[{"day":"19","citation":{"ista":"Archer LA, Bruce PG, Calvo EJ, Dewar D, Ellison JHJ, Freunberger SA, Gao X, Hardwick LJ, Horwitz G, Janek J, Johnson LR, Jordan JW, Matsuda S, Menkin S, Mondal S, Qiu Q, Samarakoon T, Temprano I, Uosaki K, Vailaya G, Wachsman ED, Wu Y, Ye S. 2023. Towards practical metal–oxygen batteries: General discussion. Faraday Discussions.","short":"L.A. Archer, P.G. Bruce, E.J. Calvo, D. Dewar, J.H.J. Ellison, S.A. Freunberger, X. Gao, L.J. Hardwick, G. Horwitz, J. Janek, L.R. Johnson, J.W. Jordan, S. Matsuda, S. Menkin, S. Mondal, Q. Qiu, T. Samarakoon, I. Temprano, K. Uosaki, G. Vailaya, E.D. Wachsman, Y. Wu, S. Ye, Faraday Discussions (2023).","ama":"Archer LA, Bruce PG, Calvo EJ, et al. Towards practical metal–oxygen batteries: General discussion. <i>Faraday Discussions</i>. 2023. doi:<a href=\"https://doi.org/10.1039/d3fd90062b\">10.1039/d3fd90062b</a>","mla":"Archer, Lynden A., et al. “Towards Practical Metal–Oxygen Batteries: General Discussion.” <i>Faraday Discussions</i>, Royal Society of Chemistry, 2023, doi:<a href=\"https://doi.org/10.1039/d3fd90062b\">10.1039/d3fd90062b</a>.","chicago":"Archer, Lynden A., Peter G. Bruce, Ernesto J. Calvo, Daniel Dewar, James H. J. Ellison, Stefan Alexander Freunberger, Xiangwen Gao, et al. “Towards Practical Metal–Oxygen Batteries: General Discussion.” <i>Faraday Discussions</i>. Royal Society of Chemistry, 2023. <a href=\"https://doi.org/10.1039/d3fd90062b\">https://doi.org/10.1039/d3fd90062b</a>.","ieee":"L. A. Archer <i>et al.</i>, “Towards practical metal–oxygen batteries: General discussion,” <i>Faraday Discussions</i>. Royal Society of Chemistry, 2023.","apa":"Archer, L. A., Bruce, P. G., Calvo, E. J., Dewar, D., Ellison, J. H. J., Freunberger, S. A., … Ye, S. (2023). Towards practical metal–oxygen batteries: General discussion. <i>Faraday Discussions</i>. Royal Society of Chemistry. <a href=\"https://doi.org/10.1039/d3fd90062b\">https://doi.org/10.1039/d3fd90062b</a>"},"publication_status":"epub_ahead","type":"journal_article","author":[{"full_name":"Archer, Lynden A.","last_name":"Archer","first_name":"Lynden A."},{"first_name":"Peter G.","last_name":"Bruce","full_name":"Bruce, Peter G."},{"first_name":"Ernesto J.","last_name":"Calvo","full_name":"Calvo, Ernesto J."},{"full_name":"Dewar, Daniel","last_name":"Dewar","first_name":"Daniel"},{"last_name":"Ellison","full_name":"Ellison, James H. J.","first_name":"James H. J."},{"id":"A8CA28E6-CE23-11E9-AD2D-EC27E6697425","first_name":"Stefan Alexander","orcid":"0000-0003-2902-5319","last_name":"Freunberger","full_name":"Freunberger, Stefan Alexander"},{"first_name":"Xiangwen","last_name":"Gao","full_name":"Gao, Xiangwen"},{"first_name":"Laurence J.","full_name":"Hardwick, Laurence J.","last_name":"Hardwick"},{"first_name":"Gabriela","last_name":"Horwitz","full_name":"Horwitz, Gabriela"},{"last_name":"Janek","full_name":"Janek, Jürgen","first_name":"Jürgen"},{"first_name":"Lee R.","full_name":"Johnson, Lee R.","last_name":"Johnson"},{"full_name":"Jordan, Jack W.","last_name":"Jordan","first_name":"Jack W."},{"last_name":"Matsuda","full_name":"Matsuda, Shoichi","first_name":"Shoichi"},{"full_name":"Menkin, Svetlana","last_name":"Menkin","first_name":"Svetlana"},{"id":"d25d21ef-dc8d-11ea-abe3-ec4576307f48","first_name":"Soumyadip","last_name":"Mondal","full_name":"Mondal, Soumyadip"},{"first_name":"Qianyuan","full_name":"Qiu, Qianyuan","last_name":"Qiu"},{"last_name":"Samarakoon","full_name":"Samarakoon, Thukshan","first_name":"Thukshan"},{"first_name":"Israel","full_name":"Temprano, Israel","last_name":"Temprano"},{"first_name":"Kohei","last_name":"Uosaki","full_name":"Uosaki, Kohei"},{"full_name":"Vailaya, Ganesh","last_name":"Vailaya","first_name":"Ganesh"},{"first_name":"Eric D.","full_name":"Wachsman, Eric D.","last_name":"Wachsman"},{"first_name":"Yiying","full_name":"Wu, Yiying","last_name":"Wu"},{"full_name":"Ye, Shen","last_name":"Ye","first_name":"Shen"}],"keyword":["Physical and Theoretical Chemistry"],"status":"public","publication":"Faraday