---
_id: '7672'
abstract:
- lang: eng
text: Large overpotentials upon discharge and charge of Li-O2 cells have motivated
extensive research into heterogeneous solid electrocatalysts or non-carbon electrodes
with the aim to improve rate capability, round-trip efficiency and cycle life.
These features are equally governed by parasitic reactions, which are now recognized
to be caused by the highly reactive singlet oxygen (1O2). However, the link between
the presence of electrocatalysts and 1O2 formation in metal-O2 cells is unknown.
Here, we show that, compared to pristine carbon black electrodes, a representative
selection of electrocatalysts or non-carbon electrodes (noble metal, transition
metal compounds) may both slightly reduce or severely increase the 1O2 formation.
The individual reaction steps, where the surfaces impact the 1O2 yield are deciphered,
showing that 1O2 yield from superoxide disproportionation as well as the decomposition
of trace H2O2 are sensitive to catalysts. Transition metal compounds in general
are prone to increase 1O2.
acknowledgement: S.A.F. thanks the International Society of Electrochemistry for awarding
the Tajima Prize 2019 “in recognition of outstanding re- searches on Li-Air batteries
by the use of a range of in-situ elec- trochemical methods to achieve comprehensive
understanding of the reactions taking place at the oxygen electrode”. This article
is dedicated to the special issue of Electrochmica Acta associated with the awarding
conference. S.A.F. is indebted to and the Austrian Federal Ministry of Science,
Research and Economy and the Austrian Research Promotion Agency (grant No. 845364
) and the European Research Council (ERC) under the European Union’s Horizon 2020
research and innovation programme (grant agreement No 636069). The authors thank
J. Schlegl for manufacturing instrumentation, M. Winkler of Acib GmbH and G. Strohmeier
for help with HPLC measurements, S. Eder for cyclic voltammetry measurements, and
C. Slugovc for discussions and continuous support. We thank S. Borisov for access
and advice with fluorescence measurements. We thank EL-Cell GmbH, Hamburg, Germany
for providing the PAT-Cell-Press electrochemical cell.
article_number: '137175'
article_processing_charge: Yes (via OA deal)
article_type: original
author:
- first_name: Aleksej
full_name: Samojlov, Aleksej
last_name: Samojlov
- first_name: David
full_name: Schuster, David
last_name: Schuster
- first_name: Jürgen
full_name: Kahr, Jürgen
last_name: Kahr
- first_name: Stefan Alexander
full_name: Freunberger, Stefan Alexander
id: A8CA28E6-CE23-11E9-AD2D-EC27E6697425
last_name: Freunberger
orcid: 0000-0003-2902-5319
citation:
ama: Samojlov A, Schuster D, Kahr J, Freunberger SA. Surface and catalyst driven
singlet oxygen formation in Li-O2 cells. Electrochimica Acta. 2020;362(12).
doi:10.1016/j.electacta.2020.137175
apa: Samojlov, A., Schuster, D., Kahr, J., & Freunberger, S. A. (2020). Surface
and catalyst driven singlet oxygen formation in Li-O2 cells. Electrochimica
Acta. Elsevier. https://doi.org/10.1016/j.electacta.2020.137175
chicago: Samojlov, Aleksej, David Schuster, Jürgen Kahr, and Stefan Alexander Freunberger.
“Surface and Catalyst Driven Singlet Oxygen Formation in Li-O2 Cells.” Electrochimica
Acta. Elsevier, 2020. https://doi.org/10.1016/j.electacta.2020.137175.
ieee: A. Samojlov, D. Schuster, J. Kahr, and S. A. Freunberger, “Surface and catalyst
driven singlet oxygen formation in Li-O2 cells,” Electrochimica Acta, vol.
362, no. 12. Elsevier, 2020.
ista: Samojlov A, Schuster D, Kahr J, Freunberger SA. 2020. Surface and catalyst
driven singlet oxygen formation in Li-O2 cells. Electrochimica Acta. 362(12),
137175.
mla: Samojlov, Aleksej, et al. “Surface and Catalyst Driven Singlet Oxygen Formation
in Li-O2 Cells.” Electrochimica Acta, vol. 362, no. 12, 137175, Elsevier,
2020, doi:10.1016/j.electacta.2020.137175.
short: A. Samojlov, D. Schuster, J. Kahr, S.A. Freunberger, Electrochimica Acta
362 (2020).
