[{"article_type":"review","date_published":"2023-12-14T00:00:00Z","doi":"10.1002/anie.202316476","year":"2023","month":"12","language":[{"iso":"eng"}],"publisher":"Wiley","title":"To DISP or not? The far‐reaching reaction mechanisms underpinning Lithium‐air batteries","scopus_import":"1","department":[{"_id":"StFr"},{"_id":"GradSch"}],"article_number":"e202316476","main_file_link":[{"url":" https://doi.org/10.1002/anie.202316476","open_access":"1"}],"date_created":"2023-12-15T16:10:13Z","type":"journal_article","publication_status":"epub_ahead","citation":{"chicago":"Jethwa, Rajesh B, Soumyadip Mondal, Bhargavi Pant, and Stefan Alexander Freunberger. “To DISP or Not? The Far‐reaching Reaction Mechanisms Underpinning Lithium‐air Batteries.” <i>Angewandte Chemie International Edition</i>. Wiley, 2023. <a href=\"https://doi.org/10.1002/anie.202316476\">https://doi.org/10.1002/anie.202316476</a>.","ieee":"R. B. Jethwa, S. Mondal, B. Pant, and S. A. Freunberger, “To DISP or not? The far‐reaching reaction mechanisms underpinning Lithium‐air batteries,” <i>Angewandte Chemie International Edition</i>. Wiley, 2023.","apa":"Jethwa, R. B., Mondal, S., Pant, B., &#38; Freunberger, S. A. (2023). To DISP or not? The far‐reaching reaction mechanisms underpinning Lithium‐air batteries. <i>Angewandte Chemie International Edition</i>. Wiley. <a href=\"https://doi.org/10.1002/anie.202316476\">https://doi.org/10.1002/anie.202316476</a>","ista":"Jethwa RB, Mondal S, Pant B, Freunberger SA. 2023. To DISP or not? The far‐reaching reaction mechanisms underpinning Lithium‐air batteries. Angewandte Chemie International Edition., e202316476.","short":"R.B. Jethwa, S. Mondal, B. Pant, S.A. Freunberger, Angewandte Chemie International Edition (2023).","ama":"Jethwa RB, Mondal S, Pant B, Freunberger SA. To DISP or not? The far‐reaching reaction mechanisms underpinning Lithium‐air batteries. <i>Angewandte Chemie International Edition</i>. 2023. doi:<a href=\"https://doi.org/10.1002/anie.202316476\">10.1002/anie.202316476</a>","mla":"Jethwa, Rajesh B., et al. “To DISP or Not? The Far‐reaching Reaction Mechanisms Underpinning Lithium‐air Batteries.” <i>Angewandte Chemie International Edition</i>, e202316476, Wiley, 2023, doi:<a href=\"https://doi.org/10.1002/anie.202316476\">10.1002/anie.202316476</a>."},"day":"14","status":"public","author":[{"first_name":"Rajesh B","last_name":"Jethwa","full_name":"Jethwa, Rajesh B","orcid":"0000-0002-0404-4356","id":"4cc538d5-803f-11ed-ab7e-8139573aad8f"},{"full_name":"Mondal, Soumyadip","last_name":"Mondal","first_name":"Soumyadip","id":"d25d21ef-dc8d-11ea-abe3-ec4576307f48"},{"id":"50c64d4d-eb97-11eb-a6c2-d33e5e14f112","first_name":"Bhargavi","full_name":"Pant, Bhargavi","last_name":"Pant"},{"id":"A8CA28E6-CE23-11E9-AD2D-EC27E6697425","first_name":"Stefan Alexander","full_name":"Freunberger, Stefan Alexander","last_name":"Freunberger","orcid":"0000-0003-2902-5319"}],"keyword":["General Chemistry","Catalysis"],"abstract":[{"lang":"eng","text":"The short history of research on Li-O2 batteries has seen a remarkable number of mechanistic U-turns over the years. From the initial use of carbonate electrolytes, that were then found to be entirely unsuitable, to the belief that (su)peroxide was solely responsible for degradation, before the more reactive singlet oxygen was found to form, to the hypothesis that capacity depends on a competing surface/solution mechanism before a practically exclusive solution mechanism was identified. Herein, we argue for an ever-fresh look at the reported data without bias towards supposedly established explanations. We explain how the latest findings on rate and capacity limits, as well as the origin of side reactions, are connected via the disproportionation (DISP) step in the (dis)charge mechanism. Therefrom, directions emerge for the design of electrolytes and mediators on how to suppress side reactions and to enable high rate and high reversible capacity."}],"date_updated":"2024-02-15T14:43:05Z","oa":1,"article_processing_charge":"Yes (via OA deal)","publication":"Angewandte Chemie International Edition","user_id":"3E5EF7F0-F248-11E8-B48F-1D18A9856A87","quality_controlled":"1","oa_version":"Published Version","_id":"14687","publication_identifier":{"eissn":["1521-3773"],"issn":["1433-7851"]}},{"article_processing_charge":"No","volume":62,"oa":1,"date_updated":"2024-01-23T08:48:14Z","oa_version":"Published Version","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","publication_identifier":{"eissn":["1521-3773"],"issn":["1433-7851"]},"_id":"14861","citation":{"chicago":"Becker, Lea Marie, Mélanie Berbon, Alicia Vallet, Axelle Grelard, Estelle Morvan, Benjamin Bardiaux, Roman Lichtenecker, Matthias Ernst, Antoine Loquet, and Paul Schanda. <i>Cover Picture: The Rigid Core and Flexible Surface of Amyloid Fibrils Probed by Magic‐Angle‐Spinning NMR Spectroscopy of Aromatic Residues</i>. <i>Angewandte Chemie International Edition</i>. Vol. 62. Wiley, 2023. <a href=\"https://doi.org/10.1002/anie.202304138\">https://doi.org/10.1002/anie.202304138</a>.","apa":"Becker, L. M., Berbon, M., Vallet, A., Grelard, A., Morvan, E., Bardiaux, B., … Schanda, P. (2023). <i>Cover Picture: The rigid core and flexible surface of amyloid fibrils probed by Magic‐Angle‐Spinning NMR spectroscopy of aromatic residues</i>. <i>Angewandte Chemie International Edition</i> (Vol. 62). Wiley. <a href=\"https://doi.org/10.1002/anie.202304138\">https://doi.org/10.1002/anie.202304138</a>","ieee":"L. M. Becker <i>et al.</i>, <i>Cover Picture: The rigid core and flexible surface of amyloid fibrils probed by Magic‐Angle‐Spinning NMR spectroscopy of aromatic residues</i>, vol. 62, no. 19. Wiley, 2023.","ista":"Becker LM, Berbon M, Vallet A, Grelard A, Morvan E, Bardiaux B, Lichtenecker R, Ernst M, Loquet A, Schanda P. 2023. Cover Picture: The rigid core and flexible surface of amyloid fibrils probed by Magic‐Angle‐Spinning NMR spectroscopy of aromatic residues, Wiley,p.","short":"L.M. Becker, M. Berbon, A. Vallet, A. Grelard, E. Morvan, B. Bardiaux, R. Lichtenecker, M. Ernst, A. Loquet, P. Schanda, Cover Picture: The Rigid Core and Flexible Surface of Amyloid Fibrils Probed by Magic‐Angle‐Spinning NMR Spectroscopy of Aromatic Residues, Wiley, 2023.","ama":"Becker LM, Berbon M, Vallet A, et al. <i>Cover Picture: The Rigid Core and Flexible Surface of Amyloid Fibrils Probed by Magic‐Angle‐Spinning NMR Spectroscopy of Aromatic Residues</i>. Vol 62. Wiley; 2023. doi:<a href=\"https://doi.org/10.1002/anie.202304138\">10.1002/anie.202304138</a>","mla":"Becker, Lea Marie, et al. “Cover Picture: The Rigid Core and Flexible Surface of Amyloid Fibrils Probed by Magic‐Angle‐Spinning NMR Spectroscopy of Aromatic Residues.” <i>Angewandte Chemie International Edition</i>, vol. 62, no. 19, e202304138, Wiley, 2023, doi:<a href=\"https://doi.org/10.1002/anie.202304138\">10.1002/anie.202304138</a>."},"publication_status":"published","keyword":["General Chemistry","Catalysis"],"author":[{"id":"36336939-eb97-11eb-a6c2-c83f1214ca79","first_name":"Lea Marie","orcid":"0000-0002-6401-5151","last_name":"Becker","full_name":"Becker, Lea Marie"},{"full_name":"Berbon, Mélanie","last_name":"Berbon","first_name":"Mélanie"},{"first_name":"Alicia","last_name":"Vallet","full_name":"Vallet, Alicia"},{"first_name":"Axelle","last_name":"Grelard","full_name":"Grelard, Axelle"},{"full_name":"Morvan, Estelle","last_name":"Morvan","first_name":"Estelle"},{"full_name":"Bardiaux, Benjamin","last_name":"Bardiaux","first_name":"Benjamin"},{"first_name":"Roman","full_name":"Lichtenecker, Roman","last_name":"Lichtenecker"},{"first_name":"Matthias","last_name":"Ernst","full_name":"Ernst, Matthias"},{"first_name":"Antoine","full_name":"Loquet, Antoine","last_name":"Loquet"},{"id":"7B541462-FAF6-11E9-A490-E8DFE5697425","orcid":"0000-0002-9350-7606","last_name":"Schanda","full_name":"Schanda, Paul","first_name":"Paul"}],"abstract":[{"lang":"eng","text":"Cover Page"}],"main_file_link":[{"open_access":"1","url":"https://doi.org/10.1002/anie.202304138"}],"article_number":" e202304138","related_material":{"link":[{"relation":"translation","url":"https://doi.org/10.1002/ange.202304138"}],"record":[{"relation":"other","id":"12675","status":"public"}]},"year":"2023","doi":"10.1002/anie.202304138","title":"Cover Picture: The rigid core and flexible surface of amyloid fibrils probed by Magic‐Angle‐Spinning NMR spectroscopy of aromatic residues","publication":"Angewandte Chemie International Edition","issue":"19","type":"other_academic_publication","day":"02","status":"public","intvolume":"        62","department":[{"_id":"PaSc"}],"date_created":"2024-01-22T11:54:34Z","date_published":"2023-05-02T00:00:00Z","month":"05","language":[{"iso":"eng"}],"publisher":"Wiley"},{"date_updated":"2023-10-11T08:45:10Z","oa":1,"volume":145,"article_processing_charge":"Yes (via OA deal)","pmid":1,"_id":"13216","publication_identifier":{"issn":["0002-7863"],"eissn":["1520-5126"]},"user_id":"8b945eb4-e2f2-11eb-945a-df72226e66a9","acknowledgement":"B.C. acknowledges resources provided by the Cambridge Tier2 system operated by the University of Cambridge Research\r\nComputing Service funded by EPSRC Tier-2 capital grant EP/\r\nP020259/1.","quality_controlled":"1","oa_version":"Published Version","publication_status":"published","citation":{"apa":"Bunting, R., Wodaczek, F., Torabi, T., &#38; Cheng, B. (2023). Reactivity of single-atom alloy nanoparticles: Modeling the dehydrogenation of propane. <i>Journal of the American Chemical Society</i>. American Chemical Society. <a href=\"https://doi.org/10.1021/jacs.3c04030\">https://doi.org/10.1021/jacs.3c04030</a>","ieee":"R. Bunting, F. Wodaczek, T. Torabi, and B. Cheng, “Reactivity of single-atom alloy nanoparticles: Modeling the dehydrogenation of propane,” <i>Journal of the American Chemical Society</i>, vol. 145, no. 27. American Chemical Society, pp. 14894–14902, 2023.","chicago":"Bunting, Rhys, Felix Wodaczek, Tina Torabi, and Bingqing Cheng. “Reactivity of Single-Atom Alloy Nanoparticles: Modeling the Dehydrogenation of Propane.” <i>Journal of the American Chemical Society</i>. American Chemical Society, 2023. <a href=\"https://doi.org/10.1021/jacs.3c04030\">https://doi.org/10.1021/jacs.3c04030</a>.","mla":"Bunting, Rhys, et al. “Reactivity of Single-Atom Alloy Nanoparticles: Modeling the Dehydrogenation of Propane.” <i>Journal of the American Chemical Society</i>, vol. 145, no. 27, American Chemical Society, 2023, pp. 14894–902, doi:<a href=\"https://doi.org/10.1021/jacs.3c04030\">10.1021/jacs.3c04030</a>.","ama":"Bunting R, Wodaczek F, Torabi T, Cheng B. Reactivity of single-atom alloy nanoparticles: Modeling the dehydrogenation of propane. <i>Journal of the American Chemical Society</i>. 2023;145(27):14894-14902. doi:<a href=\"https://doi.org/10.1021/jacs.3c04030\">10.1021/jacs.3c04030</a>","ista":"Bunting R, Wodaczek F, Torabi T, Cheng B. 2023. Reactivity of single-atom alloy nanoparticles: Modeling the dehydrogenation of propane. Journal of the American Chemical Society. 145(27), 14894–14902.","short":"R. Bunting, F. Wodaczek, T. Torabi, B. Cheng, Journal of the American Chemical Society 145 (2023) 14894–14902."},"abstract":[{"text":"Physical catalysts often have multiple sites where reactions can take place. One prominent example is single-atom alloys, where the reactive dopant atoms can preferentially locate in the bulk or at different sites on the surface of the nanoparticle. However, ab initio modeling of catalysts usually only considers one site of the catalyst, neglecting the effects of multiple sites. Here, nanoparticles of copper doped with single-atom rhodium or palladium are modeled for the dehydrogenation of propane. Single-atom alloy nanoparticles are simulated at 400–600 K, using machine learning potentials trained on density functional theory calculations, and then the occupation of different single-atom active sites is identified using a similarity kernel. Further, the turnover frequency for all possible sites is calculated for propane dehydrogenation to propene through microkinetic modeling using density functional theory calculations. The total turnover frequencies of the whole nanoparticle are then described from both the population and the individual turnover frequency of each site. Under operating conditions, rhodium as a dopant is found to almost exclusively occupy (111) surface sites while palladium as a dopant occupies a greater variety of facets. Undercoordinated dopant surface sites are found to tend to be more reactive for propane dehydrogenation compared to the (111) surface. It is found that considering the dynamics of the single-atom alloy nanoparticle has a profound effect on the calculated catalytic activity of single-atom alloys by several orders of magnitude.","lang":"eng"}],"keyword":["Colloid and Surface Chemistry","Biochemistry","General Chemistry","Catalysis"],"author":[{"id":"91deeae8-1207-11ec-b130-c194ad5b50c6","orcid":"0000-0001-6928-074X","full_name":"Bunting, Rhys","last_name":"Bunting","first_name":"Rhys"},{"id":"8b4b6a9f-32b0-11ee-9fa8-bbe85e26258e","first_name":"Felix","full_name":"Wodaczek, Felix","last_name":"Wodaczek","orcid":"0009-0000-1457-795X"},{"last_name":"Torabi","full_name":"Torabi, Tina","first_name":"Tina"},{"first_name":"Bingqing","orcid":"0000-0002-3584-9632","last_name":"Cheng","full_name":"Cheng, Bingqing","id":"cbe3cda4-d82c-11eb-8dc7-8ff94289fcc9"}],"tmp":{"image":"/images/cc_by.png","legal_code_url":"https://creativecommons.org/licenses/by/4.0/legalcode","name":"Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)","short":"CC