---
_id: '13436'
abstract:
- lang: eng
  text: Cross-metathesis reactions of α,β-unsaturated sulfones and sulfoxides in the
    presence of molybdenum and ruthenium pre-catalysts were tested. A selective metahesis
    reaction was achieved between functionalized terminal olefins and vinyl sulfones
    by using the ‘second generation’ ruthenium catalysts 1c–h while the highly active
    Schrock catalyst 1b was found to be functional group incompatible with vinyl sulfones.
    The cross-metathesis products were isolated in good yields with an excellent (E)-selectivity.
    Both the molybdenum and ruthenium-based complexes were, however, incompatible
    with α,β- and β,γ-unsaturated sulfoxides.
article_processing_charge: No
article_type: original
author:
- first_name: Anna
  full_name: Michrowska, Anna
  last_name: Michrowska
- first_name: Michał
  full_name: Bieniek, Michał
  last_name: Bieniek
- first_name: Mikhail
  full_name: Kim, Mikhail
  last_name: Kim
- first_name: Rafal
  full_name: Klajn, Rafal
  id: 8e84690e-1e48-11ed-a02b-a1e6fb8bb53b
  last_name: Klajn
- first_name: Karol
  full_name: Grela, Karol
  last_name: Grela
citation:
  ama: Michrowska A, Bieniek M, Kim M, Klajn R, Grela K. Cross-metathesis reaction
    of vinyl sulfones and sulfoxides. <i>Tetrahedron</i>. 2003;59(25):4525-4531. doi:<a
    href="https://doi.org/10.1016/s0040-4020(03)00682-3">10.1016/s0040-4020(03)00682-3</a>
  apa: Michrowska, A., Bieniek, M., Kim, M., Klajn, R., &#38; Grela, K. (2003). Cross-metathesis
    reaction of vinyl sulfones and sulfoxides. <i>Tetrahedron</i>. Elsevier. <a href="https://doi.org/10.1016/s0040-4020(03)00682-3">https://doi.org/10.1016/s0040-4020(03)00682-3</a>
  chicago: Michrowska, Anna, Michał Bieniek, Mikhail Kim, Rafal Klajn, and Karol Grela.
    “Cross-Metathesis Reaction of Vinyl Sulfones and Sulfoxides.” <i>Tetrahedron</i>.
    Elsevier, 2003. <a href="https://doi.org/10.1016/s0040-4020(03)00682-3">https://doi.org/10.1016/s0040-4020(03)00682-3</a>.
  ieee: A. Michrowska, M. Bieniek, M. Kim, R. Klajn, and K. Grela, “Cross-metathesis
    reaction of vinyl sulfones and sulfoxides,” <i>Tetrahedron</i>, vol. 59, no. 25.
    Elsevier, pp. 4525–4531, 2003.
  ista: Michrowska A, Bieniek M, Kim M, Klajn R, Grela K. 2003. Cross-metathesis reaction
    of vinyl sulfones and sulfoxides. Tetrahedron. 59(25), 4525–4531.
  mla: Michrowska, Anna, et al. “Cross-Metathesis Reaction of Vinyl Sulfones and Sulfoxides.”
    <i>Tetrahedron</i>, vol. 59, no. 25, Elsevier, 2003, pp. 4525–31, doi:<a href="https://doi.org/10.1016/s0040-4020(03)00682-3">10.1016/s0040-4020(03)00682-3</a>.
  short: A. Michrowska, M. Bieniek, M. Kim, R. Klajn, K. Grela, Tetrahedron 59 (2003)
    4525–4531.
date_created: 2023-08-01T10:39:34Z
date_published: 2003-06-16T00:00:00Z
date_updated: 2023-08-08T12:44:17Z
day: '16'
doi: 10.1016/s0040-4020(03)00682-3
extern: '1'
intvolume: '        59'
issue: '25'
keyword:
- Organic Chemistry
- Drug Discovery
- Biochemistry
language:
- iso: eng
month: '06'
oa_version: None
page: 4525-4531
publication: Tetrahedron
publication_identifier:
  eissn:
  - 1464-5416
  issn:
  - 0040-4020
publication_status: published
publisher: Elsevier
quality_controlled: '1'
scopus_import: '1'
status: public
title: Cross-metathesis reaction of vinyl sulfones and sulfoxides
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 59
year: '2003'
...