005. <a href=\"https://doi.org/10.2174/1385272043369421\">https://doi.org/10.2174/1385272043369421</a>.","ama":"Witt D, Klajn R, Barski P, Grzybowski B. Applications, properties and synthesis of w-functionalized n-alkanethiols and disulfides - the building blocks of self-assembled monolayers. <i>Current Organic Chemistry</i>. 2005;8(18):1763-1797. doi:<a href=\"https://doi.org/10.2174/1385272043369421\">10.2174/1385272043369421</a>","apa":"Witt, D., Klajn, R., Barski, P., &#38; Grzybowski, B. (2005). Applications, properties and synthesis of w-functionalized n-alkanethiols and disulfides - the building blocks of self-assembled monolayers. <i>Current Organic Chemistry</i>. Bentham Science. <a href=\"https://doi.org/10.2174/1385272043369421\">https://doi.org/10.2174/1385272043369421</a>","ista":"Witt D, Klajn R, Barski P, Grzybowski B. 2005. Applications, properties and synthesis of w-functionalized n-alkanethiols and disulfides - the building blocks of self-assembled monolayers. Current Organic Chemistry. 8(18), 1763–1797.","short":"D. Witt, R. Klajn, P. Barski, B. Grzybowski, Current Organic Chemistry 8 (2005) 1763–1797.","mla":"Witt, Dariusz, et al. “Applications, Properties and Synthesis of w-Functionalized n-Alkanethiols and Disulfides - the Building Blocks of Self-Assembled Monolayers.” <i>Current Organic Chemistry</i>, vol. 8, no. 18, Bentham Science, 2005, pp. 1763–97, doi:<a href=\"https://doi.org/10.2174/1385272043369421\">10.2174/1385272043369421</a>."},"volume":8,"extern":"1"},{"keyword":["Organic Chemistry","Drug Discovery","Biochemistry"],"language":[{"iso":"eng"}],"oa_version":"None","month":"06","publication":"Tetrahedron","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","status":"public","publication_identifier":{"issn":["0040-4020"],"eissn":["1464-5416"]},"type":"journal_article","date_published":"2003-06-16T00:00:00Z","publisher":"Elsevier","article_type":"original","quality_controlled":"1","page":"4525-4531","date_created":"2023-08-01T10:39:34Z","article_processing_charge":"No","publication_status":"published","intvolume":"        59","title":"Cross-metathesis reaction of vinyl sulfones and sulfoxides","scopus_import":"1","_id":"13436","issue":"25","author":[{"full_name":"Michrowska, Anna","first_name":"Anna","last_name":"Michrowska"},{"full_name":"Bieniek, Michał","first_name":"Michał","last_name":"Bieniek"},{"first_name":"Mikhail","last_name":"Kim","full_name":"Kim, Mikhail"},{"id":"8e84690e-1e48-11ed-a02b-a1e6fb8bb53b","first_name":"Rafal","last_name":"Klajn","full_name":"Klajn, Rafal"},{"last_name":"Grela","first_name":"Karol","full_name":"Grela, Karol"}],"volume":59,"extern":"1","day":"16","doi":"10.1016/s0040-4020(03)00682-3","abstract":[{"text":"Cross-metathesis reactions of α,β-unsaturated sulfones and sulfoxides in the presence of molybdenum and ruthenium pre-catalysts were tested. A selective metahesis reaction was achieved between functionalized terminal olefins and vinyl sulfones by using the ‘second generation’ ruthenium catalysts 1c–h while the highly active Schrock catalyst 1b was found to be functional group incompatible with vinyl sulfones. The cross-metathesis products were isolated in good yields with an excellent (E)-selectivity. Both the molybdenum and ruthenium-based complexes were, however, incompatible with α,β- and β,γ-unsaturated sulfoxides.","lang":"eng"}],"citation":{"ista":"Michrowska A, Bieniek M, Kim M, Klajn R, Grela K. 2003. Cross-metathesis reaction of vinyl sulfones and sulfoxides. Tetrahedron. 