BY (4.0)"},"isi":1,"ddc":["540"],"doi":"10.1021/jacs.3c04030","year":"2023","title":"Reactivity of single-atom alloy nanoparticles: Modeling the dehydrogenation of propane","external_id":{"isi":["001020623900001"],"pmid":["37390457"]},"issue":"27","publication":"Journal of the American Chemical Society","page":"14894-14902","file_date_updated":"2023-07-12T10:22:04Z","day":"30","type":"journal_article","intvolume":"       145","status":"public","license":"https://creativecommons.org/licenses/by/4.0/","has_accepted_license":"1","department":[{"_id":"MaIb"},{"_id":"BiCh"}],"date_created":"2023-07-12T09:16:40Z","file":[{"date_updated":"2023-07-12T10:22:04Z","access_level":"open_access","date_created":"2023-07-12T10:22:04Z","checksum":"e07d5323f9c0e5cbd1ad6453f29440ab","file_name":"2023_JACS_Bunting.pdf","file_size":3155843,"creator":"cchlebak","file_id":"13219","content_type":"application/pdf","relation":"main_file","success":1}],"month":"06","article_type":"original","date_published":"2023-06-30T00:00:00Z","publisher":"American Chemical Society","language":[{"iso":"eng"}]},{"status":"public","intvolume":"       145","type":"journal_article","day":"09","page":"4098-4108","publication":"Journal of the American Chemical Society","issue":"7","language":[{"iso":"eng"}],"scopus_import":"1","publisher":"American Chemical Society","article_type":"original","date_published":"2023-02-09T00:00:00Z","month":"02","date_created":"2023-08-01T09:33:08Z","keyword":["Colloid and Surface Chemistry","Biochemistry","General Chemistry","Catalysis"],"author":[{"first_name":"Jinhua","full_name":"Wang, Jinhua","last_name":"Wang"},{"first_name":"Tzuf Shay","full_name":"Peled, Tzuf Shay","last_name":"Peled"},{"id":"8e84690e-1e48-11ed-a02b-a1e6fb8bb53b","last_name":"Klajn","full_name":"Klajn, Rafal","first_name":"Rafal"}],"abstract":[{"text":"Integrating light-sensitive molecules within nanoparticle (NP) assemblies is an attractive approach to fabricate new photoresponsive nanomaterials. Here, we describe the concept of photocleavable anionic glue (PAG): small trianions capable of mediating interactions between (and inducing the aggregation of) cationic NPs by means of electrostatic interactions. Exposure to light converts PAGs into dianionic products incapable of maintaining the NPs in an assembled state, resulting in light-triggered disassembly of NP aggregates. To demonstrate the proof-of-concept, we work with an organic PAG incorporating the UV-cleavable o-nitrobenzyl moiety and an inorganic PAG, the photosensitive trioxalatocobaltate(III) complex, which absorbs light across the entire visible spectrum. Both PAGs were used to prepare either amorphous NP assemblies or regular superlattices with a long-range NP order. These NP aggregates disassembled rapidly upon light exposure for a specific time, which could be tuned by the incident light wavelength or the amount of PAG used. Selective excitation of the inorganic PAG in a system combining the two PAGs results in a photodecomposition product that deactivates the organic PAG, enabling nontrivial disassembly profiles under a single type of external stimulus.","lang":"eng"}],"citation":{"ista":"Wang J, Peled TS, Klajn R. 2023. Photocleavable anionic glues for light-responsive nanoparticle aggregates. Journal of the American Chemical Society. 145(7), 4098–4108.","short":"J. Wang, T.S. Peled, R. Klajn, Journal of the American Chemical Society 145 (2023) 4098–4108.","ama":"Wang J, Peled TS, Klajn R. Photocleavable anionic glues for light-responsive nanoparticle aggregates. <i>Journal of the American Chemical Society</i>. 2023;145(7):4098-4108. doi:<a href=\"https://doi.org/10.1021/jacs.2c11973\">10.1021/jacs.2c11973</a>","mla":"Wang, Jinhua, et al. “Photocleavable Anionic Glues for Light-Responsive Nanoparticle Aggregates.” <i>Journal of the American Chemical Society</i>, vol. 145, no. 7, American Chemical Society, 2023, pp. 4098–108, doi:<a href=\"https://doi.org/10.1021/jacs.2c11973\">10.1021/jacs.2c11973</a>.","chicago":"Wang, Jinhua, Tzuf Shay Peled, and Rafal Klajn. “Photocleavable Anionic Glues for Light-Responsive Nanoparticle Aggregates.” <i>Journal of the American Chemical Society</i>. American Chemical Society, 2023. <a href=\"https://doi.org/10.1021/jacs.2c11973\">https://doi.org/10.1021/jacs.2c11973</a>.","apa":"Wang, J., Peled, T. S., &#38; Klajn, R. (2023). Photocleavable anionic glues for light-responsive nanoparticle aggregates. <i>Journal of the American Chemical Society</i>. American Chemical Society. <a href=\"https://doi.org/10.1021/jacs.2c11973\">https://doi.org/10.1021/jacs.2c11973</a>","ieee":"J. Wang, T. S. Peled, and R. Klajn, “Photocleavable anionic glues for light-responsive nanoparticle aggregates,” <i>Journal of the American Chemical Society</i>, vol. 145, no. 7. American Chemical Society, pp. 4098–4108, 2023."},"publication_status":"published","quality_controlled":"1","oa_version":"Published Version","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","publication_identifier":{"issn":["0002-7863"],"eissn":["1520-5126"]},"extern":"1","_id":"13354","pmid":1,"article_processing_charge":"No","date_updated":"2023-08-02T10:44:22Z","volume":145,"oa":1,"title":"Photocleavable anionic glues for light-responsive nanoparticle aggregates","external_id":{"pmid":["36757850"]},"year":"2023","doi":"10.1021/jacs.2c11973","main_file_link":[{"url":"https://doi.org/10.1021/jacs.2c11973","open_access":"1"}]},{"language":[{"iso":"eng"}],"publisher":"Springer Nature","scopus_import":"1","date_published":"2023-06-14T00:00:00Z","article_type":"original","month":"06","date_created":"2023-08-09T13:06:59Z","status":"public","intvolume":"        14","type":"journal_article","day":"14","publication":"Nature Communications","title":"Witnessing light-driven entanglement using time-resolved resonant inelastic X-ray scattering","external_id":{"pmid":["37316515"],"arxiv":["2209.02283"]},"year":"2023","doi":"10.1038/s41467-023-38540-3","main_file_link":[{"open_access":"1","url":"https://doi.org/10.1038/s41467-023-38540-3"}],"article_number":"3512","author":[{"first_name":"Jordyn","full_name":"Hales, Jordyn","last_name":"Hales"},{"first_name":"Utkarsh","last_name":"Bajpai","full_name":"Bajpai, Utkarsh"},{"full_name":"Liu, Tongtong","last_name":"Liu","first_name":"Tongtong"},{"id":"71b4d059-2a03-11ee-914d-dfa3beed6530","first_name":"Denitsa Rangelova","last_name":"Baykusheva","full_name":"Baykusheva, Denitsa Rangelova"},{"first_name":"Mingda","last_name":"Li","full_name":"Li, Mingda"},{"last_name":"Mitrano","full_name":"Mitrano, Matteo","first_name":"Matteo"},{"first_name":"Yao","full_name":"Wang, Yao","last_name":"Wang"}],"keyword":["General Physics and Astronomy","General Biochemistry","Genetics and Molecular Biology","General Chemistry","Multidisciplinary"],"abstract":[{"lang":"eng","text":"Characterizing and controlling entanglement in quantum materials is crucial for the development of next-generation quantum technologies. However, defining a quantifiable figure of merit for entanglement in macroscopic solids is theoretically and experimentally challenging. At equilibrium the presence of entanglement can be diagnosed by extracting entanglement witnesses from spectroscopic observables and a nonequilibrium extension of this method could lead to the discovery of novel dynamical phenomena. Here, we propose a systematic approach to quantify the time-dependent quantum Fisher information and entanglement depth of transient states of quantum materials with time-resolved resonant inelastic x-ray scattering. Using a quarter-filled extended Hubbard model as an example, we benchmark the efficiency of this approach and predict a light-enhanced many-body entanglement due to the proximity to a phase boundary. Our work sets the stage for experimentally witnessing and controlling entanglement in light-driven quantum materials via ultrafast spectroscopic measurements."}],"publication_status":"published","citation":{"chicago":"Hales, Jordyn, Utkarsh Bajpai, Tongtong Liu, Denitsa Rangelova Baykusheva, Mingda Li, Matteo Mitrano, and Yao Wang. “Witnessing Light-Driven Entanglement Using Time-Resolved Resonant Inelastic X-Ray Scattering.” <i>Nature Communications</i>. Springer Nature, 2023. <a href=\"https://doi.org/10.1038/s41467-023-38540-3\">https://doi.org/10.1038/s41467-023-38540-3</a>.","apa":"Hales, J., Bajpai, U., Liu, T., Baykusheva, D. R., Li, M., Mitrano, M., &#38; Wang, Y. (2023). Witnessing light-driven entanglement using time-resolved resonant inelastic X-ray scattering. <i>Nature Communications</i>. Springer Nature. <a href=\"https://doi.org/10.1038/s41467-023-38540-3\">https://doi.org/10.1038/s41467-023-38540-3</a>","ieee":"J. Hales <i>et al.</i>, “Witnessing light-driven entanglement using time-resolved resonant inelastic X-ray scattering,” <i>Nature Communications</i>, vol. 14. Springer Nature, 2023.","ista":"Hales J, Bajpai U, Liu T, Baykusheva DR, Li M, Mitrano M, Wang Y. 2023. Witnessing light-driven entanglement using time-resolved resonant inelastic X-ray scattering. Nature Communications. 14, 3512.","short":"J. Hales, U. Bajpai, T. Liu, D.R. Baykusheva, M. Li, M. Mitrano, Y. Wang, Nature Communications 14 (2023).","ama":"Hales J, Bajpai U, Liu T, et al. Witnessing light-driven entanglement using time-resolved resonant inelastic X-ray scattering. <i>Nature Communications</i>. 2023;14. doi:<a href=\"https://doi.org/10.1038/s41467-023-38540-3\">10.1038/s41467-023-38540-3</a>","mla":"Hales, Jordyn, et al. “Witnessing Light-Driven Entanglement Using Time-Resolved Resonant Inelastic X-Ray Scattering.” <i>Nature Communications</i>, vol. 14, 3512, Springer Nature, 2023, doi:<a href=\"https://doi.org/10.1038/s41467-023-38540-3\">10.1038/s41467-023-38540-3</a>."},"user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","oa_version":"Published Version","quality_controlled":"1","_id":"13989","pmid":1,"publication_identifier":{"eissn":["2041-1723"]},"extern":"1","date_updated":"2023-08-22T06:50:04Z","volume":14,"oa":1,"article_processing_charge":"No","arxiv":1},{"month":"03","date_published":"2023-03-15T00:00:00Z","article_type":"original","publisher":"Elsevier","scopus_import":"1","language":[{"iso":"eng"}],"department":[{"_id":"MaIb"}],"date_created":"2023-01-12T11:55:02Z","day":"15","type":"journal_article","intvolume":"       613","status":"public","publication":"Applied Surface Science","doi":"10.1016/j.apsusc.2022.156101","year":"2023","title":"Two-step post-treatment to deliver high performance thermoelectric device with vertical temperature gradient","external_id":{"isi":["000911497000001"]},"article_number":"156101","isi":1,"publication_status":"epub_ahead","citation":{"short":"L. Zhang, X. Liu, T. Wu, S. Xu, G. Suo, X. Ye, X. Hou, Y. Yang, Q. Liu, H. Wang, Applied Surface Science 613 (2023).","ista":"Zhang L, Liu X, Wu T, Xu S, Suo G, Ye X, Hou X, Yang Y, Liu Q, Wang H. 2023. Two-step post-treatment to deliver high performance thermoelectric device with vertical temperature gradient. Applied Surface Science. 613, 156101.","ama":"Zhang L, Liu X, Wu T, et al. Two-step post-treatment to deliver high performance thermoelectric device with vertical temperature gradient. <i>Applied Surface Science</i>. 2023;613. doi:<a href=\"https://doi.org/10.1016/j.apsusc.2022.156101\">10.1016/j.apsusc.2022.156101</a>","mla":"Zhang, Li, et al. “Two-Step Post-Treatment to Deliver High Performance Thermoelectric Device with Vertical Temperature Gradient.” <i>Applied Surface Science</i>, vol. 613, 156101, Elsevier, 2023, doi:<a href=\"https://doi.org/10.1016/j.apsusc.2022.156101\">10.1016/j.apsusc.2022.156101</a>.","chicago":"Zhang, Li, Xingyu Liu, Ting Wu, Shengduo Xu, Guoquan Suo, Xiaohui Ye, Xiaojiang Hou, Yanling Yang, Qingfeng Liu, and Hongqiang Wang. “Two-Step Post-Treatment to Deliver High Performance Thermoelectric Device with Vertical Temperature Gradient.” <i>Applied Surface Science</i>. Elsevier, 2023. <a href=\"https://doi.org/10.1016/j.apsusc.2022.156101\">https://doi.org/10.1016/j.apsusc.2022.156101</a>.","ieee":"L. Zhang <i>et al.