Discussions","article_processing_charge":"No","date_updated":"2023-12-20T11:54:06Z","publication_identifier":{"eissn":["1364-5498"],"issn":["1359-6640"]},"_id":"14701","oa_version":"None","quality_controlled":"1","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","doi":"10.1039/d3fd90062b","year":"2023","month":"12","article_type":"review","date_published":"2023-12-19T00:00:00Z","title":"Towards practical metal–oxygen batteries: General discussion","publisher":"Royal Society of Chemistry","language":[{"iso":"eng"}],"department":[{"_id":"StFr"}],"date_created":"2023-12-20T10:48:09Z"},{"doi":"10.1039/d3fd90059b","year":"2023","month":"12","date_published":"2023-12-18T00:00:00Z","article_type":"review","title":"Materials for stable metal–oxygen battery cathodes: general discussion","publisher":"Royal Society of Chemistry","language":[{"iso":"eng"}],"department":[{"_id":"StFr"}],"date_created":"2023-12-20T10:49:43Z","day":"18","citation":{"short":"G.A. Attard, E.J. Calvo, L.A. Curtiss, D. Dewar, J.H.J. Ellison, X. Gao, C.P. Grey, L.J. Hardwick, G. Horwitz, J. Janek, L.R. Johnson, J.W. Jordan, S. Matsuda, S. Mondal, A.R. Neale, N. Ortiz-Vitoriano, I. Temprano, G. Vailaya, E.D. Wachsman, H.-H. Wang, Y. Wu, S. Ye, Faraday Discussions (2023).","ista":"Attard GA, Calvo EJ, Curtiss LA, Dewar D, Ellison JHJ, Gao X, Grey CP, Hardwick LJ, Horwitz G, Janek J, Johnson LR, Jordan JW, Matsuda S, Mondal S, Neale AR, Ortiz-Vitoriano N, Temprano I, Vailaya G, Wachsman ED, Wang H-H, Wu Y, Ye S. 2023. Materials for stable metal–oxygen battery cathodes: general discussion. Faraday Discussions.","mla":"Attard, Gary A., et al. “Materials for Stable Metal–Oxygen Battery Cathodes: General Discussion.” <i>Faraday Discussions</i>, Royal Society of Chemistry, 2023, doi:<a href=\"https://doi.org/10.1039/d3fd90059b\">10.1039/d3fd90059b</a>.","ama":"Attard GA, Calvo EJ, Curtiss LA, et al. Materials for stable metal–oxygen battery cathodes: general discussion. <i>Faraday Discussions</i>. 2023. doi:<a href=\"https://doi.org/10.1039/d3fd90059b\">10.1039/d3fd90059b</a>","chicago":"Attard, Gary A., Ernesto J. Calvo, Larry A. Curtiss, Daniel Dewar, James H. J. Ellison, Xiangwen Gao, Clare P. Grey, et al. “Materials for Stable Metal–Oxygen Battery Cathodes: General Discussion.” <i>Faraday Discussions</i>. Royal Society of Chemistry, 2023. <a href=\"https://doi.org/10.1039/d3fd90059b\">https://doi.org/10.1039/d3fd90059b</a>.","ieee":"G. A. Attard <i>et al.</i>, “Materials for stable metal–oxygen battery cathodes: general discussion,” <i>Faraday Discussions</i>. Royal Society of Chemistry, 2023.","apa":"Attard, G. A., Calvo, E. J., Curtiss, L. A., Dewar, D., Ellison, J. H. J., Gao, X., … Ye, S. (2023). Materials for stable metal–oxygen battery cathodes: general discussion. <i>Faraday Discussions</i>. Royal Society of Chemistry. <a href=\"https://doi.org/10.1039/d3fd90059b\">https://doi.org/10.1039/d3fd90059b</a>"},"publication_status":"epub_ahead","type":"journal_article","status":"public","author":[{"first_name":"Gary A.","full_name":"Attard, Gary A.","last_name":"Attard"},{"first_name":"Ernesto J.","last_name":"Calvo","full_name":"Calvo, Ernesto J."},{"full_name":"Curtiss, Larry A.","last_name":"Curtiss","first_name":"Larry A."},{"last_name":"Dewar","full_name":"Dewar, Daniel","first_name":"Daniel"},{"full_name":"Ellison, James H. J.","last_name":"Ellison","first_name":"James H. J."},{"first_name":"Xiangwen","full_name":"Gao, Xiangwen","last_name":"Gao"},{"full_name":"Grey, Clare P.","last_name":"Grey","first_name":"Clare P."},{"first_name":"Laurence J.","last_name":"Hardwick","full_name":"Hardwick, Laurence J."},{"first_name":"Gabriela","full_name":"Horwitz, Gabriela","last_name":"Horwitz"},{"last_name":"Janek","full_name":"Janek, Juergen","first_name":"Juergen"},{"first_name":"Lee R.","full_name":"Johnson, Lee R.","last_name":"Johnson"},{"first_name":"Jack W.","full_name":"Jordan, Jack W.","last_name":"Jordan"},{"first_name":"Shoichi","last_name":"Matsuda","full_name":"Matsuda, Shoichi"},{"id":"d25d21ef-dc8d-11ea-abe3-ec4576307f48","full_name":"Mondal, Soumyadip","last_name":"Mondal","first_name":"Soumyadip"},{"first_name":"Alex R.","last_name":"Neale","full_name":"Neale, Alex R."