---
_id: '13235'
abstract:
- lang: eng
text: AgSbSe2 is a promising thermoelectric (TE) p-type material for applications
in the middle-temperature range. AgSbSe2 is characterized by relatively low thermal
conductivities and high Seebeck coefficients, but its main limitation is moderate
electrical conductivity. Herein, we detail an efficient and scalable hot-injection
synthesis route to produce AgSbSe2 nanocrystals (NCs). To increase the carrier
concentration and improve the electrical conductivity, these NCs are doped with
Sn2+ on Sb3+ sites. Upon processing, the Sn2+ chemical state is conserved using
a reducing NaBH4 solution to displace the organic ligand and anneal the material
under a forming gas flow. The TE properties of the dense materials obtained from
the consolidation of the NCs using a hot pressing are then characterized. The
presence of Sn2+ ions replacing Sb3+ significantly increases the charge carrier
concentration and, consequently, the electrical conductivity. Opportunely, the
measured Seebeck coefficient varied within a small range upon Sn doping. The excellent
performance obtained when Sn2+ ions are prevented from oxidation is rationalized
by modeling the system. Calculated band structures disclosed that Sn doping induces
convergence of the AgSbSe2 valence bands, accounting for an enhanced electronic
effective mass. The dramatically enhanced carrier transport leads to a maximized
power factor for AgSb0.98Sn0.02Se2 of 0.63 mW m–1 K–2 at 640 K. Thermally, phonon
scattering is significantly enhanced in the NC-based materials, yielding an ultralow
thermal conductivity of 0.3 W mK–1 at 666 K. Overall, a record-high figure of
merit (zT) is obtained at 666 K for AgSb0.98Sn0.02Se2 at zT = 1.37, well above
the values obtained for undoped AgSbSe2, at zT = 0.58 and state-of-art Pb- and
Te-free materials, which makes AgSb0.98Sn0.02Se2 an excellent p-type candidate
for medium-temperature TE applications.
acknowledgement: Y.L. acknowledges funding from the National Natural Science Foundation
of China (NSFC) (Grants No. 22209034), the Innovation and Entrepreneurship Project
of Overseas Returnees in Anhui Province (Grant No. 2022LCX002). K.H.L. acknowledges
financial support from the National Natural Science Foundation of China (Grant No.
22208293). Y.Z. acknowledges support from the SBIR program NanoOhmics. J.L. is grateful
for the project supported by the Natural Science Foundation of Sichuan (2022NSFSC1229).
M.I. acknowledges financial support from ISTA and the Werner Siemens Foundation.
article_processing_charge: No
article_type: original
author:
- first_name: Yu
full_name: Liu, Yu
id: 2A70014E-F248-11E8-B48F-1D18A9856A87
last_name: Liu
orcid: 0000-0001-7313-6740
- first_name: Mingquan
full_name: Li, Mingquan
last_name: Li
- first_name: Shanhong
full_name: Wan, Shanhong
last_name: Wan
- first_name: Khak Ho
full_name: Lim, Khak Ho
last_name: Lim
- first_name: Yu
full_name: Zhang, Yu
last_name: Zhang
- first_name: Mengyao
full_name: Li, Mengyao
last_name: Li
- first_name: Junshan
full_name: Li, Junshan
last_name: Li
- first_name: Maria
full_name: Ibáñez, Maria
id: 43C61214-F248-11E8-B48F-1D18A9856A87
last_name: Ibáñez
orcid: 0000-0001-5013-2843
- first_name: Min
full_name: Hong, Min
last_name: Hong
- first_name: Andreu
full_name: Cabot, Andreu
last_name: Cabot
citation:
ama: 'Liu Y, Li M, Wan S, et al. Surface chemistry and band engineering in AgSbSe₂:
Toward high thermoelectric performance. ACS Nano. 2023;17(12):11923–11934.
doi:10.1021/acsnano.3c03541'
apa: 'Liu, Y., Li, M., Wan, S., Lim, K. H., Zhang, Y., Li, M., … Cabot, A. (2023).
Surface chemistry and band engineering in AgSbSe₂: Toward high thermoelectric
performance. ACS Nano. American Chemical Society. https://doi.org/10.1021/acsnano.3c03541'
chicago: 'Liu, Yu, Mingquan Li, Shanhong Wan, Khak Ho Lim, Yu Zhang, Mengyao Li,
Junshan Li, Maria Ibáñez, Min Hong, and Andreu Cabot. “Surface Chemistry and Band
Engineering in AgSbSe₂: Toward High Thermoelectric Performance.” ACS Nano.
American Chemical Society, 2023. https://doi.org/10.1021/acsnano.3c03541.'
ieee: 'Y. Liu et al., “Surface chemistry and band engineering in AgSbSe₂:
Toward high thermoelectric performance,” ACS Nano, vol. 17, no. 12. American
Chemical Society, pp. 11923–11934, 2023.'
ista: 'Liu Y, Li M, Wan S, Lim KH, Zhang Y, Li M, Li J, Ibáñez M, Hong M, Cabot
A. 2023. Surface chemistry and band engineering in AgSbSe₂: Toward high thermoelectric
performance. ACS Nano. 17(12), 11923–11934.'
mla: 'Liu, Yu, et al. “Surface Chemistry and Band Engineering in AgSbSe₂: Toward
High Thermoelectric Performance.” ACS Nano, vol. 17, no. 12, American Chemical
Society, 2023, pp. 11923–11934, doi:10.1021/acsnano.3c03541.'
short: Y. Liu, M. Li, S. Wan, K.H. Lim, Y. Zhang, M. Li, J. Li, M. Ibáñez, M. Hong,
A. Cabot, ACS Nano 17 (2023) 11923–11934.
date_created: 2023-07-16T22:01:11Z
date_published: 2023-06-13T00:00:00Z
date_updated: 2023-08-02T06:29:55Z
day: '13'
department:
- _id: MaIb
doi: 10.1021/acsnano.3c03541
external_id:
isi:
- '001008564800001'
pmid:
- '37310395'
intvolume: ' 17'
isi: 1
issue: '12'
language:
- iso: eng
month: '06'
oa_version: None
page: 11923–11934
pmid: 1
project:
- _id: 9B8F7476-BA93-11EA-9121-9846C619BF3A
name: 'HighTE: The Werner Siemens Laboratory for the High Throughput Discovery of
Semiconductors for Waste Heat Recovery'
publication: ACS Nano
publication_identifier:
eissn:
- 1936-086X
issn:
- 1936-0851
publication_status: published
publisher: American Chemical Society
quality_controlled: '1'
scopus_import: '1'
status: public
title: 'Surface chemistry and band engineering in AgSbSe₂: Toward high thermoelectric
performance'
type: journal_article
user_id: 4359f0d1-fa6c-11eb-b949-802e58b17ae8
volume: 17
year: '2023'
...
---
_id: '13346'
abstract:
- lang: eng
text: The self-assembly of nanoparticles driven by small molecules or ions may produce
colloidal superlattices with features and properties reminiscent of those of metals
or semiconductors. However, to what extent the properties of such supramolecular
crystals actually resemble those of atomic materials often remains unclear. Here,
we present coarse-grained molecular simulations explicitly demonstrating how a
behavior evocative of that of semiconductors may emerge in a colloidal superlattice.
