[{"type":"technical_report","date_published":"2020-07-01T00:00:00Z","oa":1,"publication_identifier":{"issn":["2664-1690"]},"status":"public","user_id":"8b945eb4-e2f2-11eb-945a-df72226e66a9","related_material":{"record":[{"id":"8361","relation":"later_version","status":"public"}]},"file":[{"file_size":2612498,"checksum":"d183ca1465a1cbb4f8db27875cd156f7","date_created":"2020-07-02T07:36:04Z","content_type":"application/pdf","file_name":"20200612_JPS_review_Li_metal_submitted.pdf","date_updated":"2020-07-14T12:48:08Z","relation":"main_file","access_level":"open_access","creator":"dernst","file_id":"8076"}],"has_accepted_license":"1","month":"07","oa_version":"Published Version","keyword":["Battery","Lithium metal","Lithium-sulphur","Lithium-air","All-solid-state"],"language":[{"iso":"eng"}],"citation":{"ista":"Varzi A, Thanner K, Scipioni R, Di Lecce D, Hassoun J, Dörfler S, Altheus H, Kaskel S, Prehal C, Freunberger SA. Current status and future perspectives of Lithium metal batteries, IST Austria, 63p.","short":"A. Varzi, K. Thanner, R. Scipioni, D. Di Lecce, J. Hassoun, S. Dörfler, H. Altheus, S. Kaskel, C. Prehal, S.A. Freunberger, Current Status and Future Perspectives of Lithium Metal Batteries, IST Austria, n.d.","mla":"Varzi, Alberto, et al. <i>Current Status and Future Perspectives of Lithium Metal Batteries</i>. IST Austria, doi:<a href=\"https://doi.org/10.15479/AT:ISTA:8067\">10.15479/AT:ISTA:8067</a>.","chicago":"Varzi, Alberto, Katharina Thanner, Roberto Scipioni, Daniele Di Lecce, Jusef Hassoun, Susanne Dörfler, Holger Altheus, Stefan Kaskel, Christian Prehal, and Stefan Alexander Freunberger. <i>Current Status and Future Perspectives of Lithium Metal Batteries</i>. IST Austria, n.d. <a href=\"https://doi.org/10.15479/AT:ISTA:8067\">https://doi.org/10.15479/AT:ISTA:8067</a>.","ieee":"A. Varzi <i>et al.</i>, <i>Current status and future perspectives of Lithium metal batteries</i>. IST Austria.","apa":"Varzi, A., Thanner, K., Scipioni, R., Di Lecce, D., Hassoun, J., Dörfler, S., … Freunberger, S. A. (n.d.). <i>Current status and future perspectives of Lithium metal batteries</i>. IST Austria. <a href=\"https://doi.org/10.15479/AT:ISTA:8067\">https://doi.org/10.15479/AT:ISTA:8067</a>","ama":"Varzi A, Thanner K, Scipioni R, et al. <i>Current Status and Future Perspectives of Lithium Metal Batteries</i>. IST Austria doi:<a href=\"https://doi.org/10.15479/AT:ISTA:8067\">10.15479/AT:ISTA:8067</a>"},"year":"2020","date_updated":"2023-08-22T09:20:36Z","abstract":[{"lang":"eng","text":"With the lithium-ion technology approaching its intrinsic limit with graphite-based anodes, lithium metal is recently receiving renewed interest from the battery community as potential high capacity anode for next-generation rechargeable batteries. In this focus paper, we review the main advances in this field since the first attempts in the\r\nmid-1970s. Strategies for enabling reversible cycling and avoiding dendrite growth are thoroughly discussed, including specific applications in all-solid-state (polymeric and inorganic), Lithium-sulphur and Li-O2 (air) batteries. A particular attention is paid to review recent developments in regard of prototype manufacturing and current state-ofthe-art of these battery technologies with respect to the 2030 targets of the EU Integrated Strategic Energy Technology Plan (SET-Plan) Action 7."}],"day":"01","doi":"10.15479/AT:ISTA:8067","ddc":["540"],"author":[{"first_name":"Alberto","last_name":"Varzi","full_name":"Varzi, Alberto"},{"full_name":"Thanner, Katharina","first_name":"Katharina","last_name":"Thanner"},{"full_name":"Scipioni, Roberto","last_name":"Scipioni","first_name":"Roberto"},{"full_name":"Di Lecce, Daniele","first_name":"Daniele","last_name":"Di Lecce"},{"first_name":"Jusef","last_name":"Hassoun","full_name":"Hassoun, Jusef"},{"first_name":"Susanne","last_name":"Dörfler","full_name":"Dörfler, Susanne"},{"first_name":"Holger","last_name":"Altheus","full_name":"Altheus, Holger"},{"first_name":"Stefan","last_name":"Kaskel","full_name":"Kaskel, Stefan"},{"full_name":"Prehal, Christian","first_name":"Christian","last_name":"Prehal"},{"last_name":"Freunberger","first_name":"Stefan Alexander","full_name":"Freunberger, Stefan Alexander","orcid":"0000-0003-2902-5319","id":"A8CA28E6-CE23-11E9-AD2D-EC27E6697425"}],"_id":"8067","title":"Current status and future perspectives of Lithium metal batteries","alternative_title":["IST Austria Technical