date_created: 2020-04-20T19:29:31Z
date_published: 2020-12-01T00:00:00Z
date_updated: 2023-08-21T06:14:21Z
day: '01'
ddc:
- '540'
department:
- _id: StFr
doi: 10.1016/j.electacta.2020.137175
external_id:
isi:
- '000582869700060'
file:
- access_level: open_access
checksum: 1ab1aa2024d431e2a089ea336bc08298
content_type: application/pdf
creator: dernst
date_created: 2020-10-01T13:20:45Z
date_updated: 2020-10-01T13:20:45Z
file_id: '8593'
file_name: 2020_ElectrochimicaActa_Samojlov.pdf
file_size: 1404030
relation: main_file
success: 1
file_date_updated: 2020-10-01T13:20:45Z
has_accepted_license: '1'
intvolume: ' 362'
isi: 1
issue: '12'
language:
- iso: eng
month: '12'
oa: 1
oa_version: Published Version
publication: Electrochimica Acta
publication_status: published
publisher: Elsevier
quality_controlled: '1'
scopus_import: '1'
status: public
title: Surface and catalyst driven singlet oxygen formation in Li-O2 cells
tmp:
image: /images/cc_by_nc_nd.png
legal_code_url: https://creativecommons.org/licenses/by-nc-nd/4.0/legalcode
name: Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International
(CC BY-NC-ND 4.0)
short: CC BY-NC-ND (4.0)
type: journal_article
user_id: 4359f0d1-fa6c-11eb-b949-802e58b17ae8
volume: 362
year: '2020'
...
---
_id: '7847'
abstract:
- lang: eng
text: 'Water-in-salt electrolytes based on highly concentrated bis(trifluoromethyl)sulfonimide
(TFSI) promise aqueous electrolytes with stabilities nearing 3 V. However, especially
with an electrode approaching the cathodic (reductive) stability, cycling stability
is insufficient. While stability critically relies on a solid electrolyte interphase
(SEI), the mechanism behind the cathodic stability limit remains unclear. Here,
we reveal two distinct reduction potentials for the chemical environments of ''free''
and ''bound'' water and that both contribute to SEI formation. Free-water is reduced
~1V above bound water in a hydrogen evolution reaction (HER) and responsible for
SEI formation via reactive intermediates of the HER; concurrent LiTFSI precipitation/dissolution
establishes a dynamic interface. The free-water population emerges, therefore,
as the handle to extend the cathodic limit of aqueous electrolytes and the battery
cycling stability. '
article_processing_charge: No
article_type: original
author:
- first_name: Roza
full_name: Bouchal, Roza
last_name: Bouchal
- first_name: Zhujie
full_name: Li, Zhujie
last_name: Li
- first_name: Chandra
full_name: Bongu, Chandra
last_name: Bongu
- first_name: Steven
full_name: Le Vot, Steven
last_name: Le Vot
- first_name: Romain
full_name: Berthelot, Romain
last_name: Berthelot
- first_name: Benjamin
full_name: Rotenberg, Benjamin
last_name: Rotenberg
- first_name: Fréderic
full_name: Favier, Fréderic
last_name: Favier
- first_name: Stefan Alexander
full_name: Freunberger, Stefan Alexander
id: A8CA28E6-CE23-11E9-AD2D-EC27E6697425
last_name: Freunberger
orcid: 0000-0003-2902-5319
- first_name: Mathieu
full_name: Salanne, Mathieu
last_name: Salanne
- first_name: Olivier
full_name: Fontaine, Olivier
last_name: Fontaine
citation:
ama: Bouchal R, Li Z, Bongu C, et al. Competitive salt precipitation/dissolution
during free‐water reduction in water‐in‐salt electrolyte. Angewandte Chemie
International Edition. 2020;59(37):15913-1591. doi:10.1002/anie.202005378
apa: Bouchal, R., Li, Z., Bongu, C., Le Vot, S., Berthelot, R., Rotenberg, B., …
Fontaine, O. (2020). Competitive salt precipitation/dissolution during free‐water
reduction in water‐in‐salt electrolyte. Angewandte Chemie International Edition.
Wiley. https://doi.org/10.1002/anie.202005378
chicago: Bouchal, Roza, Zhujie Li, Chandra Bongu, Steven Le Vot, Romain Berthelot,
Benjamin Rotenberg, Fréderic Favier, Stefan Alexander Freunberger, Mathieu Salanne,
and Olivier Fontaine. “Competitive Salt Precipitation/Dissolution during Free‐water
Reduction in Water‐in‐salt Electrolyte.” Angewandte Chemie International Edition.
Wiley, 2020. https://doi.org/10.1002/anie.202005378.
ieee: R. Bouchal et al., “Competitive salt precipitation/dissolution during
free‐water reduction in water‐in‐salt electrolyte,” Angewandte Chemie International
Edition, vol. 59, no. 37. Wiley, pp. 15913–1591, 2020.
ista: Bouchal R, Li Z, Bongu C, Le Vot S, Berthelot R, Rotenberg B, Favier F, Freunberger
SA, Salanne M, Fontaine O. 2020. Competitive salt precipitation/dissolution during
free‐water reduction in water‐in‐salt electrolyte. Angewandte Chemie International
Edition. 59(37), 15913–1591.
mla: Bouchal, Roza, et al. “Competitive Salt Precipitation/Dissolution during Free‐water
Reduction in Water‐in‐salt Electrolyte.” Angewandte Chemie International Edition,
vol. 59, no. 37, Wiley, 2020, pp. 15913–1591, doi:10.1002/anie.202005378.