As a case study, we focus on gold nanoparticles bearing positively charged groups
that self-assemble into FCC crystals via mediation by citrate counterions. In
silico ohmic experiments show how the dynamically diverse behavior of the ions
in different superlattice domains allows the opening of conductive ionic gates
above certain levels of applied electric fields. The observed binary conductive/nonconductive
behavior is reminiscent of that of conventional semiconductors, while, at a supramolecular
level, crossing the “band gap” requires a sufficient electrostatic stimulus to
break the intermolecular interactions and make ions diffuse throughout the superlattice’s
cavities.
article_processing_charge: No
article_type: original
author:
- first_name: Chiara
full_name: Lionello, Chiara
last_name: Lionello
- first_name: Claudio
full_name: Perego, Claudio
last_name: Perego
- first_name: Andrea
full_name: Gardin, Andrea
last_name: Gardin
- first_name: Rafal
full_name: Klajn, Rafal
id: 8e84690e-1e48-11ed-a02b-a1e6fb8bb53b
last_name: Klajn
- first_name: Giovanni M.
full_name: Pavan, Giovanni M.
last_name: Pavan
citation:
ama: Lionello C, Perego C, Gardin A, Klajn R, Pavan GM. Supramolecular semiconductivity
through emerging ionic gates in ion–nanoparticle superlattices. ACS Nano.
2023;17(1):275-287. doi:10.1021/acsnano.2c07558
apa: Lionello, C., Perego, C., Gardin, A., Klajn, R., & Pavan, G. M. (2023).
Supramolecular semiconductivity through emerging ionic gates in ion–nanoparticle
superlattices. ACS Nano. American Chemical Society. https://doi.org/10.1021/acsnano.2c07558
chicago: Lionello, Chiara, Claudio Perego, Andrea Gardin, Rafal Klajn, and Giovanni
M. Pavan. “Supramolecular Semiconductivity through Emerging Ionic Gates in Ion–Nanoparticle
Superlattices.” ACS Nano. American Chemical Society, 2023. https://doi.org/10.1021/acsnano.2c07558.
ieee: C. Lionello, C. Perego, A. Gardin, R. Klajn, and G. M. Pavan, “Supramolecular
semiconductivity through emerging ionic gates in ion–nanoparticle superlattices,”
ACS Nano, vol. 17, no. 1. American Chemical Society, pp. 275–287, 2023.
ista: Lionello C, Perego C, Gardin A, Klajn R, Pavan GM. 2023. Supramolecular semiconductivity
through emerging ionic gates in ion–nanoparticle superlattices. ACS Nano. 17(1),
275–287.
mla: Lionello, Chiara, et al. “Supramolecular Semiconductivity through Emerging
Ionic Gates in Ion–Nanoparticle Superlattices.” ACS Nano, vol. 17, no.
1, American Chemical Society, 2023, pp. 275–87, doi:10.1021/acsnano.2c07558.
short: C. Lionello, C. Perego, A. Gardin, R. Klajn, G.M. Pavan, ACS Nano 17 (2023)
275–287.
date_created: 2023-08-01T09:30:29Z
date_published: 2023-01-10T00:00:00Z
date_updated: 2023-08-02T06:51:15Z
day: '10'
doi: 10.1021/acsnano.2c07558
extern: '1'
intvolume: ' 17'
issue: '1'
keyword:
- General Physics and Astronomy
- General Engineering
- General Materials Science
language:
- iso: eng
main_file_link:
- open_access: '1'
url: https://doi.org/10.1021/acsnano.2c07558
month: '01'
oa: 1
oa_version: Published Version
page: 275-287
publication: ACS Nano
publication_identifier:
eissn:
- 1936-086X
issn:
- 1936-0851
publication_status: published
publisher: American Chemical Society
quality_controlled: '1'
scopus_import: '1'
status: public
title: Supramolecular semiconductivity through emerging ionic gates in ion–nanoparticle
superlattices
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 17
year: '2023'
...
---
_id: '12915'
abstract:
- lang: eng
text: Cu2–xS and Cu2–xSe have recently been reported as promising thermoelectric
(TE) materials for medium-temperature applications. In contrast, Cu2–xTe, another
member of the copper chalcogenide family, typically exhibits low Seebeck coefficients
that limit its potential to achieve a superior thermoelectric figure of merit,
zT, particularly in the low-temperature range where this material could be effective.
To address this, we investigated the TE performance of Cu1.5–xTe–Cu2Se nanocomposites
by consolidating surface-engineered Cu1.5Te nanocrystals. This surface engineering
strategy allows for precise adjustment of Cu/Te ratios and results in a reversible
phase transition at around 600 K in Cu1.5–xTe–Cu2Se nanocomposites, as systematically
confirmed by in situ high-temperature X-ray diffraction combined with differential
scanning calorimetry analysis. The phase transition leads to a conversion from
metallic-like to semiconducting-like TE properties. Additionally, a layer of Cu2Se
generated around Cu1.5–xTe nanoparticles effectively inhibits Cu1.5–xTe grain
growth, minimizing thermal conductivity and decreasing hole concentration. These
properties indicate that copper telluride based compounds have a promising thermoelectric
potential, translated into a high dimensionless zT of 1.3 at 560 K.
acknowledgement: 'The authors acknowledge support from the projects ENE2016-77798-C4-3-R
and NANOGEN (PID2020-116093RB-C43) funded by MCIN/AEI/10.13039/501100011033/and
by “ERDF A way of making Europe”, and by the “European Union”. K.X. and B.N. thank
the China Scholarship Council (CSC) for scholarship support. The authors acknowledge
funding from Generalitat de Catalunya 2017 SGR 327 and 2017 SGR 1246. ICN2 is supported
by the Severo Ochoa program from the Spanish MCIN/AEI (Grant No.: CEX2021-001214-S).
IREC and ICN2 are funded by the CERCA Programme/Generalitat de Catalunya. J.L. acknowledges
support from the Natural Science Foundation of Sichuan province (2022NSFSC1229).
Part of the present work was performed in the frameworks of Universitat de Barcelona
Nanoscience Ph.D. program and Universitat Autònoma de Barcelona Materials Science
Ph.D. program. Y.L. acknowledges funding from the National Natural Science Foundation
of China (Grant No. 22209034) and the Innovation and Entrepreneurship Project of
Overseas Returnees in Anhui Province (Grants No. 2022LCX002). K.H.L. acknowledges
the financial support of the National Natural Science Foundation of China (Grant
No. 22208293).'
article_processing_charge: No
article_type: original
author:
- first_name: Congcong
full_name: Xing, Congcong
last_name: Xing
- first_name: Yu
full_name: Zhang, Yu
last_name: Zhang
- first_name: Ke
full_name: Xiao, Ke
last_name: Xiao
- first_name: Xu
full_name: Han, Xu
last_name: Han
- first_name: Yu
full_name: Liu, Yu
id: 2A70014E-F248-11E8-B48F-1D18A9856A87
last_name: Liu
orcid: 0000-0001-7313-6740
- first_name: Bingfei
full_name: Nan, Bingfei
last_name: 'Nan'
- first_name: Maria Garcia
full_name: Ramon, Maria Garcia
id: 1ffff7cd-ed76-11ed-8d5f-be5e7c364eb9
last_name: Ramon
- first_name: Khak Ho
full_name: Lim, Khak Ho
last_name: Lim
- first_name: Junshan
full_name: Li, Junshan
last_name: Li
- first_name: Jordi
full_name: Arbiol, Jordi
last_name: Arbiol
- first_name: Bed
full_name: Poudel, Bed
last_name: Poudel
- first_name: Amin
full_name: Nozariasbmarz, Amin
last_name: Nozariasbmarz
- first_name: Wenjie
full_name: Li, Wenjie
last_name: Li
- first_name: Maria
full_name: Ibáñez, Maria
id: 43C61214-F248-11E8-B48F-1D18A9856A87
last_name: Ibáñez
orcid: 0000-0001-5013-2843
- first_name: Andreu
full_name: Cabot, Andreu
last_name: Cabot
citation:
ama: Xing C, Zhang Y, Xiao K, et al. Thermoelectric performance of surface-engineered
Cu1.5–xTe–Cu2Se nanocomposites. ACS Nano. 2023;17(9):8442-8452. doi:10.1021/acsnano.3c00495
apa: Xing, C., Zhang, Y., Xiao, K., Han, X., Liu, Y., Nan, B., … Cabot, A. (2023).
