[{"author":[{"last_name":"Madani","first_name":"Amiera","full_name":"Madani, Amiera"},{"orcid":"0000-0001-8689-388X","id":"93e5e5b2-0da6-11ed-8a41-af589a024726","full_name":"Pieber, Bartholomäus","first_name":"Bartholomäus","last_name":"Pieber"}],"user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","volume":15,"oa":1,"intvolume":"        15","date_updated":"2023-05-15T08:35:48Z","publication":"ChemCatChem","scopus_import":"1","main_file_link":[{"url":"https://doi.org/10.1002/cctc.202201583","open_access":"1"}],"doi":"10.1002/cctc.202201583","publication_identifier":{"issn":["1867-3880"],"eissn":["1867-3899"]},"article_type":"original","publication_status":"published","title":"In situ reaction monitoring in photocatalytic organic synthesis","article_processing_charge":"No","oa_version":"Published Version","citation":{"mla":"Madani, Amiera, and Bartholomäus Pieber. “In Situ Reaction Monitoring in Photocatalytic Organic Synthesis.” <i>ChemCatChem</i>, vol. 15, no. 7, e202201583, Wiley, 2023, doi:<a href=\"https://doi.org/10.1002/cctc.202201583\">10.1002/cctc.202201583</a>.","apa":"Madani, A., &#38; Pieber, B. (2023). In situ reaction monitoring in photocatalytic organic synthesis. <i>ChemCatChem</i>. Wiley. <a href=\"https://doi.org/10.1002/cctc.202201583\">https://doi.org/10.1002/cctc.202201583</a>","short":"A. Madani, B. Pieber, ChemCatChem 15 (2023).","chicago":"Madani, Amiera, and Bartholomäus Pieber. “In Situ Reaction Monitoring in Photocatalytic Organic Synthesis.” <i>ChemCatChem</i>. Wiley, 2023. <a href=\"https://doi.org/10.1002/cctc.202201583\">https://doi.org/10.1002/cctc.202201583</a>.","ista":"Madani A, Pieber B. 2023. In situ reaction monitoring in photocatalytic organic synthesis. ChemCatChem. 15(7), e202201583.","ieee":"A. Madani and B. Pieber, “In situ reaction monitoring in photocatalytic organic synthesis,” <i>ChemCatChem</i>, vol. 15, no. 7. Wiley, 2023.","ama":"Madani A, Pieber B. In situ reaction monitoring in photocatalytic organic synthesis. <i>ChemCatChem</i>. 2023;15(7). doi:<a href=\"https://doi.org/10.1002/cctc.202201583\">10.1002/cctc.202201583</a>"},"article_number":"e202201583","year":"2023","abstract":[{"lang":"eng","text":"Visible-light photocatalysis provides numerous useful methodologies for synthetic organic chemistry. However, the mechanisms of these reactions are often not fully understood. Common mechanistic experiments mainly aim to characterize excited state properties of photocatalysts and their interaction with other species. Recently, in situ reaction monitoring using dedicated techniques was shown to be well-suited for the identification of intermediates and to obtain kinetic insights, thereby providing more holistic pictures of the reactions of interest. This minireview surveys these technologies and discusses selected examples where reaction monitoring was used to elucidate the mechanism of photocatalytic reactions."}],"date_created":"2023-05-08T08:25:55Z","_id":"12921","publisher":"Wiley","type":"journal_article","date_published":"2023-04-06T00:00:00Z","language":[{"iso":"eng"}],"extern":"1","keyword":["Inorganic Chemistry","Organic Chemistry","Physical and Theoretical Chemistry","Catalysis"],"month":"04","status":"public","day":"06","quality_controlled":"1","issue":"7"},{"issue":"22","tmp":{"name":"Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)","image":"/images/cc_by.png","legal_code_url":"https://creativecommons.org/licenses/by/4.0/legalcode","short":"CC BY (4.0)"},"has_accepted_license":"1","quality_controlled":"1","day":"01","isi":1,"month":"11","status":"public","ddc":["580"],"language":[{"iso":"eng"}],"keyword":["Inorganic Chemistry","Organic Chemistry","Physical and Theoretical Chemistry","Computer Science Applications","Spectroscopy","Molecular Biology","General Medicine","Catalysis"],"type":"journal_article","date_published":"2023-11-01T00:00:00Z","external_id":{"isi":["001113792600001"],"pmid":["38003717"]},"pmid":1,"publisher":"MDPI","date_created":"2024-01-10T09:24:35Z","file":[{"checksum":"4df7d206ba022b7f54eff1f0aec1659a","file_id":"14791","creator":"dernst","content_type":"application/pdf","file_size":2637784,"date_created":"2024-01-10T13:39:42Z","date_updated":"2024-01-10T13:39:42Z","relation":"main_file","file_name":"2023_IJMS_Teplova.pdf","access_level":"open_access","success":1}],"_id":"14776","citation":{"short":"A. Teplova, A.A. Pigidanov, M.V. Serebryakova, S.A. Golyshev, R.A. Galiullina, N.V. Chichkova, A.B. Vartapetian, International Journal of Molecular Sciences 24 (2023).","chicago":"Teplova, Anastasiia, Artemii A. Pigidanov, Marina V. Serebryakova, Sergei A. Golyshev, Raisa A. Galiullina, Nina V. Chichkova, and Andrey B. Vartapetian. “Phytaspase Is Capable of Detaching the Endoplasmic Reticulum Retrieval Signal from Tobacco Calreticulin-3.” <i>International Journal of Molecular Sciences</i>. MDPI, 2023. <a href=\"https://doi.org/10.3390/ijms242216527\">https://doi.org/10.3390/ijms242216527</a>.","apa":"Teplova, A., Pigidanov, A. A., Serebryakova, M. V., Golyshev, S. A., Galiullina, R. A., Chichkova, N. V., &#38; Vartapetian, A. B. (2023). Phytaspase Is capable of detaching the endoplasmic reticulum retrieval signal from tobacco calreticulin-3. <i>International Journal of Molecular Sciences</i>. MDPI. <a href=\"https://doi.org/10.3390/ijms242216527\">https://doi.org/10.3390/ijms242216527</a>","mla":"Teplova, Anastasiia, et al. “Phytaspase Is Capable of Detaching the Endoplasmic Reticulum Retrieval Signal from Tobacco Calreticulin-3.” <i>International Journal of Molecular Sciences</i>, vol. 24, no. 22, 16527, MDPI, 2023, doi:<a href=\"https://doi.org/10.3390/ijms242216527\">10.3390/ijms242216527</a>.","ama":"Teplova A, Pigidanov AA, Serebryakova MV, et al. Phytaspase Is capable of detaching the endoplasmic reticulum retrieval signal from tobacco calreticulin-3. <i>International Journal of Molecular Sciences</i>. 2023;24(22). doi:<a href=\"https://doi.org/10.3390/ijms242216527\">10.3390/ijms242216527</a>","ista":"Teplova A, Pigidanov AA, Serebryakova MV, Golyshev SA, Galiullina RA, Chichkova NV, Vartapetian AB. 2023. Phytaspase Is capable of detaching the endoplasmic reticulum retrieval signal from tobacco calreticulin-3. International Journal of Molecular Sciences. 24(22), 16527.","ieee":"A. Teplova <i>et al.</i>, “Phytaspase Is capable of detaching the endoplasmic reticulum retrieval signal from tobacco calreticulin-3,” <i>International Journal of Molecular Sciences</i>, vol. 24, no. 22. MDPI, 2023."},"article_number":"16527","year":"2023","abstract":[{"text":"Soluble chaperones residing in the endoplasmic reticulum (ER) play vitally important roles in folding and quality control of newly synthesized proteins that transiently pass through the ER en route to their final destinations. These soluble residents of the ER are themselves endowed with an ER retrieval signal that enables the cell to bring the escaped residents back from the Golgi. Here, by using purified proteins, we showed that Nicotiana tabacum phytaspase, a plant aspartate-specific protease, introduces two breaks at the C-terminus of the N. tabacum ER resident calreticulin-3. These cleavages resulted in removal of either a dipeptide or a hexapeptide from the C-terminus of calreticulin-3 encompassing part or all of the ER retrieval signal. Consistently, expression of the calreticulin-3 derivative mimicking the phytaspase cleavage product in Nicotiana benthamiana cells demonstrated loss of the ER accumulation of the protein. Notably, upon its escape from the ER, calreticulin-3 was further processed by an unknown protease(s) to generate the free N-terminal (N) domain of calreticulin-3, which was ultimately secreted into the apoplast. Our study thus identified a specific proteolytic enzyme capable of precise detachment of the ER retrieval signal from a plant ER resident protein, with implications for the further fate of the escaped resident.","lang":"eng"}],"publication_status":"published","title":"Phytaspase Is capable of detaching the endoplasmic reticulum retrieval signal from tobacco calreticulin-3","article_processing_charge":"Yes","oa_version":"Published Version","file_date_updated":"2024-01-10T13:39:42Z","doi":"10.3390/ijms242216527","publication_identifier":{"issn":["1422-0067"]},"acknowledgement":"We thank C.U.T. Hellen for critically reading the manuscript. The MALDI MS facility and CLSM became available to us in the framework of Moscow State University Development Programs PNG 5.13 and PNR 5.13.\r\nThis work was funded by the Russian Science Foundation, grant numbers 19-14-00010 and 22-14-00071.","article_type":"original","department":[{"_id":"JiFr"}],"date_updated":"2024-01-10T13:41:10Z","publication":"International Journal of Molecular Sciences","intvolume":"        24","volume":24,"oa":1,"author":[{"last_name":"Teplova","first_name":"Anastasiia","full_name":"Teplova, Anastasiia","id":"e3736151-106c-11ec-b916-c2558e2762c6"},{"full_name":"Pigidanov, Artemii A.","last_name":"Pigidanov","first_name":"Artemii A."