@article{14701,
  author       = {Archer, Lynden A. and Bruce, Peter G. and Calvo, Ernesto J. and Dewar, Daniel and Ellison, James H. J. and Freunberger, Stefan Alexander and Gao, Xiangwen and Hardwick, Laurence J. and Horwitz, Gabriela and Janek, Jürgen and Johnson, Lee R. and Jordan, Jack W. and Matsuda, Shoichi and Menkin, Svetlana and Mondal, Soumyadip and Qiu, Qianyuan and Samarakoon, Thukshan and Temprano, Israel and Uosaki, Kohei and Vailaya, Ganesh and Wachsman, Eric D. and Wu, Yiying and Ye, Shen},
  issn         = {1364-5498},
  journal      = {Faraday Discussions},
  keywords     = {Physical and Theoretical Chemistry},
  publisher    = {Royal Society of Chemistry},
  title        = {{Towards practical metal–oxygen batteries: General discussion}},
  doi          = {10.1039/d3fd90062b},
  year         = {2023},
}

@article{14702,
  author       = {Attard, Gary A. and Calvo, Ernesto J. and Curtiss, Larry A. and Dewar, Daniel and Ellison, James H. J. and Gao, Xiangwen and Grey, Clare P. and Hardwick, Laurence J. and Horwitz, Gabriela and Janek, Juergen and Johnson, Lee R. and Jordan, Jack W. and Matsuda, Shoichi and Mondal, Soumyadip and Neale, Alex R. and Ortiz-Vitoriano, Nagore and Temprano, Israel and Vailaya, Ganesh and Wachsman, Eric D. and Wang, Hsien-Hau and Wu, Yiying and Ye, Shen},
  issn         = {1364-5498},
  journal      = {Faraday Discussions},
  keywords     = {Physical and Theoretical Chemistry},
  publisher    = {Royal Society of Chemistry},
  title        = {{Materials for stable metal–oxygen battery cathodes: general discussion}},
  doi          = {10.1039/d3fd90059b},
  year         = {2023},
}

@article{13044,
  abstract     = {Singlet oxygen (1O2) formation is now recognised as a key aspect of non-aqueous oxygen redox chemistry. For identifying 1O2, chemical trapping via 9,10-dimethylanthracene (DMA) to form the endoperoxide (DMA-O2) has become the mainstay method due to its sensitivity, selectivity, and ease of use. While DMA has been shown to be selective for 1O2, rather than forming DMA-O2 with a wide variety of potentially reactive O-containing species, false positives might hypothetically be obtained in the presence of previously overlooked species. Here, we first give unequivocal direct spectroscopic proof by the 1O2-specific near infrared (NIR) emission at 1270 nm for the previously proposed 1O2 formation pathways, which centre around superoxide disproportionation. We then show that peroxocarbonates, common intermediates in metal-O2 and metal carbonate electrochemistry, do not produce false-positive DMA-O2. Moreover, we identify a previously unreported 1O2-forming pathway through the reaction of CO2 with superoxide. Overall, we give unequivocal proof for 1O2 formation in non-aqueous oxygen redox and show that chemical trapping with DMA is a reliable method to assess 1O2 formation.},
  author       = {Mondal, Soumyadip and Jethwa, Rajesh B and Pant, Bhargavi and Hauschild, Robert and Freunberger, Stefan Alexander},
  issn         = {1364-5498},
  journal      = {Faraday Discussions},
  keywords     = {Physical and Theoretical Chemistry},
  publisher    = {Royal Society of Chemistry},
  title        = {{Singlet oxygen in non-aqueous oxygen redox: Direct spectroscopic evidence for formation pathways and reliability of chemical probes}},
  doi          = {10.1039/d3fd00088e},
  year         = {2023},
}

@article{7288,
  abstract     = {Nowadays commercial supercapacitors are based on purely capacitive storage at the porous carbons that are used for the electrodes. However, the limits that capacitive storage imposes on energy density calls to investigate new materials to improve the capacitance of the device. This new type of electrodes (e.g., RuO2, MnO2…) involves pseudo-capacitive faradaic redox processes with the solid material. Ion exchange with solid materials is, however, much slower than the adsorption process in capacitive storage and inevitably leads to significant loss of power. Faradaic process in the liquid state, in contrast can be similarly fast as capacitive processes due to the fast ion transport. Designing new devices with liquid like dynamics and improved specific capacitance is challenging. We present a new approach to increase the specific capacitance using biredox ionic liquids, where redox moieties are tethered to the electrolyte ions, allowing high redox concentrations and significant pseudo-capacitive storage in the liquid state. Anions and cations are functionalized with anthraquinone (AQ) and 2,2,6,6-tetramethylpiperidinyl-1-oxyl (TEMPO) moieties, respectively. Glassy carbon, carbon-onion, and commercial activated carbon electrodes that exhibit different double layer structures and thus different diffusion dynamics were used to simultaneously study the electrochemical response of biredox ionic liquids at the positive and negative electrode.},
  author       = {Bodin, C. and Mourad, E. and Zigah, D. and Le Vot, S. and Freunberger, Stefan Alexander and Favier, F. and Fontaine, O.},
  issn         = {1359-6640},
  journal      = {Faraday Discussions},
  pages        = {393--404},
  publisher    = {Royal Society of Chemistry},
  title        = {{Biredox ionic liquids: New opportunities toward high performance supercapacitors}},
  doi          = {10.1039/c7fd00174f},
  volume       = {206},
  year         = {2017},
}