short: R. Bouchal, Z. Li, C. Bongu, S. Le Vot, R. Berthelot, B. Rotenberg, F. Favier,
S.A. Freunberger, M. Salanne, O. Fontaine, Angewandte Chemie International Edition
59 (2020) 15913–1591.
date_created: 2020-05-14T21:00:30Z
date_published: 2020-09-07T00:00:00Z
date_updated: 2023-09-05T16:02:53Z
day: '07'
ddc:
- '540'
- '546'
department:
- _id: StFr
doi: 10.1002/anie.202005378
external_id:
isi:
- '000541488700001'
pmid:
- '32390281'
file:
- access_level: open_access
checksum: 7b6c2fc20e9b0ff4353352f7a7004e2d
content_type: application/pdf
creator: dernst
date_created: 2020-09-17T08:57:16Z
date_updated: 2020-09-17T08:57:16Z
file_id: '8400'
file_name: 2020_AngChemieINT_Buchal.pdf
file_size: 1966184
relation: main_file
success: 1
file_date_updated: 2020-09-17T08:57:16Z
has_accepted_license: '1'
intvolume: ' 59'
isi: 1
issue: '37'
language:
- iso: eng
month: '09'
oa: 1
oa_version: Published Version
page: 15913-1591
pmid: 1
publication: Angewandte Chemie International Edition
publication_identifier:
eissn:
- 1521-3773
issn:
- 1433-7851
publication_status: published
publisher: Wiley
quality_controlled: '1'
scopus_import: '1'
status: public
title: Competitive salt precipitation/dissolution during free‐water reduction in water‐in‐salt
electrolyte
tmp:
image: /images/cc_by.png
legal_code_url: https://creativecommons.org/licenses/by/4.0/legalcode
name: Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)
short: CC BY (4.0)
type: journal_article
user_id: c635000d-4b10-11ee-a964-aac5a93f6ac1
volume: 59
year: '2020'
...
---
_id: '7985'
abstract:
- lang: eng
text: The goal of limiting global warming to 1.5 °C requires a drastic reduction
in CO2 emissions across many sectors of the world economy. Batteries are vital
to this endeavor, whether used in electric vehicles, to store renewable electricity,
or in aviation. Present lithium-ion technologies are preparing the public for
this inevitable change, but their maximum theoretical specific capacity presents
a limitation. Their high cost is another concern for commercial viability. Metal–air
batteries have the highest theoretical energy density of all possible secondary
battery technologies and could yield step changes in energy storage, if their
practical difficulties could be overcome. The scope of this review is to provide
an objective, comprehensive, and authoritative assessment of the intensive work
invested in nonaqueous rechargeable metal–air batteries over the past few years,
which identified the key problems and guides directions to solve them. We focus
primarily on the challenges and outlook for Li–O2 cells but include Na–O2, K–O2,
and Mg–O2 cells for comparison. Our review highlights the interdisciplinary nature
of this field that involves a combination of materials chemistry, electrochemistry,
computation, microscopy, spectroscopy, and surface science. The mechanisms of
O2 reduction and evolution are considered in the light of recent findings, along
with developments in positive and negative electrodes, electrolytes, electrocatalysis
on surfaces and in solution, and the degradative effect of singlet oxygen, which
is typically formed in Li–O2 cells.
acknowledgement: "S.A.F. is indebted to the European Research Council (ERC) under
the European Union’s\r\nHorizon 2020 research and innovation programme (grant agreement
No 636069)."
article_processing_charge: No
article_type: review
author:
- first_name: WJ
full_name: Kwak, WJ
last_name: Kwak
- first_name: D
full_name: Sharon, D
last_name: Sharon
- first_name: C
full_name: Xia, C
last_name: Xia
- first_name: H
full_name: Kim, H
last_name: Kim
- first_name: LR
full_name: Johnson, LR
last_name: Johnson
- first_name: PG
full_name: Bruce, PG
last_name: Bruce
- first_name: LF
full_name: Nazar, LF
last_name: Nazar
- first_name: YK
full_name: Sun, YK
last_name: Sun
- first_name: AA
full_name: Frimer, AA
last_name: Frimer
- first_name: M
full_name: Noked, M
last_name: Noked
- first_name: Stefan Alexander
full_name: Freunberger, Stefan Alexander
id: A8CA28E6-CE23-11E9-AD2D-EC27E6697425
last_name: Freunberger
orcid: 0000-0003-2902-5319
- first_name: D
full_name: Aurbach, D
last_name: Aurbach
citation:
ama: 'Kwak W, Sharon D, Xia C, et al. Lithium-oxygen batteries and related systems:
Potential, status, and future. Chemical Reviews. 2020;120(14):6626-6683.
doi:10.1021/acs.chemrev.9b00609'
apa: 'Kwak, W., Sharon, D., Xia, C., Kim, H., Johnson, L., Bruce, P., … Aurbach,
D. (2020). Lithium-oxygen batteries and related systems: Potential, status, and
future. Chemical Reviews. American Chemical Society. https://doi.org/10.1021/acs.chemrev.9b00609'
chicago: 'Kwak, WJ, D Sharon, C Xia, H Kim, LR Johnson, PG Bruce, LF Nazar, et al.