Thermoelectric performance of surface-engineered Cu1.5–xTe–Cu2Se nanocomposites.
ACS Nano. American Chemical Society. https://doi.org/10.1021/acsnano.3c00495
chicago: Xing, Congcong, Yu Zhang, Ke Xiao, Xu Han, Yu Liu, Bingfei Nan, Maria Garcia
Ramon, et al. “Thermoelectric Performance of Surface-Engineered Cu1.5–XTe–Cu2Se
Nanocomposites.” ACS Nano. American Chemical Society, 2023. https://doi.org/10.1021/acsnano.3c00495.
ieee: C. Xing et al., “Thermoelectric performance of surface-engineered Cu1.5–xTe–Cu2Se
nanocomposites,” ACS Nano, vol. 17, no. 9. American Chemical Society, pp.
8442–8452, 2023.
ista: Xing C, Zhang Y, Xiao K, Han X, Liu Y, Nan B, Ramon MG, Lim KH, Li J, Arbiol
J, Poudel B, Nozariasbmarz A, Li W, Ibáñez M, Cabot A. 2023. Thermoelectric performance
of surface-engineered Cu1.5–xTe–Cu2Se nanocomposites. ACS Nano. 17(9), 8442–8452.
mla: Xing, Congcong, et al. “Thermoelectric Performance of Surface-Engineered Cu1.5–XTe–Cu2Se
Nanocomposites.” ACS Nano, vol. 17, no. 9, American Chemical Society, 2023,
pp. 8442–52, doi:10.1021/acsnano.3c00495.
short: C. Xing, Y. Zhang, K. Xiao, X. Han, Y. Liu, B. Nan, M.G. Ramon, K.H. Lim,
J. Li, J. Arbiol, B. Poudel, A. Nozariasbmarz, W. Li, M. Ibáñez, A. Cabot, ACS
Nano 17 (2023) 8442–8452.
date_created: 2023-05-07T22:01:04Z
date_published: 2023-05-09T00:00:00Z
date_updated: 2023-10-04T11:29:22Z
day: '09'
department:
- _id: MaIb
doi: 10.1021/acsnano.3c00495
external_id:
isi:
- '000976063200001'
pmid:
- '37071412'
intvolume: ' 17'
isi: 1
issue: '9'
language:
- iso: eng
month: '05'
oa_version: None
page: 8442-8452
pmid: 1
publication: ACS Nano
publication_identifier:
eissn:
- 1936-086X
issn:
- 1936-0851
publication_status: published
publisher: American Chemical Society
quality_controlled: '1'
scopus_import: '1'
status: public
title: Thermoelectric performance of surface-engineered Cu1.5–xTe–Cu2Se nanocomposites
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 17
year: '2023'
...
---
_id: '10042'
abstract:
- lang: eng
text: SnSe has emerged as one of the most promising materials for thermoelectric
energy conversion due to its extraordinary performance in its single-crystal form
and its low-cost constituent elements. However, to achieve an economic impact,
the polycrystalline counterpart needs to replicate the performance of the single
crystal. Herein, we optimize the thermoelectric performance of polycrystalline
SnSe produced by consolidating solution-processed and surface-engineered SnSe
particles. In particular, the SnSe particles are coated with CdSe molecular complexes
that crystallize during the sintering process, forming CdSe nanoparticles. The
presence of CdSe nanoparticles inhibits SnSe grain growth during the consolidation
step due to Zener pinning, yielding a material with a high density of grain boundaries.
Moreover, the resulting SnSe–CdSe nanocomposites present a large number of defects
at different length scales, which significantly reduce the thermal conductivity.
The produced SnSe–CdSe nanocomposites exhibit thermoelectric figures of merit
up to 2.2 at 786 K, which is among the highest reported for solution-processed
SnSe.
acknowledgement: 'This work was financially supported by IST Austria and the Werner
Siemens Foundation. Y.L. acknowledges funding from the European Union’s Horizon
2020 research and innovation program under the Marie Sklodowska-Curie grant agreement
No. 754411. S.L. and M.C. received funding from the European Union’s Horizon 2020
research and innovation program under the Marie Skłodowska-Curie Grant Agreement
No. 665385. J.D. acknowledges funding from the European Union’s Horizon 2020 research
and innovation program under the Marie Sklodowska-Curie grant agreement no. 665919
(P-SPHERE) cofunded by Severo Ochoa Programme. C.C. acknowledges funding from the
FWF “Lise Meitner Fellowship” grant agreement M 2889-N. Y.Y. and O.C.-M. acknowledge
the financial support from DFG within the project SFB 917: Nanoswitches. M.C.S.
received funding from the European Union’s Horizon 2020 research and innovation
programme under the Marie Skłodowska-Curie grant agreement No. 754510 (PROBIST)
and the Severo Ochoa programme. J.D. received funding from the European Union’s
Horizon 2020 research and innovation programme under the Marie Sklodowska-Curie
grant agreement No. 665919 (P-SPHERE) cofunded by Severo Ochoa Programme. The ICN2
is funded by the CERCA Program/Generalitat de Catalunya and by the Severo Ochoa
program of the Spanish Ministry of Economy, Industry, and Competitiveness (MINECO,
grant no. SEV-2017-0706). ICN2 acknowledges funding from Generalitat de Catalunya
2017 SGR 327 and the Spanish MINECO project NANOGEN (PID2020-116093RB-C43). This
project received funding from the European Union’s Horizon 2020 research and innovation
program under grant agreement No. 823717-ESTEEM3. The FIB sample preparation was
conducted in the LMA-INA-Universidad de Zaragoza.'
article_processing_charge: Yes (via OA deal)
article_type: original
author:
- first_name: Yu
full_name: Liu, Yu
id: 2A70014E-F248-11E8-B48F-1D18A9856A87
last_name: Liu
orcid: 0000-0001-7313-6740
- first_name: Mariano
full_name: Calcabrini, Mariano
id: 45D7531A-F248-11E8-B48F-1D18A9856A87
last_name: Calcabrini
- first_name: Yuan
full_name: Yu, Yuan
last_name: Yu
- first_name: Seungho
full_name: Lee, Seungho
id: BB243B88-D767-11E9-B658-BC13E6697425
last_name: Lee
orcid: 0000-0002-6962-8598
- first_name: Cheng
full_name: Chang, Cheng
id: 9E331C2E-9F27-11E9-AE48-5033E6697425
last_name: Chang
orcid: 0000-0002-9515-4277
- first_name: Jérémy
full_name: David, Jérémy
last_name: David
- first_name: Tanmoy
full_name: Ghosh, Tanmoy
id: a5fc9bc3-feff-11ea-93fe-e8015a3c7e9d
last_name: Ghosh
- first_name: Maria Chiara
full_name: Spadaro, Maria Chiara
last_name: Spadaro
- first_name: Chenyang
full_name: Xie, Chenyang
last_name: Xie
- first_name: Oana
full_name: Cojocaru-Mirédin, Oana
last_name: Cojocaru-Mirédin
- first_name: Jordi
full_name: Arbiol, Jordi
last_name: Arbiol
- first_name: Maria
full_name: Ibáñez, Maria
id: 43C61214-F248-11E8-B48F-1D18A9856A87
last_name: Ibáñez
orcid: 0000-0001-5013-2843
citation:
ama: Liu Y, Calcabrini M, Yu Y, et al. Defect engineering in solution-processed
polycrystalline SnSe leads to high thermoelectric performance. ACS Nano.
