[{"volume":14,"quality_controlled":"1","title":"Activated Lithium-Metal-Oxides as catalytic electrodes for Li–O2 cells","day":"02","author":[{"full_name":"Trahey, L.","last_name":"Trahey","first_name":"L."},{"full_name":"Johnson, C. S.","first_name":"C. S.","last_name":"Johnson"},{"last_name":"Vaughey","first_name":"J. T.","full_name":"Vaughey, J. T."},{"full_name":"Kang, S.-H.","last_name":"Kang","first_name":"S.-H."},{"full_name":"Hardwick, L. J.","first_name":"L. J.","last_name":"Hardwick"},{"id":"A8CA28E6-CE23-11E9-AD2D-EC27E6697425","full_name":"Freunberger, Stefan Alexander","orcid":"0000-0003-2902-5319","last_name":"Freunberger","first_name":"Stefan Alexander"},{"full_name":"Bruce, P. G.","last_name":"Bruce","first_name":"P. G."},{"first_name":"M. M.","last_name":"Thackeray","full_name":"Thackeray, M. M."}],"language":[{"iso":"eng"}],"_id":"7317","year":"2011","article_number":"A64","date_updated":"2021-01-12T08:13:00Z","intvolume":"        14","extern":"1","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","status":"public","date_created":"2020-01-15T12:20:54Z","month":"03","publication_identifier":{"issn":["1099-0062"]},"issue":"5","oa_version":"None","date_published":"2011-03-02T00:00:00Z","article_type":"original","publisher":"The Electrochemical Society","type":"journal_article","publication_status":"published","publication":"Electrochemical and Solid-State Letters","article_processing_charge":"No","abstract":[{"lang":"eng","text":"Lithium-metal oxides with a high formal Li2O content, such as Li5FeO4 (5Li2O•Fe2O3) and a Li2MnO3•LiFeO2 composite ({Li2O•MnO2}•{Li2O•Fe2O3}) have been explored as electrocatalysts for primary and rechargeable Li-O2 cells. Activation occurs predominantly by Li2O removal, either electrochemically or chemically by acid-treatment. Superior electrochemical behavior is obtained if activation occurs by acid-treatment; Li2MnO3•LiFeO2 catalysts provide 2516 mAh/g (carbon) corresponding to 931 mAh/g (electrocatalyst + carbon) during the initial discharge. The reaction is reasonably reversible during the early cycles. The approach has implications for designing electrocatalysts that participate through electrochemical Li2O extraction/reformation reactions, offering exceptionally high capacities."}],"citation":{"ama":"Trahey L, Johnson CS, Vaughey JT, et al. Activated Lithium-Metal-Oxides as catalytic electrodes for Li–O2 cells. <i>Electrochemical and Solid-State Letters</i>. 2011;14(5). doi:<a href=\"https://doi.org/10.1149/1.3555366\">10.1149/1.3555366</a>","short":"L. Trahey, C.S. Johnson, J.T. Vaughey, S.-H. Kang, L.J. Hardwick, S.A. Freunberger, P.G. Bruce, M.M. Thackeray, Electrochemical and Solid-State Letters 14 (2011).","ista":"Trahey L, Johnson CS, Vaughey JT, Kang S-H, Hardwick LJ, Freunberger SA, Bruce PG, Thackeray MM. 2011. Activated Lithium-Metal-Oxides as catalytic electrodes for Li–O2 cells. Electrochemical and Solid-State Letters. 14(5), A64.","mla":"Trahey, L., et al. “Activated Lithium-Metal-Oxides as Catalytic Electrodes for Li–O2 Cells.” <i>Electrochemical and Solid-State Letters</i>, vol. 14, no. 5, A64, The Electrochemical Society, 2011, doi:<a href=\"https://doi.org/10.1149/1.3555366\">10.1149/1.3555366</a>.","ieee":"L. Trahey <i>et al.</i>, “Activated Lithium-Metal-Oxides as catalytic electrodes for Li–O2 cells,” <i>Electrochemical and Solid-State Letters</i>, vol. 14, no. 5. The Electrochemical Society, 2011.","chicago":"Trahey, L., C. S. Johnson, J. T. Vaughey, S.-H. Kang, L. J. Hardwick, Stefan Alexander Freunberger, P. G. Bruce, and M. M. Thackeray. “Activated Lithium-Metal-Oxides as Catalytic Electrodes for Li–O2 Cells.” <i>Electrochemical and Solid-State Letters</i>. The Electrochemical Society, 2011. <a href=\"https://doi.org/10.1149/1.3555366\">https://doi.org/10.1149/1.3555366</a>.","apa":"Trahey, L., Johnson, C. S., Vaughey, J. T., Kang, S.