Report"],"article_processing_charge":"No","department":[{"_id":"StFr"}],"date_created":"2020-06-30T07:37:39Z","publication_status":"submitted","file_date_updated":"2020-07-14T12:48:08Z","page":"63","publisher":"IST Austria"},{"title":"High specific capacitance supercapacitors from hierarchically organized all-cellulose composites","month":"07","article_processing_charge":"No","department":[{"_id":"StFr"}],"date_created":"2020-07-02T20:24:42Z","publication_status":"submitted","oa_version":"Submitted Version","author":[{"first_name":"Mathias A. ","last_name":"Hobisch","full_name":"Hobisch, Mathias A. "},{"full_name":"Mourad, Eléonore ","first_name":"Eléonore ","last_name":"Mourad"},{"last_name":"Fischer","first_name":"Wolfgang J. ","full_name":"Fischer, Wolfgang J. "},{"full_name":"Prehal, Christian ","last_name":"Prehal","first_name":"Christian "},{"full_name":"Eyley, Samuel ","last_name":"Eyley","first_name":"Samuel "},{"full_name":"Childress, Anthony ","last_name":"Childress","first_name":"Anthony "},{"last_name":"Zankel","first_name":"Armin ","full_name":"Zankel, Armin "},{"full_name":"Mautner, Andreas ","first_name":"Andreas ","last_name":"Mautner"},{"last_name":"Breitenbach","first_name":"Stefan ","full_name":"Breitenbach, Stefan "},{"full_name":"Rao, Apparao M. ","last_name":"Rao","first_name":"Apparao M. "},{"full_name":"Thielemans, Wim ","last_name":"Thielemans","first_name":"Wim "},{"id":"A8CA28E6-CE23-11E9-AD2D-EC27E6697425","last_name":"Freunberger","first_name":"Stefan Alexander","full_name":"Freunberger, Stefan Alexander","orcid":"0000-0003-2902-5319"},{"full_name":"Eckhart, Rene ","last_name":"Eckhart","first_name":"Rene "},{"full_name":"Bauer, Wolfgang ","last_name":"Bauer","first_name":"Wolfgang "},{"full_name":"Spirk, Stefan ","last_name":"Spirk","first_name":"Stefan "}],"has_accepted_license":"1","_id":"8081","file_date_updated":"2020-07-14T12:48:09Z","language":[{"iso":"eng"}],"oa":1,"abstract":[{"lang":"eng","text":"Here, we employ micro- and nanosized cellulose particles, namely paper fines and cellulose\r\nnanocrystals, to induce hierarchical organization over a wide length scale. After processing\r\nthem into carbonaceous materials, we demonstrate that these hierarchically organized materials\r\noutperform the best materials for supercapacitors operating with organic electrolytes reported\r\nin literature in terms of specific energy/power (Ragone plot) while showing hardly any capacity\r\nfade over 4,000 cycles. The highly porous materials feature a specific surface area as high as\r\n2500 m2ˑg-1 and exhibit pore sizes in the range of 0.5 to 200 nm as proven by scanning electron\r\nmicroscopy and N2 physisorption. The carbonaceous materials have been further investigated\r\nby X-ray photoelectron spectroscopy and RAMAN spectroscopy. Since paper fines are an\r\nunderutilized side stream in any paper production process, they are a cheap and highly available\r\nfeedstock to prepare carbonaceous materials with outstanding performance in electrochemical\r\napplications. "}],"day":"13","type":"preprint","date_published":"2020-07-13T00:00:00Z","year":"2020","citation":{"ista":"Hobisch MA, Mourad E, Fischer WJ, Prehal C, Eyley S, Childress A, Zankel A, Mautner A, Breitenbach S, Rao AM, Thielemans W, Freunberger SA, Eckhart R, Bauer W, Spirk S. High specific capacitance supercapacitors from hierarchically organized all-cellulose composites.","short":"M.A. Hobisch, E. Mourad, W.J. Fischer, C. Prehal, S. Eyley, A. Childress, A. Zankel, A. Mautner, S. Breitenbach, A.M. Rao, W. Thielemans, S.A. Freunberger, R. Eckhart, W. Bauer, S. Spirk, (n.d.).","mla":"Hobisch, Mathias A., et al. <i>High Specific Capacitance Supercapacitors from Hierarchically Organized All-Cellulose Composites</i>.","chicago":"Hobisch, Mathias A. , Eléonore  Mourad, Wolfgang J.  Fischer, Christian  Prehal, Samuel  Eyley, Anthony  Childress, Armin  Zankel, et al. “High Specific Capacitance Supercapacitors from Hierarchically Organized All-Cellulose Composites,” n.d.","ieee":"M. A. Hobisch <i>et al.</i>, “High specific capacitance supercapacitors from hierarchically organized all-cellulose composites.” .","ama":"Hobisch MA, Mourad E, Fischer WJ, et al. High specific capacitance supercapacitors from hierarchically organized all-cellulose composites.","apa":"Hobisch, M. A., Mourad, E., Fischer, W. J., Prehal, C., Eyley, S., Childress, A., … Spirk, S. (n.d.). High specific capacitance supercapacitors from hierarchically organized all-cellulose composites."