2022;16(1):78-88. doi:10.1021/acsnano.1c06720
apa: Liu, Y., Calcabrini, M., Yu, Y., Lee, S., Chang, C., David, J., … Ibáñez, M.
(2022). Defect engineering in solution-processed polycrystalline SnSe leads to
high thermoelectric performance. ACS Nano. American Chemical Society .
https://doi.org/10.1021/acsnano.1c06720
chicago: Liu, Yu, Mariano Calcabrini, Yuan Yu, Seungho Lee, Cheng Chang, Jérémy
David, Tanmoy Ghosh, et al. “Defect Engineering in Solution-Processed Polycrystalline
SnSe Leads to High Thermoelectric Performance.” ACS Nano. American Chemical
Society , 2022. https://doi.org/10.1021/acsnano.1c06720.
ieee: Y. Liu et al., “Defect engineering in solution-processed polycrystalline
SnSe leads to high thermoelectric performance,” ACS Nano, vol. 16, no.
1. American Chemical Society , pp. 78–88, 2022.
ista: Liu Y, Calcabrini M, Yu Y, Lee S, Chang C, David J, Ghosh T, Spadaro MC, Xie
C, Cojocaru-Mirédin O, Arbiol J, Ibáñez M. 2022. Defect engineering in solution-processed
polycrystalline SnSe leads to high thermoelectric performance. ACS Nano. 16(1),
78–88.
mla: Liu, Yu, et al. “Defect Engineering in Solution-Processed Polycrystalline SnSe
Leads to High Thermoelectric Performance.” ACS Nano, vol. 16, no. 1, American
Chemical Society , 2022, pp. 78–88, doi:10.1021/acsnano.1c06720.
short: Y. Liu, M. Calcabrini, Y. Yu, S. Lee, C. Chang, J. David, T. Ghosh, M.C.
Spadaro, C. Xie, O. Cojocaru-Mirédin, J. Arbiol, M. Ibáñez, ACS Nano 16 (2022)
78–88.
date_created: 2021-09-24T07:55:12Z
date_published: 2022-01-25T00:00:00Z
date_updated: 2023-08-02T14:41:05Z
day: '25'
ddc:
- '540'
department:
- _id: MaIb
doi: 10.1021/acsnano.1c06720
ec_funded: 1
external_id:
isi:
- '000767223400008'
pmid:
- '34549956'
file:
- access_level: open_access
checksum: 74f9c1aa5f95c0b992a4328e8e0247b4
content_type: application/pdf
creator: cchlebak
date_created: 2022-03-02T16:17:29Z
date_updated: 2022-03-02T16:17:29Z
file_id: '10808'
file_name: 2022_ACSNano_Liu.pdf
file_size: 9050764
relation: main_file
success: 1
file_date_updated: 2022-03-02T16:17:29Z
has_accepted_license: '1'
intvolume: ' 16'
isi: 1
issue: '1'
keyword:
- tin selenide
- nanocomposite
- grain growth
- Zener pinning
- thermoelectricity
- annealing
- solution processing
language:
- iso: eng
month: '01'
oa: 1
oa_version: Published Version
page: 78-88
pmid: 1
project:
- _id: 260C2330-B435-11E9-9278-68D0E5697425
call_identifier: H2020
grant_number: '754411'
name: ISTplus - Postdoctoral Fellowships
- _id: 2564DBCA-B435-11E9-9278-68D0E5697425
call_identifier: H2020
grant_number: '665385'
name: International IST Doctoral Program
- _id: 9B8F7476-BA93-11EA-9121-9846C619BF3A
name: 'HighTE: The Werner Siemens Laboratory for the High Throughput Discovery of
Semiconductors for Waste Heat Recovery'
- _id: 9B8804FC-BA93-11EA-9121-9846C619BF3A
grant_number: M02889
name: Bottom-up Engineering for Thermoelectric Applications
publication: ACS Nano
publication_identifier:
eissn:
- 1936-086X
issn:
- 1936-0851
publication_status: published
publisher: 'American Chemical Society '
quality_controlled: '1'
related_material:
record:
- id: '12885'
relation: dissertation_contains
status: public
scopus_import: '1'
status: public
title: Defect engineering in solution-processed polycrystalline SnSe leads to high
thermoelectric performance
tmp:
image: /images/cc_by.png
legal_code_url: https://creativecommons.org/licenses/by/4.0/legalcode
name: Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)
short: CC BY (4.0)
type: journal_article
user_id: 4359f0d1-fa6c-11eb-b949-802e58b17ae8
volume: 16
year: '2022'
...
---
_id: '9235'
abstract:
- lang: eng
text: Cu2–xS has become one of the most promising thermoelectric materials for application
in the middle-high temperature range. Its advantages include the abundance, low
cost, and safety of its elements and a high performance at relatively elevated
temperatures. However, stability issues limit its operation current and temperature,
thus calling for the optimization of the material performance in the middle temperature
range. Here, we present a synthetic protocol for large scale production of covellite
CuS nanoparticles at ambient temperature and atmosphere, and using water as a
solvent. The crystal phase and stoichiometry of the particles are afterward tuned
through an annealing process at a moderate temperature under inert or reducing
atmosphere. While annealing under argon results in Cu1.8S nanopowder with a rhombohedral
crystal phase, annealing in an atmosphere containing hydrogen leads to tetragonal
Cu1.96S. High temperature X-ray diffraction analysis shows the material annealed
in argon to transform to the cubic phase at ca. 400 K, while the material annealed
in the presence of hydrogen undergoes two phase transitions, first to hexagonal
and then to the cubic structure. The annealing atmosphere, temperature, and time
allow adjustment of the density of copper vacancies and thus tuning of the charge
carrier concentration and material transport properties. In this direction, the
material annealed under Ar is characterized by higher electrical conductivities
but lower Seebeck coefficients than the material annealed in the presence of hydrogen.
By optimizing the charge carrier concentration through the annealing time, Cu2–xS
with record figures of merit in the middle temperature range, up to 1.41 at 710
K, is obtained. We finally demonstrate that this strategy, based on a low-cost
and scalable solution synthesis process, is also suitable for the production of
high performance Cu2–xS layers using high throughput and cost-effective printing
technologies.
acknowledgement: This work was supported by the European Regional Development Funds.
M.Y.L., X.H., T.Z., and K.X. thank the China Scholarship Council for scholarship
support. M.I. acknowledges financial support from IST Austria. J.L. acknowledges
support from the National Natural Science Foundation of China (No. 22008091), the
funding for scientific research startup of Jiangsu University (No. 19JDG044), and
Jiangsu Provincial Program for High-Level Innovative and Entrepreneurial Talents
Introduction. J.L. is a Serra Húnter fellow and is grateful to the ICREA Academia
program and projects MICINN/FEDER RTI2018-093996-B-C31 and GC 2017 SGR 128. ICN2
acknowledges funding from Generalitat de Catalunya 2017 SGR 327 and the Spanish
MINECO ENE2017-85087-C3. ICN2 is supported by the Severo Ochoa program from Spanish
MINECO (Grant No. SEV-2017-0706) and is funded by the CERCA Programme/Generalitat
de Catalunya. Part of the present work has been performed in the framework of Universitat
Autònoma de Barcelona Materials Science PhD program. T.Z. has received funding from
the CSC-UAB PhD scholarship program.