},{"first_name":"Nagore","full_name":"Ortiz-Vitoriano, Nagore","last_name":"Ortiz-Vitoriano"},{"full_name":"Temprano, Israel","last_name":"Temprano","first_name":"Israel"},{"first_name":"Ganesh","full_name":"Vailaya, Ganesh","last_name":"Vailaya"},{"first_name":"Eric D.","full_name":"Wachsman, Eric D.","last_name":"Wachsman"},{"first_name":"Hsien-Hau","last_name":"Wang","full_name":"Wang, Hsien-Hau"},{"first_name":"Yiying","last_name":"Wu","full_name":"Wu, Yiying"},{"last_name":"Ye","full_name":"Ye, Shen","first_name":"Shen"}],"keyword":["Physical and Theoretical Chemistry"],"publication":"Faraday Discussions","article_processing_charge":"No","date_updated":"2023-12-20T11:58:12Z","publication_identifier":{"issn":["1359-6640"],"eissn":["1364-5498"]},"_id":"14702","oa_version":"None","quality_controlled":"1","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87"},{"title":"Singlet oxygen in non-aqueous oxygen redox: Direct spectroscopic evidence for formation pathways and reliability of chemical probes","external_id":{"isi":["001070423500001"]},"doi":"10.1039/d3fd00088e","year":"2023","tmp":{"legal_code_url":"https://creativecommons.org/licenses/by-nc/4.0/legalcode","image":"/images/cc_by_nc.png","name":"Creative Commons Attribution-NonCommercial 4.0 International (CC BY-NC 4.0)","short":"CC BY-NC (4.0)"},"main_file_link":[{"url":"https://doi.org/10.1039/d3fd00088e","open_access":"1"}],"isi":1,"abstract":[{"text":"Singlet oxygen (1O2) formation is now recognised as a key aspect of non-aqueous oxygen redox chemistry. For identifying 1O2, chemical trapping via 9,10-dimethylanthracene (DMA) to form the endoperoxide (DMA-O2) has become the mainstay method due to its sensitivity, selectivity, and ease of use. While DMA has been shown to be selective for 1O2, rather than forming DMA-O2 with a wide variety of potentially reactive O-containing species, false positives might hypothetically be obtained in the presence of previously overlooked species. Here, we first give unequivocal direct spectroscopic proof by the 1O2-specific near infrared (NIR) emission at 1270 nm for the previously proposed 1O2 formation pathways, which centre around superoxide disproportionation. We then show that peroxocarbonates, common intermediates in metal-O2 and metal carbonate electrochemistry, do not produce false-positive DMA-O2. Moreover, we identify a previously unreported 1O2-forming pathway through the reaction of CO2 with superoxide. Overall, we give unequivocal proof for 1O2 formation in non-aqueous oxygen redox and show that chemical trapping with DMA is a reliable method to assess 1O2 formation.","lang":"eng"}],"keyword":["Physical and Theoretical Chemistry"],"author":[{"id":"d25d21ef-dc8d-11ea-abe3-ec4576307f48","first_name":"Soumyadip","full_name":"Mondal, Soumyadip","last_name":"Mondal"},{"first_name":"Rajesh B","full_name":"Jethwa, Rajesh B","last_name":"Jethwa","orcid":"0000-0002-0404-4356","id":"4cc538d5-803f-11ed-ab7e-8139573aad8f"},{"id":"50c64d4d-eb97-11eb-a6c2-d33e5e14f112","first_name":"Bhargavi","full_name":"Pant, Bhargavi","last_name":"Pant"},{"id":"4E01D6B4-F248-11E8-B48F-1D18A9856A87","full_name":"Hauschild, Robert","last_name":"Hauschild","orcid":"0000-0001-9843-3522","first_name":"Robert"},{"id":"A8CA28E6-CE23-11E9-AD2D-EC27E6697425","first_name":"Stefan Alexander","orcid":"0000-0003-2902-5319","full_name":"Freunberger, Stefan Alexander","last_name":"Freunberger"}],"citation":{"chicago":"Mondal, Soumyadip, Rajesh B Jethwa, Bhargavi Pant, Robert Hauschild, and Stefan Alexander Freunberger. “Singlet Oxygen in Non-Aqueous Oxygen Redox: Direct Spectroscopic Evidence for Formation Pathways and Reliability of Chemical Probes.” <i>Faraday Discussions</i>. Royal Society of Chemistry, 2023. <a href=\"https://doi.org/10.1039/d3fd00088e\">https://doi.org/10.1039/d3fd00088e</a>.","ieee":"S. Mondal, R. B. Jethwa, B. Pant, R. Hauschild, and S. A. Freunberger, “Singlet oxygen in non-aqueous oxygen redox: Direct spectroscopic evidence for formation pathways and reliability of chemical probes,” <i>Faraday Discussions</i>. Royal Society of Chemistry, 2023.","apa":"Mondal, S., Jethwa, R. B., Pant, B., Hauschild, R., &#38; Freunberger, S. A. (2023). Singlet