</i>, “Two-step post-treatment to deliver high performance thermoelectric device with vertical temperature gradient,” <i>Applied Surface Science</i>, vol. 613. Elsevier, 2023.","apa":"Zhang, L., Liu, X., Wu, T., Xu, S., Suo, G., Ye, X., … Wang, H. (2023). Two-step post-treatment to deliver high performance thermoelectric device with vertical temperature gradient. <i>Applied Surface Science</i>. Elsevier. <a href=\"https://doi.org/10.1016/j.apsusc.2022.156101\">https://doi.org/10.1016/j.apsusc.2022.156101</a>"},"abstract":[{"lang":"eng","text":"The power factor of poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate) (PEDOT:PSS) film can be significantly improved by optimizing the oxidation level of the film in oxidation and reduction processes. However, precise control over the oxidation and reduction effects in PEDOT:PSS remains a challenge, which greatly sacrifices both S and σ. Here, we propose a two-step post-treatment using a mixture of ethylene glycol (EG) and Arginine (Arg) and sulfuric acid (H2SO4) in sequence to engineer high-performance PEDOT:PSS thermoelectric films. The high-polarity EG dopant removes the excess non-ionized PSS and induces benzenoid-to-quinoid conformational change in the PEDOT:PSS films. In particular, basic amino acid Arg tunes the oxidation level of PEDOT:PSS and prevents the films from over-oxidation during H2SO4 post-treatment, leading to increased S. The following H2SO4 post-treatment further induces highly orientated lamellar stacking microstructures to increase σ, yielding a maximum power factor of 170.6 μW m−1 K−2 at 460 K. Moreover, a novel trigonal-shape thermoelectric device is designed and assembled by the as-prepared PEDOT:PSS films in order to harvest heat via a vertical temperature gradient. An output power density of 33 μW cm−2 is generated at a temperature difference of 40 K, showing the potential application for low-grade wearable electronic devices."}],"keyword":["Surfaces","Coatings and Films","Condensed Matter Physics","Surfaces and Interfaces","General Physics and Astronomy","General Chemistry"],"author":[{"first_name":"Li","full_name":"Zhang, Li","last_name":"Zhang"},{"last_name":"Liu","full_name":"Liu, Xingyu","first_name":"Xingyu"},{"last_name":"Wu","full_name":"Wu, Ting","first_name":"Ting"},{"last_name":"Xu","full_name":"Xu, Shengduo","first_name":"Shengduo","id":"12ab8624-4c8a-11ec-9e11-e1ac2438f22f"},{"first_name":"Guoquan","last_name":"Suo","full_name":"Suo, Guoquan"},{"first_name":"Xiaohui","last_name":"Ye","full_name":"Ye, Xiaohui"},{"last_name":"Hou","full_name":"Hou, Xiaojiang","first_name":"Xiaojiang"},{"full_name":"Yang, Yanling","last_name":"Yang","first_name":"Yanling"},{"first_name":"Qingfeng","last_name":"Liu","full_name":"Liu, Qingfeng"},{"first_name":"Hongqiang","last_name":"Wang","full_name":"Wang, Hongqiang"}],"volume":613,"date_updated":"2023-08-14T11:47:06Z","article_processing_charge":"No","_id":"12113","publication_identifier":{"issn":["0169-4332"]},"user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","acknowledgement":"Scientific Research Program Funded by Shaanxi Provincial Education Department (Program No.22JY012), Natural Science Basic Research Program of Shaanxi (Grant No.2022JZ-31), Young Talent fund of University Association for Science and Technology in Shaanxi, China (Grant No.20210411), China Postdoctoral Science Foundation (Grant No. 2021M692621), the Foundation of Shaanxi University of Science & Technology (Grant No. 2017GBJ-03), Open Foundation of Key Laboratory of Auxiliary Chemistry and Technology for Chemical Industry, Ministry of Education, Shaanxi University of Science and Technology (Grant No. KFKT2022-15), and Open Foundation of Shaanxi Collaborative Innovation Center of Industrial Auxiliary Chemistry and Technology, Shaanxi University of Science and Technology (Grant No. KFKT2022-15).","oa_version":"None","quality_controlled":"1"},{"month":"05","article_type":"original","date_published":"2023-05-01T00:00:00Z","publisher":"Wiley","language":[{"iso":"eng"}],"license":"https://creativecommons.org/licenses/by-nc/4.0/","has_accepted_license":"1","department":[{"_id":"GradSch"},{"_id":"PaSc"}],"file":[{"success":1,"file_id":"14072","creator":"dernst","relation":"main_file","content_type":"application/pdf","checksum":"7dd083ed8850faa55c34e411ed390de9","date_created":"2023-08-16T12:33:31Z","file_size":1422445,"file_name":"2023_AngewChemInt_Becker.pdf","access_level":"open_access","date_updated":"2023-08-16T12:33:31Z"}],"date_created":"2023-02-24T10:45:01Z","day":"01","type":"journal_article","intvolume":"        62","status":"public","issue":"19","publication":"Angewandte Chemie International Edition","file_date_updated":"2023-08-16T12:33:31Z","doi":"10.1002/anie.202219314","year":"2023","external_id":{"isi":["000956919900001"],"pmid":["36738230"]},"title":"The rigid core and flexible surface of amyloid fibrils probed by Magic‐Angle Spinning NMR of aromatic residues","tmp":{"legal_code_url":"https://creativecommons.org/licenses/by-nc/4.0/legalcode","image":"/images/cc_by_nc.png","name":"Creative Commons Attribution-NonCommercial 4.0 International (CC BY-NC 4.0)","short":"CC BY-NC (4.0)"},"article_number":"e202219314","isi":1,"related_material":{"record":[{"id":"14861","relation":"other","status":"public"},{"id":"12497","relation":"research_data","status":"public"}],"link":[{"url":"https://ista.ac.at/en/news/dancing-styles-of-atoms/","description":"News on ISTA website","relation":"press_release"}]},"ddc":["540"],"publication_status":"published","citation":{"chicago":"Becker, Lea Marie, Mélanie Berbon, Alicia Vallet, Axelle Grelard, Estelle Morvan, Benjamin Bardiaux, Roman Lichtenecker, Matthias Ernst, Antoine Loquet, and Paul Schanda. “The Rigid Core and Flexible Surface of Amyloid Fibrils Probed by Magic‐Angle Spinning NMR of Aromatic Residues.” <i>Angewandte Chemie International Edition</i>. Wiley, 2023. <a href=\"https://doi.org/10.1002/anie.202219314\">https://doi.org/10.1002/anie.202219314</a>.","apa":"Becker, L. M., Berbon, M., Vallet, A., Grelard, A., Morvan, E., Bardiaux, B., … Schanda, P. (2023). The rigid core and flexible surface of amyloid fibrils probed by Magic‐Angle Spinning NMR of aromatic residues. <i>Angewandte Chemie International Edition</i>. Wiley. <a href=\"https://doi.org/10.1002/anie.202219314\">https://doi.org/10.1002/anie.202219314</a>","ieee":"L. M. Becker <i>et al.</i>, “The rigid core and flexible surface of amyloid fibrils probed by Magic‐Angle Spinning NMR of aromatic residues,” <i>Angewandte Chemie International Edition</i>, vol. 62, no. 19. Wiley, 2023.","ista":"Becker LM, Berbon M, Vallet A, Grelard A, Morvan E, Bardiaux B, Lichtenecker R, Ernst M, Loquet A, Schanda P. 2023. The rigid core and flexible surface of amyloid fibrils probed by Magic‐Angle Spinning NMR of aromatic residues. Angewandte Chemie International Edition. 62(19), e202219314.","short":"L.M. Becker, M. Berbon, A. Vallet, A. Grelard, E. Morvan, B. Bardiaux, R. Lichtenecker, M. Ernst, A. Loquet, P. Schanda, Angewandte Chemie International Edition 62 (2023).","ama":"Becker LM, Berbon M, Vallet A, et al. The rigid core and flexible surface of amyloid fibrils probed by Magic‐Angle Spinning NMR of aromatic residues. <i>Angewandte Chemie International Edition</i>. 2023;62(19). doi:<a href=\"https://doi.org/10.1002/anie.202219314\">10.1002/anie.202219314</a>","mla":"Becker, Lea Marie, et al. “The Rigid Core and Flexible Surface of Amyloid Fibrils Probed by Magic‐Angle Spinning NMR of Aromatic Residues.” <i>Angewandte Chemie International Edition</i>, vol. 62, no. 19, e202219314, Wiley, 2023, doi:<a href=\"https://doi.org/10.1002/anie.202219314\">10.1002/anie.202219314</a>."},"abstract":[{"text":"Aromatic side chains are important reporters of the plasticity of proteins, and often form important contacts in protein--protein interactions. By studying a pair of structurally homologous cross-β amyloid fibrils, HET-s and HELLF, with a specific isotope-labeling approach and magic-angle-spinning (MAS) NMR, we have characterized the dynamic behavior of Phe and Tyr aromatic rings to show that the hydrophobic amyloid core is rigid, without any sign of \"breathing motions\" over hundreds of milliseconds at least. Aromatic residues exposed at the fibril surface have a rigid ring axis but undergo ring flips, on a variety of time scales from ns to µs. Our approach provides direct insight into hydrophobic-core motions, enabling a better evaluation of the conformational heterogeneity generated from a NMR structural ensemble of such amyloid cross-β architecture.","lang":"eng"}],"author":[{"orcid":"0000-0002-6401-5151","last_name":"Becker","full_name":"Becker, Lea Marie","first_name":"Lea Marie","id":"36336939-eb97-11eb-a6c2-c83f1214ca79"},{"full_name":"Berbon, Mélanie","last_name":"Berbon","first_name":"Mélanie"},{"first_name":"Alicia","last_name":"Vallet","full_name":"Vallet, Alicia"},{"full_name":"Grelard, Axelle","last_name":"Grelard","first_name":"Axelle"},{"first_name":"Estelle","last_name":"Morvan","full_name":"Morvan, Estelle"},{"last_name":"Bardiaux","full_name":"Bardiaux, Benjamin","first_name":"Benjamin"},{"first_name":"Roman","last_name":"Lichtenecker","full_name":"Lichtenecker, Roman"},{"first_name":"Matthias","last_name":"Ernst","full_name":"Ernst, Matthias"},{"full_name":"Loquet, Antoine","last_name":"Loquet","first_name":"Antoine"},{"first_name":"Paul","full_name":"Schanda, Paul","last_name":"Schanda","orcid":"0000-0002-9350-7606","id":"7B541462-FAF6-11E9-A490-E8DFE5697425"}],"keyword":["General Chemistry","Catalysis"],"volume":62,"date_updated":"2024-02-21T12:14:06Z","oa":1,"article_processing_charge":"Yes (via OA deal)","_id":"12675","pmid":1,"publication_identifier":{"issn":["1433-7851"],"eissn":["1521-3773"]},"acknowledgement":"We thank AlbertA. Smith (Leipzig)for insightful discussions. This work was supported by funding from the European Research Council (StG-2012-311318 to P.S.) and used the platforms of the Grenoble Instruct-ERIC center (ISBG;UMS 3518 CNRS-CEA-UJF-EMBL) within the Grenoble Partnership for Structural Biology(PSB) and facilities and expertiseof the Biophysical and Structural Chemistry platform (BPCS) at IECB,CNRSUAR3033,INSERMUS001 and Bordeaux University.","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","quality_controlled":"1","oa_version":"Published Version"},{"article_processing_charge":"No","volume":29,"date_updated":"2023-05-15T08:39:24Z","oa":1,"publication_identifier":{"eissn":["1521-3765"],"issn":["0947-6539"]},"extern":"1","_id":"12920","oa_version":"Published Version","quality_controlled":"1","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","citation":{"chicago":"Traxler, Michael, Susanne Reischauer, Sarah Vogl, Jérôme Roeser, Jabor Rabeah, Christopher Penschke, Peter Saalfrank, Bartholomäus Pieber, and Arne Thomas. “Programmable Photocatalytic Activity of Multicomponent Covalent Organic Frameworks Used as Metallaphotocatalysts.” <i>Chemistry – A European Journal</i>. Wiley, 2023. <a href=\"https://doi.org/10.1002/chem.202202967\">https://doi.org/10.1002/chem.202202967</a>.","ieee":"M. Traxler <i>et al.</i>, “Programmable photocatalytic activity of multicomponent covalent organic frameworks used as metallaphotocatalysts,” <i>Chemistry – A European Journal</i>, vol. 29, no. 4. Wiley, 2023.","apa":"Traxler, M., Reischauer, S., Vogl, S., Roeser, J., Rabeah, J., Penschke, C., … Thomas, A. (2023). Programmable photocatalytic activity of multicomponent covalent organic frameworks used as metallaphotocatalysts. <i>Chemistry – A European Journal</i>. Wiley. <a href=\"https://doi.org/10.1002/chem.202202967\">https://doi.org/10.1002/chem.202202967</a>","ista":"Traxler M, Reischauer S, Vogl S, Roeser J, Rabeah J, Penschke C, Saalfrank P, Pieber B, Thomas A. 2023. Programmable photocatalytic activity of multicomponent covalent organic frameworks used as metallaphotocatalysts. Chemistry – A European Journal. 29(4), e202202967.","short":"M. Traxler, S. Reischauer, S. Vogl, J. Roeser, J. Rabeah, C. Penschke, P. Saalfrank, B. Pieber, A. Thomas, Chemistry – A European Journal 29 (2023).","ama":"Traxler M, Reischauer S, Vogl S, et al. Programmable photocatalytic activity of multicomponent covalent organic frameworks used as metallaphotocatalysts. <i>Chemistry – A European Journal</i>. 2023;29(4). doi:<a href=\"https://doi.org/10.1002/chem.202202967\">10.1002/chem.202202967</a>","mla":"Traxler, Michael, et al. “Programmable Photocatalytic Activity of Multicomponent Covalent Organic Frameworks Used as Metallaphotocatalysts.” <i>Chemistry – A European Journal</i>, vol. 29, no. 4, e202202967, Wiley, 2023, doi:<a href=\"https://doi.org/10.1002/chem.202202967\">10.1002/chem.202202967</a>."},"publication_status":"published","abstract":[{"lang":"eng","text":"The multicomponent approach allows to incorporate several functionalities into a single covalent organic framework (COF) and consequently allows the construction of bifunctional materials for cooperative catalysis. The well-defined structure of such multicomponent COFs is furthermore ideally suited for structure-activity relationship studies. We report a series of multicomponent COFs that contain acridine- and 2,2’-bipyridine linkers connected through 1,3,5-benzenetrialdehyde derivatives. The acridine motif is responsible for broad light absorption, while the bipyridine unit enables complexation of nickel catalysts. These features enable the usage of the framework materials as catalysts for light-mediated carbon−heteroatom cross-couplings. Variation of the node units shows that the catalytic activity correlates to the keto-enamine tautomer isomerism. This allows switching between high charge-carrier mobility and persistent, localized charge-separated species depending on the nodes, a tool to tailor the materials for specific reactions. Moreover, nickel-loaded COFs are recyclable and catalyze cross-couplings even using red light irradiation."