@article{7317,
  abstract     = {Lithium-metal oxides with a high formal Li2O content, such as Li5FeO4 (5Li2O•Fe2O3) and a Li2MnO3•LiFeO2 composite ({Li2O•MnO2}•{Li2O•Fe2O3}) have been explored as electrocatalysts for primary and rechargeable Li-O2 cells. Activation occurs predominantly by Li2O removal, either electrochemically or chemically by acid-treatment. Superior electrochemical behavior is obtained if activation occurs by acid-treatment; Li2MnO3•LiFeO2 catalysts provide 2516 mAh/g (carbon) corresponding to 931 mAh/g (electrocatalyst + carbon) during the initial discharge. The reaction is reasonably reversible during the early cycles. The approach has implications for designing electrocatalysts that participate through electrochemical Li2O extraction/reformation reactions, offering exceptionally high capacities.},
  author       = {Trahey, L. and Johnson, C. S. and Vaughey, J. T. and Kang, S.-H. and Hardwick, L. J. and Freunberger, Stefan Alexander and Bruce, P. G. and Thackeray, M. M.},
  issn         = {1099-0062},
  journal      = {Electrochemical and Solid-State Letters},
  number       = {5},
  publisher    = {The Electrochemical Society},
  title        = {{Activated Lithium-Metal-Oxides as catalytic electrodes for Li–O2 cells}},
  doi          = {10.1149/1.3555366},
  volume       = {14},
  year         = {2011},
}

@article{7318,
  abstract     = {The decomposition reaction of H2O2 aqueous solutions (H2O2 - H2O + 1/2O2) catalyzed by transition metal oxide powders has been compared with the charging voltage of nonaqueous Li-O2 cells containing the same catalyst. An inverse linear relationship between Ln k (rate constant for the H2O2 decomposition) and the charging voltage has been found, despite differences in media and possible mechanistic differences. The results suggest that the decomposition may be a reliable, useful, and fast screening tool for materials that promote the charging process of the Li-O2 battery and may ultimately give insight into the charging mechanism.},
  author       = {Giordani, V. and Freunberger, Stefan Alexander and Bruce, P. G. and Tarascon, J.-M. and Larcher, D.},
  issn         = {1099-0062},
  journal      = {Electrochemical and Solid-State Letters},
  number       = {12},
  publisher    = {The Electrochemical Society},
  title        = {{H2O2 decomposition reaction as selecting tool for catalysts in Li–O2 cells}},
  doi          = {10.1149/1.3494045},
  volume       = {13},
  year         = {2010},
}