oxygen in non-aqueous oxygen redox: Direct spectroscopic evidence for formation pathways and reliability of chemical probes. <i>Faraday Discussions</i>. Royal Society of Chemistry. <a href=\"https://doi.org/10.1039/d3fd00088e\">https://doi.org/10.1039/d3fd00088e</a>","short":"S. Mondal, R.B. Jethwa, B. Pant, R. Hauschild, S.A. Freunberger, Faraday Discussions (2023).","ista":"Mondal S, Jethwa RB, Pant B, Hauschild R, Freunberger SA. 2023. Singlet oxygen in non-aqueous oxygen redox: Direct spectroscopic evidence for formation pathways and reliability of chemical probes. Faraday Discussions.","ama":"Mondal S, Jethwa RB, Pant B, Hauschild R, Freunberger SA. Singlet oxygen in non-aqueous oxygen redox: Direct spectroscopic evidence for formation pathways and reliability of chemical probes. <i>Faraday Discussions</i>. 2023. doi:<a href=\"https://doi.org/10.1039/d3fd00088e\">10.1039/d3fd00088e</a>","mla":"Mondal, Soumyadip, et al. “Singlet Oxygen in Non-Aqueous Oxygen Redox: Direct Spectroscopic Evidence for Formation Pathways and Reliability of Chemical Probes.” <i>Faraday Discussions</i>, Royal Society of Chemistry, 2023, doi:<a href=\"https://doi.org/10.1039/d3fd00088e\">10.1039/d3fd00088e</a>."},"publication_status":"epub_ahead","publication_identifier":{"issn":["1359-6640"],"eissn":["1364-5498"]},"_id":"13044","quality_controlled":"1","oa_version":"Published Version","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","article_processing_charge":"No","oa":1,"date_updated":"2023-12-13T11:19:07Z","publisher":"Royal Society of Chemistry","language":[{"iso":"eng"}],"month":"05","date_published":"2023-05-17T00:00:00Z","article_type":"original","date_created":"2023-05-22T06:53:34Z","license":"https://creativecommons.org/licenses/by-nc/4.0/","department":[{"_id":"StFr"},{"_id":"Bio"}],"status":"public","day":"17","type":"journal_article","publication":"Faraday Discussions"},{"publication":"Faraday Discussions","volume":206,"date_updated":"2021-06-10T06:17:17Z","article_processing_charge":"No","page":"393-404","_id":"7288","publication_identifier":{"issn":["1359-6640","1364-5498"]},"extern":"1","user_id":"3E5EF7F0-F248-11E8-B48F-1D18A9856A87","quality_controlled":"1","oa_version":"None","publication_status":"published","citation":{"chicago":"Bodin, C., E. Mourad, D. Zigah, S. Le Vot, Stefan Alexander Freunberger, F. Favier, and O. Fontaine. “Biredox Ionic Liquids: New Opportunities toward High Performance Supercapacitors.” <i>Faraday Discussions</i>. Royal Society of Chemistry, 2017. <a href=\"https://doi.org/10.1039/c7fd00174f\">https://doi.org/10.1039/c7fd00174f</a>.","ieee":"C. Bodin <i>et al.</i>, “Biredox ionic liquids: New opportunities toward high performance supercapacitors,” <i>Faraday Discussions</i>, vol. 206. Royal Society of Chemistry, pp. 393–404, 2017.","apa":"Bodin, C., Mourad, E., Zigah, D., Le Vot, S., Freunberger, S. A., Favier, F., &#38; Fontaine, O. (2017). Biredox ionic liquids: New opportunities toward high performance supercapacitors. <i>Faraday Discussions</i>. Royal Society of Chemistry. <a href=\"https://doi.org/10.1039/c7fd00174f\">https://doi.org/10.1039/c7fd00174f</a>","short":"C. Bodin, E. Mourad, D. Zigah, S. Le Vot, S.A. Freunberger, F. Favier, O. Fontaine, Faraday Discussions 206 (2017) 393–404.","ista":"Bodin C, Mourad E, Zigah D, Le Vot S, Freunberger SA, Favier F, Fontaine O. 2017. Biredox ionic liquids: New opportunities toward high performance supercapacitors. Faraday Discussions. 206, 393–404.","mla":"Bodin, C., et al. “Biredox Ionic Liquids: New Opportunities toward High Performance Supercapacitors.” <i>Faraday Discussions</i>, vol. 206, Royal Society of Chemistry, 2017, pp. 393–404, doi:<a href=\"https://doi.org/10.1039/c7fd00174f\">10.1039/c7fd00174f</a>.","ama":"Bodin C, Mourad E, Zigah D, et al. Biredox ionic liquids: New opportunities toward high performance supercapacitors. <i>Faraday Discussions</i>. 