“Lithium-Oxygen Batteries and Related Systems: Potential, Status, and Future.”
Chemical Reviews. American Chemical Society, 2020. https://doi.org/10.1021/acs.chemrev.9b00609.'
ieee: 'W. Kwak et al., “Lithium-oxygen batteries and related systems: Potential,
status, and future,” Chemical Reviews, vol. 120, no. 14. American Chemical
Society, pp. 6626–6683, 2020.'
ista: 'Kwak W, Sharon D, Xia C, Kim H, Johnson L, Bruce P, Nazar L, Sun Y, Frimer
A, Noked M, Freunberger SA, Aurbach D. 2020. Lithium-oxygen batteries and related
systems: Potential, status, and future. Chemical Reviews. 120(14), 6626–6683.'
mla: 'Kwak, WJ, et al. “Lithium-Oxygen Batteries and Related Systems: Potential,
Status, and Future.” Chemical Reviews, vol. 120, no. 14, American Chemical
Society, 2020, pp. 6626–83, doi:10.1021/acs.chemrev.9b00609.'
short: W. Kwak, D. Sharon, C. Xia, H. Kim, L. Johnson, P. Bruce, L. Nazar, Y. Sun,
A. Frimer, M. Noked, S.A. Freunberger, D. Aurbach, Chemical Reviews 120 (2020)
6626–6683.
date_created: 2020-06-19T08:42:47Z
date_published: 2020-03-05T00:00:00Z
date_updated: 2023-09-05T12:04:28Z
day: '05'
ddc:
- '540'
department:
- _id: StFr
doi: 10.1021/acs.chemrev.9b00609
external_id:
isi:
- '000555413600008'
pmid:
- '32134255'
file:
- access_level: open_access
checksum: 1a683353d46c5841c8bb2ee0a56ac7be
content_type: application/pdf
creator: sfreunbe
date_created: 2020-06-29T16:36:01Z
date_updated: 2020-07-14T12:48:06Z
file_id: '8060'
file_name: ChemRev_final.pdf
file_size: 8525678
relation: main_file
file_date_updated: 2020-07-14T12:48:06Z
has_accepted_license: '1'
intvolume: ' 120'
isi: 1
issue: '14'
language:
- iso: eng
month: '03'
oa: 1
oa_version: Submitted Version
page: 6626-6683
pmid: 1
publication: Chemical Reviews
publication_identifier:
eissn:
- 1520-6890
issn:
- 0009-2665
publication_status: published
publisher: American Chemical Society
quality_controlled: '1'
scopus_import: '1'
status: public
title: 'Lithium-oxygen batteries and related systems: Potential, status, and future'
type: journal_article
user_id: c635000d-4b10-11ee-a964-aac5a93f6ac1
volume: 120
year: '2020'
...
---
_id: '8057'
abstract:
- lang: eng
text: Water-in-salt electrolytes based on highly concentrated bis(trifluoromethyl)sulfonimide
(TFSI) promise aqueous electrolytes with stabilities approaching 3 V. However,
especially with an electrode approaching the cathodic (reductive) stability, cycling
stability is insufficient. While stability critically relies on a solid electrolyte
interphase (SEI), the mechanism behind the cathodic stability limit remains unclear.
Here, we reveal two distinct reduction potentials for the chemical environments
of ‘free’ and ‘bound’ water and that both contribute to SEI formation. Free-water
is reduced ~1V above bound water in a hydrogen evolution reaction (HER) and responsible
for SEI formation via reactive intermediates of the HER; concurrent LiTFSI precipitation/dissolution
establishes a dynamic interface. The free-water population emerges, therefore,
as the handle to extend the cathodic limit of aqueous electrolytes and the battery
cycling stability.
article_processing_charge: No
article_type: original
author:
- first_name: Roza
full_name: Bouchal, Roza
last_name: Bouchal
- first_name: Zhujie
full_name: Li, Zhujie
last_name: Li
- first_name: Chandra
full_name: Bongu, Chandra
last_name: Bongu
- first_name: Steven
full_name: Le Vot, Steven
last_name: Le Vot
- first_name: Romain
full_name: Berthelot, Romain
last_name: Berthelot
- first_name: Benjamin
full_name: Rotenberg, Benjamin
last_name: Rotenberg
- first_name: Frederic
full_name: Favier, Frederic
last_name: Favier
- first_name: Stefan Alexander
full_name: Freunberger, Stefan Alexander
id: A8CA28E6-CE23-11E9-AD2D-EC27E6697425
last_name: Freunberger
orcid: 0000-0003-2902-5319
- first_name: Mathieu
full_name: Salanne, Mathieu
last_name: Salanne
- first_name: Olivier
full_name: Fontaine, Olivier
last_name: Fontaine
citation:
ama: Bouchal R, Li Z, Bongu C, et al. Competitive salt precipitation/dissolution
during free‐water reduction in water‐in‐salt electrolyte. Angewandte Chemie.