-H., Hardwick, L. J., Freunberger, S. A., … Thackeray, M. M. (2011). Activated Lithium-Metal-Oxides as catalytic electrodes for Li–O2 cells. <i>Electrochemical and Solid-State Letters</i>. The Electrochemical Society. <a href=\"https://doi.org/10.1149/1.3555366\">https://doi.org/10.1149/1.3555366</a>"},"doi":"10.1149/1.3555366"},{"month":"10","date_created":"2020-01-15T12:21:06Z","status":"public","oa_version":"None","issue":"12","publication_identifier":{"issn":["1099-0062"]},"publication_status":"published","type":"journal_article","publication":"Electrochemical and Solid-State Letters","publisher":"The Electrochemical Society","date_published":"2010-10-04T00:00:00Z","article_type":"letter_note","doi":"10.1149/1.3494045","citation":{"ieee":"V. Giordani, S. A. Freunberger, P. G. Bruce, J.-M. Tarascon, and D. Larcher, “H2O2 decomposition reaction as selecting tool for catalysts in Li–O2 cells,” <i>Electrochemical and Solid-State Letters</i>, vol. 13, no. 12. The Electrochemical Society, 2010.","chicago":"Giordani, V., Stefan Alexander Freunberger, P. G. Bruce, J.-M. Tarascon, and D. Larcher. “H2O2 Decomposition Reaction as Selecting Tool for Catalysts in Li–O2 Cells.” <i>Electrochemical and Solid-State Letters</i>. The Electrochemical Society, 2010. <a href=\"https://doi.org/10.1149/1.3494045\">https://doi.org/10.1149/1.3494045</a>.","apa":"Giordani, V., Freunberger, S. A., Bruce, P. G., Tarascon, J.-M., &#38; Larcher, D. (2010). H2O2 decomposition reaction as selecting tool for catalysts in Li–O2 cells. <i>Electrochemical and Solid-State Letters</i>. The Electrochemical Society. <a href=\"https://doi.org/10.1149/1.3494045\">https://doi.org/10.1149/1.3494045</a>","short":"V. Giordani, S.A. Freunberger, P.G. Bruce, J.-M. Tarascon, D. Larcher, Electrochemical and Solid-State Letters 13 (2010).","ama":"Giordani V, Freunberger SA, Bruce PG, Tarascon J-M, Larcher D. H2O2 decomposition reaction as selecting tool for catalysts in Li–O2 cells. <i>Electrochemical and Solid-State Letters</i>. 2010;13(12). doi:<a href=\"https://doi.org/10.1149/1.3494045\">10.1149/1.3494045</a>","ista":"Giordani V, Freunberger SA, Bruce PG, Tarascon J-M, Larcher D. 2010. H2O2 decomposition reaction as selecting tool for catalysts in Li–O2 cells. Electrochemical and Solid-State Letters. 13(12), A180.","mla":"Giordani, V., et al. “H2O2 Decomposition Reaction as Selecting Tool for Catalysts in Li–O2 Cells.” <i>Electrochemical and Solid-State Letters</i>, vol. 13, no. 12, A180, The Electrochemical Society, 2010, doi:<a href=\"https://doi.org/10.1149/1.3494045\">10.1149/1.3494045</a>."},"abstract":[{"lang":"eng","text":"The decomposition reaction of H2O2 aqueous solutions (H2O2 - H2O + 1/2O2) catalyzed by transition metal oxide powders has been compared with the charging voltage of nonaqueous Li-O2 cells containing the same catalyst. An inverse linear relationship between Ln k (rate constant for the H2O2 decomposition) and the charging voltage has been found, despite differences in media and possible mechanistic differences. The results suggest that the decomposition may be a reliable, useful, and fast screening tool for materials that promote the charging process of the Li-O2 battery and may ultimately give insight into the charging mechanism."}],"article_processing_charge":"No","author":[{"last_name":"Giordani","first_name":"V.","full_name":"Giordani, V."},{"first_name":"Stefan Alexander","last_name":"Freunberger","orcid":"0000-0003-2902-5319","full_name":"Freunberger, Stefan Alexander","id":"A8CA28E6-CE23-11E9-AD2D-EC27E6697425"},{"full_name":"Bruce, P. G.","first_name":"P. G.","last_name":"Bruce"},{"first_name":"J.-M.","last_name":"Tarascon","full_name":"Tarascon, J.-M."},{"first_name":"D.","last_name":"Larcher","full_name":"Larcher, D."}],"day":"04","title":"H2O2 decomposition reaction as selecting tool for catalysts in Li–O2 cells","volume":13,"quality_controlled":"1","year":"2010","_id":"7318","language":[{"iso":"eng"}],"intvolume":"        13","date_updated":"2021-01-12T08:13:01Z","article_number":"A180","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","extern":"1"}]