article_processing_charge: No
article_type: original
author:
- first_name: Mengyao
full_name: Li, Mengyao
last_name: Li
- first_name: Yu
full_name: Liu, Yu
id: 2A70014E-F248-11E8-B48F-1D18A9856A87
last_name: Liu
orcid: 0000-0001-7313-6740
- first_name: Yu
full_name: Zhang, Yu
last_name: Zhang
- first_name: Xu
full_name: Han, Xu
last_name: Han
- first_name: Ting
full_name: Zhang, Ting
last_name: Zhang
- first_name: Yong
full_name: Zuo, Yong
last_name: Zuo
- first_name: Chenyang
full_name: Xie, Chenyang
last_name: Xie
- first_name: Ke
full_name: Xiao, Ke
last_name: Xiao
- first_name: Jordi
full_name: Arbiol, Jordi
last_name: Arbiol
- first_name: Jordi
full_name: Llorca, Jordi
last_name: Llorca
- first_name: Maria
full_name: Ibáñez, Maria
id: 43C61214-F248-11E8-B48F-1D18A9856A87
last_name: Ibáñez
orcid: 0000-0001-5013-2843
- first_name: Junfeng
full_name: Liu, Junfeng
last_name: Liu
- first_name: Andreu
full_name: Cabot, Andreu
last_name: Cabot
citation:
ama: Li M, Liu Y, Zhang Y, et al. Effect of the annealing atmosphere on crystal
phase and thermoelectric properties of copper sulfide. ACS Nano. 2021;15(3):4967–4978.
doi:10.1021/acsnano.0c09866
apa: Li, M., Liu, Y., Zhang, Y., Han, X., Zhang, T., Zuo, Y., … Cabot, A. (2021).
Effect of the annealing atmosphere on crystal phase and thermoelectric properties
of copper sulfide. ACS Nano. American Chemical Society . https://doi.org/10.1021/acsnano.0c09866
chicago: Li, Mengyao, Yu Liu, Yu Zhang, Xu Han, Ting Zhang, Yong Zuo, Chenyang Xie,
et al. “Effect of the Annealing Atmosphere on Crystal Phase and Thermoelectric
Properties of Copper Sulfide.” ACS Nano. American Chemical Society , 2021.
https://doi.org/10.1021/acsnano.0c09866.
ieee: M. Li et al., “Effect of the annealing atmosphere on crystal phase
and thermoelectric properties of copper sulfide,” ACS Nano, vol. 15, no.
3. American Chemical Society , pp. 4967–4978, 2021.
ista: Li M, Liu Y, Zhang Y, Han X, Zhang T, Zuo Y, Xie C, Xiao K, Arbiol J, Llorca
J, Ibáñez M, Liu J, Cabot A. 2021. Effect of the annealing atmosphere on crystal
phase and thermoelectric properties of copper sulfide. ACS Nano. 15(3), 4967–4978.
mla: Li, Mengyao, et al. “Effect of the Annealing Atmosphere on Crystal Phase and
Thermoelectric Properties of Copper Sulfide.” ACS Nano, vol. 15, no. 3,
American Chemical Society , 2021, pp. 4967–4978, doi:10.1021/acsnano.0c09866.
short: M. Li, Y. Liu, Y. Zhang, X. Han, T. Zhang, Y. Zuo, C. Xie, K. Xiao, J. Arbiol,
J. Llorca, M. Ibáñez, J. Liu, A. Cabot, ACS Nano 15 (2021) 4967–4978.
date_created: 2021-03-10T20:12:45Z
date_published: 2021-03-01T00:00:00Z
date_updated: 2023-10-03T09:59:55Z
day: '01'
department:
- _id: MaIb
doi: 10.1021/acsnano.0c09866
external_id:
isi:
- '000634569100106'
pmid:
- '33645986'
intvolume: ' 15'
isi: 1
issue: '3'
keyword:
- General Engineering
- General Physics and Astronomy
- General Materials Science
language:
- iso: eng
main_file_link:
- open_access: '1'
url: https://upcommons.upc.edu/bitstream/handle/2117/363528/Pb%20mengyao.pdf?sequence=1&isAllowed=y
month: '03'
oa: 1
oa_version: Submitted Version
page: 4967–4978
pmid: 1
publication: ACS Nano
publication_identifier:
eissn:
- 1936-086X
issn:
- 1936-0851
publication_status: published
publisher: 'American Chemical Society '
quality_controlled: '1'
scopus_import: '1'
status: public
title: Effect of the annealing atmosphere on crystal phase and thermoelectric properties
of copper sulfide
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 15
year: '2021'
...
---
_id: '7634'
abstract:
- lang: eng
text: Assemblies of colloidal semiconductor nanocrystals (NCs) in the form of thin
solid films leverage the size-dependent quantum confinement properties and the
wet chemical methods vital for the development of the emerging solution-processable
electronics, photonics, and optoelectronics technologies. The ability to control
the charge carrier transport in the colloidal NC assemblies is fundamental for
altering their electronic and optical properties for the desired applications.
Here we demonstrate a strategy to render the solids of narrow-bandgap NC assemblies
exclusively electron-transporting by creating a type-II heterojunction via shelling.
Electronic transport of molecularly cross-linked PbTe@PbS core@shell NC assemblies
is measured using both a conventional solid gate transistor and an electric-double-layer
transistor, as well as compared with those of core-only PbTe NCs. In contrast
to the ambipolar characteristics demonstrated by many narrow-bandgap NCs, the
core@shell NCs exhibit exclusive n-type transport, i.e., drastically suppressed
contribution of holes to the overall transport. The PbS shell that forms a type-II
heterojunction assists the selective carrier transport by heavy doping of electrons
into the PbTe-core conduction level and simultaneously strongly localizes the
holes within the NC core valence level. This strongly enhanced n-type transport
makes these core@shell NCs suitable for applications where ambipolar characteristics
should be actively suppressed, in particular, for thermoelectric and electron-transporting
layers in photovoltaic devices.
acknowledgement: This work is partly supported by Grants-in-Aid for Scientific Research
by Young Scientist A (KAKENHI Wakate-A) No. JP17H04802, Grants-in-Aid for Scientific
Research No. JP19H05602 from the Japan Society for the Promotion of Science, and
RIKEN Incentive Research Grant (Shoreikadai) 2016. M.V.K. and M.I. acknowledge financial
support from the European Union (EU) via FP7 ERC Starting Grant 2012 (Project NANOSOLID,
GA No. 306733) and ETH Zurich via ETH career seed grant (SEED-18 16-2). Support
from Cambridge Display Technology, Ltd., and Sumitomo Chemical Company is also acknowledged.
We thank Mrs. T. Kikitsu and Dr. D. Hashizume (RIKEN-CEMS) for access to the transmission
electron microscope facility.
article_processing_charge: No
article_type: original
author:
- first_name: Retno
full_name: Miranti, Retno
last_name: Miranti
- first_name: Daiki
full_name: Shin, Daiki
last_name: Shin
- first_name: Ricky Dwi
full_name: Septianto, Ricky Dwi
last_name: Septianto
- first_name: Maria
full_name: Ibáñez, Maria
id: 43C61214-F248-11E8-B48F-1D18A9856A87
last_name: Ibáñez
orcid: 0000-0001-5013-2843
- first_name: Maksym V.
full_name: Kovalenko, Maksym V.
last_name: Kovalenko
- first_name: Nobuhiro
full_name: Matsushita, Nobuhiro
last_name: Matsushita
- first_name: Yoshihiro
full_name: Iwasa, Yoshihiro
last_name: Iwasa
- first_name: Satria Zulkarnaen
full_name: Bisri, Satria Zulkarnaen
last_name: Bisri
citation:
ama: Miranti R, Shin D, Septianto RD, et al. Exclusive electron transport in Core@Shell
PbTe@PbS colloidal semiconductor nanocrystal assemblies. ACS Nano. 2020;14(3):3242-3250.
doi:10.1021/acsnano.9b08687
apa: Miranti, R., Shin, D., Septianto, R. D., Ibáñez, M., Kovalenko, M. V., Matsushita,
N., … Bisri, S. Z. (2020). Exclusive electron transport in Core@Shell PbTe@PbS
colloidal semiconductor nanocrystal assemblies. ACS Nano. American Chemical
Society. https://doi.org/10.1021/acsnano.9b08687
chicago: Miranti, Retno, Daiki Shin, Ricky Dwi Septianto, Maria Ibáñez, Maksym V.