2017;206:393-404. doi:<a href=\"https://doi.org/10.1039/c7fd00174f\">10.1039/c7fd00174f</a>"},"day":"29","type":"journal_article","intvolume":"       206","abstract":[{"lang":"eng","text":"Nowadays commercial supercapacitors are based on purely capacitive storage at the porous carbons that are used for the electrodes. However, the limits that capacitive storage imposes on energy density calls to investigate new materials to improve the capacitance of the device. This new type of electrodes (e.g., RuO2, MnO2…) involves pseudo-capacitive faradaic redox processes with the solid material. Ion exchange with solid materials is, however, much slower than the adsorption process in capacitive storage and inevitably leads to significant loss of power. Faradaic process in the liquid state, in contrast can be similarly fast as capacitive processes due to the fast ion transport. Designing new devices with liquid like dynamics and improved specific capacitance is challenging. We present a new approach to increase the specific capacitance using biredox ionic liquids, where redox moieties are tethered to the electrolyte ions, allowing high redox concentrations and significant pseudo-capacitive storage in the liquid state. Anions and cations are functionalized with anthraquinone (AQ) and 2,2,6,6-tetramethylpiperidinyl-1-oxyl (TEMPO) moieties, respectively. Glassy carbon, carbon-onion, and commercial activated carbon electrodes that exhibit different double layer structures and thus different diffusion dynamics were used to simultaneously study the electrochemical response of biredox ionic liquids at the positive and negative electrode."}],"status":"public","author":[{"first_name":"C.","last_name":"Bodin","full_name":"Bodin, C."},{"first_name":"E.","last_name":"Mourad","full_name":"Mourad, E."},{"first_name":"D.","full_name":"Zigah, D.","last_name":"Zigah"},{"last_name":"Le Vot","full_name":"Le Vot, S.","first_name":"S."},{"first_name":"Stefan Alexander","full_name":"Freunberger, Stefan Alexander","last_name":"Freunberger","orcid":"0000-0003-2902-5319","id":"A8CA28E6-CE23-11E9-AD2D-EC27E6697425"},{"last_name":"Favier","full_name":"Favier, F.","first_name":"F."},{"first_name":"O.","last_name":"Fontaine","full_name":"Fontaine, O."}],"date_created":"2020-01-15T12:14:04Z","doi":"10.1039/c7fd00174f","year":"2017","month":"06","date_published":"2017-06-29T00:00:00Z","article_type":"original","publisher":"Royal Society of Chemistry","title":"Biredox ionic liquids: New opportunities toward high performance supercapacitors","language":[{"iso":"eng"}]},{"publication_status":"published","citation":{"chicago":"Singh, Gurvinder, Henry Chan, T. Udayabhaskararao, Elijah Gelman, Davide Peddis, Artem Baskin, Gregory Leitus, Petr Král, and Rafal Klajn. “Magnetic Field-Induced Self-Assembly of Iron Oxide Nanocubes.” <i>Faraday Discussions</i>. Royal Society of Chemistry, 2015. <a href=\"https://doi.org/10.1039/c4fd00265b\">https://doi.org/10.1039/c4fd00265b</a>.","apa":"Singh, G., Chan, H., Udayabhaskararao, T., Gelman, E., Peddis, D., Baskin, A., … Klajn, R. (2015). Magnetic field-induced self-assembly of iron oxide nanocubes. <i>Faraday Discussions</i>. Royal Society of Chemistry. <a href=\"https://doi.org/10.1039/c4fd00265b\">https://doi.org/10.1039/c4fd00265b</a>","ieee":"G. Singh <i>et al.</i>, “Magnetic field-induced self-assembly of iron oxide nanocubes,” <i>Faraday Discussions</i>, vol. 181. Royal Society of Chemistry, pp. 403–421, 2015.","short":"G. Singh, H. Chan, T. Udayabhaskararao, E. Gelman, D. Peddis, A. Baskin, G. Leitus, P. Král, R. Klajn, Faraday Discussions 181 (2015) 403–421.","ista":"Singh G, Chan H, Udayabhaskararao T, Gelman E, Peddis D, Baskin A, Leitus G, Král P, Klajn R. 2015. Magnetic field-induced self-assembly of iron oxide nanocubes. Faraday Discussions. 181, 403–421.","mla":"Singh, Gurvinder, et al. “Magnetic Field-Induced Self-Assembly of Iron Oxide Nanocubes.” <i>Faraday Discussions</i>, vol. 181, Royal Society of Chemistry, 2015, pp. 403–21, doi:<a href=\"https://doi.org/10.1039/c4fd00265b\">10.1039/c4fd00265b</a>.","ama":"Singh G, Chan H, Udayabhaskararao T, et al. Magnetic field-induced self-assembly of iron oxide nanocubes. <i>Faraday Discussions</i>. 