}],"author":[{"first_name":"Michael","last_name":"Traxler","full_name":"Traxler, Michael"},{"full_name":"Reischauer, Susanne","last_name":"Reischauer","first_name":"Susanne"},{"first_name":"Sarah","last_name":"Vogl","full_name":"Vogl, Sarah"},{"last_name":"Roeser","full_name":"Roeser, Jérôme","first_name":"Jérôme"},{"first_name":"Jabor","last_name":"Rabeah","full_name":"Rabeah, Jabor"},{"last_name":"Penschke","full_name":"Penschke, Christopher","first_name":"Christopher"},{"last_name":"Saalfrank","full_name":"Saalfrank, Peter","first_name":"Peter"},{"id":"93e5e5b2-0da6-11ed-8a41-af589a024726","first_name":"Bartholomäus","orcid":"0000-0001-8689-388X","last_name":"Pieber","full_name":"Pieber, Bartholomäus"},{"first_name":"Arne","last_name":"Thomas","full_name":"Thomas, Arne"}],"keyword":["General Chemistry","Catalysis","Organic Chemistry"],"article_number":"e202202967","main_file_link":[{"open_access":"1","url":"https://doi.org/10.1002/chem.202202967"}],"doi":"10.1002/chem.202202967","year":"2023","title":"Programmable photocatalytic activity of multicomponent covalent organic frameworks used as metallaphotocatalysts","publication":"Chemistry – A European Journal","issue":"4","day":"18","type":"journal_article","intvolume":"        29","status":"public","date_created":"2023-05-08T08:25:34Z","month":"01","date_published":"2023-01-18T00:00:00Z","article_type":"original","scopus_import":"1","publisher":"Wiley","language":[{"iso":"eng"}]},{"oa_version":"Published Version","quality_controlled":"1","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","publication_identifier":{"issn":["1433-7851"],"eissn":["1521-3773"]},"extern":"1","_id":"12922","article_processing_charge":"No","oa":1,"volume":62,"date_updated":"2023-08-21T09:18:12Z","keyword":["General Chemistry","Catalysis"],"author":[{"last_name":"Lepre","full_name":"Lepre, Enrico","first_name":"Enrico"},{"first_name":"Sylvain","full_name":"Rat, Sylvain","last_name":"Rat"},{"first_name":"Cristian","last_name":"Cavedon","full_name":"Cavedon, Cristian"},{"full_name":"Seeberger, Peter H.","last_name":"Seeberger","first_name":"Peter H."},{"first_name":"Bartholomäus","full_name":"Pieber, Bartholomäus","last_name":"Pieber","orcid":"0000-0001-8689-388X","id":"93e5e5b2-0da6-11ed-8a41-af589a024726"},{"full_name":"Antonietti, Markus","last_name":"Antonietti","first_name":"Markus"},{"first_name":"Nieves","last_name":"López‐Salas","full_name":"López‐Salas, Nieves"}],"abstract":[{"text":"The influence of structural modifications on the catalytic activity of carbon materials is poorly understood. A collection of carbonaceous materials with different pore networks and high nitrogen content was characterized and used to catalyze four reactions to deduce structure–activity relationships. The CO2 cycloaddition and Knoevenagel reaction depend on Lewis basic sites (electron-rich nitrogen species). The absence of large conjugated carbon domains resulting from the introduction of large amounts of nitrogen in the carbon network is responsible for poor redox activity, as observed through the catalytic reduction of nitrobenzene with hydrazine and the catalytic oxidation of 3,3′,5,5′-tetramethylbenzidine using hydroperoxide. The material with the highest activity towards Lewis acid catalysis (in the hydrolysis of (dimethoxymethyl)benzene to benzaldehyde) is the most effective for small molecule activation and presents the highest concentration of electron-poor nitrogen species.","lang":"eng"}],"citation":{"ama":"Lepre E, Rat S, Cavedon C, et al. Catalytic properties of high nitrogen content carbonaceous materials. <i>Angewandte Chemie International Edition</i>. 2023;62(2). doi:<a href=\"https://doi.org/10.1002/anie.202211663\">10.1002/anie.202211663</a>","mla":"Lepre, Enrico, et al. “Catalytic Properties of High Nitrogen Content Carbonaceous Materials.” <i>Angewandte Chemie International Edition</i>, vol. 62, no. 2, e202211663, Wiley, 2023, doi:<a href=\"https://doi.org/10.1002/anie.202211663\">10.1002/anie.202211663</a>.","ista":"Lepre E, Rat S, Cavedon C, Seeberger PH, Pieber B, Antonietti M, López‐Salas N. 2023. Catalytic properties of high nitrogen content carbonaceous materials. Angewandte Chemie International Edition. 62(2), e202211663.","short":"E. Lepre, S. Rat, C. Cavedon, P.H. Seeberger, B. Pieber, M. Antonietti, N. López‐Salas, Angewandte Chemie International Edition 62 (2023).","apa":"Lepre, E., Rat, S., Cavedon, C., Seeberger, P. H., Pieber, B., Antonietti, M., &#38; López‐Salas, N. (2023). Catalytic properties of high nitrogen content carbonaceous materials. <i>Angewandte Chemie International Edition</i>. Wiley. <a href=\"https://doi.org/10.1002/anie.202211663\">https://doi.org/10.1002/anie.202211663</a>","ieee":"E. Lepre <i>et al.</i>, “Catalytic properties of high nitrogen content carbonaceous materials,” <i>Angewandte Chemie International Edition</i>, vol. 62, no. 2. Wiley, 2023.","chicago":"Lepre, Enrico, Sylvain Rat, Cristian Cavedon, Peter H. Seeberger, Bartholomäus Pieber, Markus Antonietti, and Nieves López‐Salas. “Catalytic Properties of High Nitrogen Content Carbonaceous Materials.” <i>Angewandte Chemie International Edition</i>. Wiley, 2023. <a href=\"https://doi.org/10.1002/anie.202211663\">https://doi.org/10.1002/anie.202211663</a>."},"publication_status":"published","article_number":"e202211663","main_file_link":[{"open_access":"1","url":"https://doi.org/10.1002/anie.202211663"}],"title":"Catalytic properties of high nitrogen content carbonaceous materials","year":"2023","doi":"10.1002/anie.202211663","publication":"Angewandte Chemie International Edition","issue":"2","status":"public","intvolume":"        62","type":"journal_article","day":"09","date_created":"2023-05-08T08:28:14Z","language":[{"iso":"eng"}],"scopus_import":"1","publisher":"Wiley","date_published":"2023-01-09T00:00:00Z","article_type":"original","month":"01"},{"publication":"Nature Communications","file_date_updated":"2022-05-13T09:10:51Z","day":"12","type":"journal_article","intvolume":"        13","status":"public","has_accepted_license":"1","department":[{"_id":"MaLo"}],"date_created":"2022-05-13T09:06:28Z","file":[{"checksum":"5af863ee1b95a0710f6ee864d68dc7a6","date_created":"2022-05-13T09:10:51Z","file_size":6945191,"file_name":"2022_NatureCommunications_Radler.pdf","access_level":"open_access","date_updated":"2022-05-13T09:10:51Z","success":1,"file_id":"11374","creator":"dernst","relation":"main_file","content_type":"application/pdf"}],"month":"05","article_type":"original","date_published":"2022-05-12T00:00:00Z","scopus_import":"1","publisher":"Springer Nature","language":[{"iso":"eng"}],"article_processing_charge":"No","volume":13,"oa":1,"date_updated":"2024-02-21T12:35:18Z","publication_identifier":{"issn":["2041-1723"]},"_id":"11373","project":[{"call_identifier":"H2020","_id":"2595697A-B435-11E9-9278-68D0E5697425","name":"Self-Organization of the Bacterial Cell","grant_number":"679239"},{"grant_number":"P34607","name":"Understanding bacterial cell division by in vitro\r\nreconstitution","_id":"fc38323b-9c52-11eb-aca3-ff8afb4a011d"}],"quality_controlled":"1","oa_version":"Published Version","acknowledgement":"We acknowledge members of the Loose laboratory at IST Austria for helpful discussions—in particular L. Lindorfer for his assistance with cloning and purifications. We thank J. Löwe and T. Nierhaus (MRC-LMB Cambridge, UK) for sharing unpublished work and helpful discussions, as well as D. Vavylonis and D. Rutkowski (Lehigh University, Bethlehem, PA, USA) and S. Martin (University of Lausanne, Switzerland) for sharing their code for FRAP analysis. We are also thankful for the support by the Scientific Service Units (SSU) of IST Austria through resources provided by the Imaging and Optics Facility (IOF) and the Lab Support Facility (LSF). This work was supported by the European Research Council through grant ERC 2015-StG-679239 and by the Austrian Science Fund (FWF) StandAlone P34607 to M.L. and HFSP LT 000824/2016-L4 to N.B. For the purpose of open access, we have applied a CC BY public copyright licence to any Author Accepted Manuscript version arising from this submission.","user_id":"4359f0d1-fa6c-11eb-b949-802e58b17ae8","citation":{"ista":"Radler P, Baranova NS, Dos Santos Caldas PR, Sommer CM, Lopez Pelegrin MD, Michalik D, Loose M. 2022. In vitro reconstitution of Escherichia coli divisome activation. Nature Communications. 13, 2635.","short":"P. Radler, N.S. Baranova, P.R. Dos Santos Caldas, C.M. Sommer, M.D. Lopez Pelegrin, D. Michalik, M. Loose, Nature Communications 13 (2022).","mla":"Radler, Philipp, et al. “In Vitro Reconstitution of Escherichia Coli Divisome Activation.” <i>Nature Communications</i>, vol. 13, 2635, Springer Nature, 2022, doi:<a href=\"https://doi.org/10.1038/s41467-022-30301-y\">10.1038/s41467-022-30301-y</a>.","ama":"Radler P, Baranova NS, Dos Santos Caldas PR, et al. In vitro reconstitution of Escherichia coli divisome activation. <i>Nature Communications</i>. 2022;13. doi:<a href=\"https://doi.org/10.1038/s41467-022-30301-y\">10.1038/s41467-022-30301-y</a>","chicago":"Radler, Philipp, Natalia S. Baranova, Paulo R Dos Santos Caldas, Christoph M Sommer, Maria D Lopez Pelegrin, David Michalik, and Martin Loose. “In Vitro Reconstitution of Escherichia Coli Divisome Activation.” <i>Nature Communications</i>. Springer Nature, 2022. <a href=\"https://doi.org/10.1038/s41467-022-30301-y\">https://doi.org/10.1038/s41467-022-30301-y</a>.","ieee":"P. Radler <i>et al.</i>, “In vitro reconstitution of Escherichia coli divisome activation,” <i>Nature Communications</i>, vol. 13. Springer Nature, 2022.","apa":"Radler, P., Baranova, N. S., Dos Santos Caldas, P. R., Sommer, C. M., Lopez Pelegrin, M. D., Michalik, D., &#38; Loose, M. (2022). In vitro reconstitution of Escherichia coli divisome activation. <i>Nature Communications</i>. Springer Nature. <a href=\"https://doi.org/10.1038/s41467-022-30301-y\">https://doi.org/10.1038/s41467-022-30301-y</a>"},"publication_status":"published","abstract":[{"lang":"eng","text":"The actin-homologue FtsA is essential for E. coli cell division, as it links FtsZ filaments in the Z-ring to transmembrane proteins. FtsA is thought to initiate cell constriction by switching from an inactive polymeric to an active monomeric conformation, which recruits downstream proteins and stabilizes the Z-ring. However, direct biochemical evidence for this mechanism is missing. Here, we use reconstitution experiments and quantitative fluorescence microscopy to study divisome activation in vitro. By comparing wild-type FtsA with FtsA R286W, we find that this hyperactive mutant outperforms FtsA WT in replicating FtsZ treadmilling dynamics, FtsZ filament stabilization and recruitment of FtsN. We could attribute these differences to a faster exchange and denser packing of FtsA R286W below FtsZ filaments. Using FRET microscopy, we also find that FtsN binding promotes FtsA self-interaction. We propose that in the active divisome FtsA and FtsN exist as a dynamic copolymer that follows treadmilling filaments of FtsZ."}],"keyword":["General Physics and Astronomy","General Biochemistry","Genetics and Molecular Biology","General Chemistry"],"author":[{"full_name":"Radler, Philipp","last_name":"Radler","orcid":"0000-0001-9198-2182 ","first_name":"Philipp","id":"40136C2A-F248-11E8-B48F-1D18A9856A87"},{"id":"38661662-F248-11E8-B48F-1D18A9856A87","orcid":"0000-0002-3086-9124","last_name":"Baranova","full_name":"Baranova, Natalia S.","first_name":"Natalia S."},{"id":"38FCDB4C-F248-11E8-B48F-1D18A9856A87","first_name":"Paulo R","full_name":"Dos Santos Caldas, Paulo R","last_name":"Dos Santos Caldas","orcid":"0000-0001-6730-4461"},{"first_name":"Christoph M","orcid":"0000-0003-1216-9105","last_name":"Sommer","full_name":"Sommer, Christoph M","id":"4DF26D8C-F248-11E8-B48F-1D18A9856A87"},{"last_name":"Lopez Pelegrin","full_name":"Lopez Pelegrin, Maria D","first_name":"Maria D","id":"319AA9CE-F248-11E8-B48F-1D18A9856A87"},{"id":"B9577E20-AA38-11E9-AC9A-0930E6697425","last_name":"Michalik","full_name":"Michalik, David","first_name":"David"},{"full_name":"Loose, Martin","last_name":"Loose","orcid":"0000-0001-7309-9724","first_name":"Martin","id":"462D4284-F248-11E8-B48F-1D18A9856A87"}],"tmp":{"image":"/images/cc_by.png","legal_code_url":"https://creativecommons.org/licenses/by/4.0/legalcode","name":"Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)","short":"CC BY (4.0)"},"article_number":"2635","isi":1,"related_material":{"record":[{"status":"public","id":"14280","relation":"dissertation_contains"},{"id":"10934","relation":"research_data","status":"public"}],"link":[{"relation":"erratum","url":"https://doi.org/10.1038/s41467-022-34485-1"}]},"ddc":["570"],"doi":"10.1038/s41467-022-30301-y","year":"2022","acknowledged_ssus":[{"_id":"Bio"},{"_id":"LifeSc"}],"ec_funded":1,"external_id":{"isi":["000795171100037"]},"title":"In vitro reconstitution of Escherichia coli divisome activation"},{"article_processing_charge":"No","oa":1,"volume":5,"date_updated":"2023-08-02T06:41:54Z","quality_controlled":"1","oa_version":"Published Version","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","publication_identifier":{"eissn":["2399-3669"]},"extern":"1","_id":"13347","citation":{"ama":"Yanshyna O, Białek MJ, Chashchikhin OV, Klajn R. Encapsulation within a coordination cage modulates the reactivity of redox-active dyes. <i>Communications Chemistry</i>. 