Kovalenko, Nobuhiro Matsushita, Yoshihiro Iwasa, and Satria Zulkarnaen Bisri.
“Exclusive Electron Transport in Core@Shell PbTe@PbS Colloidal Semiconductor Nanocrystal
Assemblies.” ACS Nano. American Chemical Society, 2020. https://doi.org/10.1021/acsnano.9b08687.
ieee: R. Miranti et al., “Exclusive electron transport in Core@Shell PbTe@PbS
colloidal semiconductor nanocrystal assemblies,” ACS Nano, vol. 14, no.
3. American Chemical Society, pp. 3242–3250, 2020.
ista: Miranti R, Shin D, Septianto RD, Ibáñez M, Kovalenko MV, Matsushita N, Iwasa
Y, Bisri SZ. 2020. Exclusive electron transport in Core@Shell PbTe@PbS colloidal
semiconductor nanocrystal assemblies. ACS Nano. 14(3), 3242–3250.
mla: Miranti, Retno, et al. “Exclusive Electron Transport in Core@Shell PbTe@PbS
Colloidal Semiconductor Nanocrystal Assemblies.” ACS Nano, vol. 14, no.
3, American Chemical Society, 2020, pp. 3242–50, doi:10.1021/acsnano.9b08687.
short: R. Miranti, D. Shin, R.D. Septianto, M. Ibáñez, M.V. Kovalenko, N. Matsushita,
Y. Iwasa, S.Z. Bisri, ACS Nano 14 (2020) 3242–3250.
date_created: 2020-04-05T22:00:48Z
date_published: 2020-03-24T00:00:00Z
date_updated: 2023-08-18T10:25:40Z
day: '24'
department:
- _id: MaIb
doi: 10.1021/acsnano.9b08687
external_id:
isi:
- '000526301400057'
pmid:
- '32073817'
intvolume: ' 14'
isi: 1
issue: '3'
language:
- iso: eng
month: '03'
oa_version: None
page: 3242-3250
pmid: 1
publication: ACS Nano
publication_identifier:
eissn:
- 1936-086X
publication_status: published
publisher: American Chemical Society
quality_controlled: '1'
scopus_import: '1'
status: public
title: Exclusive electron transport in Core@Shell PbTe@PbS colloidal semiconductor
nanocrystal assemblies
type: journal_article
user_id: 4359f0d1-fa6c-11eb-b949-802e58b17ae8
volume: 14
year: '2020'
...
---
_id: '6566'
abstract:
- lang: eng
text: Methodologies that involve the use of nanoparticles as “artificial atoms”
to rationally build materials in a bottom-up fashion are particularly well-suited
to control the matter at the nanoscale. Colloidal synthetic routes allow for an
exquisite control over such “artificial atoms” in terms of size, shape, and crystal
phase as well as core and surface compositions. We present here a bottom-up approach
to produce Pb–Ag–K–S–Te nanocomposites, which is a highly promising system for
thermoelectric energy conversion. First, we developed a high-yield and scalable
colloidal synthesis route to uniform lead sulfide (PbS) nanorods, whose tips are
made of silver sulfide (Ag2S). We then took advantage of the large surface-to-volume
ratio to introduce a p-type dopant (K) by replacing native organic ligands with
K2Te. Upon thermal consolidation, K2Te-surface modified PbS–Ag2S nanorods yield
p-type doped nanocomposites with PbTe and PbS as major phases and Ag2S and Ag2Te
as embedded nanoinclusions. Thermoelectric characterization of such consolidated
nanosolids showed a high thermoelectric figure-of-merit of 1 at 620 K.
article_processing_charge: Yes (in subscription journal)
article_type: original
author:
- first_name: Maria
full_name: Ibáñez, Maria
id: 43C61214-F248-11E8-B48F-1D18A9856A87
last_name: Ibáñez
orcid: 0000-0001-5013-2843
- first_name: Aziz
full_name: Genç, Aziz
last_name: Genç
- first_name: Roger
full_name: Hasler, Roger
last_name: Hasler
- first_name: Yu
full_name: Liu, Yu
id: 2A70014E-F248-11E8-B48F-1D18A9856A87
last_name: Liu
orcid: 0000-0001-7313-6740
- first_name: Oleksandr
full_name: Dobrozhan, Oleksandr
last_name: Dobrozhan
- first_name: Olga
full_name: Nazarenko, Olga
last_name: Nazarenko
- first_name: María de la
full_name: Mata, María de la
last_name: Mata
- first_name: Jordi
full_name: Arbiol, Jordi
last_name: Arbiol
- first_name: Andreu
full_name: Cabot, Andreu
last_name: Cabot
- first_name: Maksym V.
full_name: Kovalenko, Maksym V.
last_name: Kovalenko
citation:
ama: Ibáñez M, Genç A, Hasler R, et al. Tuning transport properties in thermoelectric
nanocomposites through inorganic ligands and heterostructured building blocks.
ACS Nano. 2019;13(6):6572-6580. doi:10.1021/acsnano.9b00346
apa: Ibáñez, M., Genç, A., Hasler, R., Liu, Y., Dobrozhan, O., Nazarenko, O., …
Kovalenko, M. V. (2019). Tuning transport properties in thermoelectric nanocomposites
through inorganic ligands and heterostructured building blocks. ACS Nano.
American Chemical Society. https://doi.org/10.1021/acsnano.9b00346
chicago: Ibáñez, Maria, Aziz Genç, Roger Hasler, Yu Liu, Oleksandr Dobrozhan, Olga
Nazarenko, María de la Mata, Jordi Arbiol, Andreu Cabot, and Maksym V. Kovalenko.
“Tuning Transport Properties in Thermoelectric Nanocomposites through Inorganic
Ligands and Heterostructured Building Blocks.” ACS Nano. American Chemical
Society, 2019. https://doi.org/10.1021/acsnano.9b00346.
ieee: M. Ibáñez et al., “Tuning transport properties in thermoelectric nanocomposites
through inorganic ligands and heterostructured building blocks,” ACS Nano,
vol. 13, no. 6. American Chemical Society, pp. 6572–6580, 2019.
ista: Ibáñez M, Genç A, Hasler R, Liu Y, Dobrozhan O, Nazarenko O, Mata M de la,
Arbiol J, Cabot A, Kovalenko MV. 2019. Tuning transport properties in thermoelectric
nanocomposites through inorganic ligands and heterostructured building blocks.