@article{13397,
  abstract     = {Self-assembly of inorganic nanoparticles has been studied extensively for particles having different sizes and compositions. However, relatively little attention has been devoted to how the shape and surface chemistry of magnetic nanoparticles affects their self-assembly properties. Here, we undertook a combined experiment–theory study aimed at better understanding of the self-assembly of cubic magnetite (Fe3O4) particles. We demonstrated that, depending on the experimental parameters, such as the direction of the magnetic field and nanoparticle density, a variety of superstructures can be obtained, including one-dimensional filaments and helices, as well as C-shaped assemblies described here for the first time. Furthermore, we functionalized the surfaces of the magnetic nanocubes with light-sensitive ligands. Using these modified nanoparticles, we were able to achieve orthogonal control of self-assembly using a magnetic field and light.},
  author       = {Singh, Gurvinder and Chan, Henry and Udayabhaskararao, T. and Gelman, Elijah and Peddis, Davide and Baskin, Artem and Leitus, Gregory and Král, Petr and Klajn, Rafal},
  issn         = {1364-5498},
  journal      = {Faraday Discussions},
  keywords     = {Physical and Theoretical Chemistry},
  pages        = {403--421},
  publisher    = {Royal Society of Chemistry},
  title        = {{Magnetic field-induced self-assembly of iron oxide nanocubes}},
  doi          = {10.1039/c4fd00265b},
  volume       = {181},
  year         = {2015},
}

@article{13398,
  author       = {Sun, Yugang and Scarabelli, Leonardo and Kotov, Nicholas and Tebbe, Moritz and Lin, Xiao-Min and Brullot, Ward and Isa, Lucio and Schurtenberger, Peter and Moehwald, Helmuth and Fedin, Igor and Velev, Orlin and Faivre, Damien and Sorensen, Christopher and Perzynski, Régine and Chanana, Munish and Li, Zhihai and Bresme, Fernando and Král, Petr and Firlar, Emre and Schiffrin, David and Souza Junior, Joao Batista and Fery, Andreas and Shevchenko, Elena and Tarhan, Ozgur and Alivisatos, Armand Paul and Disch, Sabrina and Klajn, Rafal and Ghosh, Suvojit},
  issn         = {1364-5498},
  journal      = {Faraday Discussions},
  keywords     = {Physical and Theoretical Chemistry},
  pages        = {463--479},
  publisher    = {Royal Society of Chemistry},
  title        = {{Field-assisted self-assembly process: General discussion}},
  doi          = {10.1039/c5fd90041g},
  volume       = {181},
  year         = {2015},
}

@article{14018,
  abstract     = {The sensitivities of high-harmonic generation (HHG) and strong-field ionization (SFI) to coupled electronic and nuclear dynamics are studied, using the nitric oxide (NO) molecule as an example. A coherent superposition of electronic and rotational states of NO is prepared by impulsive stimulated Raman scattering and probed by simultaneous detection of HHG and SFI yields. We observe a fourfold higher sensitivity of high-harmonic generation to electronic dynamics and attribute it to the presence of inelastic quantum paths connecting coherently related electronic states [Kraus et al., Phys. Rev. Lett.111, 243005 (2013)]. Whereas different harmonic orders display very different sensitivities to rotational or electronic dynamics, strong-field ionization is found to be most sensitive to electronic motion. We introduce a general theoretical formalism for high-harmonic generation from coupled nuclear-electronic wave packets. We show that the unequal sensitivities of different harmonic orders to electronic or rotational dynamics result from the angle dependence of the photorecombination matrix elements which encode several autoionizing and shape resonances in the photoionization continuum of NO. We further study the dependence of rotational and electronic coherences on the intensity of the excitation pulse and support the observations with calculations.},
  author       = {Baykusheva, Denitsa Rangelova and Kraus, Peter M. and Zhang, Song Bin and Rohringer, Nina and Wörner, Hans Jakob},
  issn         = {1364-5498},
  journal      = {Faraday Discussions},
  keywords     = {Physical and Theoretical Chemistry},
  pages        = {113--132},
  publisher    = {Royal Society of Chemistry},
  title        = {{The sensitivities of high-harmonic generation and strong-field ionization to coupled electronic and nuclear dynamics}},
  doi          = {10.1039/c4fd00018h},
  volume       = {171},
  year         = {2014},
}