2020;132(37):16047-16051. doi:10.1002/ange.202005378
apa: Bouchal, R., Li, Z., Bongu, C., Le Vot, S., Berthelot, R., Rotenberg, B., …
Fontaine, O. (2020). Competitive salt precipitation/dissolution during free‐water
reduction in water‐in‐salt electrolyte. Angewandte Chemie. Wiley. https://doi.org/10.1002/ange.202005378
chicago: Bouchal, Roza, Zhujie Li, Chandra Bongu, Steven Le Vot, Romain Berthelot,
Benjamin Rotenberg, Frederic Favier, Stefan Alexander Freunberger, Mathieu Salanne,
and Olivier Fontaine. “Competitive Salt Precipitation/Dissolution during Free‐water
Reduction in Water‐in‐salt Electrolyte.” Angewandte Chemie. Wiley, 2020.
https://doi.org/10.1002/ange.202005378.
ieee: R. Bouchal et al., “Competitive salt precipitation/dissolution during
free‐water reduction in water‐in‐salt electrolyte,” Angewandte Chemie,
vol. 132, no. 37. Wiley, pp. 16047–16051, 2020.
ista: Bouchal R, Li Z, Bongu C, Le Vot S, Berthelot R, Rotenberg B, Favier F, Freunberger
SA, Salanne M, Fontaine O. 2020. Competitive salt precipitation/dissolution during
free‐water reduction in water‐in‐salt electrolyte. Angewandte Chemie. 132(37),
16047–16051.
mla: Bouchal, Roza, et al. “Competitive Salt Precipitation/Dissolution during Free‐water
Reduction in Water‐in‐salt Electrolyte.” Angewandte Chemie, vol. 132, no.
37, Wiley, 2020, pp. 16047–51, doi:10.1002/ange.202005378.
short: R. Bouchal, Z. Li, C. Bongu, S. Le Vot, R. Berthelot, B. Rotenberg, F. Favier,
S.A. Freunberger, M. Salanne, O. Fontaine, Angewandte Chemie 132 (2020) 16047–16051.
date_created: 2020-06-29T16:15:49Z
date_published: 2020-09-07T00:00:00Z
date_updated: 2023-09-05T15:47:50Z
day: '07'
ddc:
- '540'
- '541'
department:
- _id: StFr
doi: 10.1002/ange.202005378
file:
- access_level: open_access
checksum: 7dd0a56f6bd5de08ea75b1ec388c91bc
content_type: application/pdf
creator: dernst
date_created: 2020-09-17T08:59:43Z
date_updated: 2020-09-17T08:59:43Z
file_id: '8401'
file_name: 2020_AngChemieDE_Bouchal.pdf
file_size: 1904552
relation: main_file
success: 1
file_date_updated: 2020-09-17T08:59:43Z
has_accepted_license: '1'
intvolume: ' 132'
issue: '37'
language:
- iso: eng
month: '09'
oa: 1
oa_version: Published Version
page: 16047-16051
publication: Angewandte Chemie
publication_identifier:
eissn:
- 1521-3757
issn:
- 0044-8249
publication_status: published
publisher: Wiley
quality_controlled: '1'
scopus_import: '1'
status: public
title: Competitive salt precipitation/dissolution during free‐water reduction in water‐in‐salt
electrolyte
tmp:
image: /images/cc_by.png
legal_code_url: https://creativecommons.org/licenses/by/4.0/legalcode
name: Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)
short: CC BY (4.0)
type: journal_article
user_id: c635000d-4b10-11ee-a964-aac5a93f6ac1
volume: 132
year: '2020'
...
---
_id: '8067'
abstract:
- lang: eng
text: "With the lithium-ion technology approaching its intrinsic limit with graphite-based
anodes, lithium metal is recently receiving renewed interest from the battery
community as potential high capacity anode for next-generation rechargeable batteries.
In this focus paper, we review the main advances in this field since the first
attempts in the\r\nmid-1970s. Strategies for enabling reversible cycling and avoiding
dendrite growth are thoroughly discussed, including specific applications in all-solid-state
(polymeric and inorganic), Lithium-sulphur and Li-O2 (air) batteries. A particular
attention is paid to review recent developments in regard of prototype manufacturing
and current state-ofthe-art of these battery technologies with respect to the
2030 targets of the EU Integrated Strategic Energy Technology Plan (SET-Plan)
Action 7."