2022;5. doi:<a href=\"https://doi.org/10.1038/s42004-022-00658-8\">10.1038/s42004-022-00658-8</a>","mla":"Yanshyna, Oksana, et al. “Encapsulation within a Coordination Cage Modulates the Reactivity of Redox-Active Dyes.” <i>Communications Chemistry</i>, vol. 5, 44, Springer Nature, 2022, doi:<a href=\"https://doi.org/10.1038/s42004-022-00658-8\">10.1038/s42004-022-00658-8</a>.","short":"O. Yanshyna, M.J. Białek, O.V. Chashchikhin, R. Klajn, Communications Chemistry 5 (2022).","ista":"Yanshyna O, Białek MJ, Chashchikhin OV, Klajn R. 2022. Encapsulation within a coordination cage modulates the reactivity of redox-active dyes. Communications Chemistry. 5, 44.","apa":"Yanshyna, O., Białek, M. J., Chashchikhin, O. V., &#38; Klajn, R. (2022). Encapsulation within a coordination cage modulates the reactivity of redox-active dyes. <i>Communications Chemistry</i>. Springer Nature. <a href=\"https://doi.org/10.1038/s42004-022-00658-8\">https://doi.org/10.1038/s42004-022-00658-8</a>","ieee":"O. Yanshyna, M. J. Białek, O. V. Chashchikhin, and R. Klajn, “Encapsulation within a coordination cage modulates the reactivity of redox-active dyes,” <i>Communications Chemistry</i>, vol. 5. Springer Nature, 2022.","chicago":"Yanshyna, Oksana, Michał J. Białek, Oleg V. Chashchikhin, and Rafal Klajn. “Encapsulation within a Coordination Cage Modulates the Reactivity of Redox-Active Dyes.” <i>Communications Chemistry</i>. Springer Nature, 2022. <a href=\"https://doi.org/10.1038/s42004-022-00658-8\">https://doi.org/10.1038/s42004-022-00658-8</a>."},"publication_status":"published","keyword":["Materials Chemistry","Biochemistry","Environmental Chemistry","General Chemistry"],"author":[{"first_name":"Oksana","last_name":"Yanshyna","full_name":"Yanshyna, Oksana"},{"last_name":"Białek","full_name":"Białek, Michał J.","first_name":"Michał J."},{"first_name":"Oleg V.","last_name":"Chashchikhin","full_name":"Chashchikhin, Oleg V."},{"id":"8e84690e-1e48-11ed-a02b-a1e6fb8bb53b","first_name":"Rafal","full_name":"Klajn, Rafal","last_name":"Klajn"}],"abstract":[{"lang":"eng","text":"Confining molecules within well-defined nanosized spaces can profoundly alter their physicochemical characteristics. For example, the controlled aggregation of chromophores into discrete oligomers has been shown to tune their optical properties whereas encapsulation of reactive species within molecular hosts can increase their stability. The resazurin/resorufin pair has been widely used for detecting redox processes in biological settings; yet, how tight confinement affects the properties of these two dyes remains to be explored. Here, we show that a flexible Pd<jats:sup>II</jats:sup><jats:sub>6</jats:sub>L<jats:sub>4</jats:sub> coordination cage can efficiently encapsulate both resorufin and resazurin in the form of dimers, dramatically modulating their optical properties. Furthermore, binding within the cage significantly decreases the reduction rate of resazurin to resorufin, and the rate of the subsequent reduction of resorufin to dihydroresorufin. During our studies, we also found that upon dilution, the Pd<jats:sup>II</jats:sup><jats:sub>6</jats:sub>L<jats:sub>4</jats:sub> cage disassembles to afford Pd<jats:sup>II</jats:sup><jats:sub>2</jats:sub>L<jats:sub>2</jats:sub> species, which lacks the ability to form inclusion complexes – a process that can be reversed upon the addition of the strongly binding resorufin/resazurin guests. We expect that the herein disclosed ability of a water-soluble cage to reversibly modulate the optical and chemical properties of a molecular redox probe will expand the versatility of synthetic fluorescent probes in biologically relevant environments."}],"main_file_link":[{"open_access":"1","url":"https://doi.org/10.1038/s42004-022-00658-8"}],"article_number":"44","year":"2022","doi":"10.1038/s42004-022-00658-8","title":"Encapsulation within a coordination cage modulates the reactivity of redox-active dyes","publication":"Communications Chemistry","type":"journal_article","day":"30","status":"public","intvolume":"         5","date_created":"2023-08-01T09:30:47Z","article_type":"original","date_published":"2022-03-30T00:00:00Z","month":"03","language":[{"iso":"eng"}],"scopus_import":"1","publisher":"Springer Nature"},{"date_created":"2023-08-01T09:31:01Z","language":[{"iso":"eng"}],"publisher":"American Chemical Society","scopus_import":"1","article_type":"original","date_published":"2022-11-15T00:00:00Z","month":"11","page":"21244-21254","issue":"46","publication":"Journal of the American Chemical Society","status":"public","intvolume":"       144","type":"journal_article","day":"15","main_file_link":[{"url":"https://doi.org/10.1021/jacs.2c08901","open_access":"1"}],"title":"Altering the properties of spiropyran switches using coordination cages with different symmetries","year":"2022","doi":"10.1021/jacs.2c08901","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","oa_version":"Published Version","quality_controlled":"1","_id":"13348","extern":"1","publication_identifier":{"issn":["0002-7863"],"eissn":["1520-5126"]},"date_updated":"2023-08-02T06:39:50Z","volume":144,"oa":1,"article_processing_charge":"No","author":[{"first_name":"Jinhua","last_name":"Wang","full_name":"Wang, Jinhua"},{"full_name":"Avram, Liat","last_name":"Avram","first_name":"Liat"},{"first_name":"Yael","last_name":"Diskin-Posner","full_name":"Diskin-Posner, Yael"},{"first_name":"Michał J.","full_name":"Białek, Michał J.","last_name":"Białek"},{"full_name":"Stawski, Wojciech","last_name":"Stawski","first_name":"Wojciech"},{"last_name":"Feller","full_name":"Feller, Moran","first_name":"Moran"},{"id":"8e84690e-1e48-11ed-a02b-a1e6fb8bb53b","last_name":"Klajn","full_name":"Klajn, Rafal","first_name":"Rafal"}],"keyword":["Colloid and Surface Chemistry","Biochemistry","General Chemistry","Catalysis"],"abstract":[{"text":"Molecular confinement effects can profoundly alter the physicochemical properties of the confined species. A plethora of organic molecules were encapsulated within the cavities of supramolecular hosts, and the impact of the cavity size and polarity was widely investigated. However, the extent to which the properties of the confined guests can be affected by the symmetry of the cage─which dictates the shape of the cavity─remains to be understood. Here we show that cage symmetry has a dramatic effect on the equilibrium between two isomers of the encapsulated spiropyran guests. Working with two Pd-based coordination cages featuring similarly sized but differently shaped hydrophobic cavities, we found a highly selective stabilization of the isomer whose shape matches that of the cavity of the cage. A Td-symmetric cage stabilized the spiropyrans’ colorless form and rendered them photochemically inert. In contrast, a D2h-symmetric cage favored the colored isomer, while maintaining reversible photoswitching between the two states of the encapsulated spiropyrans. We also show that the switching kinetics strongly depend on the substitution pattern on the spiropyran scaffold. This finding was used to fabricate a time-sensitive information storage medium with tunable lifetimes of the encoded messages.","lang":"eng"}],"publication_status":"published","citation":{"ieee":"J. Wang <i>et al.</i>, “Altering the properties of spiropyran switches using coordination cages with different symmetries,” <i>Journal of the American Chemical Society</i>, vol. 144, no. 46. American Chemical Society, pp. 21244–21254, 2022.","apa":"Wang, J., Avram, L., Diskin-Posner, Y., Białek, M. J., Stawski, W., Feller, M., &#38; Klajn, R. (2022). Altering the properties of spiropyran switches using coordination cages with different symmetries. <i>Journal of the American Chemical Society</i>. American Chemical Society. <a href=\"https://doi.org/10.1021/jacs.2c08901\">https://doi.org/10.1021/jacs.2c08901</a>","chicago":"Wang, Jinhua, Liat Avram, Yael Diskin-Posner, Michał J. Białek, Wojciech Stawski, Moran Feller, and Rafal Klajn. “Altering the Properties of Spiropyran Switches Using Coordination Cages with Different Symmetries.” <i>Journal of the American Chemical Society</i>. American Chemical Society, 2022. <a href=\"https://doi.org/10.1021/jacs.2c08901\">https://doi.org/10.1021/jacs.2c08901</a>.","ama":"Wang J, Avram L, Diskin-Posner Y, et al. Altering the properties of spiropyran switches using coordination cages with different symmetries. <i>Journal of the American Chemical Society</i>. 2022;144(46):21244-21254. doi:<a href=\"https://doi.org/10.1021/jacs.2c08901\">10.1021/jacs.2c08901</a>","mla":"Wang, Jinhua, et al. “Altering the Properties of Spiropyran Switches Using Coordination Cages with Different Symmetries.” <i>Journal of the American Chemical Society</i>, vol. 144, no. 46, American Chemical Society, 2022, pp. 21244–54, doi:<a href=\"https://doi.org/10.1021/jacs.2c08901\">10.1021/jacs.2c08901</a>.","ista":"Wang J, Avram L, Diskin-Posner Y, Białek MJ, Stawski W, Feller M, Klajn R. 2022. Altering the properties of spiropyran switches using coordination cages with different symmetries. Journal of the American Chemical Society. 144(46), 21244–21254.","short":"J. Wang, L. Avram, Y. Diskin-Posner, M.J. Białek, W. Stawski, M. Feller, R. Klajn, Journal of the American Chemical Society 144 (2022) 21244–21254."}},{"article_type":"original","date_published":"2022-09-08T00:00:00Z","month":"09","language":[{"iso":"eng"}],"scopus_import":"1","publisher":"Elsevier","date_created":"2023-08-01T09:32:14Z","type":"journal_article","day":"08","status":"public","intvolume":"         8","page":"2362-2379","publication":"Chem","issue":"9","doi":"10.1016/j.chempr.2022.05.008","year":"2022","external_id":{"pmid":["36133801"]},"title":"Ternary host-guest complexes with rapid exchange kinetics and photoswitchable fluorescence","main_file_link":[{"open_access":"1","url":"https://doi.org/10.1016/j.chempr.2022.05.008"}],"citation":{"chicago":"Gemen, Julius, Michał J. Białek, Miri Kazes, Linda J.W. Shimon, Moran Feller, Sergey N. Semenov, Yael Diskin-Posner, Dan Oron, and Rafal Klajn. “Ternary Host-Guest Complexes with Rapid Exchange Kinetics and Photoswitchable Fluorescence.” <i>Chem</i>. Elsevier, 2022. <a href=\"https://doi.org/10.1016/j.chempr.2022.05.008\">https://doi.org/10.1016/j.chempr.2022.05.008</a>.","apa":"Gemen, J., Białek, M. J., Kazes, M., Shimon, L. J. W., Feller, M., Semenov, S. N., … Klajn, R. (2022). Ternary host-guest complexes with rapid exchange kinetics and photoswitchable fluorescence. <i>Chem</i>. Elsevier. <a href=\"https://doi.org/10.1016/j.chempr.2022.05.008\">https://doi.org/10.1016/j.chempr.2022.05.008</a>","ieee":"J. Gemen <i>et al.</i>, “Ternary host-guest complexes with rapid exchange kinetics and photoswitchable fluorescence,” <i>Chem</i>, vol. 8, no. 9. Elsevier, pp. 2362–2379, 2022.","short":"J. Gemen, M.J. Białek, M. Kazes, L.J.W. Shimon, M. Feller, S.N. Semenov, Y. Diskin-Posner, D. Oron, R. Klajn, Chem 8 (2022) 2362–2379.","ista":"Gemen J, Białek MJ, Kazes M, Shimon LJW, Feller M, Semenov SN, Diskin-Posner Y, Oron D, Klajn R. 2022. Ternary host-guest complexes with rapid exchange kinetics and photoswitchable fluorescence. Chem. 8(9), 2362–2379.","ama":"Gemen J, Białek MJ, Kazes M, et al. Ternary host-guest complexes with rapid exchange kinetics and photoswitchable fluorescence. <i>Chem</i>. 2022;8(9):2362-2379. doi:<a href=\"https://doi.org/10.1016/j.chempr.2022.05.008\">10.1016/j.chempr.2022.05.008</a>","mla":"Gemen, Julius, et al. “Ternary Host-Guest Complexes with Rapid Exchange Kinetics and Photoswitchable Fluorescence.” <i>Chem</i>, vol. 8, no. 9, Elsevier, 2022, pp. 2362–79, doi:<a href=\"https://doi.org/10.1016/j.chempr.2022.05.008\">10.1016/j.chempr.2022.05.008</a>."},"publication_status":"published","author":[{"last_name":"Gemen","full_name":"Gemen, Julius","first_name":"Julius"},{"first_name":"Michał J.","full_name":"Białek, Michał J.","last_name":"Białek"},{"full_name":"Kazes, Miri","last_name":"Kazes","first_name":"Miri"},{"first_name":"Linda J.W.","full_name":"Shimon, Linda J.W.","last_name":"Shimon"},{"first_name":"Moran","last_name":"Feller","full_name":"Feller, Moran"},{"last_name":"Semenov","full_name":"Semenov, Sergey N.","first_name":"Sergey N."},{"first_name":"Yael","last_name":"Diskin-Posner","full_name":"Diskin-Posner, Yael"},{"first_name":"Dan","last_name":"Oron","full_name":"Oron, Dan"},{"last_name":"Klajn","full_name":"Klajn, Rafal","first_name":"Rafal","id":"8e84690e-1e48-11ed-a02b-a1e6fb8bb53b"}],"keyword":["Materials Chemistry","Biochemistry (medical)","General Chemical Engineering","Environmental Chemistry","Biochemistry","General Chemistry"],"abstract":[{"lang":"eng","text":"Confinement within molecular cages can dramatically modify the physicochemical properties of the encapsulated guest molecules, but such host-guest complexes have mainly been studied in a static context. Combining confinement effects with fast guest exchange kinetics could pave the way toward stimuli-responsive supramolecular systems—and ultimately materials—whose desired properties could be tailored “on demand” rapidly and reversibly. Here, we demonstrate rapid guest exchange between inclusion complexes of an open-window coordination cage that can simultaneously accommodate two guest molecules. Working with two types of guests, anthracene derivatives and BODIPY dyes, we show that the former can substantially modify the optical properties of the latter upon noncovalent heterodimer formation. We also studied the light-induced covalent dimerization of encapsulated anthracenes and found large effects of confinement on reaction rates. By coupling the photodimerization with the rapid guest exchange, we developed a new way to modulate fluorescence using external irradiation."