},{"last_name":"Serebryakova","first_name":"Marina V.","full_name":"Serebryakova, Marina V."},{"full_name":"Golyshev, Sergei A.","last_name":"Golyshev","first_name":"Sergei A."},{"first_name":"Raisa A.","last_name":"Galiullina","full_name":"Galiullina, Raisa A."},{"full_name":"Chichkova, Nina V.","first_name":"Nina V.","last_name":"Chichkova"},{"full_name":"Vartapetian, Andrey B.","last_name":"Vartapetian","first_name":"Andrey B."}],"user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87"},{"intvolume":"        27","publication":"Organometallics","date_updated":"2021-11-30T08:04:44Z","author":[{"first_name":"Anđela","last_name":"Šarić","id":"bf63d406-f056-11eb-b41d-f263a6566d8b","orcid":"0000-0002-7854-2139","full_name":"Šarić, Anđela"},{"full_name":"Vrček, Valerije","first_name":"Valerije","last_name":"Vrček"},{"first_name":"Michael","last_name":"Bühl","full_name":"Bühl, Michael"}],"user_id":"8b945eb4-e2f2-11eb-945a-df72226e66a9","volume":27,"year":"2008","citation":{"ista":"Šarić A, Vrček V, Bühl M. 2008. Density functional study of protonated formylmetallocenes. Organometallics. 27(3), 394–401.","ieee":"A. Šarić, V. Vrček, and M. Bühl, “Density functional study of protonated formylmetallocenes,” <i>Organometallics</i>, vol. 27, no. 3. American Chemical Society, pp. 394–401, 2008.","ama":"Šarić A, Vrček V, Bühl M. Density functional study of protonated formylmetallocenes. <i>Organometallics</i>. 2008;27(3):394-401. doi:<a href=\"https://doi.org/10.1021/om700916f\">10.1021/om700916f</a>","mla":"Šarić, Anđela, et al. “Density Functional Study of Protonated Formylmetallocenes.” <i>Organometallics</i>, vol. 27, no. 3, American Chemical Society, 2008, pp. 394–401, doi:<a href=\"https://doi.org/10.1021/om700916f\">10.1021/om700916f</a>.","chicago":"Šarić, Anđela, Valerije Vrček, and Michael Bühl. “Density Functional Study of Protonated Formylmetallocenes.” <i>Organometallics</i>. American Chemical Society, 2008. <a href=\"https://doi.org/10.1021/om700916f\">https://doi.org/10.1021/om700916f</a>.","apa":"Šarić, A., Vrček, V., &#38; Bühl, M. (2008). Density functional study of protonated formylmetallocenes. <i>Organometallics</i>. American Chemical Society. <a href=\"https://doi.org/10.1021/om700916f\">https://doi.org/10.1021/om700916f</a>","short":"A. Šarić, V. Vrček, M. Bühl, Organometallics 27 (2008) 394–401."},"abstract":[{"lang":"eng","text":"Protonated formylmetallocenes [M(C5H5)(C5H4-CHOH)]+ (M = Fe, Ru) and their isomers have been studied at the BP86 and B3LYP levels of density functional theory. Oxygen-protonated isomers are the most stable forms in each case, with a plethora of ring- or metal-protonated species at least ca. 14 and 10 kcal/mol higher in energy for M = Fe and Ru, respectively. The computed rotational barriers around the C−C bond connecting the cyclopentadienyl and protonated formyl moieties, ca. 18 kcal/mol, are indicative of substantial conjugation between these moieties. Some of the ring- and iron-protonated species are models for possible intermediates in Friedel–Crafts acylation of ferrocene, and the computations provide further evidence that exo attack is clearly favored over endo attack of the electrophile in this reaction. The structures of the most stable mono- and diprotonated formylferrocenes are corroborated by the good agreement between GIAO-B3LYP-computed and experimental NMR chemical shifts."}],"_id":"10392","date_created":"2021-11-29T15:31:06Z","main_file_link":[{"url":"https://pubs.acs.org/doi/10.1021/om700916f"}],"doi":"10.1021/om700916f","scopus_import":"1","article_type":"original","publication_identifier":{"issn":["0276-7333"],"eissn":["1520-6041"]},"acknowledgement":"M.B. wishes to thank Prof. W. Thiel and the Max-Planck-Institut für Kohlenforschung for continuing support. A Humboldt fellowship for V.V. is gratefully acknowledged. Computations were performed on Compaq XP1000 and ES40 workstations as well as on an Intel Xeon PC cluster at the MPI Mülheim. A.S. thanks the Computing Center of the University of Zagreb SRCE for allocating computer time on the Isabella cluster.","title":"Density functional study of protonated formylmetallocenes","publication_status":"published","article_processing_charge":"No","oa_version":"None","language":[{"iso":"eng"}],"keyword":["Inorganic Chemistry","Organic Chemistry","Physical and Theoretical Chemistry"],"extern":"1","month":"01","status":"public","publisher":"American Chemical Society","date_published":"2008-01-15T00:00:00Z","type":"journal_article","issue":"3","page":"394-401","day":"15","quality_controlled":"1"}]