},"date_updated":"2022-06-17T08:39:49Z","user_id":"2DF688A6-F248-11E8-B48F-1D18A9856A87","ddc":["540"],"status":"public","file":[{"file_id":"8082","creator":"sfreunbe","access_level":"open_access","relation":"main_file","date_updated":"2020-07-14T12:48:09Z","content_type":"application/pdf","file_name":"AM.pdf","date_created":"2020-07-02T20:21:59Z","file_size":1129852,"checksum":"6970d621984c03ebc2eee71adfe706dd"},{"file_name":"Supporting_Information.pdf","content_type":"application/pdf","date_updated":"2020-07-14T12:48:09Z","checksum":"cd74c7bd47d6e7163d54d67f074dcc36","file_size":945565,"date_created":"2020-07-08T12:14:04Z","creator":"cziletti","file_id":"8102","access_level":"open_access","relation":"supplementary_material"}],"acknowledgement":"The authors M.A.H., S.S., R.E., and W.B. acknowledge the industrial partners Sappi Gratkorn, Zellstoff Pöls and Mondi Frantschach, the Austrian Research Promotion Agency (FFG), COMET, BMVIT, BMWFJ, the Province of Styria and Carinthia for their financial support of the K-project Flippr²-Process Integration. E.M. and S.A.F. are indebted to the European Research Council (ERC) under the European Union’s Horizon 2020 research and innovation program (grant agreement No 636069). W. T. and S. E. thank FWO (G.0C60.13N) and the European Union’s European Fund for Regional Development and Flanders Innovation & Entrepreneurship (Accelerate3 project, Interreg Vlaanderen-Nederland program) for financial support. W. T. also thanks the Provincie West-Vlaanderen (Belgium) for his Provincial Chair in Advanced Materials. S. B. thanks the European Regional Development Fund (EFRE) and the province of Upper Austria for financial support through the program IWB 2014-2020 (project BioCarb-K). AMR gratefully acknowledges funding support through the SC EPSCoR/IDeAProgram under Award #18-SR03, and the NASA EPSCoR Program under Award #NNH17ZHA002C. Icons in Scheme 1 were provided by Good Ware, monkik, photo3idea_studio, and OCHA from www.flaticon.com."},{"doi":"10.1002/anie.202008253","day":"14","abstract":[{"text":"We show the synthesis of a redox‐active quinone, 2‐methoxy‐1,4‐hydroquinone (MHQ), from a bio‐based feedstock and its suitability as electrolyte in aqueous redox flow batteries. We identified semiquinone intermediates at insufficiently low pH and quinoid radicals as responsible for decomposition of MHQ under electrochemical conditions. Both can be avoided and/or stabilized, respectively, using H 3 PO 4 electrolyte, allowing for reversible cycling in a redox flow battery for hundreds of cycles.","lang":"eng"}],"date_updated":"2023-09-05T16:03:47Z","citation":{"ista":"Schlemmer W, Nothdurft P, Petzold A, Frühwirt P, Schmallegger M, Gescheidt-Demner G, Fischer R, Freunberger SA, Kern W, Spirk S. 2020. 2‐methoxyhydroquinone from vanillin for aqueous redox‐flow batteries. Angewandte Chemie International Edition. 59(51), 22943–22946.","short":"W. Schlemmer, P. Nothdurft, A. Petzold, P. Frühwirt, M. Schmallegger, G. Gescheidt-Demner, R. Fischer, S.A. Freunberger, W. Kern, S. Spirk, Angewandte Chemie International Edition 59 (2020) 22943–22946.","mla":"Schlemmer, Werner, et al. “2‐methoxyhydroquinone from Vanillin for Aqueous Redox‐flow Batteries.” <i>Angewandte Chemie International Edition</i>, vol. 59, no. 51, Wiley, 2020, pp. 22943–46, doi:<a href=\"https://doi.org/10.1002/anie.202008253\">10.1002/anie.202008253</a>.","ieee":"W. Schlemmer <i>et al.</i>, “2‐methoxyhydroquinone from vanillin for aqueous redox‐flow batteries,” <i>Angewandte Chemie International Edition</i>, vol. 59, no. 51. Wiley, pp. 22943–22946, 2020.","chicago":"Schlemmer, Werner, Philipp Nothdurft, Alina Petzold, Philipp Frühwirt, Max Schmallegger, Georg Gescheidt-Demner, Roland Fischer, Stefan Alexander Freunberger, Wolfgang Kern, and Stefan Spirk. “2‐methoxyhydroquinone from Vanillin for Aqueous Redox‐flow Batteries.” <i>Angewandte Chemie International Edition</i>. Wiley, 2020. <a href=\"https://doi.org/10.1002/anie.202008253\">https://doi.org/10.1002/anie.202008253</a>.","apa":"Schlemmer, W., Nothdurft, P., Petzold, A., Frühwirt, P., Schmallegger, M., Gescheidt-Demner, G., … Spirk, S. (2020). 2‐methoxyhydroquinone from vanillin for aqueous redox‐flow batteries. <i>Angewandte Chemie International Edition</i>. Wiley. <a href=\"https://doi.org/10.1002/anie.202008253\">https://doi.org/10.1002/anie.202008253</a>","ama":"Schlemmer W, Nothdurft P, Petzold A, et al. 2‐methoxyhydroquinone from vanillin for aqueous redox‐flow batteries. <i>Angewandte Chemie International Edition</i>. 