}],"article_processing_charge":"No","volume":8,"oa":1,"date_updated":"2023-08-02T09:39:35Z","oa_version":"Published Version","quality_controlled":"1","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","publication_identifier":{"issn":["2451-9308"],"eissn":["2451-9294"]},"extern":"1","_id":"13350","pmid":1},{"issue":"5","publication":"Chem","page":"1183-1186","day":"12","type":"journal_article","intvolume":"         8","status":"public","date_created":"2023-08-01T09:32:27Z","month":"05","article_type":"original","date_published":"2022-05-12T00:00:00Z","publisher":"Elsevier","scopus_import":"1","language":[{"iso":"eng"}],"volume":8,"date_updated":"2023-08-02T07:24:57Z","oa":1,"article_processing_charge":"No","_id":"13351","publication_identifier":{"issn":["2451-9308"],"eissn":["2451-9294"]},"extern":"1","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","quality_controlled":"1","oa_version":"Published Version","publication_status":"published","citation":{"apa":"Gemen, J., &#38; Klajn, R. (2022). Electron catalysis expands the supramolecular chemist’s toolbox. <i>Chem</i>. Elsevier. <a href=\"https://doi.org/10.1016/j.chempr.2022.04.022\">https://doi.org/10.1016/j.chempr.2022.04.022</a>","ieee":"J. Gemen and R. Klajn, “Electron catalysis expands the supramolecular chemist’s toolbox,” <i>Chem</i>, vol. 8, no. 5. Elsevier, pp. 1183–1186, 2022.","chicago":"Gemen, Julius, and Rafal Klajn. “Electron Catalysis Expands the Supramolecular Chemist’s Toolbox.” <i>Chem</i>. Elsevier, 2022. <a href=\"https://doi.org/10.1016/j.chempr.2022.04.022\">https://doi.org/10.1016/j.chempr.2022.04.022</a>.","ama":"Gemen J, Klajn R. Electron catalysis expands the supramolecular chemist’s toolbox. <i>Chem</i>. 2022;8(5):1183-1186. doi:<a href=\"https://doi.org/10.1016/j.chempr.2022.04.022\">10.1016/j.chempr.2022.04.022</a>","mla":"Gemen, Julius, and Rafal Klajn. “Electron Catalysis Expands the Supramolecular Chemist’s Toolbox.” <i>Chem</i>, vol. 8, no. 5, Elsevier, 2022, pp. 1183–86, doi:<a href=\"https://doi.org/10.1016/j.chempr.2022.04.022\">10.1016/j.chempr.2022.04.022</a>.","short":"J. Gemen, R. Klajn, Chem 8 (2022) 1183–1186.","ista":"Gemen J, Klajn R. 2022. Electron catalysis expands the supramolecular chemist’s toolbox. Chem. 8(5), 1183–1186."},"abstract":[{"text":"Molecular recognition is at the heart of the noncovalent synthesis of supramolecular assemblies and, at higher length scales, supramolecular materials. In a recent publication in Nature, Stoddart and co-workers demonstrate that the formation of host-guest complexes can be catalyzed by one of the simplest possible catalysts: the electron.","lang":"eng"}],"author":[{"last_name":"Gemen","full_name":"Gemen, Julius","first_name":"Julius"},{"id":"8e84690e-1e48-11ed-a02b-a1e6fb8bb53b","first_name":"Rafal","full_name":"Klajn, Rafal","last_name":"Klajn"}],"keyword":["Materials Chemistry","Biochemistry (medical)","General Chemical Engineering","Environmental Chemistry","Biochemistry","General Chemistry"],"main_file_link":[{"url":"https://doi.org/10.1016/j.chempr.2022.04.022","open_access":"1"}],"year":"2022","doi":"10.1016/j.chempr.2022.04.022","title":"Electron catalysis expands the supramolecular chemist’s toolbox"},{"main_file_link":[{"open_access":"1","url":"https://doi.org/10.1039/D1CC07081A"}],"title":"Coexistence of 1:1 and 2:1 inclusion complexes of indigo carmine","external_id":{"pmid":["35064258"]},"doi":"10.1039/d1cc07081a","year":"2022","pmid":1,"_id":"13353","publication_identifier":{"eissn":["1364-548X"],"issn":["1359-7345"]},"extern":"1","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","quality_controlled":"1","oa_version":"Published Version","date_updated":"2023-08-02T09:46:51Z","volume":58,"oa":1,"article_processing_charge":"No","abstract":[{"text":"We show that the optical properties of indigo carmine can be modulated by encapsulation within a coordination cage. Depending on the host/guest molar ratio, the cage can predominantly encapsulate either one or two dye molecules. The 1 : 1 complex is fluorescent, unique for an indigo dye in an aqueous solution. We have also found that binding two dye molecules stabilizes a previously unknown conformation of the cage.","lang":"eng"}],"keyword":["Materials Chemistry","Metals and Alloys","Surfaces","Coatings and Films","General Chemistry","Ceramics and Composites","Electronic","Optical and Magnetic Materials","Catalysis"],"author":[{"full_name":"Yanshyna, Oksana","last_name":"Yanshyna","first_name":"Oksana"},{"first_name":"Liat","full_name":"Avram, Liat","last_name":"Avram"},{"first_name":"Linda J. W.","last_name":"Shimon","full_name":"Shimon, Linda J. W."},{"id":"8e84690e-1e48-11ed-a02b-a1e6fb8bb53b","first_name":"Rafal","full_name":"Klajn, Rafal","last_name":"Klajn"}],"publication_status":"published","citation":{"ama":"Yanshyna O, Avram L, Shimon LJW, Klajn R. Coexistence of 1:1 and 2:1 inclusion complexes of indigo carmine. <i>Chemical Communications</i>. 2022;58(21):3461-3464. doi:<a href=\"https://doi.org/10.1039/d1cc07081a\">10.1039/d1cc07081a</a>","mla":"Yanshyna, Oksana, et al. “Coexistence of 1:1 and 2:1 Inclusion Complexes of Indigo Carmine.” <i>Chemical Communications</i>, vol. 58, no. 21, Royal Society of Chemistry, 2022, pp. 3461–64, doi:<a href=\"https://doi.org/10.1039/d1cc07081a\">10.1039/d1cc07081a</a>.","short":"O. Yanshyna, L. Avram, L.J.W. Shimon, R. Klajn, Chemical Communications 58 (2022) 3461–3464.","ista":"Yanshyna O, Avram L, Shimon LJW, Klajn R. 2022. Coexistence of 1:1 and 2:1 inclusion complexes of indigo carmine. Chemical Communications. 58(21), 3461–3464.","apa":"Yanshyna, O., Avram, L., Shimon, L. J. W., &#38; Klajn, R. (2022). Coexistence of 1:1 and 2:1 inclusion complexes of indigo carmine. <i>Chemical Communications</i>. Royal Society of Chemistry. <a href=\"https://doi.org/10.1039/d1cc07081a\">https://doi.org/10.1039/d1cc07081a</a>","ieee":"O. Yanshyna, L. Avram, L. J. W. Shimon, and R. Klajn, “Coexistence of 1:1 and 2:1 inclusion complexes of indigo carmine,” <i>Chemical Communications</i>, vol. 58, no. 21. Royal Society of Chemistry, pp. 3461–3464, 2022.","chicago":"Yanshyna, Oksana, Liat Avram, Linda J. W. Shimon, and Rafal Klajn. “Coexistence of 1:1 and 2:1 Inclusion Complexes of Indigo Carmine.” <i>Chemical Communications</i>. Royal Society of Chemistry, 2022. <a href=\"https://doi.org/10.1039/d1cc07081a\">https://doi.org/10.1039/d1cc07081a</a>."},"date_created":"2023-08-01T09:32:55Z","publisher":"Royal Society of Chemistry","scopus_import":"1","language":[{"iso":"eng"}],"month":"01","article_type":"original","date_published":"2022-01-22T00:00:00Z","issue":"21","publication":"Chemical Communications","page":"3461-3464","intvolume":"        58","status":"public","day":"22","type":"journal_article"},{"language":[{"iso":"eng"}],"publisher":"Swiss Chemical Society","scopus_import":"1","article_type":"original","date_published":"2022-06-29T00:00:00Z","month":"06","date_created":"2023-08-09T13:08:15Z","status":"public","intvolume":"        76","type":"journal_article","day":"29","page":"520-528","issue":"6","publication":"Chimia","title":"Attosecond photoionization dynamics: from molecules over clusters to the liquid phase","year":"2022","doi":"10.2533/chimia.2022.520","main_file_link":[{"open_access":"1","url":"https://doi.org/10.2533/chimia.2022.520"}],"author":[{"first_name":"Xiaochun","full_name":"Gong, Xiaochun","last_name":"Gong"},{"first_name":"Inga","full_name":"Jordan, Inga","last_name":"Jordan"},{"first_name":"Martin","last_name":"Huppert","full_name":"Huppert, Martin"},{"first_name":"Saijoscha","full_name":"Heck, Saijoscha","last_name":"Heck"},{"full_name":"Baykusheva, Denitsa Rangelova","last_name":"Baykusheva","first_name":"Denitsa Rangelova","id":"71b4d059-2a03-11ee-914d-dfa3beed6530"},{"last_name":"Jelovina","full_name":"Jelovina, Denis","first_name":"Denis"},{"first_name":"Axel","last_name":"Schild","full_name":"Schild, Axel"},{"first_name":"Hans Jakob","last_name":"Wörner","full_name":"Wörner, Hans Jakob"}],"keyword":["General Medicine","General Chemistry"],"abstract":[{"lang":"eng","text":"Photoionization is a process taking place on attosecond time scales. How its properties evolve from isolated particles to the condensed phase is an open question of both fundamental and practical relevance. Here, we review recent work that has advanced the study of photoionization dynamics from atoms to molecules, clusters and the liquid phase. The first measurements of molecular photoionization delays have revealed the attosecond dynamics of electron emission from a molecular shape resonance and their sensitivity to the molecular potential. Using electron-ion coincidence spectroscopy these measurements have been extended from isolated molecules to clusters. A continuous increase of the delays with the water-cluster size has been observed up to a size of 4-5 molecules, followed by a saturation towards larger clusters. Comparison with calculations has revealed a correlation of the time delay with the spatial extension of the created electron hole. Using cylindrical liquid-microjet techniques, these measurements have also been extended to liquid water, revealing a delay relative to isolated water molecules that was very similar to the largest water clusters studied. Detailed modeling based on Monte-Carlo simulations confirmed that these delays are dominated by the contributions of the first two solvation shells, which agrees with the results of the cluster measurements. These combined results open the perspective of experimentally characterizing the delocalization of electronic wave functions in complex systems and studying their evolution on attosecond time scales."}],"publication_status":"published","citation":{"chicago":"Gong, Xiaochun, Inga Jordan, Martin Huppert, Saijoscha Heck, Denitsa Rangelova Baykusheva, Denis Jelovina, Axel Schild, and Hans Jakob Wörner. “Attosecond Photoionization Dynamics: From Molecules over Clusters to the Liquid Phase.” <i>Chimia</i>. Swiss Chemical Society, 2022. <a href=\"https://doi.org/10.2533/chimia.2022.520\">https://doi.org/10.2533/chimia.2022.520</a>.","apa":"Gong, X., Jordan, I., Huppert, M., Heck, S., Baykusheva, D. R., Jelovina, D., … Wörner, H. J. (2022). Attosecond photoionization dynamics: from molecules over clusters to the liquid phase. <i>Chimia</i>. Swiss Chemical Society. <a href=\"https://doi.org/10.2533/chimia.2022.520\">https://doi.org/10.2533/chimia.2022.520</a>","ieee":"X. Gong <i>et al.</i>, “Attosecond photoionization dynamics: from molecules over clusters to the liquid phase,” <i>Chimia</i>, vol. 76, no. 6. Swiss Chemical Society, pp. 520–528, 2022.","ista":"Gong X, Jordan I, Huppert M, Heck S, Baykusheva DR, Jelovina D, Schild A, Wörner HJ. 2022. Attosecond photoionization dynamics: from molecules over clusters to the liquid phase. Chimia. 76(6), 520–528.","short":"X. Gong, I. Jordan, M. Huppert, S. Heck, D.R. Baykusheva, D. Jelovina, A. Schild, H.J. Wörner, Chimia 76 (2022) 520–528.","mla":"Gong, Xiaochun, et al. “Attosecond Photoionization Dynamics: From Molecules over Clusters to the Liquid Phase.” <i>Chimia</i>, vol. 76, no. 6, Swiss Chemical Society, 2022, pp. 520–28, doi:<a href=\"https://doi.org/10.2533/chimia.2022.520\">10.2533/chimia.2022.520</a>.","ama":"Gong X, Jordan I, Huppert M, et al. Attosecond photoionization dynamics: from molecules over clusters to the liquid phase. <i>Chimia</i>. 