@unpublished{9980,
  abstract     = {Insufficient understanding of the mechanism that reversibly converts sulphur into lithium sulphide (Li2S) via soluble polysulphides (PS) hampers the realization of high performance lithium-sulphur cells. Typically Li2S formation is explained by direct electroreduction of a PS to Li2S; however, this is not consistent with the size of the insulating Li2S deposits. Here, we use in situ small and wide angle X-ray scattering (SAXS/WAXS) to track the growth and dissolution of crystalline and amorphous deposits from atomic to sub-micron scales during charge and discharge. Stochastic modelling based on the SAXS data allows quantification of the chemical phase evolution during discharge and charge. We show that Li2S deposits predominantly via disproportionation of transient, solid Li2S2 to form primary Li2S crystallites and solid Li2S4 particles. We further demonstrate that this process happens in reverse during charge. These findings show that the discharge capacity and rate capability in Li-S battery cathodes are therefore limited by mass transport through the increasingly tortuous network of Li2S / Li2S4 / carbon pores rather than electron transport through a passivating surface film.},
  author       = {Prehal, Christian and Talian, Sara Drvarič and Vizintin, Alen and Amenitsch, Heinz and Dominko, Robert and Freunberger, Stefan Alexander and Wood, Vanessa},
  booktitle    = {Research Square},
  keywords     = {Li2S, Lithium Sulphur Batteries, SAXS, WAXS},
  pages        = {21},
  title        = {{Mechanism of Li2S formation and dissolution in Lithium-Sulphur batteries}},
  doi          = {10.21203/rs.3.rs-818607/v1},
  year         = {2021},
}

@misc{8067,
  abstract     = {With the lithium-ion technology approaching its intrinsic limit with graphite-based anodes, lithium metal is recently receiving renewed interest from the battery community as potential high capacity anode for next-generation rechargeable batteries. In this focus paper, we review the main advances in this field since the first attempts in the
mid-1970s. Strategies for enabling reversible cycling and avoiding dendrite growth are thoroughly discussed, including specific applications in all-solid-state (polymeric and inorganic), Lithium-sulphur and Li-O2 (air) batteries. A particular attention is paid to review recent developments in regard of prototype manufacturing and current state-ofthe-art of these battery technologies with respect to the 2030 targets of the EU Integrated Strategic Energy Technology Plan (SET-Plan) Action 7.},
  author       = {Varzi, Alberto and Thanner, Katharina and Scipioni, Roberto and Di Lecce, Daniele and Hassoun, Jusef and Dörfler, Susanne and Altheus, Holger and Kaskel, Stefan and Prehal, Christian and Freunberger, Stefan Alexander},
  issn         = {2664-1690},
  keywords     = {Battery, Lithium metal, Lithium-sulphur, Lithium-air, All-solid-state},
  pages        = {63},
  publisher    = {IST Austria},
  title        = {{Current status and future perspectives of Lithium metal batteries}},
  doi          = {10.15479/AT:ISTA:8067},
  year         = {2020},
}