2015;181:403-421. doi:<a href=\"https://doi.org/10.1039/c4fd00265b\">10.1039/c4fd00265b</a>"},"abstract":[{"text":"Self-assembly of inorganic nanoparticles has been studied extensively for particles having different sizes and compositions. However, relatively little attention has been devoted to how the shape and surface chemistry of magnetic nanoparticles affects their self-assembly properties. Here, we undertook a combined experiment–theory study aimed at better understanding of the self-assembly of cubic magnetite (Fe3O4) particles. We demonstrated that, depending on the experimental parameters, such as the direction of the magnetic field and nanoparticle density, a variety of superstructures can be obtained, including one-dimensional filaments and helices, as well as C-shaped assemblies described here for the first time. Furthermore, we functionalized the surfaces of the magnetic nanocubes with light-sensitive ligands. Using these modified nanoparticles, we were able to achieve orthogonal control of self-assembly using a magnetic field and light.","lang":"eng"}],"keyword":["Physical and Theoretical Chemistry"],"author":[{"first_name":"Gurvinder","full_name":"Singh, Gurvinder","last_name":"Singh"},{"last_name":"Chan","full_name":"Chan, Henry","first_name":"Henry"},{"first_name":"T.","last_name":"Udayabhaskararao","full_name":"Udayabhaskararao, T."},{"first_name":"Elijah","last_name":"Gelman","full_name":"Gelman, Elijah"},{"full_name":"Peddis, Davide","last_name":"Peddis","first_name":"Davide"},{"first_name":"Artem","full_name":"Baskin, Artem","last_name":"Baskin"},{"first_name":"Gregory","full_name":"Leitus, Gregory","last_name":"Leitus"},{"last_name":"Král","full_name":"Král, Petr","first_name":"Petr"},{"id":"8e84690e-1e48-11ed-a02b-a1e6fb8bb53b","first_name":"Rafal","last_name":"Klajn","full_name":"Klajn, Rafal"}],"volume":181,"date_updated":"2023-08-07T13:06:23Z","oa":1,"article_processing_charge":"No","pmid":1,"_id":"13397","publication_identifier":{"eissn":["1364-5498"],"issn":["1359-6640"]},"extern":"1","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","oa_version":"Published Version","quality_controlled":"1","doi":"10.1039/c4fd00265b","year":"2015","title":"Magnetic field-induced self-assembly of iron oxide nanocubes","external_id":{"pmid":["25920522"]},"main_file_link":[{"url":"https://doi.org/10.1039/C4FD00265B","open_access":"1"}],"day":"02","type":"journal_article","intvolume":"       181","status":"public","publication":"Faraday Discussions","page":"403-421","month":"01","date_published":"2015-01-02T00:00:00Z","article_type":"original","publisher":"Royal Society of Chemistry","scopus_import":"1","language":[{"iso":"eng"}],"date_created":"2023-08-01T09:45:17Z"},{"page":"463-479","publication":"Faraday Discussions","type":"journal_article","day":"07","status":"public","intvolume":"       181","date_created":"2023-08-01T09:45:29Z","date_published":"2015-07-07T00:00:00Z","article_type":"letter_note","month":"07","language":[{"iso":"eng"}],"publisher":"Royal Society of Chemistry","scopus_import":"1","volume":181,"date_updated":"2023-08-08T07:16:20Z","article_processing_charge":"No","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","quality_controlled":"1","oa_version":"None","pmid":1,"_id":"13398","publication_identifier":{"eissn":["1364-5498"],"issn":["1359-6640"]},"extern":"1","publication_status":"published","citation":{"chicago":"Sun, Yugang, Leonardo Scarabelli, Nicholas Kotov, Moritz Tebbe, Xiao-Min Lin, Ward Brullot, Lucio Isa, et al. “Field-Assisted Self-Assembly Process: General Discussion.” <i>Faraday Discussions</i>. Royal Society of Chemistry, 2015. <a href=\"https://doi.org/10.1039/c5fd90041g\">https://doi.org/10.1039/c5fd90041g</a>.","ieee":"Y. Sun <i>et al.</i>, “Field-assisted self-assembly process: General discussion,” <i>Faraday Discussions</i>, vol. 181. Royal Society of Chemistry, pp. 463–479, 2015.","apa":"Sun, Y., Scarabelli, L., Kotov, N., Tebbe, M., Lin, X.-M., Brullot, W., … Ghosh, S. (2015). Field-assisted self-assembly process: General discussion. <i>Faraday Discussions</i>. Royal Society of Chemistry. <a href=\"https://doi.org/10.1039/c5fd90041g\">https://doi.org/10.1039/c5fd90041g</a>","short":"Y. Sun, L. Scarabelli, N. Kotov, M. Tebbe, X.