2022;76(6):520-528. doi:<a href=\"https://doi.org/10.2533/chimia.2022.520\">10.2533/chimia.2022.520</a>"},"user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","quality_controlled":"1","oa_version":"Published Version","_id":"13993","publication_identifier":{"eissn":["2673-2424"],"issn":["0009-4293"]},"extern":"1","date_updated":"2023-08-22T07:26:39Z","oa":1,"volume":76,"article_processing_charge":"No"},{"ddc":["570"],"tmp":{"image":"/images/cc_by.png","legal_code_url":"https://creativecommons.org/licenses/by/4.0/legalcode","name":"Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)","short":"CC BY (4.0)"},"isi":1,"article_number":"4826","external_id":{"isi":["000841396400008"]},"title":"A direct excitatory projection from entorhinal layer 6b neurons to the hippocampus contributes to spatial coding and memory","doi":"10.1038/s41467-022-32559-8","year":"2022","acknowledged_ssus":[{"_id":"Bio"},{"_id":"SSU"}],"ec_funded":1,"publication_identifier":{"issn":["2041-1723"]},"_id":"11951","project":[{"grant_number":"692692","call_identifier":"H2020","name":"Biophysics and circuit function of a giant cortical glumatergic synapse","_id":"25B7EB9E-B435-11E9-9278-68D0E5697425"},{"grant_number":"I03600","call_identifier":"FWF","_id":"265CB4D0-B435-11E9-9278-68D0E5697425","name":"Optical control of synaptic function via adhesion molecules"},{"grant_number":"Z00312","_id":"25C5A090-B435-11E9-9278-68D0E5697425","name":"The Wittgenstein Prize","call_identifier":"FWF"}],"quality_controlled":"1","oa_version":"Published Version","user_id":"4359f0d1-fa6c-11eb-b949-802e58b17ae8","acknowledgement":"We thank F. Marr and A. Schlögl for technical assistance, E. Kralli-Beller for manuscript editing, as well as C. Sommer and the Imaging and Optics Facility of the Institute of Science and Technology Austria (ISTA) for image analysis scripts and microscopy support. We extend our gratitude to J. Wallenschus and D. Rangel Guerrero for technical assistance acquiring single-unit data and I. Gridchyn for help with single-unit clustering. Finally, we also thank B. Suter for discussions, A. Saunders, M. Jösch, and H. Monyer for critically reading earlier versions of the manuscript, C. Petersen for sharing clearing protocols, and the Scientific Service Units of ISTA for efficient support. This project was funded by the European Research Council (ERC) under the European Union’s Horizon 2020 research and innovation programme (ERC advanced grant No 692692 to P.J.) and the Fond zur Förderung der Wissenschaftlichen Forschung (Z 312-B27, Wittgenstein award for P.J. and I3600-B27 for J.G.D. and P.V.).","article_processing_charge":"No","date_updated":"2023-08-03T13:01:19Z","volume":13,"oa":1,"abstract":[{"lang":"eng","text":"The mammalian hippocampal formation (HF) plays a key role in several higher brain functions, such as spatial coding, learning and memory. Its simple circuit architecture is often viewed as a trisynaptic loop, processing input originating from the superficial layers of the entorhinal cortex (EC) and sending it back to its deeper layers. Here, we show that excitatory neurons in layer 6b of the mouse EC project to all sub-regions comprising the HF and receive input from the CA1, thalamus and claustrum. Furthermore, their output is characterized by unique slow-decaying excitatory postsynaptic currents capable of driving plateau-like potentials in their postsynaptic targets. Optogenetic inhibition of the EC-6b pathway affects spatial coding in CA1 pyramidal neurons, while cell ablation impairs not only acquisition of new spatial memories, but also degradation of previously acquired ones. Our results provide evidence of a functional role for cortical layer 6b neurons in the adult brain."}],"author":[{"id":"43DF3136-F248-11E8-B48F-1D18A9856A87","full_name":"Ben Simon, Yoav","last_name":"Ben Simon","first_name":"Yoav"},{"first_name":"Karola","full_name":"Käfer, Karola","last_name":"Käfer","id":"2DAA49AA-F248-11E8-B48F-1D18A9856A87"},{"full_name":"Velicky, Philipp","last_name":"Velicky","orcid":"0000-0002-2340-7431","first_name":"Philipp","id":"39BDC62C-F248-11E8-B48F-1D18A9856A87"},{"orcid":"0000-0002-5193-4036","last_name":"Csicsvari","full_name":"Csicsvari, Jozsef L","first_name":"Jozsef L","id":"3FA14672-F248-11E8-B48F-1D18A9856A87"},{"id":"42EFD3B6-F248-11E8-B48F-1D18A9856A87","orcid":"0000-0001-8559-3973","last_name":"Danzl","full_name":"Danzl, Johann G","first_name":"Johann G"},{"id":"353C1B58-F248-11E8-B48F-1D18A9856A87","full_name":"Jonas, Peter M","last_name":"Jonas","orcid":"0000-0001-5001-4804","first_name":"Peter M"}],"keyword":["General Physics and Astronomy","General Biochemistry","Genetics and Molecular Biology","General Chemistry","Multidisciplinary"],"citation":{"chicago":"Ben Simon, Yoav, Karola Käfer, Philipp Velicky, Jozsef L Csicsvari, Johann G Danzl, and Peter M Jonas. “A Direct Excitatory Projection from Entorhinal Layer 6b Neurons to the Hippocampus Contributes to Spatial Coding and Memory.” <i>Nature Communications</i>. Springer Nature, 2022. <a href=\"https://doi.org/10.1038/s41467-022-32559-8\">https://doi.org/10.1038/s41467-022-32559-8</a>.","apa":"Ben Simon, Y., Käfer, K., Velicky, P., Csicsvari, J. L., Danzl, J. G., &#38; Jonas, P. M. (2022). A direct excitatory projection from entorhinal layer 6b neurons to the hippocampus contributes to spatial coding and memory. <i>Nature Communications</i>. Springer Nature. <a href=\"https://doi.org/10.1038/s41467-022-32559-8\">https://doi.org/10.1038/s41467-022-32559-8</a>","ieee":"Y. Ben Simon, K. Käfer, P. Velicky, J. L. Csicsvari, J. G. Danzl, and P. M. Jonas, “A direct excitatory projection from entorhinal layer 6b neurons to the hippocampus contributes to spatial coding and memory,” <i>Nature Communications</i>, vol. 13. Springer Nature, 2022.","ista":"Ben Simon Y, Käfer K, Velicky P, Csicsvari JL, Danzl JG, Jonas PM. 2022. A direct excitatory projection from entorhinal layer 6b neurons to the hippocampus contributes to spatial coding and memory. Nature Communications. 13, 4826.","short":"Y. Ben Simon, K. Käfer, P. Velicky, J.L. Csicsvari, J.G. Danzl, P.M. Jonas, Nature Communications 13 (2022).","mla":"Ben Simon, Yoav, et al. “A Direct Excitatory Projection from Entorhinal Layer 6b Neurons to the Hippocampus Contributes to Spatial Coding and Memory.” <i>Nature Communications</i>, vol. 13, 4826, Springer Nature, 2022, doi:<a href=\"https://doi.org/10.1038/s41467-022-32559-8\">10.1038/s41467-022-32559-8</a>.","ama":"Ben Simon Y, Käfer K, Velicky P, Csicsvari JL, Danzl JG, Jonas PM. A direct excitatory projection from entorhinal layer 6b neurons to the hippocampus contributes to spatial coding and memory. <i>Nature Communications</i>. 2022;13. doi:<a href=\"https://doi.org/10.1038/s41467-022-32559-8\">10.1038/s41467-022-32559-8</a>"},"publication_status":"published","date_created":"2022-08-24T08:25:50Z","file":[{"success":1,"content_type":"application/pdf","relation":"main_file","file_id":"11990","creator":"dernst","file_name":"2022_NatureCommunications_BenSimon.pdf","file_size":5910357,"date_created":"2022-08-26T11:51:40Z","checksum":"405936d9e4d33625d80c093c9713a91f","date_updated":"2022-08-26T11:51:40Z","access_level":"open_access"}],"has_accepted_license":"1","department":[{"_id":"JoCs"},{"_id":"PeJo"},{"_id":"JoDa"}],"publisher":"Springer Nature","language":[{"iso":"eng"}],"month":"08","article_type":"original","date_published":"2022-08-16T00:00:00Z","publication":"Nature Communications","file_date_updated":"2022-08-26T11:51:40Z","intvolume":"        13","status":"public","day":"16","type":"journal_article"},{"keyword":["General Physics and Astronomy","General Biochemistry","Genetics and Molecular Biology","General Chemistry","Multidisciplinary"],"author":[{"full_name":"Huang, Jian","last_name":"Huang","first_name":"Jian"},{"first_name":"Lei","last_name":"Zhao","full_name":"Zhao, Lei"},{"first_name":"Shikha","last_name":"Malik","full_name":"Malik, Shikha"},{"first_name":"Benjamin R.","full_name":"Gentile, Benjamin R.","last_name":"Gentile"},{"last_name":"Xiong","full_name":"Xiong, Va","first_name":"Va"},{"first_name":"Tzahi","full_name":"Arazi, Tzahi","last_name":"Arazi"},{"first_name":"Heather A.","last_name":"Owen","full_name":"Owen, Heather A."},{"id":"4159519E-F248-11E8-B48F-1D18A9856A87","last_name":"Friml","full_name":"Friml, Jiří","orcid":"0000-0002-8302-7596","first_name":"Jiří"},{"last_name":"Zhao","full_name":"Zhao, Dazhong","first_name":"Dazhong"}],"abstract":[{"lang":"eng","text":"Germline determination is essential for species survival and evolution in multicellular organisms. In most flowering plants, formation of the female germline is initiated with specification of one megaspore mother cell (MMC) in each ovule; however, the molecular mechanism underlying this key event remains unclear. Here we report that spatially restricted auxin signaling promotes MMC fate in Arabidopsis. Our results show that the microRNA160 (miR160) targeted gene ARF17 (AUXIN RESPONSE FACTOR17) is required for promoting MMC specification by genetically interacting with the SPL/NZZ (SPOROCYTELESS/NOZZLE) gene. Alterations of auxin signaling cause formation of supernumerary MMCs in an ARF17- and SPL/NZZ-dependent manner. Furthermore, miR160 and ARF17 are indispensable for attaining a normal auxin maximum at the ovule apex via modulating the expression domain of PIN1 (PIN-FORMED1) auxin transporter. Our findings elucidate the mechanism by which auxin signaling promotes the acquisition of female germline cell fate in plants."}],"citation":{"chicago":"Huang, Jian, Lei Zhao, Shikha Malik, Benjamin R. Gentile, Va Xiong, Tzahi Arazi, Heather A. Owen, Jiří Friml, and Dazhong Zhao. “Specification of Female Germline by MicroRNA Orchestrated Auxin Signaling in Arabidopsis.” <i>Nature Communications</i>. Springer Nature, 2022. <a href=\"https://doi.org/10.1038/s41467-022-34723-6\">https://doi.org/10.1038/s41467-022-34723-6</a>.","ieee":"J. Huang <i>et al.</i>, “Specification of female germline by microRNA orchestrated auxin signaling in Arabidopsis,” <i>Nature Communications</i>, vol. 13. Springer Nature, 2022.","apa":"Huang, J., Zhao, L., Malik, S., Gentile, B. R., Xiong, V., Arazi, T., … Zhao, D. (2022). Specification of female germline by microRNA orchestrated auxin signaling in Arabidopsis. <i>Nature Communications</i>. Springer Nature. <a href=\"https://doi.org/10.1038/s41467-022-34723-6\">https://doi.org/10.1038/s41467-022-34723-6</a>","ista":"Huang J, Zhao L, Malik S, Gentile BR, Xiong V, Arazi T, Owen HA, Friml J, Zhao D. 2022. Specification of female germline by microRNA orchestrated auxin signaling in Arabidopsis. Nature Communications. 13, 6960.","short":"J. Huang, L. Zhao, S. Malik, B.R. Gentile, V. Xiong, T. Arazi, H.A. Owen, J. Friml, D. Zhao, Nature Communications 13 (2022).","ama":"Huang J, Zhao L, Malik S, et al. Specification of female germline by microRNA orchestrated auxin signaling in Arabidopsis. <i>Nature Communications</i>. 2022;13. doi:<a href=\"https://doi.org/10.1038/s41467-022-34723-6\">10.1038/s41467-022-34723-6</a>","mla":"Huang, Jian, et al. “Specification of Female Germline by MicroRNA Orchestrated Auxin Signaling in Arabidopsis.” <i>Nature Communications</i>, vol. 13, 6960, Springer Nature, 2022, doi:<a href=\"https://doi.org/10.1038/s41467-022-34723-6\">10.1038/s41467-022-34723-6</a>."},"publication_status":"published","oa_version":"Published Version","quality_controlled":"1","user_id":"4359f0d1-fa6c-11eb-b949-802e58b17ae8","acknowledgement":"We thank A. Cheung,W. Lukowitz, V.Walbot, D.Weijers, and R. Yadegari for critically reading the manuscript; E. Xiong and G. Zhang for preparing some experiments, T. Schuck, J. Gonnering, and P. Engevold for plant care, the Arabidopsis Biological Resource Center (ABRC) for ARF10,ARF16, ARF17, EMS1,MIR160a BAC clones and cDNAs, the SALK_090804 seed, T. Nakagawa for pGBW vectors, Y. Zhao for the YUC1 cDNA, Q. Chen for the pHEE401E vector, R. Yadegari for pAT5G01860::n1GFP, pAT5G45980:n1GFP, pAT5G50490::n1GFP, pAT5G56200:n1GFP vectors, and D.Weijers for the pGreenII KAN SV40-3×GFP and R2D2 vectors, W. Yang for the splmutant, Y. Qin for the pKNU::KNU-VENUS vector and seed, G. Tang for the STTM160/160-48 vector, and L. Colombo for pPIN1::PIN1-GFP spl and pin1-5 seeds. This work was supported by the US National Science Foundation (NSF)-Israel Binational Science Foundation (BSF) research grant to D.Z. (IOS-1322796) and T.A. (2012756). D.Z. also\r\ngratefully acknowledges supports of the Shaw Scientist Award from the Greater Milwaukee Foundation, USDA National Institute of Food and Agriculture (NIFA, 2022-67013-36294), the UWM Discovery and Innovation Grant, the Bradley Catalyst Award from the UWM Research\r\nFoundation, and WiSys and UW System Applied Research Funding Programs.","publication_identifier":{"issn":["2041-1723"]},"_id":"12130","pmid":1,"article_processing_charge":"No","volume":13,"oa":1,"date_updated":"2023-08-04T08:52:01Z","title":"Specification of female germline by microRNA orchestrated auxin signaling in Arabidopsis","external_id":{"pmid":["36379956"],"isi":["000884426700001"]},"year":"2022","doi":"10.1038/s41467-022-34723-6","ddc":["580"],"article_number":"6960","isi":1,"tmp":{"image":"/images/cc_by.png","legal_code_url":"https://creativecommons.org/licenses/by/4.0/legalcode","name":"Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)","short":"CC BY (4.0)"},"status":"public","intvolume":"        13","type":"journal_article","day":"15","file_date_updated":"2023-01-23T11:17:33Z","publication":"Nature Communications","language":[{"iso":"eng"}],"scopus_import":"1","publisher":"Springer Nature","date_published":"2022-11-15T00:00:00Z","article_type":"original","month":"11","file":[{"success":1,"creator":"dernst","file_id":"12346","content_type":"application/pdf","relation":"main_file","date_created":"2023-01-23T11:17:33Z","checksum":"233922a7b9507d9d48591e6799e4526e","file_name":"2022_NatureCommunications_Huang.pdf","file_size":3375249,"date_updated":"2023-01-23T11:17:33Z","access_level":"open_access"}],"date_created":"2023-01-12T12:02:41Z","department":[{"_id":"JiFr"}],"has_accepted_license":"1"},{"intvolume":"        13","status":"public","day":"24","type":"journal_article","publication":"Nature Communications","file_date_updated":"2023-01-27T07:19:11Z","publisher":"Springer Nature","scopus_import":"1","language":[{"iso":"eng"}],"month":"10","date_published":"2022-10-24T00:00:00Z","article_type":"original","date_created":"2023-01-16T09:45:09Z","file":[{"success":1,"file_id":"12411","creator":"dernst","content_type":"application/pdf","relation":"main_file","date_created":"2023-01-27T07:19:11Z","checksum":"5034336dbf0f860030ef745c08df9e0e","file_name":"2022_NatureCommunications_Prehal.pdf","file_size":4216931,"date_updated":"2023-01-27T07:19:11Z","access_level":"open_access"}],"has_accepted_license":"1","department":[{"_id":"StFr"}],"abstract":[{"lang":"eng","text":"The inadequate understanding of the mechanisms that reversibly convert molecular sulfur (S) into lithium sulfide (Li<jats:sub>2</jats:sub>S) via soluble polysulfides (PSs) formation impedes the development of high-performance lithium-sulfur (Li-S) batteries with non-aqueous electrolyte solutions. Here, we use operando small and wide angle X-ray scattering and operando small angle neutron scattering (SANS) measurements to track the nucleation, growth and dissolution of solid deposits from atomic to sub-micron scales during real-time Li-S cell operation. In particular, stochastic modelling based on the SANS data allows quantifying the nanoscale phase evolution during battery cycling. We show that next to nano-crystalline Li<jats:sub>2</jats:sub>S the deposit comprises solid short-chain PSs particles. The analysis of the experimental data suggests that initially, Li<jats:sub>2</jats:sub>S<jats:sub>2</jats:sub> precipitates from the solution and then is partially converted via solid-state electroreduction to Li<jats:sub>2</jats:sub>S. We further demonstrate that mass transport, rather than electron transport through a thin passivating film, limits the discharge capacity and rate performance in Li-S cells."