alternative_title:
- IST Austria Technical Report
article_processing_charge: No
author:
- first_name: Alberto
full_name: Varzi, Alberto
last_name: Varzi
- first_name: Katharina
full_name: Thanner, Katharina
last_name: Thanner
- first_name: Roberto
full_name: Scipioni, Roberto
last_name: Scipioni
- first_name: Daniele
full_name: Di Lecce, Daniele
last_name: Di Lecce
- first_name: Jusef
full_name: Hassoun, Jusef
last_name: Hassoun
- first_name: Susanne
full_name: Dörfler, Susanne
last_name: Dörfler
- first_name: Holger
full_name: Altheus, Holger
last_name: Altheus
- first_name: Stefan
full_name: Kaskel, Stefan
last_name: Kaskel
- first_name: Christian
full_name: Prehal, Christian
last_name: Prehal
- first_name: Stefan Alexander
full_name: Freunberger, Stefan Alexander
id: A8CA28E6-CE23-11E9-AD2D-EC27E6697425
last_name: Freunberger
orcid: 0000-0003-2902-5319
citation:
ama: Varzi A, Thanner K, Scipioni R, et al. Current Status and Future Perspectives
of Lithium Metal Batteries. IST Austria doi:10.15479/AT:ISTA:8067
apa: Varzi, A., Thanner, K., Scipioni, R., Di Lecce, D., Hassoun, J., Dörfler, S.,
… Freunberger, S. A. (n.d.). Current status and future perspectives of Lithium
metal batteries. IST Austria. https://doi.org/10.15479/AT:ISTA:8067
chicago: Varzi, Alberto, Katharina Thanner, Roberto Scipioni, Daniele Di Lecce,
Jusef Hassoun, Susanne Dörfler, Holger Altheus, Stefan Kaskel, Christian Prehal,
and Stefan Alexander Freunberger. Current Status and Future Perspectives of
Lithium Metal Batteries. IST Austria, n.d. https://doi.org/10.15479/AT:ISTA:8067.
ieee: A. Varzi et al., Current status and future perspectives of Lithium
metal batteries. IST Austria.
ista: Varzi A, Thanner K, Scipioni R, Di Lecce D, Hassoun J, Dörfler S, Altheus
H, Kaskel S, Prehal C, Freunberger SA. Current status and future perspectives
of Lithium metal batteries, IST Austria, 63p.
mla: Varzi, Alberto, et al. Current Status and Future Perspectives of Lithium
Metal Batteries. IST Austria, doi:10.15479/AT:ISTA:8067.
short: A. Varzi, K. Thanner, R. Scipioni, D. Di Lecce, J. Hassoun, S. Dörfler, H.
Altheus, S. Kaskel, C. Prehal, S.A. Freunberger, Current Status and Future Perspectives
of Lithium Metal Batteries, IST Austria, n.d.
date_created: 2020-06-30T07:37:39Z
date_published: 2020-07-01T00:00:00Z
date_updated: 2023-08-22T09:20:36Z
day: '01'
ddc:
- '540'
department:
- _id: StFr
doi: 10.15479/AT:ISTA:8067
file:
- access_level: open_access
checksum: d183ca1465a1cbb4f8db27875cd156f7
content_type: application/pdf
creator: dernst
date_created: 2020-07-02T07:36:04Z
date_updated: 2020-07-14T12:48:08Z
file_id: '8076'
file_name: 20200612_JPS_review_Li_metal_submitted.pdf
file_size: 2612498
relation: main_file
file_date_updated: 2020-07-14T12:48:08Z
has_accepted_license: '1'
keyword:
- Battery
- Lithium metal
- Lithium-sulphur
- Lithium-air
- All-solid-state
language:
- iso: eng
month: '07'
oa: 1
oa_version: Published Version
page: '63'
publication_identifier:
issn:
- 2664-1690
publication_status: submitted
publisher: IST Austria
related_material:
record:
- id: '8361'
relation: later_version
status: public
status: public
title: Current status and future perspectives of Lithium metal batteries
type: technical_report
user_id: 8b945eb4-e2f2-11eb-945a-df72226e66a9
year: '2020'
...
---
_id: '8081'
abstract:
- lang: eng
text: "Here, we employ micro- and nanosized cellulose particles, namely paper fines
and cellulose\r\nnanocrystals, to induce hierarchical organization over a wide
length scale. After processing\r\nthem into carbonaceous materials, we demonstrate
that these hierarchically organized materials\r\noutperform the best materials
for supercapacitors operating with organic electrolytes reported\r\nin literature
in terms of specific energy/power (Ragone plot) while showing hardly any capacity\r\nfade
over 4,000 cycles. The highly porous materials feature a specific surface area
as high as\r\n2500 m2ˑg-1 and exhibit pore sizes in the range of 0.5 to 200 nm
as proven by scanning electron\r\nmicroscopy and N2 physisorption. The carbonaceous
materials have been further investigated\r\nby X-ray photoelectron spectroscopy
and RAMAN spectroscopy. Since paper fines are an\r\nunderutilized side stream
in any paper production process, they are a cheap and highly available\r\nfeedstock
to prepare carbonaceous materials with outstanding performance in electrochemical\r\napplications. "
acknowledgement: 'The authors M.A.H., S.S., R.E., and W.B. acknowledge the industrial
partners Sappi Gratkorn, Zellstoff Pöls and Mondi Frantschach, the Austrian Research
Promotion Agency (FFG), COMET, BMVIT, BMWFJ, the Province of Styria and Carinthia
for their financial support of the K-project Flippr²-Process Integration. E.M. and
S.A.F. are indebted to the European Research Council (ERC) under the European Union’s
Horizon 2020 research and innovation program (grant agreement No 636069). W. T.