59(25), 4525–4531.","mla":"Michrowska, Anna, et al. “Cross-Metathesis Reaction of Vinyl Sulfones and Sulfoxides.” <i>Tetrahedron</i>, vol. 59, no. 25, Elsevier, 2003, pp. 4525–31, doi:<a href=\"https://doi.org/10.1016/s0040-4020(03)00682-3\">10.1016/s0040-4020(03)00682-3</a>.","short":"A. Michrowska, M. Bieniek, M. Kim, R. Klajn, K. Grela, Tetrahedron 59 (2003) 4525–4531.","ieee":"A. Michrowska, M. Bieniek, M. Kim, R. Klajn, and K. Grela, “Cross-metathesis reaction of vinyl sulfones and sulfoxides,” <i>Tetrahedron</i>, vol. 59, no. 25. Elsevier, pp. 4525–4531, 2003.","chicago":"Michrowska, Anna, Michał Bieniek, Mikhail Kim, Rafal Klajn, and Karol Grela. “Cross-Metathesis Reaction of Vinyl Sulfones and Sulfoxides.” <i>Tetrahedron</i>. Elsevier, 2003. <a href=\"https://doi.org/10.1016/s0040-4020(03)00682-3\">https://doi.org/10.1016/s0040-4020(03)00682-3</a>.","apa":"Michrowska, A., Bieniek, M., Kim, M., Klajn, R., &#38; Grela, K. (2003). Cross-metathesis reaction of vinyl sulfones and sulfoxides. <i>Tetrahedron</i>. Elsevier. <a href=\"https://doi.org/10.1016/s0040-4020(03)00682-3\">https://doi.org/10.1016/s0040-4020(03)00682-3</a>","ama":"Michrowska A, Bieniek M, Kim M, Klajn R, Grela K. Cross-metathesis reaction of vinyl sulfones and sulfoxides. <i>Tetrahedron</i>. 2003;59(25):4525-4531. doi:<a href=\"https://doi.org/10.1016/s0040-4020(03)00682-3\">10.1016/s0040-4020(03)00682-3</a>"},"year":"2003","date_updated":"2023-08-08T12:44:17Z"},{"user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","status":"public","publication_identifier":{"issn":["0936-5214"],"eissn":["1437-2096"]},"type":"journal_article","date_published":"2000-12-01T00:00:00Z","keyword":["Organic Chemistry"],"language":[{"iso":"eng"}],"oa_version":"None","month":"12","publication":"Synlett","volume":2000,"extern":"1","day":"01","doi":"10.1055/s-2000-8670","abstract":[{"text":"Liquid/liquid Phase Transfer Catalysis (PTC) reaction of 4-chlorobutyronitrile with nonenolisable aldehydes leads via an addition-cyclisation reaction sequence to derivatives of tetrahydrofuran-3-carbonitrile.","lang":"eng"}],"year":"2000","citation":{"short":"M. Macogonkosza, J. Przyborowski, R. Klajn, A. Kwast, Synlett 2000 (2000) 1773–1774.","mla":"Macogonkosza, Mieczysław, et al. “Simple Synthesis of 2-Substituted Tetrahydrofuran-3-Carbonitriles.” <i>Synlett</i>, vol. 2000, no. 12, Georg Thieme Verlag, 2000, pp. 1773–74, doi:<a href=\"https://doi.org/10.1055/s-2000-8670\">10.1055/s-2000-8670</a>.","ista":"Macogonkosza M, Przyborowski J, Klajn R, Kwast A. 2000. Simple synthesis of 2-substituted Tetrahydrofuran-3-carbonitriles. Synlett. 2000(12), 1773–1774.","ama":"Macogonkosza M, Przyborowski J, Klajn R, Kwast A. Simple synthesis of 2-substituted Tetrahydrofuran-3-carbonitriles. <i>Synlett</i>. 2000;2000(12):1773-1774. doi:<a href=\"https://doi.org/10.1055/s-2000-8670\">10.1055/s-2000-8670</a>","apa":"Macogonkosza, M., Przyborowski, J., Klajn, R., &#38; Kwast, A. (2000). Simple synthesis of 2-substituted Tetrahydrofuran-3-carbonitriles. <i>Synlett</i>. Georg Thieme Verlag. <a href=\"https://doi.org/10.1055/s-2000-8670\">https://doi.org/10.1055/s-2000-8670</a>","ieee":"M. Macogonkosza, J. Przyborowski, R. Klajn, and A. Kwast, “Simple synthesis of 2-substituted Tetrahydrofuran-3-carbonitriles,” <i>Synlett</i>, vol. 2000, no. 12. Georg Thieme Verlag, pp. 1773–1774, 2000.","chicago":"Macogonkosza, Mieczysław, Jacek Przyborowski, Rafal Klajn, and Andrzej Kwast. “Simple Synthesis of 2-Substituted Tetrahydrofuran-3-Carbonitriles.” <i>Synlett</i>. Georg Thieme Verlag, 2000. <a href=\"https://doi.org/10.1055/s-2000-8670\">https://doi.org/10.1055/s-2000-8670</a>."},"date_updated":"2023-08-02T07:54:46Z","publisher":"Georg Thieme Verlag","article_type":"letter_note","quality_controlled":"1","page":"1773-1774","date_created":"2023-08-01T10:39:48Z","article_processing_charge":"No","publication_status":"published","intvolume":"      2000","title":"Simple synthesis of 2-substituted Tetrahydrofuran-3-carbonitriles","scopus_import":"1","_id":"13437","issue":"12","author":[{"first_name":"Mieczysław","last_name":"Macogonkosza","full_name":"Macogonkosza, Mieczysław"},{"full_name":"Przyborowski, Jacek","first_name":"Jacek","last_name":"Przyborowski"},{"id":"8e84690e-1e48-11ed-a02b-a1e6fb8bb53b","full_name":"Klajn, Rafal","last_name":"Klajn","first_name":"Rafal"},{"full_name":"Kwast, Andrzej","first_name":"Andrzej","last_name":"Kwast"}]}]