ACS Nano. 13(6), 6572–6580.
mla: Ibáñez, Maria, et al. “Tuning Transport Properties in Thermoelectric Nanocomposites
through Inorganic Ligands and Heterostructured Building Blocks.” ACS Nano,
vol. 13, no. 6, American Chemical Society, 2019, pp. 6572–80, doi:10.1021/acsnano.9b00346.
short: M. Ibáñez, A. Genç, R. Hasler, Y. Liu, O. Dobrozhan, O. Nazarenko, M. de
la Mata, J. Arbiol, A. Cabot, M.V. Kovalenko, ACS Nano 13 (2019) 6572–6580.
date_created: 2019-06-18T13:54:34Z
date_published: 2019-06-25T00:00:00Z
date_updated: 2023-08-28T12:20:53Z
day: '25'
ddc:
- '540'
department:
- _id: MaIb
doi: 10.1021/acsnano.9b00346
ec_funded: 1
external_id:
isi:
- '000473248300043'
pmid:
- '31185159'
file:
- access_level: open_access
content_type: application/pdf
creator: dernst
date_created: 2019-07-16T14:17:09Z
date_updated: 2020-07-14T12:47:33Z
file_id: '6644'
file_name: 2019_ACSNano_Ibanez.pdf
file_size: 8628690
relation: main_file
file_date_updated: 2020-07-14T12:47:33Z
has_accepted_license: '1'
intvolume: ' 13'
isi: 1
issue: '6'
keyword:
- colloidal nanoparticles
- asymmetric nanoparticles
- inorganic ligands
- heterostructures
- catalyst assisted growth
- nanocomposites
- thermoelectrics
language:
- iso: eng
month: '06'
oa: 1
oa_version: Published Version
page: 6572-6580
pmid: 1
project:
- _id: 260C2330-B435-11E9-9278-68D0E5697425
call_identifier: H2020
grant_number: '754411'
name: ISTplus - Postdoctoral Fellowships
publication: ACS Nano
publication_identifier:
eissn:
- 1936-086X
issn:
- 1936-0851
publication_status: published
publisher: American Chemical Society
quality_controlled: '1'
scopus_import: '1'
status: public
title: Tuning transport properties in thermoelectric nanocomposites through inorganic
ligands and heterostructured building blocks
type: journal_article
user_id: 4359f0d1-fa6c-11eb-b949-802e58b17ae8
volume: 13
year: '2019'
...
---
_id: '10362'
abstract:
- lang: eng
text: Nuclear pore complexes (NPCs) form gateways that control molecular exchange
between the nucleus and the cytoplasm. They impose a diffusion barrier to macromolecules
and enable the selective transport of nuclear transport receptors with bound cargo.
The underlying mechanisms that establish these permeability properties remain
to be fully elucidated but require unstructured nuclear pore proteins rich in
Phe-Gly (FG)-repeat domains of different types, such as FxFG and GLFG. While physical
modeling and in vitro approaches have provided a framework for explaining how
the FG network contributes to the barrier and transport properties of the NPC,
it remains unknown whether the number and/or the spatial positioning of different
FG-domains along a cylindrical, ∼40 nm diameter transport channel contributes
to their collective properties and function. To begin to answer these questions,
we have used DNA origami to build a cylinder that mimics the dimensions of the
central transport channel and can house a specified number of FG-domains at specific
positions with easily tunable design parameters, such as grafting density and
topology. We find the overall morphology of the FG-domain assemblies to be dependent
on their chemical composition, determined by the type and density of FG-repeat,
and on their architectural confinement provided by the DNA cylinder, largely consistent
with here presented molecular dynamics simulations based on a coarse-grained polymer
model. In addition, high-speed atomic force microscopy reveals local and reversible
FG-domain condensation that transiently occludes the lumen of the DNA central
channel mimics, suggestive of how the NPC might establish its permeability properties.
acknowledgement: We thank J. Edel and members of the Lusk, Lin and Hoogenboom lab
for discussion and acknowledge A. Pyne and R. Thorogate for support carrying out
the AFM experiments. This work was funded by the NIH (R21GM109466 to CPL, CL and
TJM, DP2GM114830 to CL, RO1GM105672 to CPL, and T32GM007223 to PDEF) and the UK
Engineering and Physical Sciences Research Council (EP/L015277/1, EP/L504889/1,
and EP/M028100/1).
article_processing_charge: No
article_type: original
author:
- first_name: Patrick D. Ellis
full_name: Fisher, Patrick D. Ellis
last_name: Fisher
- first_name: Qi
full_name: Shen, Qi
last_name: Shen
- first_name: Bernice
full_name: Akpinar, Bernice
last_name: Akpinar
- first_name: Luke K.
full_name: Davis, Luke K.
last_name: Davis
- first_name: Kenny Kwok Hin
full_name: Chung, Kenny Kwok Hin
last_name: Chung
- first_name: David
full_name: Baddeley, David
last_name: Baddeley
- first_name: Anđela
full_name: Šarić, Anđela
id: bf63d406-f056-11eb-b41d-f263a6566d8b
last_name: Šarić
orcid: 0000-0002-7854-2139
- first_name: Thomas J.
full_name: Melia, Thomas J.
last_name: Melia
- first_name: Bart W.
full_name: Hoogenboom, Bart W.
last_name: Hoogenboom
- first_name: Chenxiang
full_name: Lin, Chenxiang
last_name: Lin
- first_name: C. Patrick
full_name: Lusk, C. Patrick
last_name: Lusk
citation:
ama: Fisher PDE, Shen Q, Akpinar B, et al. A Programmable DNA origami platform for
organizing intrinsically disordered nucleoporins within nanopore confinement.
ACS Nano. 2018;12(2):1508-1518. doi:10.1021/acsnano.7b08044
apa: Fisher, P. D. E., Shen, Q., Akpinar, B., Davis, L. K., Chung, K. K. H., Baddeley,
D., … Lusk, C. P. (2018). A Programmable DNA origami platform for organizing intrinsically
disordered nucleoporins within nanopore confinement. ACS Nano. American
Chemical Society. https://doi.org/10.1021/acsnano.7b08044
chicago: Fisher, Patrick D. Ellis, Qi Shen, Bernice Akpinar, Luke K. Davis, Kenny
Kwok Hin Chung, David Baddeley, Anđela Šarić, et al. “A Programmable DNA Origami
Platform for Organizing Intrinsically Disordered Nucleoporins within Nanopore
Confinement.” ACS Nano. American Chemical Society, 2018. https://doi.org/10.1021/acsnano.7b08044.
ieee: P. D. E. Fisher et al., “A Programmable DNA origami platform for organizing
intrinsically disordered nucleoporins within nanopore confinement,” ACS Nano,
vol. 12, no. 2. American Chemical Society, pp. 1508–1518, 2018.
ista: Fisher PDE, Shen Q, Akpinar B, Davis LK, Chung KKH, Baddeley D, Šarić A, Melia
TJ, Hoogenboom BW, Lin C, Lusk CP. 2018. A Programmable DNA origami platform for
organizing intrinsically disordered nucleoporins within nanopore confinement.
ACS Nano. 12(2), 1508–1518.
mla: Fisher, Patrick D. Ellis, et al. “A Programmable DNA Origami Platform for Organizing
Intrinsically Disordered Nucleoporins within Nanopore Confinement.” ACS Nano,
vol. 12, no. 2, American Chemical Society, 2018, pp. 1508–18, doi:10.1021/acsnano.7b08044.
short: P.D.E. Fisher, Q. Shen, B. Akpinar, L.K. Davis, K.K.H. Chung, D. Baddeley,
A. Šarić, T.J. Melia, B.W. Hoogenboom, C. Lin, C.P. Lusk, ACS Nano 12 (2018) 1508–1518.
date_created: 2021-11-26T15:15:00Z
date_published: 2018-01-19T00:00:00Z
date_updated: 2021-11-26T15:57:02Z
day: '19'
doi: 10.1021/acsnano.7b08044
extern: '1'
external_id:
pmid:
- '29350911'
intvolume: ' 12'
issue: '2'
keyword:
- general physics and astronomy
language:
- iso: eng
month: '01'
oa_version: None
page: 1508-1518
pmid: 1
publication: ACS Nano
publication_identifier:
eissn:
- 1936-086X
issn:
- 1936-0851
publication_status: published
publisher: American Chemical Society
quality_controlled: '1'
scopus_import: '1'
status: public
title: A Programmable DNA origami platform for organizing intrinsically disordered
nucleoporins within nanopore confinement
type: journal_article
user_id: 8b945eb4-e2f2-11eb-945a-df72226e66a9
volume: 12
year: '2018'
...