-M. Lin, W. Brullot, L. Isa, P. Schurtenberger, H. Moehwald, I. Fedin, O. Velev, D. Faivre, C. Sorensen, R. Perzynski, M. Chanana, Z. Li, F. Bresme, P. Král, E. Firlar, D. Schiffrin, J.B. Souza Junior, A. Fery, E. Shevchenko, O. Tarhan, A.P. Alivisatos, S. Disch, R. Klajn, S. Ghosh, Faraday Discussions 181 (2015) 463–479.","ista":"Sun Y, Scarabelli L, Kotov N, Tebbe M, Lin X-M, Brullot W, Isa L, Schurtenberger P, Moehwald H, Fedin I, Velev O, Faivre D, Sorensen C, Perzynski R, Chanana M, Li Z, Bresme F, Král P, Firlar E, Schiffrin D, Souza Junior JB, Fery A, Shevchenko E, Tarhan O, Alivisatos AP, Disch S, Klajn R, Ghosh S. 2015. Field-assisted self-assembly process: General discussion. Faraday Discussions. 181, 463–479.","ama":"Sun Y, Scarabelli L, Kotov N, et al. Field-assisted self-assembly process: General discussion. <i>Faraday Discussions</i>. 2015;181:463-479. doi:<a href=\"https://doi.org/10.1039/c5fd90041g\">10.1039/c5fd90041g</a>","mla":"Sun, Yugang, et al. “Field-Assisted Self-Assembly Process: General Discussion.” <i>Faraday Discussions</i>, vol. 181, Royal Society of Chemistry, 2015, pp. 463–79, doi:<a href=\"https://doi.org/10.1039/c5fd90041g\">10.1039/c5fd90041g</a>."},"keyword":["Physical and Theoretical Chemistry"],"author":[{"first_name":"Yugang","last_name":"Sun","full_name":"Sun, Yugang"},{"full_name":"Scarabelli, Leonardo","last_name":"Scarabelli","first_name":"Leonardo"},{"full_name":"Kotov, Nicholas","last_name":"Kotov","first_name":"Nicholas"},{"first_name":"Moritz","full_name":"Tebbe, Moritz","last_name":"Tebbe"},{"first_name":"Xiao-Min","full_name":"Lin, Xiao-Min","last_name":"Lin"},{"first_name":"Ward","full_name":"Brullot, Ward","last_name":"Brullot"},{"first_name":"Lucio","full_name":"Isa, Lucio","last_name":"Isa"},{"first_name":"Peter","full_name":"Schurtenberger, Peter","last_name":"Schurtenberger"},{"first_name":"Helmuth","full_name":"Moehwald, Helmuth","last_name":"Moehwald"},{"first_name":"Igor","last_name":"Fedin","full_name":"Fedin, Igor"},{"full_name":"Velev, Orlin","last_name":"Velev","first_name":"Orlin"},{"full_name":"Faivre, Damien","last_name":"Faivre","first_name":"Damien"},{"first_name":"Christopher","full_name":"Sorensen, Christopher","last_name":"Sorensen"},{"full_name":"Perzynski, Régine","last_name":"Perzynski","first_name":"Régine"},{"full_name":"Chanana, Munish","last_name":"Chanana","first_name":"Munish"},{"first_name":"Zhihai","last_name":"Li","full_name":"Li, Zhihai"},{"first_name":"Fernando","full_name":"Bresme, Fernando","last_name":"Bresme"},{"last_name":"Král","full_name":"Král, Petr","first_name":"Petr"},{"full_name":"Firlar, Emre","last_name":"Firlar","first_name":"Emre"},{"last_name":"Schiffrin","full_name":"Schiffrin, David","first_name":"David"},{"first_name":"Joao Batista","last_name":"Souza Junior","full_name":"Souza Junior, Joao Batista"},{"first_name":"Andreas","full_name":"Fery, Andreas","last_name":"Fery"},{"first_name":"Elena","last_name":"Shevchenko","full_name":"Shevchenko, Elena"},{"first_name":"Ozgur","last_name":"Tarhan","full_name":"Tarhan, Ozgur"},{"first_name":"Armand Paul","full_name":"Alivisatos, Armand Paul","last_name":"Alivisatos"},{"first_name":"Sabrina","full_name":"Disch, Sabrina","last_name":"Disch"},{"first_name":"Rafal","last_name":"Klajn","full_name":"Klajn, Rafal","id":"8e84690e-1e48-11ed-a02b-a1e6fb8bb53b"},{"last_name":"Ghosh","full_name":"Ghosh, Suvojit","first_name":"Suvojit"}],"doi":"10.1039/c5fd90041g","year":"2015","title":"Field-assisted self-assembly process: General discussion","external_id":{"pmid":["26149295"]}},{"external_id":{"pmid":["25415558"]},"title":"The sensitivities of high-harmonic generation and strong-field ionization to coupled electronic and nuclear dynamics","doi":"10.1039/c4fd00018h","year":"2014","abstract":[{"text":"The sensitivities of high-harmonic generation (HHG) and strong-field ionization (SFI) to coupled electronic and nuclear dynamics are studied, using the nitric oxide (NO) molecule as an example. A coherent superposition of electronic and rotational states of NO is prepared by impulsive stimulated Raman scattering and probed by simultaneous detection of HHG and SFI yields. We observe a fourfold higher sensitivity of