and S. E. thank FWO (G.0C60.13N) and the European Union’s European Fund for Regional
Development and Flanders Innovation & Entrepreneurship (Accelerate3 project, Interreg
Vlaanderen-Nederland program) for financial support. W. T. also thanks the Provincie
West-Vlaanderen (Belgium) for his Provincial Chair in Advanced Materials. S. B.
thanks the European Regional Development Fund (EFRE) and the province of Upper Austria
for financial support through the program IWB 2014-2020 (project BioCarb-K). AMR
gratefully acknowledges funding support through the SC EPSCoR/IDeAProgram under
Award #18-SR03, and the NASA EPSCoR Program under Award #NNH17ZHA002C. Icons in
Scheme 1 were provided by Good Ware, monkik, photo3idea_studio, and OCHA from www.flaticon.com.'
article_processing_charge: No
author:
- first_name: 'Mathias A. '
full_name: 'Hobisch, Mathias A. '
last_name: Hobisch
- first_name: 'Eléonore '
full_name: 'Mourad, Eléonore '
last_name: Mourad
- first_name: 'Wolfgang J. '
full_name: 'Fischer, Wolfgang J. '
last_name: Fischer
- first_name: 'Christian '
full_name: 'Prehal, Christian '
last_name: Prehal
- first_name: 'Samuel '
full_name: 'Eyley, Samuel '
last_name: Eyley
- first_name: 'Anthony '
full_name: 'Childress, Anthony '
last_name: Childress
- first_name: 'Armin '
full_name: 'Zankel, Armin '
last_name: Zankel
- first_name: 'Andreas '
full_name: 'Mautner, Andreas '
last_name: Mautner
- first_name: 'Stefan '
full_name: 'Breitenbach, Stefan '
last_name: Breitenbach
- first_name: 'Apparao M. '
full_name: 'Rao, Apparao M. '
last_name: Rao
- first_name: 'Wim '
full_name: 'Thielemans, Wim '
last_name: Thielemans
- first_name: Stefan Alexander
full_name: Freunberger, Stefan Alexander
id: A8CA28E6-CE23-11E9-AD2D-EC27E6697425
last_name: Freunberger
orcid: 0000-0003-2902-5319
- first_name: 'Rene '
full_name: 'Eckhart, Rene '
last_name: Eckhart
- first_name: 'Wolfgang '
full_name: 'Bauer, Wolfgang '
last_name: Bauer
- first_name: 'Stefan '
full_name: 'Spirk, Stefan '
last_name: Spirk
citation:
ama: Hobisch MA, Mourad E, Fischer WJ, et al. High specific capacitance supercapacitors
from hierarchically organized all-cellulose composites.
apa: Hobisch, M. A., Mourad, E., Fischer, W. J., Prehal, C., Eyley, S., Childress,
A., … Spirk, S. (n.d.). High specific capacitance supercapacitors from hierarchically
organized all-cellulose composites.
chicago: Hobisch, Mathias A. , Eléonore Mourad, Wolfgang J. Fischer, Christian Prehal,
Samuel Eyley, Anthony Childress, Armin Zankel, et al. “High Specific Capacitance
Supercapacitors from Hierarchically Organized All-Cellulose Composites,” n.d.
ieee: M. A. Hobisch et al., “High specific capacitance supercapacitors from
hierarchically organized all-cellulose composites.” .
ista: Hobisch MA, Mourad E, Fischer WJ, Prehal C, Eyley S, Childress A, Zankel A,
Mautner A, Breitenbach S, Rao AM, Thielemans W, Freunberger SA, Eckhart R, Bauer
W, Spirk S. High specific capacitance supercapacitors from hierarchically organized
all-cellulose composites.
mla: Hobisch, Mathias A., et al. High Specific Capacitance Supercapacitors from
Hierarchically Organized All-Cellulose Composites.