---
_id: '14302'
abstract:
- lang: eng
text: One key goal of DNA nanotechnology is the bottom-up construction of macroscopic
crystalline materials. Beyond applications in fields such as photonics or plasmonics,
DNA-based crystal matrices could possibly facilitate the diffraction-based structural
analysis of guest molecules. Seeman and co-workers reported in 2009 the first
designed crystal matrices based on a 38 kDa DNA triangle that was composed of
seven chains. The crystal lattice was stabilized, unprecedentedly, by Watson–Crick
base pairing. However, 3D crystallization of larger designed DNA objects that
include more chains such as DNA origami remains an unsolved problem. Larger objects
would offer more degrees of freedom and design options with respect to tailoring
lattice geometry and for positioning other objects within a crystal lattice. The
greater rigidity of multilayer DNA origami could also positively influence the
diffractive properties of crystals composed of such particles. Here, we rationally
explore the role of heterogeneity and Watson–Crick interaction strengths in crystal
growth using 40 variants of the original DNA triangle as model multichain objects.
Crystal growth of the triangle was remarkably robust despite massive chemical,
geometrical, and thermodynamical sample heterogeneity that we introduced, but
the crystal growth sensitively depended on the sequences of base pairs next to
the Watson–Crick sticky ends of the triangle. Our results point to weak lattice
interactions and high concentrations as decisive factors for achieving productive
crystallization, while sample heterogeneity and impurities played a minor role.
article_processing_charge: No
article_type: original
author:
- first_name: Evi
full_name: Stahl, Evi
last_name: Stahl
- first_name: Florian M
full_name: Praetorius, Florian M
id: dfec9381-4341-11ee-8fd8-faa02bba7d62
last_name: Praetorius
- first_name: Carina C.
full_name: de Oliveira Mann, Carina C.
last_name: de Oliveira Mann
- first_name: Karl-Peter
full_name: Hopfner, Karl-Peter
last_name: Hopfner
- first_name: Hendrik
full_name: Dietz, Hendrik
last_name: Dietz
citation:
ama: Stahl E, Praetorius FM, de Oliveira Mann CC, Hopfner K-P, Dietz H. Impact of
heterogeneity and lattice bond strength on DNA triangle crystal growth. ACS
Nano. 2016;10(10):9156-9164. doi:10.1021/acsnano.6b04787
apa: Stahl, E., Praetorius, F. M., de Oliveira Mann, C. C., Hopfner, K.-P., &
Dietz, H. (2016). Impact of heterogeneity and lattice bond strength on DNA triangle
crystal growth. ACS Nano. American Chemical Society. https://doi.org/10.1021/acsnano.6b04787
chicago: Stahl, Evi, Florian M Praetorius, Carina C. de Oliveira Mann, Karl-Peter
Hopfner, and Hendrik Dietz. “Impact of Heterogeneity and Lattice Bond Strength
on DNA Triangle Crystal Growth.” ACS Nano. American Chemical Society, 2016.
https://doi.org/10.1021/acsnano.6b04787.
ieee: E. Stahl, F. M. Praetorius, C. C. de Oliveira Mann, K.-P. Hopfner, and H.
Dietz, “Impact of heterogeneity and lattice bond strength on DNA triangle crystal
growth,” ACS Nano, vol. 10, no. 10. American Chemical Society, pp. 9156–9164,
2016.
ista: Stahl E, Praetorius FM, de Oliveira Mann CC, Hopfner K-P, Dietz H. 2016. Impact
of heterogeneity and lattice bond strength on DNA triangle crystal growth. ACS
Nano. 10(10), 9156–9164.
mla: Stahl, Evi, et al. “Impact of Heterogeneity and Lattice Bond Strength on DNA
Triangle Crystal Growth.” ACS Nano, vol. 10, no. 10, American Chemical
Society, 2016, pp. 9156–64, doi:10.1021/acsnano.6b04787.
short: E. Stahl, F.M. Praetorius, C.C. de Oliveira Mann, K.-P. Hopfner, H. Dietz,
ACS Nano 10 (2016) 9156–9164.
date_created: 2023-09-06T12:52:00Z
date_published: 2016-09-01T00:00:00Z
date_updated: 2023-11-07T12:08:46Z
day: '01'
doi: 10.1021/acsnano.6b04787
extern: '1'
external_id:
pmid:
- '27583560'
intvolume: ' 10'
issue: '10'
language:
- iso: eng
month: '09'
oa_version: None
page: 9156-9164
pmid: 1
publication: ACS Nano
publication_identifier:
eissn:
- 1936-086X
issn:
- 1936-0851
publication_status: published
publisher: American Chemical Society
quality_controlled: '1'
scopus_import: '1'
status: public
title: Impact of heterogeneity and lattice bond strength on DNA triangle crystal growth
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 10
year: '2016'
...
---
_id: '13399'
abstract:
- lang: eng
text: Nature has long inspired scientists with its seemingly unlimited ability to
harness solar energy and to utilize it to drive various physiological processes.
With the help of man-made molecular photoswitches, we now have the potential to
outperform natural systems in many ways, with the ultimate goal of fabricating
multifunctional materials that operate at different light wavelengths. An important
challenge in developing light-controlled artificial molecular machines lies in
attaining a detailed understanding of the photoisomerization-coupled conformational
changes that occur in macromolecules and molecular assemblies. In this issue of
ACS Nano, Bléger, Rabe, and co-workers use force microscopy to provide interesting
insights into the behavior of individual photoresponsive molecules and to identify
contraction, extension, and crawling events accompanying light-induced isomerization.
article_processing_charge: No
article_type: original
author:
- first_name: Pintu K.
full_name: Kundu, Pintu K.
last_name: Kundu
- first_name: Rafal
full_name: Klajn, Rafal
id: 8e84690e-1e48-11ed-a02b-a1e6fb8bb53b
last_name: Klajn
citation:
ama: Kundu PK, Klajn R. Watching single molecules move in response to light. ACS
Nano. 2014;8(12):11913-11916. doi:10.1021/nn506656r
apa: Kundu, P. K., & Klajn, R. (2014). Watching single molecules move in response
to light. ACS Nano. American Chemical Society. https://doi.org/10.1021/nn506656r
chicago: Kundu, Pintu K., and Rafal Klajn. “Watching Single Molecules Move in Response
to Light.” ACS Nano. American Chemical Society, 2014. https://doi.org/10.1021/nn506656r.
ieee: P. K. Kundu and R. Klajn, “Watching single molecules move in response to light,”
ACS Nano, vol. 8, no. 12. American Chemical Society, pp. 11913–11916, 2014.
ista: Kundu PK, Klajn R. 2014. Watching single molecules move in response to light.
ACS Nano. 8(12), 11913–11916.
mla: Kundu, Pintu K., and Rafal Klajn. “Watching Single Molecules Move in Response
to Light.” ACS Nano, vol. 8, no. 12, American Chemical Society, 2014, pp.
11913–16, doi:10.1021/nn506656r.
short: P.K. Kundu, R. Klajn, ACS Nano 8 (2014) 11913–11916.
date_created: 2023-08-01T09:45:42Z
date_published: 2014-12-23T00:00:00Z
date_updated: 2023-08-08T07:18:58Z
day: '23'
doi: 10.1021/nn506656r
extern: '1'
external_id:
pmid:
- '25474733'
intvolume: ' 8'
issue: '12'
keyword:
- General Physics and Astronomy
- General Engineering
- General Materials Science
language:
- iso: eng
month: '12'
oa_version: None
page: 11913-11916
pmid: 1
publication: ACS Nano
publication_identifier:
eissn:
- 1936-086X
issn:
- 1936-0851
publication_status: published
publisher: American Chemical Society
quality_controlled: '1'
scopus_import: '1'
status: public
title: Watching single molecules move in response to light
type: journal_article
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
volume: 8
year: '2014'
...