}],"author":[{"first_name":"Christian","last_name":"Prehal","full_name":"Prehal, Christian"},{"last_name":"von Mentlen","full_name":"von Mentlen, Jean-Marc","first_name":"Jean-Marc"},{"first_name":"Sara","last_name":"Drvarič Talian","full_name":"Drvarič Talian, Sara"},{"first_name":"Alen","last_name":"Vizintin","full_name":"Vizintin, Alen"},{"last_name":"Dominko","full_name":"Dominko, Robert","first_name":"Robert"},{"first_name":"Heinz","full_name":"Amenitsch, Heinz","last_name":"Amenitsch"},{"last_name":"Porcar","full_name":"Porcar, Lionel","first_name":"Lionel"},{"last_name":"Freunberger","full_name":"Freunberger, Stefan Alexander","orcid":"0000-0003-2902-5319","first_name":"Stefan Alexander","id":"A8CA28E6-CE23-11E9-AD2D-EC27E6697425"},{"full_name":"Wood, Vanessa","last_name":"Wood","first_name":"Vanessa"}],"keyword":["General Physics and Astronomy","General Biochemistry","Genetics and Molecular Biology","General Chemistry","Multidisciplinary"],"publication_status":"published","citation":{"apa":"Prehal, C., von Mentlen, J.-M., Drvarič Talian, S., Vizintin, A., Dominko, R., Amenitsch, H., … Wood, V. (2022). On the nanoscale structural evolution of solid discharge products in lithium-sulfur batteries using operando scattering. <i>Nature Communications</i>. Springer Nature. <a href=\"https://doi.org/10.1038/s41467-022-33931-4\">https://doi.org/10.1038/s41467-022-33931-4</a>","ieee":"C. Prehal <i>et al.</i>, “On the nanoscale structural evolution of solid discharge products in lithium-sulfur batteries using operando scattering,” <i>Nature Communications</i>, vol. 13. Springer Nature, 2022.","chicago":"Prehal, Christian, Jean-Marc von Mentlen, Sara Drvarič Talian, Alen Vizintin, Robert Dominko, Heinz Amenitsch, Lionel Porcar, Stefan Alexander Freunberger, and Vanessa Wood. “On the Nanoscale Structural Evolution of Solid Discharge Products in Lithium-Sulfur Batteries Using Operando Scattering.” <i>Nature Communications</i>. Springer Nature, 2022. <a href=\"https://doi.org/10.1038/s41467-022-33931-4\">https://doi.org/10.1038/s41467-022-33931-4</a>.","ama":"Prehal C, von Mentlen J-M, Drvarič Talian S, et al. On the nanoscale structural evolution of solid discharge products in lithium-sulfur batteries using operando scattering. <i>Nature Communications</i>. 2022;13. doi:<a href=\"https://doi.org/10.1038/s41467-022-33931-4\">10.1038/s41467-022-33931-4</a>","mla":"Prehal, Christian, et al. “On the Nanoscale Structural Evolution of Solid Discharge Products in Lithium-Sulfur Batteries Using Operando Scattering.” <i>Nature Communications</i>, vol. 13, 6326, Springer Nature, 2022, doi:<a href=\"https://doi.org/10.1038/s41467-022-33931-4\">10.1038/s41467-022-33931-4</a>.","ista":"Prehal C, von Mentlen J-M, Drvarič Talian S, Vizintin A, Dominko R, Amenitsch H, Porcar L, Freunberger SA, Wood V. 2022. On the nanoscale structural evolution of solid discharge products in lithium-sulfur batteries using operando scattering. Nature Communications. 13, 6326.","short":"C. Prehal, J.-M. von Mentlen, S. Drvarič Talian, A. Vizintin, R. Dominko, H. Amenitsch, L. Porcar, S.A. Freunberger, V. Wood, Nature Communications 13 (2022)."},"pmid":1,"_id":"12208","publication_identifier":{"issn":["2041-1723"]},"acknowledgement":"This project has received funding from the European Union’s Horizon 2020 research and innovation program under the Marie Skłodowska-Curie grant NanoEvolution, grant agreement No 894042. The authors acknowledge the CERIC-ERIC Consortium for the access to the Austrian SAXS beamline and TU Graz for support through the Lead Project LP-03.\r\nLikewise, the use of SOMAPP Lab, a core facility supported by the Austrian Federal Ministry of Education, Science and Research, the Graz University of Technology, the University of Graz, and Anton Paar GmbH is acknowledged. In addition, the authors acknowledge access to the D-22SANS beamline at the ILL neutron source. Electron microscopy measurements were performed at the Scientific Scenter for Optical and Electron Microscopy (ScopeM) of the Swiss Federal Institute of Technology. C.P. and J.M.M. thank A. Senol for her support with the SANS\r\nbeamtime preparation. S.D.T, A.V. and R.D. acknowledge the financial support by the Slovenian Research Agency (ARRS) research core funding P2-0393 and P2-0423. Furthermore, A.V. acknowledge the funding from the Slovenian Research Agency, research project Z2−1863.\r\nS.A.F. is indebted to IST Austria for support. ","user_id":"4359f0d1-fa6c-11eb-b949-802e58b17ae8","oa_version":"Published Version","quality_controlled":"1","oa":1,"volume":13,"date_updated":"2023-08-04T09:15:31Z","article_processing_charge":"No","title":"On the nanoscale structural evolution of solid discharge products in lithium-sulfur batteries using operando scattering","external_id":{"isi":["000871563700006"],"pmid":["36280671"]},"year":"2022","doi":"10.1038/s41467-022-33931-4","ddc":["540"],"tmp":{"image":"/images/cc_by.png","legal_code_url":"https://creativecommons.org/licenses/by/4.0/legalcode","name":"Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)","short":"CC BY (4.0)"},"isi":1,"article_number":"6326"},{"project":[{"grant_number":"851288","_id":"05943252-7A3F-11EA-A408-12923DDC885E","name":"Design Principles of Branching Morphogenesis","call_identifier":"H2020"}],"quality_controlled":"1","oa_version":"Published Version","acknowledgement":"A.R.B. acknowledges the financial support of the European Research Council (ERC) through the funding of the grant Principles of Integrin Mechanics and Adhesion (PoINT) and the German Research Foundation (DFG, SFB 1032, project ID 201269156). E.H. was supported by the European Union (European Research Council Starting Grant 851288). D.S., M.R., and R.R. acknowledge the support by the German Research Foundation (DFG, SFB1321 Modeling and Targeting Pancreatic Cancer, Project S01, project ID 329628492). C.S. and M.R. acknowledge the support by the German Research Foundation (DFG, SFB1321 Modeling and Targeting Pancreatic Cancer, Project 12, project ID 329628492). M.R. was supported by the German Research Foundation (DFG RE 3723/4-1). A.P. and M.R. were supported by the German Cancer Aid (Max-Eder Program 111273 and 70114328).\r\nOpen Access funding enabled and organized by Projekt DEAL.","user_id":"4359f0d1-fa6c-11eb-b949-802e58b17ae8","publication_identifier":{"issn":["2041-1723"]},"_id":"12217","article_processing_charge":"No","volume":13,"oa":1,"date_updated":"2023-08-04T09:25:23Z","author":[{"last_name":"Randriamanantsoa","full_name":"Randriamanantsoa, S.","first_name":"S."},{"first_name":"A.","last_name":"Papargyriou","full_name":"Papargyriou, A."},{"full_name":"Maurer, H. C.","last_name":"Maurer","first_name":"H. C."},{"first_name":"K.","full_name":"Peschke, K.","last_name":"Peschke"},{"first_name":"M.","last_name":"Schuster","full_name":"Schuster, M."},{"first_name":"G.","full_name":"Zecchin, G.","last_name":"Zecchin"},{"last_name":"Steiger","full_name":"Steiger, K.","first_name":"K."},{"last_name":"Öllinger","full_name":"Öllinger, R.","first_name":"R."},{"first_name":"D.","last_name":"Saur","full_name":"Saur, D."},{"last_name":"Scheel","full_name":"Scheel, C.","first_name":"C."},{"first_name":"R.","last_name":"Rad","full_name":"Rad, R."},{"id":"3A9DB764-F248-11E8-B48F-1D18A9856A87","last_name":"Hannezo","full_name":"Hannezo, Edouard B","orcid":"0000-0001-6005-1561","first_name":"Edouard B"},{"full_name":"Reichert, M.","last_name":"Reichert","first_name":"M."},{"full_name":"Bausch, A. R.","last_name":"Bausch","first_name":"A. R."}],"keyword":["General Physics and Astronomy","General Biochemistry","Genetics and Molecular Biology","General Chemistry","Multidisciplinary"],"abstract":[{"text":"The development dynamics and self-organization of glandular branched epithelia is of utmost importance for our understanding of diverse processes ranging from normal tissue growth to the growth of cancerous tissues. Using single primary murine pancreatic ductal adenocarcinoma (PDAC) cells embedded in a collagen matrix and adapted media supplementation, we generate organoids that self-organize into highly branched structures displaying a seamless lumen connecting terminal end buds, replicating in vivo PDAC architecture. We identify distinct morphogenesis phases, each characterized by a unique pattern of cell invasion, matrix deformation, protein expression, and respective molecular dependencies. We propose a minimal theoretical model of a branching and proliferating tissue, capturing the dynamics of the first phases. Observing the interaction of morphogenesis, mechanical environment and gene expression in vitro sets a benchmark for the understanding of self-organization processes governing complex organoid structure formation processes and branching morphogenesis.","lang":"eng"}],"citation":{"ama":"Randriamanantsoa S, Papargyriou A, Maurer HC, et al. Spatiotemporal dynamics of self-organized branching in pancreas-derived organoids. <i>Nature Communications</i>. 2022;13. doi:<a href=\"https://doi.org/10.1038/s41467-022-32806-y\">10.1038/s41467-022-32806-y</a>","mla":"Randriamanantsoa, S., et al. “Spatiotemporal Dynamics of Self-Organized Branching in Pancreas-Derived Organoids.” <i>Nature Communications</i>, vol. 13, 5219, Springer Nature, 2022, doi:<a href=\"https://doi.org/10.1038/s41467-022-32806-y\">10.1038/s41467-022-32806-y</a>.","ista":"Randriamanantsoa S, Papargyriou A, Maurer HC, Peschke K, Schuster M, Zecchin G, Steiger K, Öllinger R, Saur D, Scheel C, Rad R, Hannezo EB, Reichert M, Bausch AR. 2022. Spatiotemporal dynamics of self-organized branching in pancreas-derived organoids. Nature Communications. 13, 5219.","short":"S. Randriamanantsoa, A. Papargyriou, H.C. Maurer, K. Peschke, M. Schuster, G. Zecchin, K. Steiger, R. Öllinger, D. Saur, C. Scheel, R. Rad, E.B. Hannezo, M. Reichert, A.R. Bausch, Nature Communications 13 (2022).","ieee":"S. Randriamanantsoa <i>et al.</i>, “Spatiotemporal dynamics of self-organized branching in pancreas-derived organoids,” <i>Nature Communications</i>, vol. 13. Springer Nature, 2022.","apa":"Randriamanantsoa, S., Papargyriou, A., Maurer, H. C., Peschke, K., Schuster, M., Zecchin, G., … Bausch, A. R. (2022). Spatiotemporal dynamics of self-organized branching in pancreas-derived organoids. <i>Nature Communications</i>. Springer Nature. <a href=\"https://doi.org/10.1038/s41467-022-32806-y\">https://doi.org/10.1038/s41467-022-32806-y</a>","chicago":"Randriamanantsoa, S., A. Papargyriou, H. C. Maurer, K. Peschke, M. Schuster, G. Zecchin, K. Steiger, et al. “Spatiotemporal Dynamics of Self-Organized Branching in Pancreas-Derived Organoids.” <i>Nature Communications</i>. Springer Nature, 2022. <a href=\"https://doi.org/10.1038/s41467-022-32806-y\">https://doi.org/10.1038/s41467-022-32806-y</a>."},"publication_status":"published","ddc":["570"],"related_material":{"record":[{"id":"13068","relation":"research_data","status":"public"}]},"article_number":"5219","isi":1,"tmp":{"image":"/images/cc_by.png","legal_code_url":"https://creativecommons.org/licenses/by/4.0/legalcode","name":"Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)","short":"CC BY (4.0)"},"external_id":{"isi":["000850348400025"]},"title":"Spatiotemporal dynamics of self-organized branching in pancreas-derived organoids","ec_funded":1,"year":"2022","doi":"10.1038/s41467-022-32806-y","file_date_updated":"2023-01-27T08:14:48Z","publication":"Nature Communications","status":"public","intvolume":"        13","type":"journal_article","day":"05","file":[{"success":1,"relation":"main_file","content_type":"application/pdf","file_id":"12416","creator":"dernst","file_size":22645149,"file_name":"2022_NatureCommunications_Randriamanantsoa.pdf","checksum":"295261b5172274fd5b8f85a6a6058828","date_created":"2023-01-27T08:14:48Z","access_level":"open_access","date_updated":"2023-01-27T08:14:48Z"}],"date_created":"2023-01-16T09:46:53Z","department":[{"_id":"EdHa"}],"has_accepted_license":"1","language":[{"iso":"eng"}],"scopus_import":"1","publisher":"Springer Nature","article_type":"original","date_published":"2022-09-05T00:00:00Z","month":"09"}]