short: M.A. Hobisch, E. Mourad, W.J. Fischer, C. Prehal, S. Eyley, A. Childress,
A. Zankel, A. Mautner, S. Breitenbach, A.M. Rao, W. Thielemans, S.A. Freunberger,
R. Eckhart, W. Bauer, S. Spirk, (n.d.).
date_created: 2020-07-02T20:24:42Z
date_published: 2020-07-13T00:00:00Z
date_updated: 2022-06-17T08:39:49Z
day: '13'
ddc:
- '540'
department:
- _id: StFr
file:
- access_level: open_access
checksum: 6970d621984c03ebc2eee71adfe706dd
content_type: application/pdf
creator: sfreunbe
date_created: 2020-07-02T20:21:59Z
date_updated: 2020-07-14T12:48:09Z
file_id: '8082'
file_name: AM.pdf
file_size: 1129852
relation: main_file
- access_level: open_access
checksum: cd74c7bd47d6e7163d54d67f074dcc36
content_type: application/pdf
creator: cziletti
date_created: 2020-07-08T12:14:04Z
date_updated: 2020-07-14T12:48:09Z
file_id: '8102'
file_name: Supporting_Information.pdf
file_size: 945565
relation: supplementary_material
file_date_updated: 2020-07-14T12:48:09Z
has_accepted_license: '1'
language:
- iso: eng
month: '07'
oa: 1
oa_version: Submitted Version
publication_status: submitted
status: public
title: High specific capacitance supercapacitors from hierarchically organized all-cellulose
composites
type: preprint
user_id: 2DF688A6-F248-11E8-B48F-1D18A9856A87
year: '2020'
...
---
_id: '9780'
abstract:
- lang: eng
text: "PADREV : 4,4'-dimethoxy[1,1'-biphenyl]-2,2',5,5'-tetrol\r\nSpace Group: C
2 (5), Cell: a 24.488(16)Å b 5.981(4)Å c 3.911(3)Å, α 90° β 91.47(3)° γ 90°"
article_processing_charge: No
author:
- first_name: Werner
full_name: Schlemmer, Werner
last_name: Schlemmer
- first_name: Philipp
full_name: Nothdurft, Philipp
last_name: Nothdurft
- first_name: Alina
full_name: Petzold, Alina
last_name: Petzold
- first_name: Gisbert
full_name: Riess, Gisbert
last_name: Riess
- first_name: Philipp
full_name: Frühwirt, Philipp
last_name: Frühwirt
- first_name: Max
full_name: Schmallegger, Max
last_name: Schmallegger
- first_name: Georg
full_name: Gescheidt-Demner, Georg
last_name: Gescheidt-Demner
- first_name: Roland
full_name: Fischer, Roland
last_name: Fischer
- first_name: Stefan Alexander
full_name: Freunberger, Stefan Alexander
id: A8CA28E6-CE23-11E9-AD2D-EC27E6697425
last_name: Freunberger
orcid: 0000-0003-2902-5319
- first_name: Wolfgang
full_name: Kern, Wolfgang
last_name: Kern
- first_name: Stefan
full_name: Spirk, Stefan
last_name: Spirk
citation:
ama: 'Schlemmer W, Nothdurft P, Petzold A, et al. CCDC 1991959: Experimental Crystal
Structure Determination. 2020. doi:10.5517/ccdc.csd.cc24vsrk'
apa: 'Schlemmer, W., Nothdurft, P., Petzold, A., Riess, G., Frühwirt, P., Schmallegger,
M., … Spirk, S. (2020). CCDC 1991959: Experimental Crystal Structure Determination.
CCDC. https://doi.org/10.5517/ccdc.csd.cc24vsrk'
chicago: 'Schlemmer, Werner, Philipp Nothdurft, Alina Petzold, Gisbert Riess, Philipp
Frühwirt, Max Schmallegger, Georg Gescheidt-Demner, et al. “CCDC 1991959: Experimental
Crystal Structure Determination.” CCDC, 2020. https://doi.org/10.5517/ccdc.csd.cc24vsrk.'
ieee: 'W. Schlemmer et al., “CCDC 1991959: Experimental Crystal Structure
Determination.” CCDC, 2020.'
ista: 'Schlemmer W, Nothdurft P, Petzold A, Riess G, Frühwirt P, Schmallegger M,
Gescheidt-Demner G, Fischer R, Freunberger SA, Kern W, Spirk S. 2020. CCDC 1991959:
Experimental Crystal Structure Determination, CCDC, 10.5517/ccdc.csd.cc24vsrk.'
mla: 'Schlemmer, Werner, et al. CCDC 1991959: Experimental Crystal Structure
Determination. CCDC, 2020, doi:10.5517/ccdc.csd.cc24vsrk.'
short: W. Schlemmer, P. Nothdurft, A. Petzold, G. Riess, P. Frühwirt, M. Schmallegger,
G. Gescheidt-Demner, R. Fischer, S.A. Freunberger, W. Kern, S. Spirk, (2020).
date_created: 2021-08-06T07:41:07Z
date_published: 2020-03-22T00:00:00Z
date_updated: 2023-09-05T16:03:47Z
day: '22'
department:
- _id: StFr
doi: 10.5517/ccdc.csd.cc24vsrk
main_file_link:
- open_access: '1'
url: https://dx.doi.org/10.5517/ccdc.csd.cc24vsrk
month: '03'
oa: 1
oa_version: Published Version
publisher: CCDC
related_material:
record:
- id: '8329'
relation: used_in_publication
status: public
status: public
title: 'CCDC 1991959: Experimental Crystal Structure Determination'
type: research_data_reference
user_id: 6785fbc1-c503-11eb-8a32-93094b40e1cf
year: '2020'
...