2020;59(51):22943-22946. doi:<a href=\"https://doi.org/10.1002/anie.202008253\">10.1002/anie.202008253</a>"},"year":"2020","isi":1,"external_id":{"isi":["000576148700001"]},"volume":59,"acknowledgement":"The Austrian Research Promotion Agency (FFG) is gratefully acknowledged for financial support of the project LignoBatt (860429).","publication_status":"published","department":[{"_id":"StFr"}],"date_created":"2020-09-03T16:10:56Z","article_processing_charge":"No","title":"2‐methoxyhydroquinone from vanillin for aqueous redox‐flow batteries","intvolume":"        59","_id":"8329","scopus_import":"1","author":[{"last_name":"Schlemmer","first_name":"Werner","full_name":"Schlemmer, Werner"},{"first_name":"Philipp","last_name":"Nothdurft","full_name":"Nothdurft, Philipp"},{"last_name":"Petzold","first_name":"Alina","full_name":"Petzold, Alina"},{"last_name":"Frühwirt","first_name":"Philipp","full_name":"Frühwirt, Philipp"},{"full_name":"Schmallegger, Max","first_name":"Max","last_name":"Schmallegger"},{"full_name":"Gescheidt-Demner, Georg","last_name":"Gescheidt-Demner","first_name":"Georg"},{"last_name":"Fischer","first_name":"Roland","full_name":"Fischer, Roland"},{"id":"A8CA28E6-CE23-11E9-AD2D-EC27E6697425","last_name":"Freunberger","first_name":"Stefan Alexander","full_name":"Freunberger, Stefan Alexander","orcid":"0000-0003-2902-5319"},{"full_name":"Kern, Wolfgang","first_name":"Wolfgang","last_name":"Kern"},{"full_name":"Spirk, Stefan","last_name":"Spirk","first_name":"Stefan"}],"issue":"51","publisher":"Wiley","article_type":"original","page":"22943-22946","quality_controlled":"1","publication_identifier":{"issn":["1433-7851"],"eissn":["1521-3773"]},"oa":1,"date_published":"2020-12-14T00:00:00Z","type":"journal_article","main_file_link":[{"open_access":"1","url":"https://doi.org/10.1002/anie.202008253"}],"related_material":{"record":[{"relation":"research_data","id":"9780","status":"public"}]},"user_id":"c635000d-4b10-11ee-a964-aac5a93f6ac1","status":"public","oa_version":"Published Version","month":"12","publication":"Angewandte Chemie International Edition","language":[{"iso":"eng"}]},{"date_published":"2020-12-31T00:00:00Z","type":"journal_article","publication_identifier":{"issn":["0378-7753"]},"oa":1,"main_file_link":[{"url":"https://doi.org/10.1016/j.jpowsour.2020.228803","open_access":"1"}],"related_material":{"record":[{"status":"public","relation":"earlier_version","id":"8067"}]},"status":"public","user_id":"4359f0d1-fa6c-11eb-b949-802e58b17ae8","publication":"Journal of Power Sources","oa_version":"Published Version","month":"12","article_number":"228803","language":[{"iso":"eng"}],"date_updated":"2023-08-22T09:20:37Z","year":"2020","citation":{"ista":"Varzi A, Thanner K, Scipioni R, Di Lecce D, Hassoun J, Dörfler S, Altheus H, Kaskel S, Prehal C, Freunberger SA. 2020. Current status and future perspectives of lithium metal batteries. Journal of Power Sources. 480(12), 228803.","mla":"Varzi, Alberto, et al. “Current Status and Future Perspectives of Lithium Metal Batteries.” <i>Journal of Power Sources</i>, vol. 480, no. 12, 228803, Elsevier, 2020, doi:<a href=\"https://doi.org/10.1016/j.jpowsour.2020.228803\">10.1016/j.jpowsour.2020.228803</a>.","short":"A. Varzi, K. Thanner, R. Scipioni, D. Di Lecce, J. Hassoun, S. Dörfler, H. Altheus, S. Kaskel, C. Prehal, S.A. Freunberger, Journal of Power Sources 480 (2020).","chicago":"Varzi, Alberto, Katharina Thanner, Roberto Scipioni, Daniele Di Lecce, Jusef Hassoun, Susanne Dörfler, Holger Altheus, Stefan Kaskel, Christian Prehal, and Stefan Alexander Freunberger. “Current Status and Future Perspectives of Lithium Metal Batteries.” <i>Journal of Power Sources</i>. Elsevier, 2020. <a href=\"https://doi.org/10.1016/j.jpowsour.2020.228803\">https://doi.org/10.1016/j.jpowsour.2020.228803</a>.","ieee":"A. Varzi <i>et al.</i>, “Current status and future perspectives of lithium metal batteries,” <i>Journal of Power Sources</i>, vol. 480, no. 12. Elsevier, 2020.","apa":"Varzi, A., Thanner, K., Scipioni, R., Di Lecce, D., Hassoun, J., Dörfler, S., … Freunberger, S. A. (2020). Current status and future perspectives of lithium metal batteries. <i>Journal of Power Sources</i>. Elsevier. <a href=\"https://doi.org/10.1016/j.jpowsour.2020.228803\">https://doi.org/10.1016/j.jpowsour.2020.228803</a>","ama":"Varzi A, Thanner K, Scipioni R, et al. Current status and future perspectives of lithium metal batteries. <i>Journal of Power Sources</i>. 