Scalable heating-up synthesis of monodisperse Cu2ZnSnS4 nanocrystals
Shavel A, Ibáñez M, Luo Z, De Roo J, Carrete A, Dimitrievska M, Genç A, Meyns M, Pérez Rodríguez A, Kovalenko M, Arbol J, Cabot A. 2016. Scalable heating-up synthesis of monodisperse Cu2ZnSnS4 nanocrystals. Chemistry of Materials. 28(3), 720–726.
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Journal Article
| Published
| English
Author
Shavel, Alexey;
Ibáñez , MariaISTA 
;
Luo, Zhishan;
De Roo, Jonathan;
Carrete, Alex;
Dimitrievska, Mirjana;
Genç, Aziz;
Meyns, Michaela;
Pérez Rodríguez, Alejandro;
Kovalenko, Maksym;
Arbol, Jordi;
Cabot, Andreu
All
;
Luo, Zhishan;
De Roo, Jonathan;
Carrete, Alex;
Dimitrievska, Mirjana;
Genç, Aziz;
Meyns, Michaela;
Pérez Rodríguez, Alejandro;
Kovalenko, Maksym;
Arbol, Jordi;
Cabot, Andreu
All
Abstract
Monodisperse Cu2ZnSnS4 (CZTS) nanocrystals (NCs), with quasi-spherical shape, were prepared by a facile, high-yield, scalable, and high-concentration heat-up procedure. The key parameters to minimize the NC size distribution were efficient mixing and heat transfer in the reaction mixture through intensive argon bubbling and improved control of the heating ramp stability. Optimized synthetic conditions allowed the production of several grams of highly monodisperse CZTS NCs per batch, with up to 5 wt % concentration in a crude solution and a yield above 90%.
Publishing Year
Date Published
2016-01-17
Journal Title
Chemistry of Materials
Publisher
American Chemical Society
Volume
28
Issue
3
Page
720 - 726
IST-REx-ID
Cite this
Shavel A, Ibáñez M, Luo Z, et al. Scalable heating-up synthesis of monodisperse Cu2ZnSnS4 nanocrystals. Chemistry of Materials. 2016;28(3):720-726. doi:10.1021/acs.chemmater.5b03417
Shavel, A., Ibáñez, M., Luo, Z., De Roo, J., Carrete, A., Dimitrievska, M., … Cabot, A. (2016). Scalable heating-up synthesis of monodisperse Cu2ZnSnS4 nanocrystals. Chemistry of Materials. American Chemical Society. https://doi.org/10.1021/acs.chemmater.5b03417
Shavel, Alexey, Maria Ibáñez, Zhishan Luo, Jonathan De Roo, Alex Carrete, Mirjana Dimitrievska, Aziz Genç, et al. “Scalable Heating-up Synthesis of Monodisperse Cu2ZnSnS4 Nanocrystals.” Chemistry of Materials. American Chemical Society, 2016. https://doi.org/10.1021/acs.chemmater.5b03417.
A. Shavel et al., “Scalable heating-up synthesis of monodisperse Cu2ZnSnS4 nanocrystals,” Chemistry of Materials, vol. 28, no. 3. American Chemical Society, pp. 720–726, 2016.
Shavel A, Ibáñez M, Luo Z, De Roo J, Carrete A, Dimitrievska M, Genç A, Meyns M, Pérez Rodríguez A, Kovalenko M, Arbol J, Cabot A. 2016. Scalable heating-up synthesis of monodisperse Cu2ZnSnS4 nanocrystals. Chemistry of Materials. 28(3), 720–726.
Shavel, Alexey, et al. “Scalable Heating-up Synthesis of Monodisperse Cu2ZnSnS4 Nanocrystals.” Chemistry of Materials, vol. 28, no. 3, American Chemical Society, 2016, pp. 720–26, doi:10.1021/acs.chemmater.5b03417.
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