high-harmonic generation to electronic dynamics and attribute it to the presence of inelastic quantum paths connecting coherently related electronic states [Kraus et al., Phys. Rev. Lett.111, 243005 (2013)]. Whereas different harmonic orders display very different sensitivities to rotational or electronic dynamics, strong-field ionization is found to be most sensitive to electronic motion. We introduce a general theoretical formalism for high-harmonic generation from coupled nuclear-electronic wave packets. We show that the unequal sensitivities of different harmonic orders to electronic or rotational dynamics result from the angle dependence of the photorecombination matrix elements which encode several autoionizing and shape resonances in the photoionization continuum of NO. We further study the dependence of rotational and electronic coherences on the intensity of the excitation pulse and support the observations with calculations.","lang":"eng"}],"author":[{"first_name":"Denitsa Rangelova","full_name":"Baykusheva, Denitsa Rangelova","last_name":"Baykusheva","id":"71b4d059-2a03-11ee-914d-dfa3beed6530"},{"last_name":"Kraus","full_name":"Kraus, Peter M.","first_name":"Peter M."},{"last_name":"Zhang","full_name":"Zhang, Song Bin","first_name":"Song Bin"},{"full_name":"Rohringer, Nina","last_name":"Rohringer","first_name":"Nina"},{"first_name":"Hans Jakob","full_name":"Wörner, Hans Jakob","last_name":"Wörner"}],"keyword":["Physical and Theoretical Chemistry"],"citation":{"chicago":"Baykusheva, Denitsa Rangelova, Peter M. Kraus, Song Bin Zhang, Nina Rohringer, and Hans Jakob Wörner. “The Sensitivities of High-Harmonic Generation and Strong-Field Ionization to Coupled Electronic and Nuclear Dynamics.” <i>Faraday Discussions</i>. Royal Society of Chemistry, 2014. <a href=\"https://doi.org/10.1039/c4fd00018h\">https://doi.org/10.1039/c4fd00018h</a>.","apa":"Baykusheva, D. R., Kraus, P. M., Zhang, S. B., Rohringer, N., &#38; Wörner, H. J. (2014). The sensitivities of high-harmonic generation and strong-field ionization to coupled electronic and nuclear dynamics. <i>Faraday Discussions</i>. Royal Society of Chemistry. <a href=\"https://doi.org/10.1039/c4fd00018h\">https://doi.org/10.1039/c4fd00018h</a>","ieee":"D. R. Baykusheva, P. M. Kraus, S. B. Zhang, N. Rohringer, and H. J. Wörner, “The sensitivities of high-harmonic generation and strong-field ionization to coupled electronic and nuclear dynamics,” <i>Faraday Discussions</i>, vol. 171. Royal Society of Chemistry, pp. 113–132, 2014.","short":"D.R. Baykusheva, P.M. Kraus, S.B. Zhang, N. Rohringer, H.J. Wörner, Faraday Discussions 171 (2014) 113–132.","ista":"Baykusheva DR, Kraus PM, Zhang SB, Rohringer N, Wörner HJ. 2014. The sensitivities of high-harmonic generation and strong-field ionization to coupled electronic and nuclear dynamics. Faraday Discussions. 171, 113–132.","mla":"Baykusheva, Denitsa Rangelova, et al. “The Sensitivities of High-Harmonic Generation and Strong-Field Ionization to Coupled Electronic and Nuclear Dynamics.” <i>Faraday Discussions</i>, vol. 171, Royal Society of Chemistry, 2014, pp. 113–32, doi:<a href=\"https://doi.org/10.1039/c4fd00018h\">10.1039/c4fd00018h</a>.","ama":"Baykusheva DR, Kraus PM, Zhang SB, Rohringer N, Wörner HJ. The sensitivities of high-harmonic generation and strong-field ionization to coupled electronic and nuclear dynamics. <i>Faraday Discussions</i>. 2014;171:113-132. doi:<a href=\"https://doi.org/10.1039/c4fd00018h\">10.1039/c4fd00018h</a>"},"publication_status":"published","publication_identifier":{"issn":["1359-6640"],"eissn":["1364-5498"]},"extern":"1","_id":"14018","pmid":1,"quality_controlled":"1","oa_version":"None","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","article_processing_charge":"No","date_updated":"2023-08-22T08:58:12Z","volume":171,"scopus_import":"1","publisher":"Royal Society of Chemistry","language":[{"iso":"eng"}],"month":"04","date_published":"2014-04-14T00:00:00Z","article_type":"original","date_created":"2023-08-10T06:38:19Z","intvolume":"       171","status":"public","day":"14","type":"journal_article","publication":"Faraday Discussions","page":"113-132"}]