2020;480(12). doi:<a href=\"https://doi.org/10.1016/j.jpowsour.2020.228803\">10.1016/j.jpowsour.2020.228803</a>"},"isi":1,"external_id":{"isi":["000593857300001"]},"doi":"10.1016/j.jpowsour.2020.228803","day":"31","abstract":[{"lang":"eng","text":"With the lithium-ion technology approaching its intrinsic limit with graphite-based anodes, Li metal is recently receiving renewed interest from the battery community as potential high capacity anode for next-generation rechargeable batteries. In this focus paper, we review the main advances in this field since the first attempts in the mid-1970s. Strategies for enabling reversible cycling and avoiding dendrite growth are thoroughly discussed, including specific applications in all-solid-state (inorganic and polymeric), Lithium–Sulfur (Li–S) and Lithium-O2 (air) batteries. A particular attention is paid to recent developments of these battery technologies and their current state with respect to the 2030 targets of the EU Integrated Strategic Energy Technology Plan (SET-Plan) Action 7."}],"volume":480,"acknowledgement":"A.V. and K.T. acknowledge, respectively, the financial support of the Helmholtz Association and BMW AG. J.H. acknowledges the collabo-ration project “Accordo di Collaborazione Quadro 2015” between Uni-versity of  Ferrara (Department of  Chemical and Pharmaceutical Sciences) and Sapienza University of Rome (Department of Chemistry). S.D., H.A. and S.K. thank the Fraunhofer Gesellschaft, Technische Uni-versit ̈at  Dresden and would like to  acknowledge European Union’s Horizon 2020 research and innovation programme under grant agree-ment No 814471. S.A.F. and C.P. are indebted to the European Research Council (ERC) under the European Union’s Horizon 2020 research and innovation program (grant agreement no. 636069) and IST Austria.","_id":"8361","author":[{"orcid":"0000-0001-5069-0589","full_name":"Varzi, Alberto","first_name":"Alberto","last_name":"Varzi"},{"full_name":"Thanner, Katharina","orcid":"0000-0001-5394-2323","last_name":"Thanner","first_name":"Katharina"},{"last_name":"Scipioni","first_name":"Roberto","full_name":"Scipioni, Roberto","orcid":"0000-0003-1926-421X"},{"first_name":"Daniele","last_name":"Di Lecce","full_name":"Di Lecce, Daniele"},{"first_name":"Jusef","last_name":"Hassoun","full_name":"Hassoun, Jusef"},{"full_name":"Dörfler, Susanne","first_name":"Susanne","last_name":"Dörfler"},{"last_name":"Altheus","first_name":"Holger","full_name":"Altheus, Holger"},{"first_name":"Stefan","last_name":"Kaskel","full_name":"Kaskel, Stefan"},{"last_name":"Prehal","first_name":"Christian","full_name":"Prehal, Christian","orcid":"0000-0003-0654-0940"},{"last_name":"Freunberger","first_name":"Stefan Alexander","full_name":"Freunberger, Stefan Alexander","orcid":"0000-0003-2902-5319","id":"A8CA28E6-CE23-11E9-AD2D-EC27E6697425"}],"issue":"12","publication_status":"published","article_processing_charge":"No","date_created":"2020-09-10T10:48:40Z","department":[{"_id":"StFr"}],"title":"Current status and future perspectives of lithium metal batteries","intvolume":"       480","quality_controlled":"1","publisher":"Elsevier","article_type":"original"},{"volume":11,"ddc":["530"],"citation":{"ama":"Prehal C, Fitzek H, Kothleitner G, et al. Persistent and reversible solid iodine electrodeposition in nanoporous carbons. <i>Nature Communications</i>. 2020;11. doi:<a href=\"https://doi.org/10.1038/s41467-020-18610-6\">10.1038/s41467-020-18610-6</a>","apa":"Prehal, C., Fitzek, H., Kothleitner, G., Presser, V., Gollas, B., Freunberger, S. A., &#38; Abbas, Q. (2020). Persistent and reversible solid iodine electrodeposition in nanoporous carbons. <i>Nature Communications</i>. Springer Nature. <a href=\"https://doi.org/10.1038/s41467-020-18610-6\">https://doi.org/10.1038/s41467-020-18610-6</a>","chicago":"Prehal, Christian, Harald Fitzek, Gerald Kothleitner, Volker Presser, Bernhard Gollas, Stefan Alexander Freunberger, and Qamar Abbas. “Persistent and Reversible Solid Iodine Electrodeposition in Nanoporous Carbons.” <i>Nature Communications</i>. Springer Nature, 2020. <a href=\"https://doi.org/10.1038/s41467-020-18610-6\">https://doi.org/10.1038/s41467-020-18610-6</a>.","ieee":"C. Prehal <i>et al.</i>, “Persistent and reversible solid iodine electrodeposition in nanoporous carbons,” <i>Nature Communications</i>, vol. 11. Springer Nature, 2020.","mla":"Prehal, Christian, et al. “Persistent and Reversible Solid Iodine Electrodeposition in Nanoporous Carbons.” <i>Nature Communications</i>, vol. 11, 4838, Springer Nature, 2020, doi:<a href=\"https://doi.org/10.1038/s41467-020-18610-6\">10.1038/s41467-020-18610-6</a>.","short":"C. Prehal, H. Fitzek, G. Kothleitner, V. Presser, B. Gollas, S.A. Freunberger, Q. Abbas, Nature Communications 11 (2020).","ista":"Prehal C, Fitzek H, Kothleitner G, Presser V, Gollas B, Freunberger SA, Abbas Q. 2020. Persistent and reversible solid iodine electrodeposition in nanoporous carbons. Nature Communications. 11, 4838."},"year":"2020","date_updated":"2023-08-22T09:37:24Z","external_id":{"isi":["000573756600004"]},"isi":1,"day":"24","doi":"10.1038/s41467-020-18610-6","abstract":[{"lang":"eng","text":"Aqueous iodine based electrochemical energy storage is considered a potential candidate to improve sustainability and performance of current battery and supercapacitor technology. It harnesses the redox activity of iodide, iodine, and polyiodide species in the confined geometry of nanoporous carbon electrodes. However, current descriptions of the electrochemical reaction mechanism to interconvert these species are elusive. Here we show that electrochemical oxidation of iodide in nanoporous carbons forms persistent solid iodine deposits. Confinement slows down dissolution into triiodide and pentaiodide, responsible for otherwise significant self-discharge via shuttling. The main tools for these insights are in situ Raman spectroscopy and in situ small and wide-angle X-ray scattering (in situ SAXS/WAXS). In situ Raman confirms the reversible formation of triiodide and pentaiodide. In situ SAXS/WAXS indicates remarkable amounts of solid iodine deposited in the carbon nanopores. Combined with stochastic modeling, in situ SAXS allows quantifying the solid iodine volume fraction and visualizing the iodine structure on 3D lattice models at the sub-nanometer scale. Based on the derived mechanism, we demonstrate strategies for improved iodine pore filling capacity and prevention of self-discharge, applicable to hybrid supercapacitors and batteries."}],"quality_controlled":"1","file_date_updated":"2020-09-28T13:16:15Z","publisher":"Springer Nature","article_type":"original","_id":"8568","author":[{"full_name":"Prehal, Christian","first_name":"Christian","last_name":"Prehal"},{"full_name":"Fitzek, Harald","last_name":"Fitzek","first_name":"Harald"},{"last_name":"Kothleitner","first_name":"Gerald","full_name":"Kothleitner, Gerald"},{"full_name":"Presser, Volker","first_name":"Volker","last_name":"Presser"},{"full_name":"Gollas, Bernhard","last_name":"Gollas","first_name":"Bernhard"},{"id":"A8CA28E6-CE23-11E9-AD2D-EC27E6697425","first_name":"Stefan Alexander","last_name":"Freunberger","orcid":"0000-0003-2902-5319","full_name":"Freunberger, Stefan Alexander"},{"full_name":"Abbas, Qamar","last_name":"Abbas","first_name":"Qamar"}],"date_created":"2020-09-25T07:23:13Z","department":[{"_id":"StFr"}],"article_processing_charge":"No","publication_status":"published","intvolume":"        11","title":"Persistent and reversible solid iodine electrodeposition in nanoporous carbons","file":[{"creator":"dernst","file_id":"8585","relation":"main_file","success":1,"access_level":"open_access","file_name":"2020_NatureComm_Prehal.pdf","content_type":"application/pdf","date_updated":"2020-09-28T13:16:15Z","checksum":"eada7bc8dd16a49390137cff882ef328","file_size":1822469,"date_created":"2020-09-28T13:16:15Z"}],"status":"public","user_id":"4359f0d1-fa6c-11eb-b949-802e58b17ae8","related_material":{"link":[{"relation":"erratum","url":"https://doi.org/10.1038/s41467-020-19720-x"}]},"tmp":{"legal_code_url":"https://creativecommons.org/licenses/by/4.0/legalcode","short":"CC BY (4.0)","image":"/images/cc_by.png","name":"Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)"},"type":"journal_article","date_published":"2020-09-24T00:00:00Z","publication_identifier":{"issn":["2041-1723"]},"oa":1,"keyword":["General Biochemistry","Genetics and Molecular Biology","General Physics and Astronomy","General Chemistry"],"language":[{"iso":"eng"}],"has_accepted_license":"1","publication":"Nature Communications","oa_version":"Published Version","article_number":"4838","month":"09"},{"article_type":"original","publisher":"Elsevier","file_date_updated":"2020-10-01T13:20:45Z","quality_controlled":"1","intvolume":"       362","title":"Surface and catalyst driven singlet oxygen formation in Li-O2 cells","article_processing_charge":"Yes (via OA deal)","department":[{"_id":"StFr"}],"date_created":"2020-04-20T19:29:31Z","publication_status":"published","issue":"12","author":[{"full_name":"Samojlov, Aleksej","first_name":"Aleksej","last_name":"Samojlov"},{"first_name":"David","last_name":"Schuster","full_name":"Schuster, David"},{"full_name":"Kahr, Jürgen","last_name":"Kahr","first_name":"Jürgen"},{"first_name":"Stefan Alexander","last_name":"Freunberger","orcid":"0000-0003-2902-5319","full_name":"Freunberger, Stefan Alexander","id":"A8CA28E6-CE23-11E9-AD2D-EC27E6697425"}],"scopus_import":"1","license":"https://creativecommons.org/licenses/by-nc-nd/4.0/","_id":"7672","ddc":["540"],"volume":362,"acknowledgement":"S.A.F. thanks the International Society of Electrochemistry for awarding the Tajima Prize 2019 “in recognition of outstanding re- searches on Li-Air batteries by the use of a range of in-situ elec- trochemical methods to achieve comprehensive understanding of the reactions taking place at the oxygen electrode”. This article is dedicated to the special issue of Electrochmica Acta associated with the awarding conference. S.A.F. is indebted to and the Austrian Federal Ministry of Science, Research and Economy and the Austrian Research Promotion Agency (grant No. 845364 ) and the European Research Council (ERC) under the European Union’s Horizon 2020 research and innovation programme (grant agreement No 636069). The authors thank J. Schlegl for manufacturing instrumentation, M. Winkler of Acib GmbH and G. Strohmeier for help with HPLC measurements, S. Eder for cyclic voltammetry measurements, and C. Slugovc for discussions and continuous support. We thank S. Borisov for access and advice with fluorescence measurements. We thank EL-Cell GmbH, Hamburg, Germany for providing the PAT-Cell-Press electrochemical cell.","abstract":[{"text":"Large overpotentials upon discharge and charge of Li-O2 cells have motivated extensive research into heterogeneous solid electrocatalysts or non-carbon electrodes with the aim to improve rate capability, round-trip efficiency and cycle life. These features are equally governed by parasitic reactions, which are now recognized to be caused by the highly reactive singlet oxygen (1O2). However, the link between the presence of electrocatalysts and 1O2 formation in metal-O2 cells is unknown. Here, we show that, compared to pristine carbon black electrodes, a representative selection of electrocatalysts or non-carbon electrodes (noble metal, transition metal compounds) may both slightly reduce or severely increase the 1O2 formation. The individual reaction steps, where the surfaces impact the 1O2 yield are deciphered, showing that 1O2 yield from superoxide disproportionation as well as the decomposition of trace H2O2 are sensitive to catalysts. Transition metal compounds in general are prone to increase 1O2.","lang":"eng"}],"day":"01","doi":"10.1016/j.electacta.2020.137175","external_id":{"isi":["000582869700060"]},"isi":1,"citation":{"chicago":"Samojlov, Aleksej, David Schuster, Jürgen Kahr, and Stefan Alexander Freunberger. “Surface and Catalyst Driven Singlet Oxygen Formation in Li-O2 Cells.” <i>Electrochimica Acta</i>. Elsevier, 2020. <a href=\"https://doi.org/10.1016/j.electacta.2020.137175\">https://doi.org/10.1016/j.electacta.2020.137175</a>.","ieee":"A. Samojlov, D. Schuster, J. Kahr, and S. A. Freunberger, “Surface and catalyst driven singlet oxygen formation in Li-O2 cells,” <i>Electrochimica Acta</i>, vol. 362, no. 12. Elsevier, 2020.","ama":"Samojlov A, Schuster D, Kahr J, Freunberger SA. Surface and catalyst driven singlet oxygen formation in Li-O2 cells. <i>Electrochimica Acta</i>. 2020;362(12). doi:<a href=\"https://doi.org/10.1016/j.electacta.2020.137175\">10.1016/j.electacta.2020.137175</a>","apa":"Samojlov, A., Schuster, D., Kahr, J., &#38; Freunberger, S. A. (2020). Surface and catalyst driven singlet oxygen formation in Li-O2 cells. <i>Electrochimica Acta</i>. Elsevier. <a href=\"https://doi.org/10.1016/j.electacta.2020.137175\">https://doi.org/10.1016/j.electacta.2020.137175</a>","ista":"Samojlov A, Schuster D, Kahr J, Freunberger SA. 2020. Surface and catalyst driven singlet oxygen formation in Li-O2 cells. Electrochimica Acta. 362(12), 137175.","short":"A. Samojlov, D. Schuster, J. Kahr, S.A. Freunberger, Electrochimica Acta 362 (2020).","mla":"Samojlov, Aleksej, et al. “Surface and Catalyst Driven Singlet Oxygen Formation in Li-O2 Cells.” <i>Electrochimica Acta</i>, vol. 362, no. 12, 137175, Elsevier, 2020, doi:<a href=\"https://doi.org/10.1016/j.electacta.2020.137175\">10.1016/j.electacta.2020.137175</a>."},"year":"2020","date_updated":"2023-08-21T06:14:21Z","language":[{"iso":"eng"}],"article_number":"137175","month":"12","oa_version":"Published Version","has_accepted_license":"1","publication":"Electrochimica Acta","user_id":"4359f0d1-fa6c-11eb-b949-802e58b17ae8","status":"public","file":[{"access_level":"open_access","relation":"main_file","success":1,"file_id":"8593","creator":"dernst","date_created":"2020-10-01T13:20:45Z","file_size":1404030,"checksum":"1ab1aa2024d431e2a089ea336bc08298","date_updated":"2020-10-01T13:20:45Z","file_name":"2020_ElectrochimicaActa_Samojlov.pdf","content_type":"application/pdf"}],"oa":1,"type":"journal_article","date_published":"2020-12-01T00:00:00Z","tmp":{"legal_code_url":"https://creativecommons.org/licenses/by-nc-nd/4.0/legalcode","short":"CC BY-NC-ND (4.0)","name":"Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0)","image":"/images/cc_by_nc_nd.png"}},{"publisher":"CCDC","_id":"9780","author":[{"last_name":"Schlemmer","first_name":"Werner","full_name":"Schlemmer, Werner"},{"full_name":"Nothdurft, Philipp","first_name":"Philipp","last_name":"Nothdurft"},{"full_name":"Petzold, Alina","first_name":"Alina","last_name":"Petzold"},{"last_name":"Riess","first_name":"Gisbert","full_name":"Riess, Gisbert"},{"full_name":"Frühwirt, Philipp","last_name":"Frühwirt","first_name":"Philipp"},{"first_name":"Max","last_name":"Schmallegger","full_name":"Schmallegger, Max"},{"full_name":"Gescheidt-Demner, Georg","last_name":"Gescheidt-Demner","first_name":"Georg"},{"last_name":"Fischer","first_name":"Roland","full_name":"Fischer, Roland"},{"last_name":"Freunberger","first_name":"Stefan Alexander","full_name":"Freunberger, Stefan Alexander","orcid":"0000-0003-2902-5319","id":"A8CA28E6-CE23-11E9-AD2D-EC27E6697425"},{"full_name":"Kern, Wolfgang","last_name":"Kern","first_name":"Wolfgang"},{"first_name":"Stefan","last_name":"Spirk","full_name":"Spirk, Stefan"}],"oa_version":"Published Version","department":[{"_id":"StFr"}],"article_processing_charge":"No","date_created":"2021-08-06T07:41:07Z","month":"03","title":"CCDC 1991959: Experimental Crystal Structure Determination","main_file_link":[{"open_access":"1","url":"https://dx.doi.org/10.5517/ccdc.csd.cc24vsrk"}],"user_id":"6785fbc1-c503-11eb-8a32-93094b40e1cf","status":"public","related_material":{"record":[{"status":"public","id":"8329","relation":"used_in_publication"}]},"date_updated":"2023-09-05T16:03:47Z","year":"2020","citation":{"ista":"Schlemmer W, Nothdurft P, Petzold A, Riess G, Frühwirt P, Schmallegger M, Gescheidt-Demner G, Fischer R, Freunberger SA, Kern W, Spirk S. 2020. CCDC 1991959: Experimental Crystal Structure Determination, CCDC, <a href=\"https://doi.org/10.5517/ccdc.csd.cc24vsrk\">10.5517/ccdc.csd.cc24vsrk</a>.","mla":"Schlemmer, Werner, et al. <i>CCDC 1991959: Experimental Crystal Structure Determination</i>. CCDC, 2020, doi:<a href=\"https://doi.org/10.5517/ccdc.csd.cc24vsrk\">10.5517/ccdc.csd.cc24vsrk</a>.","short":"W. Schlemmer, P. Nothdurft, A. Petzold, G. Riess, P. Frühwirt, M. Schmallegger, G. Gescheidt-Demner, R. Fischer, S.A. Freunberger, W. Kern, S. Spirk, (2020).","chicago":"Schlemmer, Werner, Philipp Nothdurft, Alina Petzold, Gisbert Riess, Philipp Frühwirt, Max Schmallegger, Georg Gescheidt-Demner, et al. “CCDC 1991959: Experimental Crystal Structure Determination.” CCDC, 2020. <a href=\"https://doi.org/10.5517/ccdc.csd.cc24vsrk\">https://doi.org/10.5517/ccdc.csd.cc24vsrk</a>.","ieee":"W. Schlemmer <i>et al.</i>, “CCDC 1991959: Experimental Crystal Structure Determination.” CCDC, 2020.","ama":"Schlemmer W, Nothdurft P, Petzold A, et al. CCDC 1991959: Experimental Crystal Structure Determination. 2020. doi:<a href=\"https://doi.org/10.5517/ccdc.csd.cc24vsrk\">10.5517/ccdc.csd.cc24vsrk</a>","apa":"Schlemmer, W., Nothdurft, P., Petzold, A., Riess, G., Frühwirt, P., Schmallegger, M., … Spirk, S. (2020). CCDC 1991959: Experimental Crystal Structure Determination. CCDC. <a href=\"https://doi.org/10.5517/ccdc.csd.cc24vsrk\">https://doi.org/10.5517/ccdc.csd.cc24vsrk</a>"},"date_published":"2020-03-22T00:00:00Z","type":"research_data_reference","doi":"10.5517/ccdc.csd.cc24vsrk","day":"22","abstract":[{"text":"PADREV : 4,4'-dimethoxy[1,1'-biphenyl]-2,2',5,5'-tetrol\r\nSpace Group: C 2 (5), Cell: a 24.488(16)Å b 5.981(4)Å c 3.911(3)Å, α 90° β 91.47(3)° γ 90°","lang":"eng"}],"oa":1}]